The inverse problem of argon diffusion from minerals: Determination of kinetic parameters from stepwise-heating experiments
Results of two routine 40 Ar/ 39 Ar stepwise heating experiments on a biotite and a basanite are interpreted in terms of Fick's and Arrhenius' laws. Both patterns represent a saddle-shaped 39 Ar release. Argon isotope spectra are suggested to be controlled by the activation energy of diffusion E and the frequency factor D o . The activation energy of 39 Ar is lower than the one of 40 Ar. This results in a preferable release of 40 Ar relatively to 39 Ar at high-temperature steps and an increasing high-temperature wing in the saddle-shaped age spectrum. At low temperatures, considerable losses and irregularities in release of mainly 39 Ar are observed, which cause the decreasing low-temperature wing in the “saddle”. The suggestion of argon losses (mainly of 39 Ar) from a loose, “unstable” zone of the mineral structures becomes justified. The n -irradiation of the samples and the shift of E of 39 Ar towards lower values seems to explain the saddle-shaped age-spectra often encountered in 40 Ar/ 39 Ar-geochronometry.