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S.P. Phillips

Publications and source records attributed to S.P. Phillips.

9 recordsLinked to original sources

Influences of the unsaturated, saturated, and riparian zones on the transport of nitrate near the Merced River, California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50-100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N2 in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area. ?? Springer-Verlag 2007.

Hydrogeology Journal

Limited occurrence of denitrification in four shallow aquifers in agricultural areas of the United States

The ability of natural attenuation to mitigate agricultural nitrate contamination in recharging aquifers was investigated in four important agricultural settings in the United States. The study used laboratory analyses, field measurements, and flow and transport modeling for monitoring well transects (0.5 to 2.5 km in length) in the San Joaquin watershed, California, the Elkhorn watershed, Nebraska, the Yakima watershed, Washington, and the Chester watershed, Maryland. Ground water analyses included major ion chemistry, dissolved gases, nitrogen and oxygen stable isotopes, and estimates of recharge date. Sediment analyses included potential electron donors and stable nitrogen and carbon isotopes. Within each site and among aquifer-based medians, dissolved oxygen decreases with ground water age, and excess N 2 from denitrification increases with age. Stable isotopes and excess N 2 imply minimal denitrifying activity at the Maryland and Washington sites, partial denitrification at the California site, and total denitrification across portions of the Nebraska site. At all sites, recharging electron donor concentrations are not sufficient to account for the losses of dissolved oxygen and nitrate, implying that relict, solid phase electron donors drive redox reactions. Zero-order rates of denitrification range from 0 to 0.14 μmol N L −1 d −1 , comparable to observations of other studies using the same methods. Many values reported in the literature are, however, orders of magnitude higher, which is attributed to a combination of method limitations and bias for selection of sites with rapid denitrification. In the shallow aquifers below these agricultural fields, denitrification is limited in extent and will require residence times of decades or longer to mitigate modern nitrate contamination.

Journal of Environmental Quality

Detection of aquifer system compaction and land subsidence using interferometric synthetic aperture radar, Antelope Valley, Mojave Desert, California

Interferometric synthetic aperture radar (InSAR) has great potential to detect and quantify land subsidence caused by aquifer system compaction. InSAR maps with high spatial detail and resolution of range displacement (±10 mm in change of land surface elevation) were developed for a groundwater basin (∼10 3 km 2 ) in Antelope Valley, California, using radar data collected from the ERS-1 satellite. These data allow comprehensive comparison between recent (1993–1995) subsidence patterns and those detected historically (1926–1992) by more traditional methods. The changed subsidence patterns are generally compatible with recent shifts in land and water use. The InSAR-detected patterns are generally consistent with predictions based on a coupled model of groundwater flow and aquifer system compaction. The minor inconsistencies may reflect our imperfect knowledge of the distribution and properties of compressible sediments. When used in conjunction with coincident measurements of groundwater levels and other geologic information, InSAR data may be useful for constraining parameter estimates in simulations of aquifer system compaction.

California

Geohydrology, water quality, and estimation of ground-water recharge in San Francisco, California, 1987-92

The city of San Francisco is considering further development of local groundwater resources as a supplemental source of water for potable or nonpotable use. By the year 2010, further water demand is projected to exceed the delivery capacity of the existing supply system, which is fed by surface-water sources; thus supplies are susceptible to drought conditions and damage to conveyance lines by earthquakes. The primary purpose of this study is to describe local geohydrology and water quality and to estimate groundwater recharge in the area of the city of San Francisco. Seven groundwater basins were identified in San Francisco on the basis of geologic and geophysical data. Basins on the east side of the city are relatively thin and contain a greater percentage of fine-grained sediments than those on the west side. The relatively small capacity of the basins and greater potential for contamination from sewer sources may limit the potential for groundwater development on the east side. Basins on the west side of the city have a relatively large capacity and low density sewer network. Water-level data indicate that the southern part of the largest basin on the west side of the city (Westside basin) probably cannot accommodate additional groundwater development without adversely affecting water levels and water quality in Lake Merced; however, the remainder of the basin, which is largely undeveloped, could be developed further. A hydrologic routing model was developed for estimating groundwater recharge throughout San Francisco. The model takes into account climatic factors, land and water use, irrigation, leakage from underground pipes, rainfall runoff, evapotranspiration, and other factors associated with an urban environment. Results indicate that area recharge rates for water years 1987-88 for the 7 groundwater basins ranged from 0.32 to 0.78 feet per year. Recharge for the Westside basin was estimated at 0.51 feet per year. Average annual groundwater recharge represents the maximum annual long-term yield of the basin. Attainable yield may be less than the volume of groundwater recharge because interception of all discharge from the basin may not be feasible without inducing seawater intrusion or causing other undesirable effects.

Water-Resources Investigations Report

Simulation of water-table response to management alternatives, central part of the western San Joaquin Valley, California

The occurrence of selenium in agricultural drainwater in the central pan of the western San Joaquin Valley, California, has focused concern on alternatives other than agricultural drains for managing shallow, poor-quality ground water. A transient, three-dimensional, finite-difference ground-water flow model was developed to assess the response of the water table to various management alternatives. The modeled area is 551 square miles and includes the semiconfined and confined zones above and below the Corcoran Clay Member of the Tulare Formation of Pleistocene age. The model was calibrated using hydrologic data from 1972 to 1988 and was able to reproduce the average change in water-table altitude to within 4 percent. The calibrated model was extended to forecast to the year 2040 for various management alternatives including maintenance of present practices, land retirement, reduced recharge, increased ground-water pumping, combinations of these alternatives, and five alternatives proposed by the U.S. Bureau of Reclamation. The model indicates that if current rates of recharge and pumping (as determined from an analysis of 1980 water-budget data) are maintained, the total area subject to bare-soil evaporation will increase by more than 50 percent and drainflow will increase by 20 percent. Model results indicate that retirement of land will result in a water-table decline beneath the area retired, but the effect on adjacent areas will be small to negligible. The effects of reducing recharge or increasing ground-water pumping vary with the magnitude of the change relative to average conditions and the size of the area managed. The area of land subject to bare-soil evaporation and the amount of drainflow in the model area can be reduced by more than 40 and 50 percent, respectively, if (1) recharge is reduced by 40 percent (about 0.3 foot per year) in areas that currently use only surface water, and by 15 percent (an average of about O. 1 foot per year) in the remainder of the model area; (2) pumping is increased by 0.5 foot per year in areas that currently use surface and ground water.

Water-Resources Investigations Report

Calibration of a texture-based model of a ground-water flow system, western San Joaquin Valley, California

The occurrence of selenium in agricultural drain water from the western San Joaquin Valley, California, has focused concern on the semiconfined ground-water flow system, which is underlain by the Corcoran Clay Member of the Tulare Formation. A two-step procedure is used to calibrate a preliminary model of the system for the purpose of determining the steady-state hydraulic properties. Horizontal and vertical hydraulic conductivities are modeled as functions of the percentage of coarse sediment, hydraulic conductivities of coarse-textured (Keearse) and fine-textured (Kfine) end members, and averaging methods used to calculate equivalent hydraulic conductivities. The vertical conductivity of the Corcoran (Keen) is an additional parameter to be evaluated. In the first step of the calibration procedure, the model is run by systematically varying the following variables: (1) Kcoarse/Kfine' (2) KcoarsdKcorc' and (3) choice of averaging methods in the horizontal and vertical directions. Root mean square error and bias values calculated from the model results are functions of these variables. These measures of error provide a means for evaluating model sensitivity and for selecting values of Keearse, Kfine, and Kcorc for use in the second step of the calibration procedure. In the second step, recharge rates are evaluated as functions of Keearse, Kcere, and a combination of averaging methods. The associated Kfine values are selected so that the root mean square error is minimized on the basis of the results from the first step. The results of the two-step procedure indicate that the spatial distribution of hydraulic conductivity that best produces the measured hydraulic head distribution is created through the use of arithmetic averaging in the horizontal direction and either geometric or harmonic averaging in the vertical. The equivalent hydraulic conductivities resulting from either combination of averaging methods compare favorably to field- and laboratory-based values.

California