Geology topics

S.N. Williams

Publications and source records attributed to S.N. Williams.

3 recordsLinked to original sources

USGS1998

Geochemical surveillance of magmatic volatiles at Popocatepetl volcano, Mexico

Surveillance of Popocatépetl volcanic plume geochemistry and SO 2 flux began in early 1994 after fumarolic and seismic activity increased significantly during 1993. Volatile traps placed around the summit were collected at near-monthly intervals until the volcano erupted on December 21, 1994. Additional trap samples were obtained in early 1996 before the volcano erupted again, emplacing a small dacite dome in the summit crater. Abundances of volatile constituents (ppm/day of Cl, S total , F, CO 2 , Hg, and As) varied, but most constituents were relatively high in early and late 1994. However, ratios of these constituents to Cl were highest in mid-1994. δ 34 S-S total in trap solutions ranged from 1.5‰ to 6.4‰; lowest values generally occurred during late 1994. δ 13 C-CO 2 of trap solutions were greatly contaminated with atmospheric CO 2 and affected by absorption kinetics. When trap data are combined with SO 2 flux measurements made through November 1996, Popocatépetl released about 3.9 Mt SO 2 , 16 Mt CO 2 , 0.75 Mt HCl, 0.075 Mt HF, 260 t As, 2.6 t Hg, and roughly 200 Mt H 2 O. Near-vent gas concentrations in the volcanic plume measured by correlation spectrometer (COSPEC) and Fourier transform infrared (FTIR) commonly exceed human recommended exposure limits and may constitute a potential health hazard. Volatile geochemistry combined with petrologic observations and melt-inclusion studies show that mafic magma injection into a preexisting silicic chamber has accompanied renewed volcanism at Popocatépetl. Minor assimilation of Cretaceous wall rocks probably occurred in mid-1994.

Mexico↗

USGS1997

14 C ages and activity for the past 50 ka at Volcán Galeras, Colombia

Volcán Galeras is the southernmost Colombian volcano with well-recorded historic activity. The volcano is part of a large and complex volcanic center upon which 400,000 people live. Historic activity has centered on a small-volume cone inside the youngest of several large amphitheaters that breach the west flank of the volcano, away from the city of Pasto (population 300,000). Lava flows (SiO 2 between 54.6 and 64.7 wt.%) have dominated activity for more than 1 Ma, but explosive events have also occurred. Joint studies by volcanologists from Colombia, Ecuador, Peru, Bolivia, Argentina, and the United States produced 24 new 14 C ages and more than 100 stratigraphic sections to interpret the past 50 ka of activity at Galeras, including sector collapse events. The youngest collapse event truncated 12.8 ka lava flows and may have occurred as recently as 8 to 10 ka. Tephra-fall material rapidly thins and becomes finer away from the vent area. The only widespread marker in the < 10 ka section is a biotite-bearing tephra deposited between 4.1 and 4.5 ka from a source south of Galeras. It separates cryoturbated from largely undisturbed layers on Galeras, and thus dates a stratigraphic horizon which is useful in the interpretation of other volcanoes and geotectonics in the equatorial Andes. Pyroclastic flows during the past 50 ka have been small to moderate in volume, but they have left numerous thin deposits on the north and east flanks where lava flows have been impeded by crater and amphitheater walls. Many of the pyroclastic-flow deposits are lithic rich, with fines and clasts so strongly altered by hydrothermal action before eruption that they, as well as the sector collapse deposits, resemble waste dumps of leached cappings from disseminated sulfide deposits more than volcanogenic deposits. This evidence of a long-lived hydrothermal system indicates susceptibility to mass failure and explosive events higher than expected for a volcano built largely by lava flows and modest Vulcanian eruptions. Photographs, written accounts, and our study document historic north and east flank pyroclastic flows as far as 10 km from the summit; however, none have left recognizable deposits in Pasto for more than 40 ka.

Journal of Volcanology and Geothermal Research↗

USGS1981

Mt. St. Helens: evidence of increased magmatic gas component

This paper presents measurements of SO2 flux and ash leachate chemistry from Mt. St. Helens volcano during the period May 18 to July 22 which are in contrast to similar data from before May 18. Comparison of post-18 May SO2 data with similar data from other volcanoes leads to the conclusion that between 15 and 25 May the SO2 flux reached typical magmatic levels. Ash leachate chemistry from the eruption of 18 May, 22 June and 22 July also indicate a large magmatic gas component. Concentrations of Cl- and SO2-4 on May 18 ash increase with distance from the volcano and decrease with time. Leachate chemistry is used to estimate that a minimum of 2.4 ?? 105 tons of S were released on May 18. Low F concentrations on the ash, though increasing, present to health hazards. ?? 1981.

Journal of Volcanology and Geothermal Research↗