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S. N. Hamlin

Publications and source records attributed to S. N. Hamlin.

11 recordsLinked to original sources
USGS2007

Preservation of samples for dissolved mercury

Water samples for dissolved mercury requires special treatment because of the high chemical mobility and volatility of this element. Widespread use of mercury and its compounds has provided many avenues for contamination of water. Two laboratory tests were done to determine the relative permeabilities of glass and plastic sample bottles to mercury vapor. Plastic containers were confirmed to be quite permeable to airborne mercury, glass containers were virtually impermeable. Methods of preservation include the use of various combinations of acids, oxidants, and complexing agents. The combination of nitric acid and potassium dichromate successfully preserved mercury in a large variety of concentrations and dissolved forms. Because this acid-oxidant preservative acts as a sink for airborne mercury and plastic containers are permeable to mercury vapor, glass bottles are preferred for sample collection. To maintain a healthy work environment and minimize the potential for contamination of water samples, mercury and its compounds are isolated from the atmosphere while in storage. Concurrently, a program to monitor environmental levels of mercury vapor in areas of potential contamination is needed to define the extent of mercury contamination and to assess the effectiveness of mercury clean-up procedures.Water samples for dissolved mercury require special treatment because of the high chemical mobility and volatility of this element. Widespread use of mercury and its compounds has provided many avenues for contamination of water. Two laboratory tests were done to determine the relative permeabilities of glass and plastic sample bottles to mercury vapor. Plastic containers were confirmed to be quite permeable to airborne mercury, glass containers were virtually impermeable. Methods of preservation include the use of various combinations of acids, oxidants, and complexing agents. The combination of nitric acid and potassium dichromate successfully preserved mercury in a large variety of concentrations and dissolved forms.

Water Resources Bulletin↗
USGS1995

Hydrologic effects associated with the January 17, 1994 Northridge, California, earthquake

This report compiles hydrologic observations in southern California associated with the 1994 Mw = 6.7 Northridge, California earthquake. In southern California, the largest ground water level change was a drop of 52 cm at Crystalaire. Most of the steplike water-level changes recorded following the Northridge earthquake agreed in direction with the sign of the calculated coseismic volume strain field. A spring discharge increase at Southern Pacific Springs was reported to have preceded the earthquake by several days. Outside of southern California, water-level changes were also observed, but are not consistent in sign or size with the static strain field of the earthquake sequence.

California, Nevada, Oregon↗
USGS1995

Hydrogeology and geochemistry of acid mine drainage in ground water in the vicinity of Penn Mine and Camanche Reservoir, Calaveras County, California: First-year summary

Acid drainage from the Penn Mine in Calaveras County, California, has caused contamination of ground water between Mine Run Dam and Camanche Reservoir. The Penn Mine was first developed in the 1860's primarily for copper and later produced lesser amounts of zinc, lead, silver, and gold from steeply dipping massive sulfide lenses in metamorphic rocks. Surface disposal of sulfidic waste rock and tailings from mine operations has produced acidic drainage with pH values between 2.3 and 2.7 and elevated concentrations of sulfate and metals, including copper, zinc, cadmium, iron, and aluminum. During the mine's operation and after its subsequent abandonment in the late 1950's, acid mine drainage flowed down Mine Run into the Mokelumne River. Construction of Camanche Dam in 1963 flooded part of the Mokelumne River adjacent to Penn Mine. Surface-water diversions and unlined impoundments were constructed at Penn Mine in 1979 to reduce runoff from the mine, collect contaminated surface water, and enhance evaporation. Some of the contaminated surface water infiltrates the ground water and flows toward Camanche Reservoir. Ground- water flow in the study area is controlled by the local hydraulic gradient and the hydraulic characteristics of two principal rock types, a Jurassic metavolcanic unit and the underlying Salt Spring slate. The hydraulic gradient is west from Mine Run impoundment toward Camanche Reservoir. The median hydraulic conductivity was about 10 to 50 times higher in the metavolcanic rock (0.1 foot per day) than in the slate (0.002 to 0.01 foot per day); most flow occurs in the metavolcanic rock where hydraulic conductivity is as high as 50 feet per day in two locations. The contact between the two rock units is a fault plane that strikes N20?W, dips 20?NE, and is a likely conduit for ground-water flow, based on down-hole measurements with a heatpulse flowmeter. Analyses of water samples collected during April 1992 provide a comprehensive characterization of ground water below Mine Run Dam at the Penn Mine. Specific conductance of the samples ranged from 1,810 to 18,000 microsiemens per centimeter. pH values of sampled ground water ranged from 3.7 to 7.8. Dissolved constituents in ground water ranged from less than 0.010 to 86 milligrams per liter for copper, from less than 0.010 to 240 milligrams per liter for iron, from less than 0.01 to 250 milligrams per liter for aluminum, and from 0.020 to 600 milligrams per liter for zinc. A contaminated ground-water plume appears to originate in the metavolcanic unit along the north abutment of Mine Run Dam. The plume is characterized by low pH, high concentrations of sulfate and dissolved metals, and enrichment of the heavy stable isotopes of hydrogen and oxygen. Dissolved iron and sulfate correlate positively, suggesting pyrite as the probable source of these elements. The concentrations of some dissolved constituents apparently are controlled by equilibrium with solid mineral phases. Poorly crystalline hydrous ferric oxide and microcrystalline gibbsite are close to saturation in ground water with pH values between 4 and 7.8 and probably control the solubility of Fe 3+ and Al 3+ , respectively. Using a range of bulk hydraulic conductivity values for the metavolcanic unit from the median value (0.1 foot per day) to the highest values (50 feet per day), together with a representative cross-sectional area (3,000 square feet) for the contaminated ground-water plume and a hydraulic gradient of 0.14 from August 1992, the following range in ground-water flow rates is estimated by Darcy's law: 42 to 21,000 cubic feet per day, or 10 5 to 5x10 7 gallons per year. Multiplying this estimated range in ground-water flow by representative metal concentrations from the contaminated plume gives the following estimates for annual metal transport to Camanche Reservoir by ground water: 86 to 42,000 pounds of copper; 310 to 150,000 pounds of zinc; and 1.5 to 750 pounds of cadmium.

California↗
USGS1993

Geohydrology, water quality, and estimation of ground-water recharge in San Francisco, California, 1987-92

The city of San Francisco is considering further development of local groundwater resources as a supplemental source of water for potable or nonpotable use. By the year 2010, further water demand is projected to exceed the delivery capacity of the existing supply system, which is fed by surface-water sources; thus supplies are susceptible to drought conditions and damage to conveyance lines by earthquakes. The primary purpose of this study is to describe local geohydrology and water quality and to estimate groundwater recharge in the area of the city of San Francisco. Seven groundwater basins were identified in San Francisco on the basis of geologic and geophysical data. Basins on the east side of the city are relatively thin and contain a greater percentage of fine-grained sediments than those on the west side. The relatively small capacity of the basins and greater potential for contamination from sewer sources may limit the potential for groundwater development on the east side. Basins on the west side of the city have a relatively large capacity and low density sewer network. Water-level data indicate that the southern part of the largest basin on the west side of the city (Westside basin) probably cannot accommodate additional groundwater development without adversely affecting water levels and water quality in Lake Merced; however, the remainder of the basin, which is largely undeveloped, could be developed further. A hydrologic routing model was developed for estimating groundwater recharge throughout San Francisco. The model takes into account climatic factors, land and water use, irrigation, leakage from underground pipes, rainfall runoff, evapotranspiration, and other factors associated with an urban environment. Results indicate that area recharge rates for water years 1987-88 for the 7 groundwater basins ranged from 0.32 to 0.78 feet per year. Recharge for the Westside basin was estimated at 0.51 feet per year. Average annual groundwater recharge represents the maximum annual long-term yield of the basin. Attainable yield may be less than the volume of groundwater recharge because interception of all discharge from the basin may not be feasible without inducing seawater intrusion or causing other undesirable effects.

Water-Resources Investigations Report↗
USGS1989

Geohydrology of the Laura fresh-water lens, Majuro atoll: A hydrogeochemical approach

In small limestone islands, the depositional history and subsequent chemical interactions between ground water and the aquifer host rock play critical roles in the occurrence, movement, and chemical quality of ground water. The hydrogeochemistry of the Laura fresh-water lens, Majuro atoll, Marshall Islands, is an example of these relations. Laura is underlain by two principal hydrologic units. The upper unit is a back-reef-marginal-lagoonal deposit which formed during the Holocene interglacial stage. It is composed of moderately permeable carbonate sediments. The lower hydrologic unit consists of highly permeable limestone that was subaerially exposed, most likely during a Pleistocene glacial lowstand. Similar stratification is found at Bikini and Enewetak atolls. The upper hydrologic unit contains a calcium bicarbonate-rich fresh-water lens, in which a potable fresh-water nucleus as much as 14 m thick occurs on the lagoon side of the island. Storage in the fresh-water nucleus ranged from 1.70 x 10 6 to 2.08 x 10 6 m 3 during 1984-1985. Ground-water occurrence and flow are governed by an asymmetric distribution of lithofacies about the longitudinal axis of the island and an abrupt increase in permeability at the contact between the upper and lower hydrologic units. The highly permeable lower hydrologic unit contains sea water and truncates the fresh-water-sea-water mixing zone. The fresh-water lens and associated fresh-water-sea-water mixing zone are the site of continuously occurring diagenetic reactions that significantly affect the porosity and permeability of the aquifer. Non-equilibrium dissolution-precipitation reactions, coupled with variations in CO 2 input, control the chemical evolution of Laura ground water. At the present rate of chemical weathering, 465 m 3 of sediment are being dissolved and transported to the sea by ground water each year. This dissolution results in an annual increase in porosity of 0.01%. The primary factors controlling the occurrence and flow of ground water in the leeward reef islet of Laura are (1) the depositional history of the upper hydrologic unit, which has resulted in a greater accumulation of low-permeability (fine-grained) sediments beneath the lagoon side of the island and a high- to low-permeability (coarse-to fine-grained sediment) gradation between the ocean and lagoon; and (2) the diagenetic history of the lower hydrologic unit, which has resulted in a highly permeable basement.

Geological Society of America Bulletin↗
USGS1987

Ground-water resources of the Laura area, Majuro Atoll, Marshall Islands

The water system that supplies the heavily populated Dalap-Uliga-Darrit (DUD) area of Majuro atoll, Marshall Island, relies almost entirely upon airstrip catchment of rain water. Droughts cause severe water supply problems and water rationing is required, even during periods of normal rainfall. The Laura area contains a substantial lens of fresh groundwater that could be developed for export to the DUD area 30 mi to the east. Study of the groundwater resource at Laura involved a survey of existing wells, installation of monitoring wells and test holes, compilation of continuous records of rainfall and water level fluctuations, and collection of water quality data. Test hole data permitted the definition of three geohydrologic units which correlate well with similar units in Bikini and Enewetak atolls. The units consist of two layers of unconsolidated reef and lagoon sediments resting on a dense, highly permeable limestone. The potable water zone, or freshwater nucleus, of the lens is contained mostly within the unconsolidated layers, which are much less permeable than the basal limestone. Recharge to the Laura freshwater lens is estimated to be 1.8 mil gal/day, based on an average annual rainfall of 140 in. Sustainable yield is estimated to be about 400,000 gal/day. Shallow skimming wells or infiltration galleries similar to those used on Kwajalein atoll would be appropriate to develop the freshwater lens. The impact of development on the lens can be determined by monitoring the salinity in developed water and in a network of monitor wells.

Laura area, Majuro Atoll↗
USGS1987

Evaluation of the potential for artificial ground-water recharge in eastern San Joaquin County, California — Phase 3

Infiltration tests were used to evaluate the potential of basin spreading surface water as a means of artificially recharging the aquifer system in eastern San Joaquin County, California. Two infiltration sites near Lockeford and Linden were selected on the basis of information collected during the first two phases of the study. Data from the infiltration tests indicate that the two sites are acceptable for recharge by the basin-spreading method. Infiltration rates ranged between 6.7 and 10.5 ft/day near Lockeford and between 2.6 and 11.2 ft/day near Linden. Interpretation of these data is limited by lack of information on the response of the saturated zone during testing and by the inherent difficulty in extrapolating the results of small-scale tests to larger long-term operations. Lithology is a major factor that controls infiltration rates at the test sites. The unsaturated zone is characterized by heterogeneous layers of coarse- and fine- grained materials. Clay layers of low hydraulic conductivity commonly form discontinuous lenses that may cause a transient perched water table to develop during recharge. Water level measurements from wells screened in the unsaturated zone indicate that the perched water table could reach the land surface after 2 and 5 months of recharge near Lockeford and Linden, respectively. These figures probably represent the minimum time necessary for saturation of the land. Another major factor that affects infiltration rates is the quality of the recharge water, particularly the suspended sediment content. The clogging action of suspended sediment may be minimized by: (1) pretreatment of recharge water in a settling pond, (2) adherence to a routine program of monitoring and maintenance, and (3) proper design of the recharge facility. Other factors that affect infiltration rates include basin excavation technique, basin shape, and maintenance procedures. Efficient operation of the recharge facility requires careful attention to the relation between subsurface water levels and infiltration rates.

California↗
USGS1985

An investigation of ground-water recharge by injection in the Palo Alto Baylands, California: Hydraulic and chemical interactions — Final report

The U.S. Geological Survey, in cooperation with the Santa Clara Valley Water District, has completed a study of ground-water recharge by injection in the Palo Alto baylands along San Francisco Bay, California. Selected wells within the Water District 's injection-extraction network were monitored to determine hydraulic and chemical interactions affecting well-field operation. The well field was installed to prevent and eliminate saline contamination in the local shallow aquifer system. The primary focus of this study is on factors that affect injection efficiency, specifically well and aquifer clogging. Mixing and break-through curves for major chemical constituents indicate ion exchange, adsorption, and dissolution reactions. Freshwater breakthrough was detected in water-level data, which reflected fluid-density change as well as head buildup. Dissolution of calcium carbonate caused by dilution of saline ground water probably accounts for an apparent increase in specific capacity possibly related to improved aquifer permeability. Adsorption evidently removed trace elements during passage of injected water through the aquifer. In terms of hydraulic and chemical compatibility, the well field is a viable system for ground-water recharge. Aquifer heterogeneity and operational constraints reduce the efficiency of the system. Efficiency may be maximized by careful attention to extraction distribution and quantity and to injection distribution, quantity, and water quality. (USGS)

California↗
USGS1983

Injection of treated wastewater for ground-water recharge in the Palo Alto Baylands, California, hydraulic and chemical interactions — Preliminary report

An injection-extraction well network in the Palo Alto Baylands along the San Francisco Bay, California, was designed to flush the shallow aquifer system of saline water and prevent further inland saline contamination. Clogging processes and solution migration in the vicinity of one injection well were studied. Cyclic evaporative concentration of bay water and infiltration have generated a concentrated ground-water brine. Montmorillonite and illite are the primary clay minerals present in the shallow aquifer system. X-ray diffraction analysis of these clays showed a marked increase in the d-spacing of the crystal lattice when native hypersaline pure water was replaced by injection water. Chloride:magnesium and chloride:potassium ratios in the aquifer system changed during injection, most likely due to ionic exchange reaction. Similar variations in chloride:boron, chloride:iron, and chloride:manganese ratios probably resulted from reduction-oxidation reactions. Ground-water quality appears to have been chiefly affected by the processes of dilution and dispersion. Extraction pump test data yielded a transmissivity value of 960 feet squared per day and a storage coefficient of 0.0005. Vertical permeability of the upper confining layer is 0.08 feet per day.

California↗