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S. J. Sutley

Publications and source records attributed to S. J. Sutley.

At least 37 records · Page 2Linked to original sources

Geochemistry of sediments from coastal marshes of Louisiana

As a part of the U.S. Geological Survey Global Change and Climate History Program we have been studying the biogeochemistry of coastal marshes in Terrebonne Basin, Louisiana. Louisiana has about 40 percent of the coastal wetlands in the conterminous U.S. and it is losing wetlands at one of the highest rates in the U.S. with the conversion of about 65 km2/yr of marsh to open water (Britsch and Dunbar, 1993). The losses have been attributed to human and natural causes including saltwater intrusion through man-made canals, reduced sediment input, and regional subsidence. The net effect of these influences is to change the salinity of interior marshes in a fashion similar to a eustatic sea level rise. We are studying the cycling of carbon, sulfur, and other elements in sediments, waters, and marsh macrophytes in fresh, intermediate/brackish, and saltwater marshes in order to better understand how sea level rise, one aspect of global change, will influence and in turn be influenced by cycling of these elements. By characterizing the critical biogeochemical processes and the recent past environments in these rapidly changing marshes, we can improve predictions of future changes and interpretations of the historic geologic record in similar environments. In this report we describe our coastal marsh study sites in Louisiana, the types of samples collected, the collection methods, the chemical analysis methods, and selected chemical analysis results. Also included are summaries of the project quality control results. The raw chemical analysis results are provided in this report without interpretation. Interpretations will be provided in subsequent reports.

Louisiana↗

McCrillisite, NaCs(Be,Li)Zr2(PO4)4.1-2H2O, a new mineral species from Mount Mica, Oxford County, Maine, and new data for gainesite

McCrillisite, a member of the gainesite group, occurs in the Mount Mica granitic pegmatite, South Paris, Oxford County, Maine. The mineral is a product of late-stage hydrothermal alteration and is associated with approximately 20 other silicate, oxide, carbonate, arsenite and phosphate minerals. Crystals occur in mm- to cm-sized cavities, and individuals are up to 1.2 mm in maximum dimension. The crystallography and mineral chemistry of McCrillisite are described. -from Authors

Canadian Mineralogist↗

Kosnarite, KZr2(PO4)3, a new mineral from Mount Mica and Black Mountain, Oxford County, Maine

Kosnarite, ideally KZr2(PO4)3, has been identified as part of a late-stage, secondary phosphate mineral assemblage from the Mount Mica pegmatite at Paris, and from the Black Mountain pegmatite, Rumford, Oxford County, Maine. Kosnarite from Mount Mica occurs as pseudocubic rhombohedral crystals, as much as 0.9 mm in maximum dimension, that display the dominant {102} form. Color ranges from pale blue to blue-green to nearly colorless. The mineral has a white streak, is transparent, has a vitreous luster, and is nonfluorescent in ultraviolet light. It has a hardness of 4.5, is brittle with a conchoidal fracture, and has perfect {102} cleavage. Kosnarite from Black Mountain is almost pure KZr2(PO4)3 with only trace amounts of Hf, Mn, Na, and Rb. The mineral is one of three known alkali zirconium phosphates; the others are gainesite and the Cs analogue of gainesite. -from Author

American Mineralogist↗

A comparison of geochemical exploration techniques and sample media within accretionary continental margins: an example from the Pacific Border Ranges, Southern Alaska, U.S.A.

The Pacific Border Ranges of the southern Alaskan Cordillera are composed of a number of allochthonous tectonostratigraphic terranes. Within these terranes are widespread volcanogenic, massive sulfide deposits in and adjacent to portions of accreted ophiolite complexes, bands and disseminations of chromite in accreted island-arc ultramafic rocks, and epigenetic, gold-bearing quartz veins in metamorphosed turbidite sequences. A geochemical pilot study was undertaken to determine the most efficient exploration strategy for locating these types of mineral deposits within the Pacific Border Ranges and other typical convergent continental margin environments. High-density sediment sampling was carried out in first- and second-order stream channels surrounding typical gold, chromite and massive sulfide occurrences. At each site, a stream-sediment and a panned-concentrate sample were collected. In the laboratory, the stream sediments were sieved into coarse-sand, fine- to medium-sand, and silt- to clay-size fractions prior to analysis. One split of the panned concentrates was retained for analysis; a second split was further concentrated by gravity separation in heavy liquids and then divided into magnetic, weakly magnetic and nonmagnetic fractions for analysis. A number of different techniques including atomic absorption spectrometry, inductively coupled plasma atomic emission spectrometry and semi-quantitative emission spectrography were used to analyze the various sample media. Comparison of the various types of sample media shows that in this tectonic environment it is most efficient to include a silt- to clay-size sediment fraction and a panned-concentrate sample. Even with the relatively low detection limits for many elements by plasma spectrometry and atomic absorption spectrometry, anomalies reflecting the presence of gold veins could not be identified in any of the stream-sediment fractions. Unseparated panned-concentrate samples should be analyzed by emission spectroscopy and atomic absorption spectrometry for Ag and Au. If, however, magnetic and nonmagnetic concentrate fractions are used in a reconnaissance program, semiquantitative emission spectrography is adequate for all analytical work.

Journal of Geochemical Exploration↗

Production of sulfur gases and carbon dioxide by synthetic weathering of crushed drill cores from the Santa Cruz porphyry copper deposit near Casa Grande, Pinal County, Arizona

Samples of ground drill cores from the southern part of the Santa Cruz porphyry copper deposit, Casa Grande, Arizona, were oxidized in simulated weathering experiments. The samples were also separated into various mineral fractions and analyzed for contents of metals and sulfide minerals. The principal sulfide mineral present was pyrite. Gases produced in the weathering experiments were measured by gas chromatography. Carbon dioxide, oxygen, carbonyl sulfide, sulfur dioxide and carbon disulfide were found in the gases; no hydrogen sulfide, organic sulfides, or mercaptans were detected. Oxygen concentration was very important for production of the volatiles measured; in general, oxygen concentration was more important to gas production than were metallic element content, sulfide mineral content, or mineral fraction (oxide or sulfide) of the sample. The various volatile species also appeared to be interactive; some of the volatiles measured may have been formed through gas reactions.

Journal of Geochemical Exploration↗