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Roy Haggerty

Publications and source records attributed to Roy Haggerty.

6 recordsLinked to original sources

Pore network modeling of the electrical signature of solute transport in dual-domain media

Dual-domain models are used to explain anomalous solute transport behavior observed in diverse hydrologic settings and applications, from groundwater remediation to hyporheic exchange. To constrain such models, new methods are needed with sensitivity to both immobile and mobile domains. Recent experiments indicate that dual-domain transport of ionic tracers has an observable geoelectrical signature, appearing as a nonlinear, hysteretic relation between paired bulk and fluid electrical conductivity. Here we present a mechanistic explanation for this geoelectrical signature and evaluate assumptions underlying a previously published petrophysical model for bulk conductivity in dual-domain media. Pore network modeling of fluid flow, solute transport, and electrical conduction (1) verifies the geoelectrical signature of dual-domain transport, (2) reveals limitations of the previously used petrophysical model, and (3) demonstrates that a new petrophysical model, based on differential effective media theory, closely approximates the simulated bulk/fluid conductivity relation. These findings underscore the potential of geophysically based calibration of dual-domain models.

Geophysical Research Letters

Descriptors of natural thermal regimes in streams and their responsiveness to change in the Pacific Northwest of North America

1. Temperature is a major driver of ecological processes in stream ecosystems, yet the dynamics of thermal regimes remain poorly described. Most work has focused on relatively simple descriptors that fail to capture the full range of conditions that characterise thermal regimes of streams across seasons or throughout the year. 2. To more completely describe thermal regimes, we developed several descriptors of magnitude, variability, frequency, duration and timing of thermal events throughout a year. We evaluated how these descriptors change over time using long-term (1979–2009), continuous temperature data from five relatively undisturbed cold-water streams in western Oregon, U.S.A. In addition to trends for each descriptor, we evaluated similarities among them, as well as patterns of spatial coherence, and temporal synchrony. 3. Using different groups of descriptors, we were able to more fully capture distinct aspects of the full range of variability in thermal regimes across space and time. A subset of descriptors showed both higher coherence and synchrony and, thus, an appropriate level of responsiveness to examine evidence of regional climatic influences on thermal regimes. Most notably, daily minimum values during winter–spring were the most responsive descriptors to potential climatic influences. 4. Overall, thermal regimes in streams we studied showed high frequency and low variability of cold temperatures during the cold-water period in winter and spring, and high frequency and high variability of warm temperatures during the warm-water period in summer and autumn. The cold and warm periods differed in the distribution of events with a higher frequency and longer duration of warm events in summer than cold events in winter. The cold period exhibited lower variability in the duration of events, but showed more variability in timing. 5. In conclusion, our results highlight the importance of a year-round perspective in identifying the most responsive characteristics or descriptors of thermal regimes in streams. The descriptors we provide herein can be applied across hydro-ecological regions to evaluate spatial and temporal patterns in thermal regimes. Evaluation of coherence and synchrony of different components of thermal regimes can facilitate identification of impacts of regional climate variability or local human or natural influences.

Freshwater Biology

Direct geoelectrical evidence of mass transfer at the laboratory scale

Previous field-scale experimental data and numerical modeling suggest that the dual-domain mass transfer (DDMT) of electrolytic tracers has an observable geoelectrical signature. Here we present controlled laboratory experiments confirming the electrical signature of DDMT and demonstrate the use of time-lapse electrical measurements in conjunction with concentration measurements to estimate the parameters controlling DDMT, i.e., the mobile and immobile porosity and rate at which solute exchanges between mobile and immobile domains. We conducted column tracer tests on unconsolidated quartz sand and a material with a high secondary porosity: the zeolite clinoptilolite. During NaCl tracer tests we collected nearly colocated bulk direct-current electrical conductivity (σ b ) and fluid conductivity (σ f ) measurements. Our results for the zeolite show (1) extensive tailing and (2) a hysteretic relation between σ f and σ b , thus providing evidence of mass transfer not observed within the quartz sand. To identify best-fit parameters and evaluate parameter sensitivity, we performed over 2700 simulations of σ f , varying the immobile and mobile domain and mass transfer rate. We emphasized the fit to late-time tailing by minimizing the Box-Cox power transformed root-mean square error between the observed and simulated σ f . Low-field proton nuclear magnetic resonance (NMR) measurements provide an independent quantification of the volumes of the mobile and immobile domains. The best-fit parameters based on σ f match the NMR measurements of the immobile and mobile domain porosities and provide the first direct electrical evidence for DDMT. Our results underscore the potential of using electrical measurements for DDMT parameter inference.

Water Resources Research

Increasing synchrony of high temperature and low flow in western North American streams: double trouble for coldwater biota?

Flow and temperature are strongly linked environmental factors driving ecosystem processes in streams. Stream temperature maxima ( T max_w ) and stream flow minima ( Q min ) can create periods of stress for aquatic organisms. In mountainous areas, such as western North America, recent shifts toward an earlier spring peak flow and decreases in low flow during summer/fall have been reported. We hypothesized that an earlier peak flow could be shifting the timing of low flow and leading to a decrease in the interval between T max_w and Q min . We also examined if years with extreme low Q min were associated with years of extreme high T max_w . We tested these hypotheses using long32 term data from 22 minimally human-influenced streams for the period 1950-2010. We found trends toward a shorter time lag between T max_w and Q min over time and a strong negative association between their magnitudes. Our findings show that aquatic biota may be increasingly experiencing narrower time windows to recover or adapt between these extreme events of low flow and high temperature. This study highlights the importance of evaluating multiple environmental drivers to better gauge the effects of the recent climate variability in freshwaters.

Hydrobiologia

The paradox of cooling streams in a warming world: Regional climate trends do not parallel variable local trends in stream temperature in the Pacific continental United States

Temperature is a fundamentally important driver of ecosystem processes in streams. Recent warming of terrestrial climates around the globe has motivated concern about consequent increases in stream temperature. More specifically, observed trends of increasing air temperature and declining stream flow are widely believed to result in corresponding increases in stream temperature. Here, we examined the evidence for this using long-term stream temperature data from minimally and highly human-impacted sites located across the Pacific continental United States. Based on hypothesized climate impacts, we predicted that we should find warming trends in the maximum, mean and minimum temperatures, as well as increasing variability over time. These predictions were not fully realized. Warming trends were most prevalent in a small subset of locations with longer time series beginning in the 1950s. More recent series of observations (1987-2009) exhibited fewer warming trends and more cooling trends in both minimally and highly human-influenced systems. Trends in variability were much less evident, regardless of the length of time series. Based on these findings, we conclude that our perspective of climate impacts on stream temperatures is clouded considerably by a lack of long-termdata on minimally impacted streams, and biased spatio-temporal representation of existing time series. Overall our results highlight the need to develop more mechanistic, process-based understanding of linkages between climate change, other human impacts and stream temperature, and to deploy sensor networks that will provide better information on trends in stream temperatures in the future.

Geophysical Research Letters

Transient groundwater chemistry near a river: Effects on U(VI) transport in laboratory column experiments

In the 300 Area of a U(VI)-contaminated aquifer at Hanford, Washington, USA, inorganic carbon and major cations, which have large impacts on U(VI) transport, change on an hourly and seasonal basis near the Columbia River. Batch and column experiments were conducted to investigate the factors controlling U(VI) adsorption/desorption by changing chemical conditions over time. Low alkalinity and low Ca concentrations (Columbia River water) enhanced adsorption and reduced aqueous concentrations. Conversely, high alkalinity and high Ca concentrations (Hanford groundwater) reduced adsorption and increased aqueous concentrations of U(VI). An equilibrium surface complexation model calibrated using laboratory batch experiments accounted for the decrease in U(VI) adsorption observed with increasing (bi)carbonate concentrations and other aqueous chemical conditions. In the column experiment, alternating pulses of river and groundwater caused swings in aqueous U(VI) concentration. A multispecies multirate surface complexation reactive transport model simulated most of the major U(VI) changes in two column experiments. The modeling results also indicated that U(VI) transport in the studied sediment could be simulated by using a single kinetic rate without loss of accuracy in the simulations. Moreover, the capability of the model to predict U(VI) transport in Hanford groundwater under transient chemical conditions depends significantly on the knowledge of real-time change of local groundwater chemistry.

Washington