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Roxanne Marino

Publications and source records attributed to Roxanne Marino.

2 recordsLinked to original sources

Using multiple lines of evidence to evaluate spatio‐temporal trends in nitrogen loading to a eutrophic estuary

Nitrogen (N) pollution in groundwater in coastal watersheds can have negative impacts on the health of estuaries. West Falmouth Harbor, a shallow lagoon on Cape Cod, MA, USA, has experienced a marked increase in N load since the 1990s due to input from a groundwater aquifer contaminated by a municipal wastewater treatment facility. As part of a broader, long-term research effort to understand the changes to the ecosystem associated with this N input, this study takes an integrative approach at quantifying groundwater N load to the estuary from 1985 through 2024 by combining traditional groundwater well sampling with a wintertime open water mixing model. The latter gives a robust spatially averaged nitrate concentration in discharged groundwater, supplementing the spatial and temporal patterns from the well data. We calculate a conservative estimate for the mean N load to West Falmouth Harbor during peak loading years (2008–2013) of 3.1 mmol m−2 d−1. This then decreased by approximately 25% by 2024 as a result of wastewater treatment improvements and should continue to decline over the next decade. The long-term trends observed in the groundwater well network complement the open water sampling, providing confidence in the accuracy of the latter approach and allowing us to interpolate an estimate of N loading to West Falmouth Harbor back to 1985. This integrative approach to evaluating groundwater inputs to this ecosystem dramatically improves our ability to quantify total N load and can be a powerful tool for studies in groundwater-fed lagoonal estuaries with a short residence time.

Massachusetts↗

Tidal and groundwater fluxes to a shallow, microtidal estuary: Constraining inputs through field observations and hydrodynamic modeling

Increased nutrient loading to estuaries has led to eutrophication, degraded water quality, and ecological transformations. Quantifying nutrient loads in systems with significant groundwater input can be difficult due to the challenge of measuring groundwater fluxes. We quantified tidal and freshwater fluxes over an 8-week period at the entrance of West Falmouth Harbor, Massachusetts, a eutrophic, groundwater-fed estuary. Fluxes were estimated from velocity and salinity measurements and a total exchange flow (TEF) methodology. Intermittent cross-sectional measurements of velocity and salinity were used to convert point measurements to cross-sectionally averaged values over the entire deployment (index relationships). The estimated mean freshwater flux (0.19 m 3 /s) for the 8-week period was mainly due to groundwater input (0.21 m 3 /s) with contributions from precipitation to the estuary surface (0.026 m 3 /s) and removal by evaporation (0.048 m 3 /s). Spring–neap variations in freshwater export that appeared in shorter-term averages were mostly artifacts of the index relationships. Hydrodynamic modeling with steady groundwater input demonstrated that while the TEF methodology resolves the freshwater flux signal, calibration of the index–salinity relationships during spring tide conditions only was responsible for most of the spring–neap signal. The mean freshwater flux over the entire period estimated from the combination of the index-velocity, index–salinity, and TEF calculations were consistent with the model, suggesting that this methodology is a reliable way of estimating freshwater fluxes in the estuary over timescales greater than the spring–neap cycle. Combining this type of field campaign with hydrodynamic modeling provides guidance for estimating both magnitude of groundwater input and estuarine storage of freshwater and sets the stage for robust estimation of the nutrient load in groundwater.

Massachusetts↗