Roberto Iannuzzi | Search USGS

USGS2025

The demise of an icehouse: Calibrating the end of the LPIA

Earth has experienced three complete icehouse-greenhouse turnovers in the Phanerozoic, with the Late Paleozoic Ice Age (LPIA) recognized as the last and most extreme icehouse. The nature, scale and dynamics of the LPIA are characterized by periods of intense glaciation, which are often interrupted by short-lived (1–2 Myrs) intervals associated with ice-free or distal from ice conditions. In this study, we focus on constraining the icehouse-greenhouse turnover across southcentral Gondwana (SCG) reporting new high-resolution U Pb zircon CA-ID-TIMS ages from immediate postglacial facies in the Kalahari and Karoo basins. We integrate these ages with published U Pb zircon CA-ID-TIMS ages ( n = 20) to build a stratigraphic framework for SCG, to investigate the duration and nature of the demise of the LPIA. We confirm the stepwise deglaciation of Gondwana over a ca. 20 Myr period, with deglaciation occurring first in the Paraná Basin at ca. 300 Ma and in the Karoo Basin by 282 Ma. Low-latitude marine carbonates deposited contemporaneously with the final demise of ice is characterized by a major shift towards isotopically depleted δ 13 C and δ 18 O values. We interpret the perturbations in stable isotopes records to be driven by either mantle outgassing or the release of methane and the addition of glacial melt water to the paleo-ocean during warming. The presented stratigraphic framework is built in intracratonic basins, far from any syn - tectonic affects, suggesting a largely climatic driver behind deglaciation events.

Global and Planetary Change↗

USGS2023

A Carboniferous apex for the late Paleozoic icehouse

Icehouse climate systems occur across an abbreviated portion of Earth history, constituting c. 25% of the Phanerozoic record. The Late Paleozoic Ice Age (LPIA) was the most extreme and longest lasting glaciation of the Phanerozoic and is characterized by periods of acute continental-scale glaciation, separated by periods of ice minima or ice-free conditions on the order of <10 6 years. The late Paleozoic glaciogenic record of the Paraná and Kalahari basins of southern Gondwana form one of the largest, best-preserved and well-calibrated records of this glaciation. In the Carboniferous, the eastern and southern margins of the Paraná Basin and the Kalahari Basin were characterized by subglacial conditions, with evidence for continental and upland glaciers. In the latest Carboniferous, these basins transitioned from subglacial reservoirs to ice-free or ‘ice distal‘ conditions evidenced by the widespread deposition of marine deposits juxtaposed on subglacial bedforms. High-precision U–Pb zircon chemical abrasion thermal ionization mass spectrometry geochronological constraints from volcanic ash deposits in the deglacial marine black shales of the Kalahari Basin and from fluvial and coal successions, which overlie marine deposits in the Paraná Basin, indicate subglacial evidence in these regions is constrained to the Carboniferous. The loss of ice in these regions is congruent with a late Carboniferous peak in p CO 2 and widespread marine anoxia in the late Carboniferous. The permeant retreat of glaciers in basinal settings, despite an early Permian p CO 2 nadir, highlights the influence of short-term perturbations on the longer-term CO 2 record and suggests an ice threshold had been crossed in the latest Carboniferous. A definitive driver for greenhouse gases in the LPIA, such as abundant and sustained volcanic activity or an increased biological pump driven by ocean fertilization, is unresolved for this period. Lastly, the proposed Carboniferous apex for the high-latitude LPIA record is incongruent with observations from the low-latitude tropics where an early Permian peak is proposed.

Geological Society, London, Special Publications↗