Geology topics

Robert C. Reedy

Publications and source records attributed to Robert C. Reedy.

12 recordsLinked to original sources

USGS2026

Regional characterization of coal resources in the Gulf Coast Coal Region—In support of coal as a potential source for critical minerals and rare earth elements

There is increasing interest in extracting critical minerals (CM), including rare earth elements (REE), from coals in the United States to address the overreliance on imported REE. The Gulf Coast and the Fort Union regions are the two major lignite-bearing regions within the United States. Recent REE and CM studies of the lignite in these regions have indicated that the coals may be a viable source material for REE and CM extraction. To evaluate in-place coal as a potential source of REE and CM, the coal resources need to be quantified. This study presents the results of a regional analysis of Gulf Coast Coal Region lignite and bituminous coal resources that might be available as potential sources of REE and CM. The resource analysis used kriging methods to develop isopleth maps of cumulative coal thickness throughout the region using data from drill holes and measured mine and outcrop sections for a total of 31,181 data points. The estimated total remaining coal resource in the Gulf Coast Coal Region is about 83 billion metric tons in the upper 90 meters (approximately 300 feet) of the subsurface. The current estimate of remaining coal resources includes approximately 1.88 billion metric tons of coal that have been extracted in the region since 1983. Texas accounted for 39 percent (32 billion metric tons) of the remaining total resource, followed by Mississippi (24 percent, 20 billion metric tons ), Louisiana (14 percent, 12 billion metric tons), Tennessee (10 percent, 8.5 billion metric tons), and Arkansas (6 percent, 5.1 billion metric tons). Alabama, Georgia, Kentucky, and Missouri each accounted for less than 5 percent of the total resource; Georgia had the smallest resource estimated at 7 million metric tons. Here we report the first known statewide lignite resource estimates for Georgia, Kentucky (820 million metric tons), and Missouri (1,800 million metric tons). A comparison of the results of this study with those of previous Gulf Coast Coal Region and Fort Union Coal Region resource studies is difficult because each study used different data sources, assessment methodologies, overburden depths, and qualifying coal thicknesses.

Alabama, Arkansas, Florida, Georgia, Illinois, Lou↗

USGS2026

Rare earth element potential in coal and coal ash in the U.S. Gulf Coast

United States heavy reliance on imports of critical minerals (CMs), including rare earth elements (REEs), underscores the importance of development of domestic sources. The study objective was to quantify CM and REE concentrations in coal and coal ash in the US Gulf Coast region. CM and REE concentrations were measured for 118 samples from outcrops and 14 mines in the Gulf Coast. Results show that total REE + Yttrium (REY) concentrations (dry coal basis) are comparable to those of the upper continental crust (UCC) with localized hot spots, such as the Texas Gibbons Creek mine (REY ≤ ~ 2860 ppm). When normalized to UCC REY concentration (169 ppm, dry coal basis), REY to UCC ratios for Gulf Coast coal samples range from 0.1 to 17 (median ratio 0.6). REE extractability from lignites is high (median: 63%–93%) using environmentally benign weak acid. In addition to raw coal, coal ash from power plants could also serve as an REE source with a median ratio of REY in ash relative to coal of 4; however, extractability from coal ash is generally much lower (≤ 5% using the same weak acid as in coal). The median basket price for extracted REY as oxides from coal, assuming 70% extractability, is $3.2 per tonne of coal and $186 billion based on 58 billion metric tonnes of dry coal in the Gulf Coast. REEs important for magnets (Pr + Nd + Tb + Dy) account for ~ 80% of the total value. The corresponding median basket price for extracted REY as oxides from coal ash, assuming ~ 30% extractability, is ~$4.4 per tonne of ash and $1.2 billion based on 258 million tonnes of ash. REE production from coal would likely require co-products, such as activated carbon or humic acids, to attain economic viability. Production of REEs from coal ash could offset remediation costs related to potential water contamination. This reconnaissance study shows the potential for REE production from coal and coal ash in the Gulf Coast; however, carbon coproducts and/or societal benefits would likely be required for socioeconomic viability.

Alabama, Florida, Louisiana, Mississippi, Texas↗

USGS2025

Regional characterization of coal resources in the U.S. Gulf Coast

There is increasing interest in extracting critical minerals (CM), including rare earth elements (REE), from coals in the United States to address the overreliance on imported REE. The U.S. Gulf Coast and the Williston basins are the two major lignite-bearing basins within the country. Recent REE and CM studies of the lignite in these basins have indicated that the coals may be a viable source material for REE and CM extraction. To evaluate in-place coal as a potential source of REE and CM, the coal resources need to be quantified. This study presents the results of a regional analysis of the U.S. Gulf Coast lignite and bituminous coal resources that might be available as potential sources of REE and CM. The resource analysis used kriging methods to develop isopleth maps of cumulative coal thickness throughout the region using data from 31,181 drill holes and other data points. The estimated total coal resource in the Gulf Coast is about 83 billion metric tons in the upper 90 m (~ 300 ft) of the subsurface. Texas accounted for 40 percent (32 billion metric tons) of the total resource, followed by Mississippi (24 %, 20 billion metric tons), Louisiana (14 %, 12 billion metric tons), Tennessee (10 %, 8.5 billion metric tons), and Arkansas (6 %, 5.1 billion metric tons). The remaining states each accounted for less than 5 percent of the total resource. Georgia had the smallest resource estimated at 7 million metric tons. Here we report the first known state-wide lignite resource estimates for Georgia, Kentucky (820 million metric tons), and Missouri (1,800 million metric tons). A comparison of the results of this study with those of previous Gulf Coast and Williston Basin resource studies is difficult because each study used different data sources, assessment methodologies, overburden depths, and qualifying coal thicknesses. Coal-power electric generation has sharply decreased in past decades and mining of these coals for CM and REE could provide additional co-products such as activated carbon and other uses such as fertilizer (soil enhancer).

EarthArXiv↗

USGS2025

Gulf Coast Basin CORE-CM initiative final report

The Bureau of Economic Geology at the University of Texas at Austin (UT-BEG) is leading the Gulf Coast Carbon Ore, Rare Earth, and Critical Minerals (CORE-CM) Initiative to assess the potential to produce critical minerals (CMs), including rare earth elements (REEs) from coal, coal ash, and produced water related to oil and gas production, and related materials (alumina processing waste [red mud], heavy mineral sands, graphite, and zeolite) within the Gulf Coast Basin. This project represents the first phase in a long-term program and provides reconnaissance data that will be foundational for future work by assessing resources and suggesting plans to be conducted in future work and expanding stakeholder engagement. The project includes several tasks designed to identify, characterize, and assess several necessary aspects for development of CMs and REEs in the Gulf Coast Basin.

Gulf Coast basin↗

USGS2023

Distribution of rare earth and other critical elements in lignites from the Eocene Jackson Group, Texas

Coal is increasingly evaluated as a source of rare earth elements (REEs) in the United States to address the overreliance on imported REEs. The objective of this study was to assess the distribution of REEs in lignites from selected mining areas in the Texas Gulf Coastal Plain region. Thirty-one archived lignite and rock samples previously collected by the U.S. Geological Survey were analyzed for their rare earth element and critical mineral content. These include samples from one core (5400 and 5500 lignite horizons) and two opencast lignite mines (Gibbons Creek 3500 and 4500 horizons, and San Miguel horizons A to D) in the Eocene Jackson Group of the Texas Gulf of Mexico Coastal Plain. Some lithologies in the Gibbons Creek 3500 and 4500 lignite-bearing sections have high total rare earth, yttrium (Y), and scandium (Sc) (REYSc) values, up to 7800 ppm (ash basis) REYSc. The lignite lithologies show an enrichment in rare earths, [samarium (Sm) through gadolinium (Gd)]. The basal Gibbons Creek 3500 lignite bench shows a heavy rare earth element enrichment pattern resembling that often seen in peats through high volatile A bituminous coals. The 5500 lignite sequence, overlying the latter lignite sections, shows a light rare earth enrichment. The San Miguel lignite benches have heavy rare earth enrichments with a negative europium (Eu) anomaly.

Texas↗

USGS2016

Enhancing drought resilience with conjunctive use and managed aquifer recharge in California and Arizona

Projected longer‐term droughts and intense floods underscore the need to store more water to manage climate extremes. Here we show how depleted aquifers have been used to store water by substituting surface water use for groundwater pumpage (conjunctive use, CU) or recharging groundwater with surface water (Managed Aquifer Recharge, MAR). Unique multi‐decadal monitoring from thousands of wells and regional modeling datasets for the California Central Valley and central Arizona were used to assess CU and MAR. In addition to natural reservoir capacity related to deep water tables, historical groundwater depletion further expanded aquifer storage by ~44 km3 in the Central Valley and by ~100 km3 in Arizona, similar to or exceeding current surface reservoir capacity by up to three times. Local river water and imported surface water, transported through 100s of km of canals, is substituted for groundwater (≤15 km3/yr, CU) or is used to recharge groundwater (MAR, ≤1.5 km3/yr) during wet years shifting to mostly groundwater pumpage during droughts. In the Central Valley, CU and MAR locally reversed historically declining water‐level trends, which contrasts with simulated net regional groundwater depletion. In Arizona, CU and MAR also reversed historically declining groundwater level trends in Active Management Areas. These rising trends contrast with current declining trends in irrigated areas that lack access to surface water to support CU or MAR. Use of depleted aquifers as reservoirs could expand with winter flood irrigation or capturing flood discharges to the Pacific (0 – 1.6 km3/yr, 2000–2014) with additional infrastructure in California. Because flexibility and expanded portfolio options translate to resilience, CU and MAR enhance drought resilience through multi‐year storage, complementing shorter term surface reservoir storage, and facilitating water markets.

Environmental Research Letters↗

USGS2015

Hydrologic implications of GRACE satellite data in the Colorado River Basin

Use of GRACE (Gravity Recovery and Climate Experiment) satellites for assessing global water resources is rapidly expanding. Here we advance application of GRACE satellites by reconstructing long-term total water storage (TWS) changes from ground-based monitoring and modeling data. We applied the approach to the Colorado River Basin which has experienced multiyear intense droughts at decadal intervals. Estimated TWS declined by 94 km 3 during 1986–1990 and by 102 km 3 during 1998–2004, similar to the TWS depletion recorded by GRACE (47 km 3 ) during 2010–2013. Our analysis indicates that TWS depletion is dominated by reductions in surface reservoir and soil moisture storage in the upper Colorado basin with additional reductions in groundwater storage in the lower basin. Groundwater storage changes are controlled mostly by natural responses to wet and dry cycles and irrigation pumping outside of Colorado River delivery zones based on ground-based water level and gravity data. Water storage changes are controlled primarily by variable water inputs in response to wet and dry cycles rather than increasing water use. Surface reservoir storage buffers supply variability with current reservoir storage representing ∼2.5 years of available water use. This study can be used as a template showing how to extend short-term GRACE TWS records and using all available data on storage components of TWS to interpret GRACE data, especially within the context of droughts.

Water Resources Research↗

USGS2013

Neutron absorption constraints on the composition of 4 Vesta

Global maps of the macroscopic thermal neutron absorption cross section of Vesta's regolith by the Gamma Ray and Neutron Detector (GRaND) on board the NASA Dawn spacecraft provide constraints on the abundance and distribution of Fe, Ca, Al, Mg, and other rock-forming elements. From a circular, polar low-altitude mapping orbit, GRaND sampled the regolith to decimeter depths with a spatial resolution of about 300 km. At this spatial scale, the variation in neutron absorption is about seven times lower than that of the Moon. The observed variation is consistent with the range of absorption for howardite whole-rock compositions, which further supports the connection between Vesta and the howardite, eucrite, and diogenite meteorites. We find a strong correlation between neutron absorption and the percentage of eucritic materials in howardites and polymict breccias, which enables petrologic mapping of Vesta's surface. The distribution of basaltic eucrite and diogenite determined from neutron absorption measurements is qualitatively similar to that indicated by visible and near infrared spectroscopy. The Rheasilvia basin and ejecta blanket has relatively low absorption, consistent with Mg-rich orthopyroxene. Based on a combination of Fe and neutron absorption measurements, olivine-rich lithologies are not detected on the spatial scales sampled by GRaND. The sensitivity of GRaND to the presence of mantle material is described and implications for the absence of an olivine signature are discussed. High absorption values found in Vesta's “dark” hemisphere, where exogenic hydrogen has accumulated, indicate that this region is richer in basaltic eucrite, representative of Vesta's ancient upper crust.

Meteoritics and Planetary Science↗

USGS2012

Groundwater depletion and sustainability of irrigation in the US High Plains and Central Valley

Aquifer overexploitation could significantly impact crop production in the United States because 60% of irrigation relies on groundwater. Groundwater depletion in the irrigated High Plains and California Central Valley accounts for ∼50% of groundwater depletion in the United States since 1900. A newly developed High Plains recharge map shows that high recharge in the northern High Plains results in sustainable pumpage, whereas lower recharge in the central and southern High Plains has resulted in focused depletion of 330 km 3 of fossil groundwater, mostly recharged during the past 13,000 y. Depletion is highly localized with about a third of depletion occurring in 4% of the High Plains land area. Extrapolation of the current depletion rate suggests that 35% of the southern High Plains will be unable to support irrigation within the next 30 y. Reducing irrigation withdrawals could extend the lifespan of the aquifer but would not result in sustainable management of this fossil groundwater. The Central Valley is a more dynamic, engineered system, with north/south diversions of surface water since the 1950s contributing to ∼7× higher recharge. However, these diversions are regulated because of impacts on endangered species. A newly developed Central Valley Hydrologic Model shows that groundwater depletion since the 1960s, totaling 80 km 3 , occurs mostly in the south (Tulare Basin) and primarily during droughts. Increasing water storage through artificial recharge of excess surface water in aquifers by up to 3 km 3 shows promise for coping with droughts and improving sustainability of groundwater resources in the Central Valley.

California, Colorago, Kansas, Nebraska, New Mexico↗

USGS2012

Elemental mapping by Dawn reveals exogenic H in Vesta's regolith

Using Dawn’s Gamma Ray and Neutron Detector, we tested models of Vesta’s evolution based on studies of howardite, eucrite, and diogenite (HED) meteorites. Global Fe/O and Fe/Si ratios are consistent with HED compositions. Neutron measurements confirm that a thick, diogenitic lower crust is exposed in the Rheasilvia basin, which is consistent with global magmatic differentiation. Vesta’s regolith contains substantial amounts of hydrogen. The highest hydrogen concentrations coincide with older, low-albedo regions near the equator, where water ice is unstable. The young, Rheasilvia basin contains the lowest concentrations. These observations are consistent with gradual accumulation of hydrogen by infall of carbonaceous chondrites—observed as clasts in some howardites—and subsequent removal or burial of this material by large impacts.

Science↗

USGS2009

Inventories and mobilization of unsaturated zone sulfate, fluoride, and chloride related to land use change in semiarid regions, southwestern United States and Australia

Unsaturated zone salt reservoirs are potentially mobilized by increased groundwater recharge as semiarid lands are cultivated. This study explores the amounts of pore water sulfate and fluoride relative to chloride in unsaturated zone profiles, evaluates their sources, estimates mobilization due to past land use change, and assesses the impacts on groundwater quality. Inventories of water‐extractable chloride, sulfate, and fluoride were determined from borehole samples of soils and sediments collected beneath natural ecosystems ( N = 4), nonirrigated (“rain‐fed”) croplands ( N = 18), and irrigated croplands ( N = 6) in the southwestern United States and in the Murray Basin, Australia. Natural ecosystems contain generally large sulfate inventories (7800–120,000 kg/ha) and lower fluoride inventories (630–3900 kg/ha) relative to chloride inventories (6600–41,000 kg/ha). Order‐of‐magnitude higher chloride concentrations in precipitation and generally longer accumulation times result in much larger chloride inventories in the Murray Basin than in the southwestern United States. Atmospheric deposition during the current dry interglacial climatic regime accounts for most of the measured sulfate in both U.S. and Australian regions. Fluoride inventories are greater than can be accounted for by atmospheric deposition in most cases, suggesting that fluoride may accumulate across glacial/interglacial climatic cycles. Chemical modeling indicates that fluorite controls fluoride mobility and suggests that water‐extractable fluoride may include some fluoride from mineral dissolution. Increased groundwater drainage/recharge following land use change readily mobilized chloride. Sulfate displacement fronts matched or lagged chloride fronts by up to 4 m. In contrast, fluoride mobilization was minimal in all regions. Understanding linkages between salt inventories, increased recharge, and groundwater quality is important for quantifying impacts of anthropogenic activities on groundwater quality and is required for remediating salinity problems.

Water Resources Research↗

USGS2005

Impact of land use and land cover change on groundwater recharge and quality in the southwestern US

Humans have exerted large‐scale changes on the terrestrial biosphere, primarily through agriculture; however, the impacts of such changes on the hydrologic cycle are poorly understood. The purpose of this study was to test the hypothesis that the conversion of natural rangeland ecosystems to agricultural ecosystems impacts the subsurface portion of the hydrologic cycle by changing groundwater recharge and flushing salts to underlying aquifers. The hypothesis was examined through point and areal studies investigating the effects of land use/land cover (LU/LC) changes on groundwater recharge and solute transport in the Amargosa Desert (AD) in Nevada and in the High Plains (HP) in Texas, US. Studies use the fact that matric (pore‐water‐pressure) potential and environmental‐tracer profiles in thick unsaturated zones archive past changes in recharging fluxes. Results show that recharge is related to LU/LC as follows: discharge through evapotranspiration (i.e., no recharge; upward fluxes <0.1 mm yr −1 ) in natural rangeland ecosystems (low matric potentials; high chloride and nitrate concentrations); moderate‐to‐high recharge in irrigated agricultural ecosystems (high matric potentials; low‐to‐moderate chloride and nitrate concentrations) (AD recharge: ∼130–640 mm yr −1 ); and moderate recharge in nonirrigated (dryland) agricultural ecosystems (high matric potentials; low chloride and nitrate concentrations, and increasing groundwater levels) (HP recharge: ∼9–32 mm yr −1 ). Replacement of rangeland with agriculture changed flow directions from upward (discharge) to downward (recharge). Recent replacement of rangeland with irrigated ecosystems was documented through downward displacement of chloride and nitrate fronts. Thick unsaturated zones contain a reservoir of salts that are readily mobilized under increased recharge related to LU/LC changes, potentially degrading groundwater quality. Sustainable land use requires quantitative knowledge of the linkages between ecosystem change, recharge, and groundwater quality.

Global Change Biology↗