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Robert A. Ayuso

Publications and source records attributed to Robert A. Ayuso.

47 records · Page 3Linked to original sources
USGS2003

Arsenic in New England: Mineralogical and geochemical studies of sources and enrichment pathways

Detailed mineralogical, geochemical and radiogenic isotopic studies of iron-sulfide and secondary iron oxy-hydroxide minerals in natural bedrock in coastal Maine and New Hampshire test the link between arsenic-rich sulfide minerals in bedrock and secondary oxy-hydroxide minerals. Samples were selected from over 70 bedrock localities, including 22 within the regionally extensive and sulfide-mineral-rich Penobscot Formation and 10 associated with mineral deposits from coastal New Hampshire and Maine, and coupled with data from drill core collected at several sites including areas where well waters contain anomalous As abundances (e.g., Northport, ME). The data were used to establish a diversity of primary and secondary mineralogical hosts for arsenic in bedrock of this part of New England. The studies show that bedrock mineralogy is critical to contributing arsenic to groundwater and suggest a number of mineralogical pathways for arsenic that define weathering processes. The studies show that lead isotopic compositions of the sulfides and iron oxy-hydroxides overlap and establish a genetic link between the sulfides and secondary minerals. The data and interpretive results were presented at Arsenic in New England -- A multidisciplinary Scientific Conference, Manchester, New Hampshire, May 29-31, 2002, sponsored by the New Hampshire Consortium on Arsenic, are available in abstract and poster (full size = 84 by 36 inch sheet) formats.

Maine, New Hampshire↗
USGS2001

Sulfur and lead isotope geochemistry of hypogene mineralization at the Barite Hill Gold Deposit, Carolina Slate Belt, southeastern United States: A window into and through regional metamorphism

The Barite Hill gold deposit, at the southwestern end of the Carolina slate belt in the southeastern United States, is one of four gold deposits in the region that have a combined yield of 110 metric tons of gold over the past 10 years. At Barite Hill, production has dominantly come from oxidized ores. Sulfur isotope data from hypogene portions of the Barite Hill gold deposit vary systematically with pyrite–barite associations and provide insights into both the pre-metamorphic Late Proterozoic hydrothermal and the Paleozoic regional metamorphic histories of the deposit. The δ 34 S values of massive barite cluster tightly between 25.0 and 28.0‰, which closely match the published values for Late Proterozoic seawater and thus support a seafloor hydrothermal origin. The δ 34 S values of massive sulfide range from 1.0 to 5.3‰ and fall within the range of values observed for modern and ancient seafloor hydrothermal sulfide deposits. In contrast, δ 34 S values for finer-grained, intergrown pyrite (5.1–6.8‰) and barite (21.0–23.9‰) are higher and lower than their massive counterparts, respectively. Calculated sulfur isotope temperatures for the latter barite–pyrite pairs (Δ=15.9–17.1‰) range from 332–355 °C and probably reflect post-depositional equilibration at greenschist-facies regional metamorphic conditions. Thus, pyrite and barite occurring separately from one another provide pre-metamorphic information about the hydrothermal origin of the deposit, whereas pyrite and barite occurring together equilibrated to record the metamorphic conditions. Preliminary fluid inclusion data from sphalerite are consistent with a modified seawater source for the mineralizing fluids, but data from quartz and barite may reflect later metamorphic and (or) more recent meteoric water input. Lead isotope values from pyrites range for 206 Pb/ 204 Pb from 18.005–18.294, for 207 Pb/ 204 Pb from 15.567–15.645, and for 208 Pb/ 204 Pb from 37.555–38.015. The data indicate derivation of the ore leads from the country rocks, which themselves show evidence for contributions from relatively unradiogenic, mantle-like lead, and more evolved or crustal lead. Geological relationships, and stable and radiogenic isotopic data, suggest that the Barite Hill gold deposit formed on the Late Proterozoic seafloor through exhalative hydrothermal processes similar to those that were responsible for the massive sulfide deposits of the Kuroko district, Japan. On the basis of similarities with other gold-rich massive sulfide deposits and modern seafloor hydrothermal systems, the gold at Barite Hill was probably introduced as an integral part of the formation of the massive sulfide deposit.

Georgia, North Carolina, South Carolina, Virginia↗
USGS1998

Carolina slate belt gold deposits in Virginia, North Carolina, South Carolina, and Georgia

The Southeastern United States, in particular, the Carolina slate belt of Virginia, North Carolina, South Carolina, and Georgia, has been an important region of mineral production (fig. 1). This region is thought to have major potential for containing large undiscovered deposits of gold and silver, as well as copper, lead, zinc, molybdenum, and tin. Gold production from the major mines (Haile, Brewer, Ridgeway, and Barite Hill) in South Carolina ranked sixth in the Nation in 1992. Despite the closing of all but one mine in 1997, the region continues to attract intense scrutiny by the mining industry. Current U.S. Geological Survey (USGS) efforts in the slate belt are led by a multidisciplinary team focused on an integrated, multistate, and multiyear project that has the potential to result in a fundamental reinterpretation of the economic geology of the region. The slate belt is considered a scientific frontier because of the rapid pace of data acquisition by the USGS, academia, and private sector geologists and because emerging concepts of its geologic evolution are controversial. Establishing the origin of the gold deposits is important, not only in guiding exploration, but for more accurate assessment of the potential for the occurrence of new deposits throughout the southern Appalachians. These efforts may result in further industry exploration that may lead to discovery of new economically viable mineral deposits, which would have a broad economic impact on the region. Another goal is to find ways to prevent human activities related to gold extraction from remobilizing toxic metals found in these deposits, which could have potential harmful effects on the environment.

Georgia, North Carolina, South Carolina, Virginia↗
USGS1998

Radiogenic isotopes and the Eastern Mineral Resources Program of the U.S. Geological Survey

Radiogenic isotope geology relies on a small group of naturally occurring but unstable elements that naturally produce energy and disintegrate or decay to more stable atoms of different elements. Because this phenomenon occurs at a known rate, is unaffected by most physical and chemical processes, and takes place over periods of time comparable to the age of the Earth, these elements can be used in radiometric dating or geochronology.

Information Handout↗
USGS1996

Pb and O isotopic constraints on the source of granitic rocks from Cape Breton Island, Nova Scotia, Canada

Pb isotopic compositions of leached feldspars from twenty-three plutons in Cape Breton Island can be divided into two groups: anorthosite, syenite, and granite in the Blair River Complex, which have the least radiogenic compositions on the Island, and granitic rocks from terranes (Aspy, Bras d'Or, and Mira) to the south. Pb isotopic data for the Blair River Complex ( 206 Pb/ 204 Pb = 17.399-18.107; 207 Pb/ 204 Pb = 15.505-15.560; 208 Pb/ 204 Pb = 36.689-37.733) are consistent with an old source region ultimately derived from the mantle and contaminated by sialic crust. Oxygen isotopic compositions of syenite in the Blair River Complex ( δ 18 O = +8.0 to +8.5 permil) are slightly higher than anorthosite (+7.0 to +8.3 permil); a Silurian granite in the Blair River Complex has δ 18 O = +7.5 permil. Cambrian to Devonian plutons in the Aspy, Bras d'Or, and Mira terranes are more radiogenic ( 206 Pb/ 204 Pb = 18.192-18.981; 207 Pb/ 204 Pb = 15.574-15.712; 208 Pb/ 204 Pb =37.815-38.936) than the Blair River Complex and were generated from source regions having a predominant crustal Pb signature (high μ ). The δ 18 O values of granites and granodiorites in the Aspy terrane (+7.5 to +9.2 permil; avg = +8.6 permil) and Bras d'Or (+3.7 to +11.3 permil; avg = +9.4 permil) are also consistent with involvement of sialic crust. Many Late Proterozoic granites from the Mira terrane have anomalously low δ 18 O values (+0.2 to +5.9 permil), perhaps produced from protoliths that had undergone hydrothermal alteration prior to melting. Paleozoic granitic rocks from the Aspy, Bras d'Or, and Mira terranes cannot be uniquely distinguished on the basis of their Pb and O isotopic compositions. The granitic rocks could have been generated during terrane amalgamation from combinations of unradiogenic (Grenville-like) and more radiogenic (Avalon-like) sources.

Nova Scotia↗
USGS1994

Lead isotope compositions as guides to early gold mineralization: The North Amethyst vein system, Creede district, Colorado

The North Amethyst vein system, which is hosted by approximately 27 Ma Carpenter Ridge Tuff and approximately 26 Ma Nelson Mountain Tuff, has two mineral associations separated by brecciation and sedimentation in the veins. The early association consists of quartz, rhodonite, hematite, magnetite, electrum (Au (sub 0.3-0.5) Ag (sub 0.7-0.5)) , and Mn carbonate, Au-Ag sulfide, Ag sulfosalt, and base metal sulfide minerals. The later mineral association cuts the Mn- and Au-bearing assemblages and consists of quartz, calcite, sericite, chlorite, hematite, adularia, fluorite, base metal sulfides, and Ag-bearing tetrahedrite.Our detailed studies show that the Pb isotope compositions of paragenetically early galenas associated with Au-rich mineralization in the North Amethyst vein system are relatively unradiogenic ( 206 Pb/ 204 Pb: 18.826-18.881, 207 Pb/ 204 Pb: 15.588-15.602, and 208 Pb/ 204 Pb: 37.790-37.926) compared to Pb isotope compositions of galenas formed later at about 25 Ma during Ag and base metal mineralization ( 206 Pb/ 204 Pb: 19.041-19.115, 207 Pb/ 204 Pb: 15.627- 15.672, and 208 Pb/ 204 Pb: 37.829-38.057). New Pb isotope data for the central and southern parts of the Creede district, which are located 5 to 7 km south of the North Amethyst area, agree with the results of a regional study by Doe et al. (1979) that included five samples from the main part of the Creede district. Galenas and adularia from the central and southern Creede district and galenas from the Bondholder district, 7 km north of the North Amethyst area, are similar to the Pb isotope compositions of galenas formed later in the North Amethyst area during Ag and base metal mineralization. Galenas from the Alpha-Corsair vein, which was mined for Ag prior to 1910, are isotopically similar to galenas associated with North Amethyst Au-stage mineralization. This isotopic similarity suggests that unexplored segments of the Alpha-Corsair structure may have the same mineralogy as the North Amethyst Au stage; thus, the Alpha-Corsair structure has the potential for high gold contents.Pb isotope compositions from the late stage of the North Amethyst vein system and from the Bondholder and central and southern Creede mining districts are more radiogenic than the host volcanic rocks of the central cluster of the San Juan volcanic field. Our Pb isotope results indicate that early Au mineralization of the North Amethyst area may represent the product of an older and relatively local hydrothermal system distinct from that of the younger base metal and Ag mineralization found throughout the region. Fluids that deposited Au minerals may have derived their Pb isotope composition by a greater degree of interaction with shallow, relatively less radiogenic volcanic wall rocks. The younger, base metal and Ag-rich mineralization that overprints the Au mineralization in the North Amethyst area clearly has a more radiogenic isotopic signature, which implies that the later mineralization derived a greater component of its Pb from Proterozoic source rocks, or sediments derived from them.Paragenetically early sulfide-rich vein assemblages have the least radiogenic galenas and generally also have the highest Au contents. Thus, identification of paragenetically early vein assemblages with relatively unradiogenic Pb isotope compositions similar to those of the North Amethyst area provides an additional exploration tool for Au in the central San Juan Mountains area.

Colorado↗
USGS1987

White mica geochemistry of the Catheart Mountain porphyry copper deposit, Maine

White micas from hydrothermally altered and mineralized zones in the Catheart Mountain Cu-Mo porphyry deposit have regular compositional variations that are generally related to the contents of copper, total iron, and sulfur in the whole rock. Micas in unmineralized rocks exhibit no such relationship. White mica compositions reflect primarily the control imposed by the celadonitic substitution AIIV +Aiv1 =Si+ (Fe, Mg). The variation in white mica composition in the Catheart Mountain porphyry may be explained by superposition and overprinting of mineral assemblages by ore fluids during mineralization and during the waning stages of hydrothermal alteration. Local bulk compositional differences, changing PHao and fluid compositions during mineralization, and superposition of mineral assemblages along microzoned veins contributed to variation in white mica composition. However, the general relation between white mica composition and base-metal content in the mineralized rocks at Catheart Mountain suggests that identification of this white mica population might be useful as an indicator of mineralization gradients.

Bulletin↗
USGS1985

Significance of tourmaline-rich rocks in the Grenville Complex of St. Lawrence County, New York

Feldspathic quartzite and metapelite of Middle Proterozic age north of Gouverneur, N.Y., contain abundant dravite-uvite (magnesian tourmaline). These rocks, more than 1,000 feet thick, are regionally metamorphosed to the upper amphibolite facies, are pyritic, and locally contain porphyroblastic scapolite. The rocks are underlain by talctremolite schist and a thick sequence of calcitic and dolomitic marble, and are overlain by quartz, calc-silicate carbonate rock, and a pyroxene scapolite unit. All rocks are part of the metasedimentary Grenville Complex. Individual tourmaline-rich layers in the quartzite are as thick as 3 cm and contain as much as 50 percent finegrained, brownish-green dravite. Subjacent talc schist contains fine-grained amber dravite, and silicated marble locally contains brown porphyroblasts of uvite. Gneissic granite, pegmatite, and migmatitic segregations cutting the tourmaline-bearing quartzite, gneisses, and schists are rich in black schorl. Tourmalines from the tourmaline-rich quartzite and other metasedimentary and metaigneous rocks were analyzed by means of an electron microprobe. The compositions of tourmalines in the North Gouverneur area are clearly a function of the bulk composition of the rock. Tourmaline compositions in the quartzite have a wide range in FeO/(Fe+MgO) ratios, from 0.15 to 0.58, which are distinct from the ratios for tourmalines in granitic and pegmatitic rocks that range from 0.55 to 0.75. Tourmalines in the area have Na2O contents that range from 0.85 to 4.25 weight percent. Aluminum in all tourmalines ranges widely from about 25 to 37 weight percent AI 2O3 . The most heterogeneous tourmaline compositions are in the quartzites, although most compositions cluster in the dravite-uvite solid solution series. Substitutions involving Na, Ca, Mg, Fe, and Al result in the following compositional schemes: Na+Fe = Al+vacancy, and Na = Ca. Such coupled substitutions probably represent valid constraints for tourmalines from North Gouverneur. The abundance of magnesian tourmaline in the metasedimentary rocks of the North Gouverneur area is comparable to that of tourmaline-rich rocks associated with sedimenthosted massive sulfide deposits for example, Sullivan Mine, British Columbia. A recently described large lead-zinc deposit at Dugald River, Australia, is associated with tourmaline- and scapolite-bearing rocks similar in many respects to those north of Gouverneur. Compared with known tourmaline compositions in the Sullivan Mine area, tourmalines from North Gouverneur have comparable FeO and MgO values. We suggest that other tourmaline components such as a low TiO2 content, variable Na/(Na + Ca + K) ratios, and the antipathetic correlation of Na and Ca might also be useful in discriminating tourmalines associated with ore deposits. Ore bodies at the nearby Balmat-Edwards mining district are in marbles associated with rocks of evaporitic origin. The boron- and scapolite-rich rocks under consideration in this study possibly also are related to an evaporite-producing environment. Similar rocks that have an evaporite origin are associated with stratabound sulfide deposits at many places.

Bulletin↗
USGS1983

Quartz-molybdenite veins in the Priestly Lake granodiorite, north-central Maine

Quartz-molybdenite veins up to 15 cm in width occur in fine to medium-grained porphyritic biotite-hornblende granodiorite at Priestly Lake north-central Maine. An area of about 150 m x 150 m contains quartz-molybdenite veins; a larger area is characterized by barren quartz veins. Quartz-molybdenite veins are concentrated within the most felsic variants of the intrusion as suggested by lower mafic mineral contents. The pluton has a narrow range in SiO2 (67-70 wt.%), major oxides, and in trace-element compositions. Molybdenite occurs as coarse grained clusters in pockets within the quartz veins, and fills fractures in the quartz veins and host rocks. Disseminated molybdenite in the granodiorite is relatively rare and occurs only in the area characterized by a high density of quartz veins (up to 50 veins per square meter). Alteration envelopes along the quartz veins are very thin or absent, although in some areas the granodiorite appears to be selectively and pervasively altered. Sericite, chlorite, epidote, calcite, pyrite, and quartz are concentrated near the quartz-molybdenite veins. Many of the field and geochemical characteristics of the Priestly Lake pluton are unlike those of major molybdenum-producing areas (Climax, Henderson, Urad). For example, the area of alteration seems to be of limited extent, the host rock is not intensely altered hydrothermally at the surface, the density of fractures is rather low in the mineralized area, and the amount of disseminated molybdenite appears to be small. However, the Priestly Lake pluton may be a small fraction of a concealed batholith as suggested by geophysical data. It is conceivable that the type of mineralization at the surface might be the expression of more extensive molybdenite mineralization at depth. The quartz-molybdenite veins in the Priestly Lake pluton are significant because they indicate that potential molybdenum sources for producing mineralized granites were available at depth. Future studies should be aimed at delineating the area of quartz-molybdenite mineralization, documenting hydrothermal alteration and zonation, determining fracture density, and evaluating the sulfide assemblage.

Open-File Report↗