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Raegan L. Huffman

Publications and source records attributed to Raegan L. Huffman.

17 recordsLinked to original sources

Concentrations of nutrients at the water table beneath forage fields receiving seasonal applications of manure, Whatcom County, Washington, autumn 2011–spring 2015

The U.S. Geological Survey, in cooperation with the Whatcom Conservation District (WCD), collected groundwater-quality data for roughly 3 years (October 2011–May 2015) from near the water table beneath forage fields receiving regular seasonal applications of liquid dairy manure in Whatcom County, Washington. The work was done as part of an evaluation of WCD’s prototypical Application Risk Management (ARM) decision support system. The ARM system uses a combination of field-specific hydrology, stage of crop-growth, manure management practices, soil conditions, and precipitation forecast to evaluate the timing of manure application via a set of decision support tools (Manure Spreading Advisory, ARM Worksheet, manure application setback distances) in order to reduce the risk of contamination of surface water and groundwater. The ARM system’s effectiveness in reducing leaching of nitrate to groundwater was evaluated by monitoring nitrate concentrations in recently recharged groundwater beneath paired test plots receiving manure application scheduled using either conventional (CON) manure scheduling procedures, which utilize fixed start and end dates for manure application along with projected crop nutrient requirements or ARM manure scheduling procedures using an approach to manure application timing based on projected crop nutrient needs, field conditions, and weather forecast. Water-quality samples from the surface of the water table were collected synoptically from paired test plots (2–5 monitoring wells per test plot) at approximately monthly intervals at three different dairy field sites. Water-quality samples from near the water table were isolated from the underlying aquifer using a combination of an inflatable packer and a fine-grained sand pack encompassing the well-screen interval. Concentrations of nitrate and chloride measured at the water table beneath test plots were highly variable. Concentrations of nitrate ranged from non-detectable to 116 milligrams nitrogen per liter (mg-N/L), and chloride ranged from 1.15 to 153 mg/L. In each test plot, seasonal variations were much greater than spatial variations. Differences in nitrate concentrations in groundwater between the two treatments were inconclusive. Nitrate concentrations in groundwater at paired treatment plots (Mann Whitney, p<0.05) were significantly lower beneath the ARM treatment plot at site B, yet significantly higher beneath the ARM treatment plot at site C. Nitrate concentrations in ground water varied significantly among individual wells at each site (Kruskal-Wallis, p<0.05), indicating that leaching of nitrates from soil following manure application is spatially variable at the field scale tested regardless of manure application strategy. At all three paired test plots, average concentrations of nitrate and chloride at the water table were lowest near the end of the growing season (September) and increased rapidly with the onset of autumn rains (October–December). Under both the conventional (calendar-based) and treatment (ARM-based) manure application scheduling systems, high soil nitrate concentrations in autumn were coincident with rising groundwater levels, suggesting that nitrate and chloride were flushed from soil to groundwater by recharge from the seasonal rains. Under both treatments, concentrations of nitrate in shallow (10–25 feet) groundwater beneath forage fields receiving manure applications were greater than the nitrate drinking water standard of 10 mg-N/L in approximately 85 percent of samples. Yearly mass loading of nitrogen to the groundwater system calculated from nitrate concentrations at the water table and estimates of recharge volume ranged from 86 to 196 pounds-N per acre, which was equivalent to approximately 16–37 percent of the recommended manure application rate for projected forage production yield of 7 dry tons per acre per year. Manure nitrogen applied in the autumn, when crop nutrient needs decrease due to reduced sunlight and cooler temperatures and commensurate with ongoing mineralization of soil organic-nitrogen and increased seasonal precipitation, are more likely to exceed the immediate plant nutritional requirements and hence be flushed to groundwater than manure applications occurring near the peak of the growing season.

Washington

Concentrations of nitrate in drinking water in the lower Yakima River Basin, Groundwater Management Area, Yakima County, Washington, 2017

The U.S. Geological Survey, in cooperation with the lower Yakima River Basin Groundwater Management Area (GWMA) group, conducted an intensive groundwater sampling collection effort of collecting nitrate concentration data in drinking water to provide a baseline for future nitrate assessments within the GWMA. About every 6 weeks from April through December 2017, a total of 1,059 samples were collected from 156 wells and 24 surface-water drains. The domestic wells were selected based on known location, completion depth, ability to collect a sample prior to treatment on filtration, and distribution across the GWMA. The drains were pre-selected by the GWMA group, and further assessed based on ability to access sites and obtain a representative sample. More than 20 percent of samples from the domestic wells and 12.8 percent of drain samples had nitrate concentrations that exceeded the maximum contaminant level (MCL) of 10 milligrams per liter established by the U.S. Environmental Protection Agency. At least one nitrate concentration above the MCL was detected in 26 percent of wells and 33 percent of drains sampled. Nitrate was not detected in 13 percent of all samples collected.

Washington

Quality-assurance plan for water-quality activities in the U.S. Geological Survey Washington Water Science Center

In accordance with guidelines set forth by the Office of Water Quality in the Water Mission Area of the U.S. Geological Survey, a quality-assurance plan has been created for use by the Washington Water Science Center (WAWSC) in conducting water-quality activities. This qualityassurance plan documents the standards, policies, and procedures used by the WAWSC for activities related to the collection, processing, storage, analysis, and publication of water-quality data. The policies and procedures documented in this quality-assurance plan for water-quality activities complement the quality-assurance plans for surface-water and groundwater activities at the WAWSC.

Open-File Report

Sediment load and distribution in the lower Skagit River, Skagit County, Washington

The Skagit River delivers about 40 percent of all fluvial sediment that enters Puget Sound, influencing flood hazards in the Skagit lowlands, critically important estuarine habitat in the delta, and some of the most diverse and productive agriculture in western Washington. A total of 175 measurements of suspended-sediment load, made routinely from 1974 to 1993, and sporadically from 2006 to 2009, were used to develop and evaluate regression models of sediment transport (also known as “sediment-rating curves”) for estimating suspended-sediment load as a function of river discharge. Using a flow-range model and 75 years of daily discharge record (acquired from 1941 to 2015), the mean annual suspended-sediment load for the Skagit River near Mount Vernon, Washington, was estimated to be 2.5 teragrams (Tg, where 1 Tg = 1 million metric tons). The seasonal model indicates that 74 percent of the total annual suspended‑sediment load is delivered to Puget Sound during the winter storm season (from October through March), but also indicates that discharge is a poor surrogate for suspended‑sediment concentration (SSC) during the summer low-flow season. Sediment-rating curves developed for different time periods revealed that the regression model slope of the SSC-discharge relation increased 66 percent between the periods of 1974–76 and 2006–09 when suspended-sediment samples were collected, implying that changes in sediment supply, channel hydraulics, and (or) basin hydrology occurred between the two time intervals. In the relatively wet water year 2007 (October 1, 2006, through September 30, 2007), an automated sampler was used to collect daily samples of suspended sediment from which an annual load of 4.5 Tg was calculated, dominated by a single large flood event that contributed 1.8 Tg, or 40 percent of the total. In comparison, the annual load calculated for water year 2007 using the preferred flow-range model was 4.8 Tg (+6.7 percent), in close agreement with the measured value. Particle size affects sediment transport, fate and distribution across watersheds, and therefore is important for predicting how coastal environments, particularly deltas and beaches, will respond to changes in climate and sea-level. Particle-size analysis of winter storm samples indicated that about one-half of the suspended-sediment load consisted of fines (that is, silt- and clay-sized particles smaller than 0.0625 mm in diameter), and the remainder consisted of mostly fine- to medium-sized sand (0.0625–0.5 mm), whereas bedload during winter storm flows (about 1–3 percent of total sediment load) was predominantly composed of medium to coarse sand (0.25–1 mm). A continuous turbidity record from the Anacortes Water Treatment Plant (water years 1999–2013), used as a surrogate for the concentration of fines ( R 2 = 0.93, p = 4.2E-10, n = 17), confirms that about one-half of the mean annual suspended-sediment load is composed of fines. The distribution of flow through the delta distributaries (that is, the channels into which the main stem splits as it approaches the delta) is dynamic, with twice as much flow through the North Fork of the Skagit River relative to the South Fork during low-flow conditions, and close to equal flows in the two channels during high-flow conditions. Turbidity, monitored at several locations in the lower river in spring 2009, was essentially uniform among sites, indicating that fines are well mixed in the lower Skagit River system (defined as the Skagit River and all its distributaries downstream of the Mount Vernon streamgage). A strong relation ( R 2 = 0.95, p = 3.2E-14, n = 21; linear regression) between the concentration of fines and turbidity measured at various locations in summer 2009 indicates that turbidity is an effective surrogate for the concentration of fines, independent of location in the river, under naturally well-mixed fluvial conditions. This relation is especially useful for monitoring suspended sediment in western Washington rivers that are seasonally dominated by glacier meltwater because glacial melting typically produces suspended-sediment concentrations that are not well correlated with discharge. These results provide a comprehensive set of tools to estimate sediment delivery and delta responses of interest to scientists and resource managers including decision-makers examining options for flood hazard mitigation, estuary restoration, and climate change adaptation.

Washington

Monitoring plant tissue nitrogen isotopes to assess nearshore inputs of nitrogen to Lake Crescent, Olympic National Park, Washington

Mats of filamentous-periphytic algae present in some nearshore areas of Lake Crescent, Olympic National Park, Washington, may indicate early stages of eutrophication from nutrient enrichment of an otherwise highly oligotrophic lake. Natural abundance ratios of stable isotopes of nitrogen (δ 15 N) measured in plant tissue growing in nearshore areas of the lake indicate that the major source of nitrogen used by these primary producing plants is derived mainly from atmospherically fixed nitrogen in an undeveloped forested ecosystem. Exceptions to this pattern occurred in the Barnes Point area where elevated δ 15 N ratios indicate that effluent from septic systems also contribute nitrogen to filamentous-periphytic algae growing in the littoral zone of that area. Near the Lyre River outlet of Lake Crescent, the δ 15 N of filamentous-periphytic algae growing in close proximity to the spawning areas of a unique species of trout show little evidence of elevated δ 15 N indicating that nitrogen from on-site septic systems is not a substantial source of nitrogen for these plants. The δ 15 N data corroborate estimates that nitrogen input to Lake Crescent from septic sources is comparatively small relative to input from motor vehicle exhaust and vegetative sources in undeveloped forests, including litterfall, pollen, and symbiotic nitrogen fixation. The seasonal timing of blooms of filamentous-periphytic algal near the lake shoreline is also consistent with nitrogen exported from stands of red alder trees ( Alnus rubra ). Isotope biomonitoring of filamentous-periphytic algae may be an effective approach to monitoring the littoral zone for nutrient input to Lake Crescent from septic sources.

Washington

Groundwater geochemical and selected volatile organic compound data, Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington, July 2015

Previous investigations indicate that concentrations of chlorinated volatile organic compounds (CVOCs) are substantial in groundwater beneath the 9-acre former landfill at Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington. The U.S. Geological Survey has continued to monitor groundwater geochemistry to ensure that conditions remain favorable for contaminant biodegradation as specified in the Record of Decision for the site. This report presents groundwater geochemical and selected CVOC data collected at Operable Unit 1 by the U.S. Geological Survey during July 6&ndash;8 and July 31, 2015 in support of long-term monitoring for natural attenuation. Water samples were collected from 13 wells, 9 piezometers, and 13 shallow groundwater passive-diffusion sampling sites in the nearby marsh. Samples from all wells and piezometers were analyzed for oxidation-reduction (redox) sensitive constituents. Samples from all piezometers and four wells also were analyzed for CVOCs and dissolved gases, as were all samples from the passive-diffusion sampling sites. In 2015, concentrations of redox-sensitive constituents measured at all wells and piezometers were consistent with those measured in previous years, with dissolved oxygen concentrations all less than 1 milligram per liter; little to no detectable nitrate; abundant dissolved manganese, iron, and methane; and commonly detected sulfide. In the upper aquifer of the northern plantation in 2015, CVOC concentrations at all piezometers were similar to those measured in previous years, and concentrations of the reductive dechlorination byproducts ethane and ethene were equivalent to the concentrations measured in 2014. In the upper aquifer of the southern plantation, CVOC concentrations measured in piezometers during 2015 continued to be variable as in previous years, and often very high, and reductive dechlorination byproducts were detected in one of the three wells and in piezometers. Beneath the marsh adjacent to the southern plantation, CVOC concentrations measured in 2015 continued to vary spatially and temporally, and were high. The total CVOC concentration, at what have been historically the most contaminated passive-diffusion sampler sites (S-4 T, S-4B T, and S-5 T), continued elevated trends, as did one of the new sampler sites (S-9 T) installed in 2015. For the intermediate aquifer in 2015, concentrations of reductive dechlorination byproducts ethane and ethene and CVOCs were consistent with those measured in previous years.

Washington

Groundwater geochemical and selected volatile organic compound data, Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington, June and September 2014

Previous investigations indicate that concentrations of chlorinated volatile organic compounds (CVOCs) are substantial in groundwater beneath the 9-acre former landfill at Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington. The U.S. Geological Survey has continued to monitor groundwater geochemistry to ensure that conditions remain favorable for contaminant biodegradation at the site. This report presents groundwater geochemical and selected CVOC data collected at Operable Unit 1 by the U.S. Geological Survey during June 23&ndash;25 and September 4, 2014, in support of long-term monitoring for natural attenuation. Groundwater samples were collected from 13 wells and 9 piezometers, as well as from 10 shallow groundwater passive-diffusion sampling sites in the nearby marsh. Samples from all wells and piezometers were analyzed for oxidation-reduction (redox) sensitive constituents and dissolved gases. Samples from all piezometers and four wells also were analyzed for CVOCs, as were all samples from the passive-diffusion sampling sites. In 2014, concentrations of redox-sensitive constituents measured at all wells and piezometers were consistent with those measured in previous years, with dissolved oxygen concentrations all less than 1 milligram per liter; little to no detectable nitrate; abundant dissolved manganese, iron, and methane; and commonly detected sulfide. In the upper aquifer of the northern plantation in 2014, CVOC concentrations at all piezometers were similar to those measured in previous years, and concentrations of the reductive dechlorination byproducts ethane and ethene were slightly lower or the same as concentrations measured in 2013. In the upper aquifer of the southern plantation, CVOC concentrations measured in piezometers during 2014 continued to be variable as in previous years, often high, and reductive dechlorination byproducts were detected in one of the three wells and in all but two piezometers. Beneath the marsh adjacent to the southern plantation, chloroethene concentrations measured in 2014 continued to vary spatially and temporally, and were high. Trends for total CVOC concentration continued to increase at the historically most contaminated passive‑diffusion sampler sites (S-4, S-4B, and S-5). For the intermediate aquifer in 2014, concentrations of reductive dechlorination byproducts ethane and ethene and CVOCs were consistent with those measured in previous years.

Washington

Groundwater geochemical and selected volatile organic compound data, Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington, July 2013

Previous investigations indicate that concentrations of chlorinated volatile organic compounds (CVOCs) are substantial in groundwater beneath the 9-acre former landfill at Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington. The U.S. Geological Survey has continued to monitor groundwater geochemistry to ensure that conditions remain favorable for contaminant biodegradation as specified in the Record of Decision for the site. This report presents groundwater geochemical and selected CVOC data collected at Operable Unit 1 by the U.S. Geological Survey during July 9–18, 2013, in support of longterm monitoring for natural attenuation. Groundwater samples were collected from 13 wells and 9 piezometers, as well as from 10 shallow groundwater passive-diffusion sampling sites in the nearby marsh. Samples from all wells and piezometers were analyzed for oxidation-reduction (redox) sensitive constituents and dissolved gases. Samples from all piezometers and four wells also were analyzed for CVOCs, as were all samples from the passive-diffusion sampling sites. In 2013, concentrations of redox-sensitive constituents measured at all wells and piezometers were consistent with those measured in previous years, with dissolved oxygen concentrations at all except an upgradient well 0.2 milligrams per liter or less; little to no detectable nitrate; abundant dissolved manganese, iron, and methane; and commonly detected sulfide. In the upper aquifer of the northern plantation in 2013, CVOC concentrations at all piezometers were similar to those measured in previous years, and concentrations of the reductive dechlorination byproducts ethane and ethene were slightly lower or the same as concentrations measured in 2012. In the upper aquifer of the southern plantation, CVOC concentrations measured in piezometers during 2013 continued to be variable as in previous years, and often very high, and reductive dechlorination byproducts were detected in two of the three wells and in all but one piezometer. Beneath the marsh adjacent to the southern plantation, chloroethene concentrations measured in 2013 continued to vary spatially and temporaly, and also were very high. Total CVOC concentrations, at what have been historically the most contaminated passive-diffusion sampler sites (S-4, S-4B, S-5, and S-5B) remained elevated. For the intermediate aquifer in 2013, concentrations of reductive dechlorination byproducts ethane and ethene and CVOCs were consistent with those measured in previous years.

Washington

Groundwater geochemical and selected volatile organic compound data, Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington, June 2011

Previous investigations indicate that concentrations of chlorinated volatile organic compounds are substantial in groundwater beneath the 9-acre former landfill at Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington. Phytoremediation combined with ongoing natural attenuation processes was the preferred remedy selected by the U.S. Navy, as specified in the Record of Decision for the site. The U.S. Navy planted two hybrid poplar plantations on the landfill in spring 1999 to remove and to control the migration of chlorinated volatile organic compounds in shallow groundwater. The U.S. Geological Survey has continued to monitor groundwater geochemistry to ensure that conditions remain favorable for contaminant biodegradation as specified in the Record of Decision. This report presents groundwater geochemical and selected volatile organic compound data collected at Operable Unit 1 by the U.S. Geological Survey during June 20-22, 2011, in support of long-term monitoring for natural attenuation. In 2011, groundwater samples were collected from 13 wells and 9 piezometers. Samples from all wells and piezometers were analyzed for redox sensitive constituents and dissolved gases, and samples from 5 of 13 wells and all piezometers also were analyzed for chlorinated volatile organic compounds. Concentrations of redox sensitive constituents measured in 2011 were consistent with previous years, with dissolved oxygen concentrations all at 0.4 milligram per liter or less; little to no detectable nitrate; abundant dissolved manganese, iron, and methane; and commonly detected sulfide. The reductive declorination byproducts - methane, ethane, and ethene - were either not detected in samples collected from the upgradient wells in the landfill and the upper aquifer beneath the northern phytoremediation plantation or were detected at concentrations less than those measured in 2010. Chlorinated volatile organic compound concentrations in 2011 at most piezometers were similar to or slightly less than chlorinated volatile organic compound concentrations measured in previous years. For the upper aquifer beneath the southern phytoremediation plantation, chlorinated volatile organic compound concentrations in 2011 in groundwater from the piezometers were extremely high and continued to vary considerably over space and between years. At piezometer P1-9, the total chlorinated volatile organic compound concentrations increased from 9,500 micrograms per liter in 2010 to more than 44,000 micrograms per liter in 2011. Total chlorinated volatile organic compound concentrations decreased at piezometers P1-6, P1-7, and P1-10 compared to the concentrations measured in 2010. One or both of the reductive dechlorination byproducts ethane and ethene were detected at all piezometers and three of the four wells in the southern plantation. For the intermediate aquifer, concentrations of redox sensitive constituents and chlorinated volatile organic compounds in 2011 were consistent with concentrations measured in previous years, with the exception of notable decreases in sulfate and chloride concentrations at well MW1-28. Concentrations of the reductive dechlorination byproducts ethane and ethene decreased at wells MW1-25 and MW1-28 compared to previously measured concentrations.

Washington

Sources and sinks of filtered total mercury and concentrations of total mercury of solids and of filtered methylmercury, Sinclair Inlet, Kitsap County, Washington, 2007-10

The majority of filtered total mercury in the marine water of Sinclair Inlet originates from salt water flowing from Puget Sound. About 420 grams of filtered total mercury are added to Sinclair Inlet each year from atmospheric, terrestrial, and sedimentary sources, which has increased filtered total mercury concentrations in Sinclair Inlet (0.33 nanograms per liter) to concentrations greater than those of the Puget Sound (0.2 nanograms per liter). The category with the largest loading of filtered total mercury to Sinclair Inlet included diffusion of porewaters from marine sediment to the water column of Sinclair Inlet and discharge through the largest stormwater drain on the Bremerton naval complex, Bremerton, Washington. However, few data are available to estimate porewater and stormwater releases with any certainty. The release from the stormwater drain does not originate from overland flow of stormwater. Rather total mercury on soils is extracted by the chloride ions in seawater as the stormwater is drained and adjacent soils are flushed with seawater by tidal pumping. Filtered total mercury released by an unknown freshwater mechanism also was observed in the stormwater flowing through this drain. Direct atmospheric deposition on the Sinclair Inlet, freshwater discharge from creek and stormwater basins draining into Sinclair Inlet, and saline discharges from the dry dock sumps of the naval complex are included in the next largest loading category of sources of filtered total mercury. Individual discharges from a municipal wastewater treatment plant and from the industrial steam plant of the naval complex constituted the loading category with the third largest loadings. Stormwater discharge from the shipyard portion of the naval complex and groundwater discharge from the base are included in the loading category with the smallest loading of filtered total mercury. Presently, the origins of the solids depositing to the sediment of Sinclair Inlet are uncertain, and consequently, concentrations of sediments can be qualitatively compared only to total mercury concentrations of solids suspended in the water column. Concentrations of total mercury of suspended solids from creeks, stormwater, and even wastewater effluent discharging into greater Sinclair Inlet were comparable to concentrations of solids suspended in the water column of Sinclair Inlet. Concentrations of total mercury of suspended solids were significantly lower than those of marine bed sediment of Sinclair Inlet; these suspended solids have been shown to settle in Sinclair Inlet. The settling of suspended solids in the greater Sinclair Inlet and in Operable Unit B Marine of the naval complex likely will result in lower concentrations of total mercury in sediments. Such a decrease in total mercury concentrations was observed in the sediment of Operable Unit B Marine in 2010. However, total mercury concentrations of solids discharged from several sources from the Bremerton naval complex were higher than concentrations in sediment collected from Operable Unit B Marine. The combined loading of solids from these sources is small compared to the amount of solids depositing in OU B Marine. However, total mercury concentration in sediment collected at a monitoring station just offshore one of these sources, the largest stormwater drain on the Bremerton naval complex, increased considerably in 2010. Low methylmercury concentrations were detected in groundwater, stormwater, and effluents discharged from the Bremerton naval complex. The highest methylmercury concentrations were measured in the porewaters of highly reducing marine sediment in greater Sinclair Inlet. The marine sediment collected off the largest stormwater drain contained low concentrations of methylmercury in porewater because these sediments were not highly reducing.

Washington

Sediment Loading from Crab Creek and Other Sources to Moses Lake, Washington, 2007 and 2008

The average sediment-accumulation rate on the bed of Moses Lake since 1980, based on the identification of Mount St. Helens ash in lakebed cores, was 0.24 inches per year. Summed over the lake surface area, the average sediment-accumulation rate on the lakebed is 190,000 tons per year. Based on USGS stream-gaging station data, the average annual sediment load to Moses Lake from Crab Creek was 32,000 tons per year between 1943 and 2008; the post Mount St. Helens eruption annual load from Crab Creek was calculated to be 13,000 tons per year. The total mass input from Crab Creek and other fluvially derived sediment sources since 1980 has been about 20,000 tons per year. Eolian sediment loading to Moses Lake was about 50,000 tons per year before irrigation and land-use development largely stabilized the Moses Lake dune field. Currently, eolian input to the lake is less than 2,000 tons per year. Considering all sediment sources to the lake, most (from 80 to 90 percent) of post-1980 lakebed-sediment accumulation is from autochthonous, or locally formed, mineral matter, including diatom frustuals and carbonate shells, derived from biogenic production in phytoplankton and zooplankton. Suspended-sediment samples collected from Crab Creek and similar nearby waterways in 2007 and 2008 combined with other USGS data from the region indicated that a proposed Bureau of Reclamation supplemental feed of as much as 650 cubic feet per second through Crab Creek might initially contain a sediment load of as much as 1,500 tons per day. With time, however, this sediment load would decrease to about 10 tons per day in the sediment-supply-limited creek as available sediment in the channel is depleted. Sediment loads in the supplemental feed ultimately would be similar to loads in other bypass canals near Moses Lake. Considering the hydrology and geomorphology of the creek over multiple years, there is little evidence that the proposed supplemental feed would substantially increase the overall sediment load from Crab Creek to Moses Lake relative to natural, background conditions. Because Moses Lake is relatively shallow and subject to significant wind-driven circulation currents, mixing also would redistribute some of the fluvial sediment load deposited from Crab Creek throughout Parker Horn and the rest of Moses Lake, further mitigating the local effect of Crab Creek sedimentation near the City of Moses Lake.

Scientific Investigations Report

Hydrogeologic Framework, Groundwater Movement, and Water Budget in Tributary Subbasins and Vicinity, Lower Skagit River Basin, Skagit and Snohomish Counties, Washington

A study to characterize the groundwater-flow system in four tributary subbasins and vicinity of the lower Skagit River basin was conducted by the U.S. Geological Survey to assist Skagit County and the Washington State Department of Ecology in evaluating the effects of potential groundwater withdrawals and consumptive use on tributary streamflows. This report presents information used to characterize the groundwater and surface-water flow system in the subbasins, and includes descriptions of the geology and hydrogeologic framework of the subbasins; groundwater recharge and discharge; groundwater levels and flow directions; seasonal groundwater-level fluctuations; interactions between aquifers and the surface-water system; and a water budget for the subbasins. The study area covers about 247 mi2 along the Skagit River and its tributary subbasins (East Fork Nookachamps Creek, Nookachamps Creek, Carpenter Creek, and Fisher Creek) in southwestern Skagit County and northwestern Snohomish County, Washington. The geology of the area records a complex history of accretion along the continental margin, mountain building, deposition of terrestrial and marine sediments, igneous intrusion, and the repeated advance and retreat of continental glaciers. A simplified surficial geologic map was developed from previous mapping in the area, and geologic units were grouped into nine hydrogeologic units consisting of aquifers and confining units. A surficial hydrogeologic unit map was constructed and, with lithologic information from 296 drillers'logs, was used to produce unit extent and thickness maps and four hydrogeologic sections. Groundwater in unconsolidated aquifers generally flows towards the northwest and west in the direction of the Skagit River and Puget Sound. This generalized flow pattern is likely complicated by the presence of low-permeability confining units that separate discontinuous bodies of aquifer material and act as local groundwater-flow barriers. Groundwater-flow directions in the sedimentary aquifer likely reflect local topographic relief (radial flow from bedrock highs) and more regional westward flow from the mountains to the Puget Sound. The largest groundwater-level fluctuations observed during the monitoring period (October 2006 through September 2008) occurred in wells completed in the sedimentary aquifer, and ranged from about 3 to 27 feet. Water levels in wells completed in unconsolidated hydrogeologic units exhibited seasonal variations ranging from less than 1 to about 10 feet. Synoptic streamflow measurements made in August 2007 and June 2008 indicate a total groundwater discharge to creeks in the tributary subbasin area of about 13.15 and 129.6 cubic feet per second (9,520 and 93,830 acre-feet per year), respectively. Streamflow measurements illustrate a general pattern in which the upper reaches of creeks in the study area tended to gain flow from the groundwater system, and lower creek reaches tended to lose water. Large inflows from tributaries to major creeks in the study area suggest the presence of groundwater discharge from upland areas underlain by bedrock. The groundwater system within the subbasins received an average (September 1, 2006 to August 31, 2008) of about 92,400 acre-feet or about 18 inches of recharge from precipitation a year. Most of this recharge (65 percent) discharges to creeks, and only about 3 percent is withdrawn from wells. The remaining groundwater recharge (32 percent) leaves the subbasin groundwater system as discharge to the Skagit River and Puget Sound.

Scientific Investigations Report

Conceptual Model of Hydrologic and Thermal Conditions of the Eastbank Aquifer System near Rocky Reach Dam, Douglas County, Washington

The Lower and Combined Aquifers of the Eastbank Aquifer system, located in a river-terrace deposit along the Columbia River near Rocky Reach Dam, Washington, are primarily recharged by the Columbia River and provide water to the Eastbank Hatchery and the regional water system servicing the cities of Wenatchee, East Wenatchee, and parts of unincorporated Chelan and Douglas Counties. In 2006, mean annual pumpage from the aquifers by the hatchery and regional water system was about 43 and 16 cubic feet per second, respectively. Reportedly, temperatures of ground water pumped by the hatchery have been increasing, thereby making water potentially too warm for salmonid fish production. An evaluation of hourly ground-water and river temperatures from January 1991 through August 2007 indicates increasing interannual trends in temperatures in most of the Lower and Combined Aquifers from 1999 through 2006 that correspond to increasing trends in the annual mean and annual maximum river temperatures during the same period of 0.07 and 0.17?C per year, respectively. There were no trends in the annual minimum river temperatures from 1999 through 2006, and there were no trends in the annual minimum, mean, and maximum river temperatures from 1991 through 1998 and from 1991 through 2007. Increases in river temperatures from 1999 through 2006 are within the natural variability of the river temperatures. Most of the Lower and Combined Aquifers reached thermal equilibrium?defined by constant time lags between changes in river temperatures and subsequent changes in ground-water temperatures?during 1991?98. The only exceptions are the Combined Aquifer north of the well field of the regional water system, which had not reached thermal equilibrium by 2006, and the Lower Aquifer west of the well fields of the hatchery and the regional water system, which reached thermal equilibrium prior to 1991. Because most of the Lower and Combined Aquifers were in thermal equilibrium from 1999 through 2006 and seasonal pumpage patterns were relatively stable, reported trends of increasing temperatures of water pumped by the hatchery well field are most likely explained by increasing trends in river temperatures. Most of the water pumped by the hatchery well field recharges in an area west to southwest of the well field about 2 months prior to the time it is pumped from the aquifer. The northern extent of the hatchery well field may pump some colder water from a bedrock depression to the north and west of the well field. The conceptual model of hydrologic and thermal conditions is supported by analyses of historical water temperatures, water-level data collected on July 18, 2007, and dissolved-constituent and bacterial concentrations in samples collected on August 20?22, 2007.

Scientific Investigations Report

Occurrence, distribution, and transport of pesticides in agricultural irrigation-return flow from four drainage basins in the Columbia Basin Project, Washington, 2002-04, and comparison with historical data

Water-quality samples were collected from sites in four irrigation return-flow drainage basins in the Columbia Basin Project from July 2002 through October 2004. Ten samples were collected throughout the irrigation season (generally April through October) and two samples were collected during the non-irrigation season. Samples were analyzed for temperature, pH, specific conductance, dissolved oxygen, major ions, trace elements, nutrients, and a suite of 107 pesticides and pesticide metabolites (pesticide transformation products) and to document the occurrence, distribution, and pesticides transport and pesticide metabolites. The four drainage basins vary in size from 19 to 710 square miles. Percentage of agricultural cropland ranges from about 35 percent in Crab Creek drainage basin to a maximum of 75 percent in Lind Coulee drainage basin. More than 95 percent of cropland in Red Rock Coulee, Crab Creek, and Sand Hollow drainage basins is irrigated, whereas only 30 percent of cropland in Lind Coulee is irrigated. Forty-two pesticides and five metabolites were detected in samples from the four irrigation return-flow drainage basins. The most compounds detected were in samples from Sand Hollow with 37, followed by Lind Coulee with 33, Red Rock Coulee with 30, and Crab Creek with 28. Herbicides were the most frequently detected pesticides, followed by insecticides, metabolites, and fungicides. Atrazine, bentazon, diuron, and 2,4-D were the most frequently detected herbicides and chlorpyrifos and azinphos-methyl were the most frequently detected insecticides. A statistical comparison of pesticide concentrations in surface-water samples collected in the mid-1990s at Crab Creek and Sand Hollow with those collected in this study showed a statistically significant increase in concentrations for diuron and a statistically significant decrease for ethoprophos and atrazine in Crab Creek. Statistically significant increases were in concentrations of bromacil, diuron, and pendimethalin at Sand Hollow and statistically significant decreases were in concentrations of 2,6-diethylanaline, alachlor, atrazine, DCPA, and EPTC. A seasonal Kendall trend test on data from Lind Coulee indicated no statistically significant trends for any pesticide for 1994 through 2004. A comparison of pesticide concentrations detected in this study with those detected in previous U.S. Geological Survey National Water-Quality Assessment studies of the Central Columbia Plateau, Yakima River basin, and national agricultural studies indicated that concentrations in this study generally were in the middle to lower end of the concentration spectrum for the most frequently detected herbicides and insecticides, but that the overall rate of detection was near the high end. Thirty-one of the 42 herbicides, insecticides, and fungicides detected in surface-water samples were applied to the major agricultural crops in the drainage basins, and 11 of the detected pesticides are sold for residential application. Eight of the pesticides detected in surface-water samples were not reported as having any agricultural or residential use. The overall pattern of pesticide use depends on which crops are grown in each drainage basin. Drainage basins with predominantly more orchards have higher amounts of insecticides applied, whereas basins with larger percentages of field crops tend to have more herbicides applied. Pesticide usage was most similar in Crab Creek and Sand Hollow, where the largest total amounts applied were the insecticides azinphos-methyl, carbaryl, and chlorpyrifos and the herbicide EPTC. In Red Rock Coulee basin, DCPA was the most heavily applied herbicide, followed by the fungicide chlorothalonil, the herbicide EPTC, and the insecticides chlorpyrifos and azinphos-methyl. In Lind Coulee, which has a large percentage of dryland agricultural area, the herbicides 2,4-D and EPTC were applied in the largest amount, followed by the fungicide chlorothalonil. The

Scientific Investigations Report

Freshwater and saline loads of dissolved inorganic nitrogen to Hood Canal and Lynch Cove, western Washington

Hood Canal is a long (110 kilometers), deep (175 meters) and narrow (2 to 4 kilometers wide) fjord of Puget Sound in western Washington. The stratification of a less dense, fresh upper layer of the water column causes the cold, saltier lower layer of the water column to be isolated from the atmosphere in the late summer and autumn, which limits reaeration of the lower layer. In the upper layer of Hood Canal, the production of organic matter that settles and consumes dissolved oxygen in the lower layer appears to be limited by the load of dissolved inorganic nitrogen (DIN): nitrate, nitrite, and ammonia. Freshwater and saline loads of DIN to Hood Canal were estimated from available historical data. The freshwater load of DIN to the upper layer of Hood Canal, which could be taken up by phytoplankton, came mostly from surface and ground water from subbasins, which accounts for 92 percent of total load of DIN to the upper layer of Hood Canal. Although DIN in rain falling on land surfaces amounts to about one-half of the DIN entering Hood Canal from subbasins, rain falling directly on the surface of marine waters contributed only 4 percent of the load to the upper layer. Point-source discharges and subsurface flow from shallow shoreline septic systems contributed less than 4 percent of the DIN load to the upper layer. DIN in saline water flowing over the sill into Hood Canal from Admiralty Inlet was at least 17 times the total load to the upper layer of Hood Canal. In September and October 2004, field data were collected to estimate DIN loads to Lynch Cove - the most inland marine waters of Hood Canal that routinely contain low dissolved-oxygen waters. Based on measured streamflow and DIN concentrations, surface discharge was estimated to have contributed about one-fourth of DIN loads to the upper layer of Lynch Cove. Ground-water flow from subbasins was estimated to have contributed about one-half of total DIN loads to the upper layer. In autumn 2004, the relative contribution of DIN from shallow shoreline septic systems to the upper layer was higher in Lynch Cove (23 percent) than in the entire Hood Canal. Net transport of DIN into Lynch Cove by marine currents was measured during August and October 2004-a time of high biological productivity. The net transport of lower-layer water into Lynch Cove was significantly diminished relative to the flow entering Hood Canal at its entrance. Even though the net transport of saline water into the lower layer of Lynch Cove was only 119 cubic meters per second, estuarine currents between 33 and 47 m were estimated to have carried more than 35 times the total freshwater load of DIN to the upper layer from surface and ground water, shallow shoreline septic systems, and direct atmospheric rainfall. The subsurface maximums in measured turbidity, chlorophyll a, particulate organic carbon, and particulate organic nitrogen strongly suggest that the upward mixing of nitrate-rich deeper water is a limiting factor in supplying DIN to the upper layer that enhances marine productivity in Lynch Cove. The presence of phosphate in the upper layer in the absence of dissolved inorganic nitrogen also suggests that the biological productivity that leads to low dissolved-oxygen concentrations in the lower layer of Lynch Cove is limited by the supply of nitrogen rather than by phosphate loads. Although the near-shore zones of the shallow parts of Lynch Cove were sampled, a biogeochemical signal from terrestrial nitrogen was not found. Reversals in the normal estuarine circulation suggest that if the relative importance of the DIN load of freshwater terrestrial and atmospheric sources and the DIN load from transport of saline water by the estuarine circulation in controlling dissolved-oxygen concentrations in Lynch Cove is to be better understood, then the physical forces driving Hood Canal circulation must be better defined.

Scientific Investigations Report

Comparison of passive diffusion bag samplers and submersible pump sampling methods for monitoring volatile organic compounds in ground water at Area 6, Naval Air Station, Whidbey Island, Washington

Ground-water samples were collected in April 1999 at Naval Air Station Whidbey Island, Washington, with passive diffusion samplers and a submersible pump to compare concentrations of volatile organic compounds (VOCs) in water samples collected using the two sampling methods. Single diffusion samplers were installed in wells with 10-foot screened intervals, and multiple diffusion samplers were installed in wells with 20- to 40-foot screened intervals. The diffusion samplers were recovered after 20 days and the wells were then sampled using a submersible pump. VOC concentrations in the 10-foot screened wells in water samples collected with diffusion samplers closely matched concentrations in samples collected with the submersible pump. Analysis of VOC concentrations in samples collected from the 20- to 40-foot screened wells with multiple diffusion samplers indicated vertical concentration variation within the screened interval, whereas the analysis of VOC concentrations in samples collected with the submersible pump indicated mixing during pumping. The results obtained using the two sampling methods indicate that the samples collected with the diffusion samplers were comparable with and can be considerably less expensive than samples collected using a submersible pump.

Water-Resources Investigations Report