Geology topics

R.L. Kuzniar

Publications and source records attributed to R.L. Kuzniar.

8 recordsLinked to original sources

USGS2009

Bear Spray Safety Program

A bear spray safety program for the U.S. Geological Survey (USGS) was officially initiated by the Firearms Safety Committee to address accident prevention and to promote personnel training in bear spray and its transportation, storage, and use for defense against wild animals. Used as part of a system including firearms, or used alone for those who choose not to carry a firearm, bear spray is recognized as an effective tool that can prevent injury in a wild animal attack.

Fact Sheet↗

USGS2007

Herbicide and nitrate variation in alluvium underlying a cornfield at a site in Iowa County, Iowa

A hydrologic investigation to determine vertical and seasonal variation of atrazine, alachlor, cyanazine, and nitrate at one location and to relate the variation to ground-water movement in the Iowa River alluvium was conducted in Iowa County, Iowa, from March 1986 to December 1987. Water samples were collected at discrete intervals through the alluvial sequence from the soil zone to the base of the aquifer. Alachlor, atrazine, and cyanazine were detected most frequently in the soil zone but also were present in the upper part of the alluvial aquifer. Alachlor was detected sporadically, whereas, atrazine, cyanazine, and nitrate were present throughout the year. In the alluvial aquifer, the herbicides generally were not detected during 1986 and were present in detectable concentrations for only a short period of time in the upper 1.6 meters of the aquifer during 1987. Nitrate was present throughout the alluvium and was stratified in the alluvial aquifer. The largest nitrate concentrations were detected in the middle part of the aquifer. Nitrate concentrations were variable only in the upper 2 meters of the aquifer. Vertical movement of herbicides and nitrate in the soil correlated with precipitation and degree of saturation. A clay layer retarded vertical movement of atrazine but not nitrate from the soil layer to the aquifer. Vertical movement could not account for the chemical variation in the alluvial aquifer.

Iowa↗

USGS1999

Selected hydrologic data from the Cedar Rapids area, Linn County, Iowa, April 1996 through March 1999

The City of Cedar Rapids, Iowa obtains its municipal water supply from four well fields along the Cedar River. The wells are completed at depths of about 60 to 80 feet in a shallow alluvial aquifer adjacent to the Cedar River. The City of Cedar Rapids and the U.S. Geological Survey have conducted a cooperative study of the groundwater flow system and water quality near the well fields since 1992. The purpose of this report is to document selected hydrologic data collected from April 1996 through March 1999. Data include the results of water-quality analyses, ground-waterlevels continuously measured with pressure transducers and data recorders, and physical properties continuously monitored using multiprobe instruments. Water-quality samples were collected from selected wells and the Cedar River to conduct periodic monitoring, to evaluate ground-water geochemistry, to assess the occurrence of pesticides and herbicide degradates in the alluvial aquifer, and to characterize water quality in shallow ground water near a wetland area in the Seminole Well Field. Types of water-quality analyses included common ions (calcium, chloride, iron, magnesium, manganese, potassium, silica, sodium, and sulfate), trace elements (boron, bromide, and fluoride), nutrients (ammonia as nitrogen, nitrite as nitrogen, nitrite plus nitrate as nitrogen, and orthophosphate as phosphorus), dissolved organic carbon, and selected pesticides and herbicide degradates. Ground-water levels in selected observation wells were continuously measured to assess temporal trends in groundwater levels in the alluvial aquifer and bedrock aquifer, to help calibrate a ground-water flow model being constructed to simulate local groundwater flow under transient conditions near the well fields, and to assess hydrologic conditions near a wetland area in the Seminole Well Field. Physical properties (specific conductance, pH, dissolved oxygen, and water temperature) were continuously monitored to assess temporal variation and to help evaluate the interaction between the Cedar River and ground water in the alluvial aquifer.

Iowa↗

USGS1995

Hydrogeology and water quality of the Mississippi River alluvium near Muscatine, Iowa, June 1992 through June 1994

A study of the Mississippi River alluvium near Muscatine, Iowa, was conducted to evaluate ground-water flow and water quality using data collected from June 1992 through June 1994. The study area included approximately 80 square miles in parts of Muscatine and Louisa Counties in Iowa and Rock Island and Mercer Counties in Illinois. A steady-state, ground-water flow model was constructed using February 1993 hydrologic conditions. Model results indicate that drawdown in the lower alluvium caused by the pumping centers in Iowa extends beneath the Muscatine Slough in the northwest part of the study area and beneath the Mississippi River in the central and northern parts of the area. The primary sources of ground water in the alluvium are recharge from precipitation, leakage from the Mississippi River, and infiltration of upland runoff. The bedrock is not a major contributor of ground water to the alluvium. The areal distribution of selected water-quality properties and constituents in ground water results from several factors. Localized large chloride and nitrite-plus-nitrate nitrogen concentrations could be indicative of contamination from human activity. Specific conductance and calcium, magnesium, and sulfate concentrations are larger in ground water near the boundary between the river valley and upland area and could result from infiltration of upland runoff or lithologic differences in the alluvium. Large iron or manganese concentrations occur in the ground water near the Mississippi River and Muscatine Slough that result from microbial processes and the presence of dissolved organic carbon. Temporal variations of concentrations for selected water-quality constituents in groundwater samples attest to the dynamic nature of the ground-water system as it responds to natural and human-induced changes in water quality. Leakage from the Mississippi River affects ground-water quality in the alluvium adjacent to the river. Temporal variations in water quality of the Mississippi River can be caused by seasonally, amount of discharge, or upstream human activities. The quality of ground water induced from discrete zones of the alluvium by the pumping centers in Iowa has implications for the entire ground-water resource. The ground-water flow model calculated that 10 percent of the water that enters the zone of active pumping on the Iowa side of the Mississippi River originates from the zone west and north of Muscatine Slough, and that 5.2 percent originates from the zone on the Illinois side of the Mississippi River east of the center of the river channel.

Illinois, Iowa↗

USGS1994

Hydrologic data for the Big Spring basin, Clayton County, Iowa, water year 1991

Hydrologic data were collected in the Big Spring Basin located in Clayton County, Iowa, during the 1991 water year. The data were collected by the U.S. Geological Survey in cooperation with the Iowa Department of Natural Resources, Geological Survey Bureau, to provide information on variation and movement of agricultural chemicals in the hydrologic cycle in the basin. Precipitation, surface-water, and ground-water data were collected. The largest amount of rainfall during water year 1991 (54.69 inches) was measured at the monitoring site on Unnamed Creek near Luana. The largest monthly rainfall (14.72 inches) occurred in June. Analyses of 39 rain samples indicated that calcium and sulfate were the predominant ions and that median concentrations of nitrate and ammonia as nitrogen were 0.36 and 0.49 mg/L (milligrams per liter), respectively. Stream discharge, specific conductance, pH, and water temperature were monitored continuously, and monthly water-quality samples were collected at a site on Roberts Creek and at Big Spring. Nitrite plus nitrate as nitrogen concentrations in 27 samples from Roberts Creek at the point where it leaves the study area ranged from 1.8 to 22 mg/L. Herbicide concentrations in 26 samples from the Roberts Creek site ranged from less than 0.10 μ g/L (micrograms per liter) to 43 μ g/L. Alachlor was detected in 42 percent of the samples; atrazine in 92 percent; and cyanazine and metolachlor in 35 percent of the samples. The total suspended-sediment load discharged in Roberts Creek was about 160,000 tons. At Big Spring, the ground-water discharge point, the daily mean specific conductance ranged from 414 to 788 microsiemens per centimeter at 25 degrees Celsius, the daily median pH ranged from 6.7 to 7.1, and the daily mean water temperature ranged from 8.5 to 13.0 degrees Celsius. Concentrations of nitrite plus nitrate as nitrogen in 23 samples ranged from 4.2 to 17 mg/L. The total measured suspended-sediment discharged from Big Spring was about 17,000 tons. Alachlor was detected in 26 percent; atrazine in 100 percent; cyanazine in 26 percent, and metolachlor in 9 percent of the samples. The maximum atrazine concentration was 16 μ g/L.

Iowa↗

USGS1992

Hydrologic data for the Big Spring basin, Clayton County, Iowa, water year 1990

Hydrologic data were collected in the Big Spring basin located in Clayton County, Iowa, during the 1990 water year. The data were collected by the U.S. Geological Survey in cooperation with the Iowa Department of Natural Resources, Geological Survey Bureau, to provide information on variation and movement of agricultural chemicals in the hydrologic cycle in the basin. Precipitation, surface-water, and ground-water data were collected. Rainfall recorded during water year 1990 at a monitoring site on Roberts Creek totaled 43.67 inches. The greatest monthly rainfall (14.45 inches) occurred in August. Calcium and sulfate were the predominant ions in the rain, and the median concentrations of nitrate and ammonia as nitrogen were 0.35 and 0.48 milligrams per liter, respectively. Stream discharge, specific conductance, pH, and water temperature were monitored continuously, and monthly water-quality samples were collected at three sites in the basin. The predominant ions in samples from Roberts Creek at the point where it leaves the basin were calcium, magnesium, and bicarbonate. Nitrite plus nitrate as nitrogen concentrations in 42 samples ranged from less than 0.10 to 18 milligrams per liter. Pesticide concentrations in 34 samples ranged from less than 0.10 to 12 micrograms per liter. Alachlor was detected in 56 percent of the samples; atrazine in 100 percent; cyanazine in 68 percent; and metolachlor in 47 percent. At Big Spring, the ground-water discharge point, the daily mean specific conductance ranged from 378 to 796 microsiemens per centimeter at 25 degrees Celsius, the daily median pH ranged from 6.5 to 7.2, and the daily mean water temperature ranged from 5.5 to 11.5 degrees Celsius. Calcium, magnesium, and bicarbonate generally were the predominant ions in solution. Concentrations of nitrite plus nitrate as nitrogen in 32 samples ranged from 3.4 to 16 milligrams per liter. Alachlor was detected in 22 percent of the samples; atrazine in 100 percent; cyanazine in 44 percent, and metplachlor in 6 percent. The maximum atrazine concentration was 4.5 micrograms per liter. During a low-flow seepage study, May 29 and 30,1990, the measured discharge lost by streams in the basin was 8.56 cubic feet per second, the measured dissolved nitrogen load lost was 0.29 ton per day, and the measured atrazine load lost was 0.028 pound per day. The total measured discharge and total dissolved nitrogen load leaving the basin in streams were 3.63 cubic feet per second and about 0.04 ton per day, respectively.

Iowa↗

USGS1991

Hydrologic data for the Big Spring basin, Clayton County, Iowa; water year 1989

Hydrologic data were collected in the Big Spring Basin located in Clayton County, Iowa, during the 1989 water year. The data were collected in cooperation with the Iowa Department of Natural Resources, Geological Survey Bureau, to provide information on variation and movement of agricultural chemicals in the hydrologic cycle in the Big Spring Basin. Precipitation, stream, and ground-water data were collected. Total rainfall in the basin ranged from 20.0 to 24.4 inches. The greatest monthly rainfall was in August. Calcium and sulfate were the predominant ions in the rain and the median nitrate and ammonia concentrations as nitrogen were 0.40 and 0.63 mg/L (milligrams per liter), respectively. Stream discharge, water temperature, specific conductance, and pH were monitored continuously, and monthly water-quality samples were collected at three sites in the basin. The predominant ions in Roberts Creek, at the site where it leaves the basin, were calcium, magnesium, and bicarbonate. Nitrate plus nitrite as nitrogen concentrations ranged from 0.2 to 6.2 mg/L. Pesticide concentrations in 23 samples ranged from less than 0.10 μ /L (micrograms per liter) to 4.4 μ /L. Atrazine was detected in 100 percent of the samples, cyanazine and metolachlor in 43 percent of the samples and alachlor in 35 percent of the samples. At Big Spring, the ground-water discharge point, the daily mean water temperature ranged from 5.1 to 10.6 degrees Celsius, the daily mean specific conductance ranged from 271 to 793 micro Siemens per centimeter at 25 degrees Celsius, and the daily median pH ranged from 63 to 7.1. Calcium, magnesium, and bicarbonate were the predominant ions in solution. Nitrate plus nitrite as nitrogen concentrations ranged from 2.0 to 7.4 mg/L. Atrazine was detected in 95 percent of the samples, cyanazine was detected in 26 percent of the samples, and metolachlor and alachlor were detected in 16 percent of the samples. The maximum atrazine concentration was 3.3 μ /L. Water levels in the unconsolidated aquifers and the Galena aquifer were highest in the spring after snowmelt and in September after the greatest monthly rainfall. Water levels in the Saint Peter aquifer declined by approximately 0 J to 3.0 feet. During a baseflow seepage study, August 16 and 17, the measured discharge lost by streams in the basin was 2.82 cubic feet per second, the measured dissolved nitrogen load lost was 80 pounds per day, and the measured atrazine load lost was 0.002 pound per day. The total measured discharge and total dissolved nitrogen load leaving the basin in streams was 0.07 cubic feet per second and less than 20 pounds per day, respectively.

Iowa↗

USGS1988

Occurrence and distribution of nitrate and herbicides in the Iowa River alluvial aquifer, Iowa: May 1984 to November 1985

From May 1984 to November 1985, the U.S. Geological Survey, in cooperation with the University of Iowa Hygienic Laboratory and the Iowa Department of Natural Resources, Geological Survey Bureau, investigated nitrate and herbicides in the Iowa River alluvial aquifer. The occurrence and distribution of nitrate and selected herbicides were determined in the Iowa River alluvial aquifer, a sand and gravel aquifer beneath agricultural land along the Iowa River in Iowa County, Iowa. Test drilling and water-quality sampling of the aquifer indicated that the areal distribution of nitrate in the aquifer is variable. Nitrate (as nitrogen) concentrations range from less than 0.10 to 79 milligrams per liter. Although nitrate distribution is variable, extensive aquifer contamination by nitrate is not apparent. Median nitrate concentrations were 5.9 milligrams per liter for municipal wells and 7.2 milligrams per liter for area streams, but were less than 2.0 milligrams per liter for test wells and domestic wells. Atrazine, cyanazine, metribuzin, alachlor, metolachlor, and trifluralin were detected in ground-water samples. Maximum concentration of atrazine in ground-water samples was 2.4 micrograms per liter; maximum concentration of metribuzin was 8.1 micrograms per liter. Area streams also contained herbicides in concentrations generally larger than concentrations in ground water. At a municipal well adjacent to a stream, similar seasonal concentrations of atrazine were detected for both ground- and surface-water samples. Surface water sometimes may be a source of nitrate and herbicides to adjacent ground water. Detailed sampling of vertical profiles using well nests indicated that the distribution of nitrate and selected herbicides is not vertically homogeneous. Generally, larger nitrate concentrations were detected at shallow depths in the aquifer; at greater depths, the nitrate concentrations were near the detection limit. Herbicides were detected in a pattern similar to that determined for nitrate. The true areal distribution of nitrate may be masked by inconsistent depths of sampling or incomplete vertical sampling. Variations in nitrate concentrations with depth possibly are because local aquifer flow is predominantly horizontal and may limit significant vertical dispersion of nitrate and herbicides, and because nitrate may not act conservatively in ground water and may be removed from the system by denitrification. For nested wells, the seasonal variations of nitrate and herbicides were greater at the shallower sampling depths for domestic and test wells. Seasonal variations of nitrate and herbicides illustrate that these constituents move quickly from surface application to shallow underlying aquifers. These constituents can be detected in ground water soon after chemical applications, usually within 6 weeks.

Iowa↗