R.H. McNutt | Search USGS

USGS2006

Grenvillian magmatism in the northern Virginia Blue Ridge: Petrologic implications of episodic granitic magma production and the significance of postorogenic A-type charnockite

Grenvillian (1.2 to 1.0 Ga) plutonic rocks in northern Virginia preserve evidence of episodic, mostly granitic magmatism that spanned more than 150 million years (m.y.) of crustal reworking. Crystallization ages determined by sensitive high resolution ion microprobe (SHRIMP) U-Pb isotopic analyses of zircon and monazite, combined with results from previous studies, define three periods of magmatic activity at 1183-1144 Ma (Magmatic Interval I), 1120-1111 Ma (Magmatic Interval II), and 1078-1028 Ma (Magmatic Interval III). Magmatic activity produced dominantly tholeiitic plutons composed of (1) low-silica charnockite, (2) leucogranite, (3) non-leucocratic granitoid (with or without orthopyroxene (opx)), and (4) intermediate biotite-rich granitoid. Field, petrologic, geochemical, and geochronologic data indicate that charnockite and non-charnockitic granitoids were closely associated in both space and time, indicating that presence of opx is related to magmatic conditions, not metamorphic grade. Geochemical and Nd isotopic data, combined with results from experimental studies, indicate that leucogranites (Magmatic Intervals I and III) and non-leucocratic granitoids (Magmatic Intervals I and II) were derived from parental magmas produced by either a high degree of partial melting of isotopically evolved tonalitic sources or less advanced partial melting of dominantly tonalitic sources that also included a more mafic component. Post-orogenic, circa 1050 Ma low-silica charnockite is characterized by A-type compositional affinity including high FeOt/(FeOt + MgO), Ga/Al, Zr, Nb, Y, and Zn, and was derived from parental magmas produced by partial melting of potassic mafic sources in the lower crust. Linear geochemical trends defined by leucogranites, low-silica charnockite, and biotite-rich monzogranite emplaced during Magmatic Interval III reflect differences in source-related characteristics; these features do not represent an igneous fractionation sequence. A compositional gap between circa 1160 Ma magnesian low-silica charnockite and penecontemporaneous higher silica lithologies likewise precludes a fractionation relationship among plutons intruded during Magmatic Interval I. Correspondence in timing of magmatic activity between the Blue Ridge and neighboring Mesoproterozoic terranes underscores the widespread nature of Grenvillian processes in the region.

Precambrian Research↗

USGS1992

Ground water chemistry and geochemical modeling of water-rock interactions at the Osamu Utsumi mine and the Morro do Ferro analogue study sites, Poços de Caldas, Minas Gerais, Brazil

Surface and ground waters, collected over a period of three years from the Osamu Utsumi uranium mine and the Morro do Ferro thorium/rare-earth element (Th/REE) deposits, were analyzed and interpreted to identify the major hydrogeochemical processes. These results provided information on the current geochemical evolution of ground waters for two study sites within the Poços de Caldas Natural Analogue Project. The ground waters are a K–Fe–SO 4 –F type, a highly unusual composition related to intense weathering of a hydrothermally altered and mineralized complex of phonolites. Tritium and stable isotope data indicate that ground waters are of meteoric origin and are not affected significantly by evaporation or water–rock interactions. Recharging ground waters at both study sites demonstrate water of less than about 35 years in age, whereas deeper, more evolved ground waters are below 1 TU but still contain in most cases detectable tritium. These deeper ground waters may be interpreted as being of 35 to 60 or more years in age, resulting mainly from an admixture of younger with older ground waters and/or indicating the influence of subsurface produced tritium. Geochemical processes involving water–rock–gas interactions have been modeled using ground water compositions, mineralogic data, ion plots and computations of speciation, non-thermodynamic mass balance and thermodynamic mass transfer. The geochemical reaction models can reproduce the water chemistry and mineral occurrences and they were validated by comparing the results of thermodynamic mass transfer calculations (using the PHREEQE program, Parkhurst et al., 1980). The results from the geochemical reaction models reveal that the dominant processes are production of CO 2 in the soil zone through aerobic decay of organic matter, dissolution of fluorite, calcite, K-feldspar, albite, chlorite and manganese oxides, oxidation of pyrite and sphalerite, and precipitation of ferric oxides, silica and kaolinite. Gibbsite precipitation can be modeled for the shallow (recharge) water chemistry at Morro do Ferro, consistent with known mineralogy. Recharge waters are undersaturated with respect to barite and discharging waters and deeper ground waters are saturated to supersaturated with respect to barite demonstrating a strong solubility control. Strontium isotope data demonstrate that sources other than calcium-bearing minerals are required to account for the dissolved strontium in the ground waters. These may include K-feldspar, smectite–chlorite mixed-layer clays and goyazite [SrAl 3 (PO 4 ) 2 (OH) 5 • H 2 O]. 1992.

Journal of Geochemical Exploration↗