Kentucky ground-water quality
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Geology topics
Publications and source records attributed to R. W. Davis.
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Eight test holes were core-drilled from various altitudes in a typical coal-bearing sequence rocks of Pennsylvania age in Pike County, eastern Kentucky. Vertical fractures were common in cores from shallow depths, but became less common or absent toward the bottom of two test holes drilled 400 and 291 ft deep. Most fractures readily injected water, and near the bottoms of the two deep holes, coal beds accepted water in the non-fractured rocks. Rhodamin-WT dye was injected in a 61-ft deep ridge-top well on October 24, 1985 and was detected in varying concentrations in water samples taken from all down-gradient piezometers at the study site on November 7, 1985. The presence of dye in down-gradient piezometers indicated that groundwater in the Eastern Kentucky coal field can move from areas of higher head to areas of lower head. The movement probably occurs in a stair-step fashion through a complex system of near-vertical fractures, and laterally through permeable rocks, which probably are the coal beds. This suggests that land uses on ridges could affect the quality of water from wells or springs at lower altitudes on hillsides or in the valley bottoms even though separated by a thick interval of rocks that include beds of low primary permeability. (Author 's abstract)
Oil shales in Kentucky are rocks of predominantly Devonian age. The most prominant are the Ohio, Chattanooga, and New Albany Shales. A leaching study was done on six fresh oil shale samples and one retorted oil shale sample. Leaching reagents were distilled water, 0.0005 N sulfuric acid, and 0.05 N sulfuric acid. The concentration of constituents in the leachates were highly variable. The concentration of sodium, manganese, and zinc in the retorted shale leachate was several orders of magnitude higher than those of the leachates of fresh shale samples. The major oil shale outcrop covers approximately 1,000 square miles in a horseshoe pattern from Vanceburg, Lewis County , in the east, to Louisville, Jefferson County, in the west. The Kentucky, Red, and Licking Rivers cross the outcrop belt, the Rolling Fork River flows along the strike of the shale in the southwest part of the outcrop, and the Ohio River flows past the outcrop at the ends of the horseshoe. Oil shale does not appear to significantly alter the water quality of these streams. Oil shale is not an aquifer, but seeps and springs found in the shale indicate that water moves through it. Ground water quality is highly variable. (USGS)
The report reviews and summarizes 10,578 chemical analyses, from 2,362 wells and springs in Kentucky. These water-quality data were collected prior to September 30, 1981, and are available in computer files of the U.S. Geological Survey. The principal water-bearing rocks in Kentucky were combined into 10 major groups to aid in data summary preparation and general description of the ground-water quality of the State. Ground water in Kentucky is generally fresh near the outcrop of the rocks comprising the aquifer. Slightly saline to briny water occurs at variable depths beneath the freshwater. Preparation of quadrilinear diagrams revealed three principal geochemical processes in the aquifers of Kentucky: (1) mixing of freshwater and saline water in an interface zone; (2) dedolomitization of the Devonian and Silurian and Lower Mississippian carbonate rocks; (3) sodium for calcium exchange in the freshwater sections of many of the sandstone-shale aquifers. A number of errors and deficiencies were found in the data base. The principal deficiencies were: (1) very few complete analyses which included important field measurements; (2) inadequate definition of the chemistry of the freshwater-saline water interface zone throughout much of the State; (3) no analyses of stable isotopes and dissolved gases; (4) fewer than 10 analyses of most trace metals, radionuclides, and man-made organic chemicals; and (5) no data on bacteria in ground water from any aquifer in the State. (USGS)
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A well in the Ohio River alluvium at Louisville, Ky., has been yielding water with chloroform concentrations as high as 34.80 milligrams per liter since July 1975. A spill of 5,000 gallons of chloroform in 1970, 120 feet from the well, is probably the source of the contamination. The chloroform is adsorbed in the unsaturated zone in the alluvium; the greatest concentrations are presently at and slightly above the water table. Lesser amounts of carbon tetrachloride are found with the chloroform. Its source is unknown. The two contaminants were above the water table in the alluvium until a long-term trend of rising ground-water levels caused water to reach the contaminants and the water-chloroform mixture began moving downgradient to the well. High river stages cause a seasonal cycle of water-level rise, generally in late spring and midsummer; the ground water comes in contact with more chloroform and the chloroform concentration of the well water increases. No carbon tetrachloride has been observed in the well water.
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