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R. M. Tosdal

Publications and source records attributed to R. M. Tosdal.

At least 19 recordsLinked to original sources

Structural evidence for northeastward movement on the Chocolate Mountains Thrust, southeasternmost California

The Late Cretaceous Chocolate Mountains thrust of southeastern California and southwestern Arizona places a block of Proterozoic and Mesozoic continental crust over the late Mesozoic continental margin oceanic sedimentary and volcanic rocks of the regionally distinctive Orocopia Schist. The Chocolate Mountains thrust is interpreted as a thrust (burial, subduction) fault rather than a low-angle normal (exhumation, unroofing, uplift) fault. An important parameter required to understand the tectonic significance of the Chocolate Mountains and related thrusts is their sense of movement. The Chocolate Mountains thrust zone contains sparse to locally abundant mesoscopic asymmetric folds. Fabric relations, supported by regional geologic evidence, indicate that these folds are an integral part of and coeval with the thrust zone. On a lower hemisphere equal-area plot representing the orientation and sense of asymmetry of 80 thrust zone folds from 36 localities, spread over an area 60 by 10 km, Z folds plot northwest of and S folds plot southeast of a northeast-southwest striking vertical plane of overall monoclinic symmetry. The only sense of movement consistent with the collective asymmetry of the thrust zone folds is top to the northeast. Asymmetric microstructures studied at several localities also indicate top to the northeast movement. Paleomagnetic data suggest that the original sense of thrusting, prior to Neogene vertical axis tectonic rotation related to the San Andreas fault system, was northward. The essential point is that movement of the upper plate of the Chocolate Mountains thrust evidently was continentward. Continentward thrusting suggests a tectonic scenario in which an insular or peninsular microcontinental fragment collided with mainland southern California. The suture predicted by this model is elusive; but the Chocolate Mountains thrust and underlying Orocopia Schist themselves may represent the suture, at the present level of exposure. Alternative tectonic models involving subduction of the Orocopia Schist eastward beneath continental southern California circumvent the suture problem but are presently not supported by any direct structural evidence.

Journal of Geophysical Research

U-Pb (zircon) and geochemical constraints on the age, origin, and evolution of Paleozoic arc magmas in the Oyu Tolgoi porphyry Cu-Au district, southern Mongolia

Uranium–Pb (zircon) ages are linked with geochemical data for porphyry intrusions associated with giant porphyry Cu–Au systems at Oyu Tolgoi to place those rocks within the petrochemical framework of Devonian and Carboniferous rocks of southern Mongolia. In this part of the Gurvansayhan terrane within the Central Asian Orogenic Belt , the transition from Devonian tholeiitic marine rocks to unconformably overlying Carboniferous calc-alkaline subaerial to shallow marine volcanic rocks reflects volcanic arc thickening and maturation. Radiogenic Nd and Pb isotopic compositions ( ε Nd(t) range from + 3.1 to + 7.5 and 206 Pb/ 204 Pb values for feldspars range from 17.97 to 18.72), as well as low high-field strength element (HFSE) contents of most rocks (mafic rocks typically have < 1.5% TiO 2 ) are consistent with magma derivation from depleted mantle in an intra-oceanic volcanic arc. The Late Devonian and Carboniferous felsic rocks are dominantly medium- to high-K calc-alkaline and characterized by a decrease in Sr/Y ratios through time, with the Carboniferous rocks being more felsic than those of Devonian age. Porphyry Cu–Au related intrusions were emplaced in the Late Devonian during the transition from tholeiitic to calc-alkaline arc magmatism . Uranium–Pb (zircon) geochronology indicates that the Late Devonian pre- to syn-mineral quartz monzodiorite intrusions associated with the porphyry Cu–Au deposits are ~ 372 Ma, whereas granodiorite intrusions that post-date major shortening and are associated with less well-developed porphyry Cu–Au mineralization are ~ 366 Ma. Trace element geochemistry of zircons in the Late Devonian intrusions associated with the porphyry Cu–Au systems contain distinct Th/U and Yb/Gd ratios, as well as Hf and Y concentrations that reflect mixing of magma of distinct compositions. These characteristics are missing in the unmineralized Carboniferous intrusions. High Sr/Y and evidence for magma mixing in syn- to late-mineral intrusions distinguish the Late Devonian rocks associated with giant Cu–Au deposits from younger magmatic suites in the district.

Southern Mongolia

Devonian and carboniferous arcs of the oyu tolgoi porphyry Cu-Au district, South Gobi region, Mongolia

The Central Asian orogenic belt consists of microcontinental blocks and mobile belts positioned between the Siberian craton and the Tarim and North China cratons. Extending across Asia for 5000 km, the belt consists of terranes that decrease in age southward away from the Siberian craton. A time-stratigraphic-structural sequence for the rocks is critical to defining the tectonic evolution of the belt. In the Oyu Tolgoi area of the South Gobi Desert (Mongolia), Devonian and Carboniferous rocks record the construction of multiple arcs, formation of a giant porphyry Cu-Au system, exhumation, and polyphase deformation. The oldest rocks are basaltic volcanic and subvolcanic rocks of the Devonian Alagbayan Group intruded by Late Devonian quartz monzodiorite stocks and dikes, which host giant porphyry Cu-Au deposits. The rocks were exhumed, overlain by pyroclastic rocks, and then tectonically buried by marine mafic supracrustal rocks prior to the youngest Devonian granodiorite intrusions. The postmineral Carboniferous Gurvankharaat Group unconformably overlying the deformed terrane consists of effusive, pyroclastic, subvolcanic and volcaniclastic rocks, as well as sedimentary units. The supracrustal rocks underwent polyphase shortening after 330 Ma and prior to 290 Ma. Variations in stratigraphic sequences suggest that the region is underlain by a submarine arc that became emergent during the Upper Devonian and remained subaerial to shallow subaqueous through much of the Carboniferous. Xenocrystic zircons in igneous rocks suggest that the offshore arcs were sufficiently close to ancient crust to have interacted with detritus shed into marine basins, most likely from the Siberian craton and fringing early Paleozoic terranes. ?? 2011 Geological Society of America.

Geological Society of America Bulletin

El Salvador, Chile porphyry copper deposit revisited: Geologic and geochronologic framework

The Eocene (42 to 41 Ma) El Salvador porphyry copper deposit in the Indio Muerto district, northern Chile (26° 15′ S Lat.), formerly thought to have formed at the culmination of a 9-m.y. period of episodic magmatism, is shown by new mapping, U-Pb and K-Ar geochronology, and petrologic data to have formed during the younger of two distinct but superposed magmatic events-a Paleocene (∼63 to 58 Ma) and an Eocene (44 to 41 Ma) event. In the district, high-K Paleocene volcano-plutonic activity was characterized by a variety of eruptive styles and magmatic compositions, including a collapse caldera associated with explosive rhyolitic magmatism (El Salvador trapdoor caldera), a post-collapse rhyolite dome field (Cerro Indio Muerto), and andesitic-trachyandesitic stratovolcanos (Kilometro Catorce-Los Amarillos sequence). Pre-caldera basement faults were reactivated during Paleocene volcanism as part of the collapse margin of the caldera. Beneath Cerro Indio Muerto, where the porphyry Cu deposit subsequently formed, the intersection of two major basement faults and the NNE-striking rotational axis of tilted ignimbrites of the Paleocene El Salvador caldera localized emplacement of post-collapse rhyolite domes and peripheral dikes and sills. Subsequent Eocene rhyolitic and granodioritic-dacitic porphyries intruded ~14 m.y. after cessation of Paleocene magmatism along the same NNE-striking structural belt through Cerro Indio Muerto as did the post-collapse Paleocene rhyolite domes. Eocene plutonism over a 3-m.y. period was contemporaneous with NW-SE-directed shortening associated with regional sinistral transpression along the Sierra Castillo fault, lying ∼10 km to the east. Older Eocene rhyolitic porphyries in the Indio Muerto district were emplaced between 44 and 43 Ma, and have a small uneconomic Cu center associated with a porphyry at Old Camp. The oldest granodioritic-dacitic porphyries also were emplaced at ∼44 to 43 Ma, but their petrogenetic relation to the rhyolitic porphyries and younger granodioritic-dacitic porphyries in the district is unclear. The main porphyry Cu-Mo-related granodioritic-dacitic stocks in Quebrada Turquesa on Cerro Indio Muerto intruded, cooled, and were mineralized within ∼1 m.y. between 42 and 41 Ma. Volumetrically minor late- to post-mineral porphyries are slightly more mafic than earlier granodioritic-dacitic porphyries, a compositional trend possibly repeated on several scales and more than once over the 3-million-year Eocene magmatic history of the Indio Muerto district. This compositional trend requires either addition of basaltic material into an open-system silicic magma chamber or tapping of progressively deeper levels of a vertically zoned magma chamber. Eocene porphyry magmas were more hydrous and their residual source mineralogy richer in garnet than the relatively anhydrous Paleocene rocks, whose source was rich in pyroxene. The presence of inherited zircons in Paleocene and Eocene rocks requires interaction with crustal rocks of Paleozoic and/or Proterozoic age.

International Geology Review

Widespread effects of middle Mississippian deformation in the Great Basin of western North America

Stratigraphic analyses in central and eastern Nevada reveal the importance of a deformation event in middle Mississippian time that caused widespread deformation, uplift, and erosion. It occurred between middle Osagean and late Meramecian time and resulted in deposition of both synorogenic and postorogenic sediments. The deformation resulted in east-west shortening, expressed as east-vergent folding and east-directed thrusting; it involved sedimentary rocks of the Antler foredeep as well as strata associated with the Roberts Mountains allochthon. A latest Meramecian to early Chesterian unconformity, with correlative conformable lithofacies changes, postdates this deformation and occurs throughout Nevada. A tectonic highland-created in the middle Mississippian and lasting into the Pennsylvanian and centered in the area west and southwest of Carlin, Nevada- shed sediments eastward across the Antler foreland, burying the unconformity. Postorogenic strata are late Meramecian to early Chesterian at the base and are widespread throughout the Great Basin. The tectonism therefore occurred 20 to 30 m.y. after inception of the Late Devonian Antler orogeny, significantly extending the time span of this orogeny or representing a generally unrecognized orogenic event in the Paleozoic evolution of western North America. We propose a revised stratigraphic nomenclature for Mississippian strata in Nevada, based on detailed age control and the recognition of unconformities. This approach resolves the ambiguity of some stratigraphic names and emphasizes genetic relationships within the upper Paleozoic section. We take advantage of better stratigraphic understanding to propose two new stratigraphic units for southern and eastern Nevada: the middle Mississippian Gap Wash and Late Mississippian Captain Jack Formations.

Geological Society of America Bulletin

Lead in the Getchell-Turquoise ridge Carlin-type gold deposits from the perspective of potential igneous and sedimentary rock sources in Northern Nevada: Implications for fluid and metal sources

Lead isotope compositions of bulk mineral samples (fluorite, orpiment, and realgar) determined using conventional techniques and of ore-stage arsenian pyrite using the Sensitive High Resolution Ion-Microprobe (SHRIMP) in the Getchell and Turquoise Ridge Carlin - type gold deposits (Osgood Mountains) require contribution from two different Pb sources . One Pb source dominates the ore stage. It has a limited Pb isotope range characterized by 208 Pb/ 206 Pb values of 2.000 to 2.005 and 207 Pb/ 206 Pb values of 0.8031 to 0.8075, as recorded by 10-μm-diameter spot SHRIMP analyses of ore-stage arsenian pyrite. These values approximately correspond to 206 Pb/ 204 Pb of 19.3 to 19.6, 207 Pb/ 204 Pb of 15.65 to 15.75, and 208 Pb/ 204 Pb of 39.2 to 39.5. This Pb source is isotopically similar to that in average Neoproterozoic and Cambrian elastic rocks but not to any potential magmatic sources . Whether those clastic rocks provided Pb to the ore fluid cannot be unequivocally proven because their Pb isotope compositions over the same range as in ore-stage arsenian pyrite are similar to those of Ordovician to Devonian siliciclastic and calcareous rocks. The Pb source in the calcareous rocks most likely is largely detrital minerals, since that detritus was derived from the same sources as the detritus in the Neoproterozoic and Cambrian clastic rocks. The second Pb source is characterized by a large range of 206 Pb/ 204 Pb values (18-34) with a limited range of 208 Pb/ 204 Pb values (38.1-39.5), indicating low but variable Th/U and high and variable U/Pb values. The second Pb source dominates late and postore-stage minerals but is also found in preore sulfide minerals. These Pb isotope characteristics typify Ordovician to Devonian siliciclastic and calcareous rocks around the Carlin trend in northeast Nevada . Petrologically similar rocks host the Getchell and Turquoise Ridge deposits . Lead from the second source was either contributed from the host sedimentary rock sequences or brought into the hydrothermal system by oxidized ground water as the system collapsed. Late ore- and postore-stage sulfide minerals (pyrite, orpiment, and stibnite) from the Betze-Post and Meikle deposits in the Carlin trend and from the Jerritt Canyon mining district have Pb isotope characteristics similar to those determined in Getchell and Turquoise Ridge . This observation suggests that the Pb isotope compositions of their ore fluids may be similar to those at Getchell and Turquoise Ridge . Two models can explain the Pb isotope compositions of the ore-stage arsenian pyrite versus the late ore or postore sulfide minerals. In either model, Pb from the Ordovician to Devonian siliciclastic and calcareous rock source enters the hydrothermal system late in the ore stage but not to any extent during the main stage of ore deposition. In one model, ore-stage Pb was derived from a source with Pb isotope compositions similar to those of the Neoproterozoic and Cambrian clastic sequence, transported as part of the ore fluid and then deposited in the ore-stage arsenian pyrite and fluorite. The second model is based on the observation that the Pb isotope characteristics of the ore-stage minerals also are found in some Ordovician to Devonian calcareous and siliciclastic rocks. Hence, ore-stage Pb could have been derived locally and simply concentrated during the ore stage. Critical to the second model is the removal of all high 206 Pb/ 204 Pb (>20) material during alteration. It Also requires the retention of only the low 206 Pb/ 204 Pb component of the Ordovician to Devonian sedimentary rocks. This critical step is possible only if the high 206 Pb/ 204 Pb values are contained in readily dissolvable mineral phases, whereas the low 206 Pb/ 204 Pb values are found only in refractory minerals that released Pb during a final alteration stage just prior deposition of auriferous arsenian pyrite. Distinguishing between Pb transported with the ore fluid or inherited from the site of mineral deposition is not straightforward; however, it is simpler to explain the Pb isotope compositions of ore-stage arsenian pyrite and fluorite in two different but spatially related Carlin - type deposits ( Getchell and Turquoise Ridge ) with different host rocks by input of Pb with the ore fluid . Once the limited Pb in the hydrothermal fluid was exhausted by incorporation in ore-stage arsenian pyrite or other ore-stage minerals, Pb from the second source , the Ordovician to Devonian sedimentary rock sequences, became available for incorporation in some but not all of the late-stage sulfide minerals.

Nevada

Conventional U-Pb dating versus SHRIMP of the Santa Barbara Granite Massif, Rondonia, Brazil

The Santa Ba??rbara Granite Massif is part of the Younger Granites of Rondo??nia (998 - 974 Ma) and is included in the Rondo??nia Tin Province (SW Amazonian Craton). It comprises three highly fractionated metaluminous to peraluminous within-plate A-type granite units emplaced in older medium-grade metamorphic rocks. Sn-mineralization is closely associated with the late-stage unit. U-Pb monazite conventional dating of the early-stage Serra do Cicero facies and late-stage Serra Azul facies yielded ages of 993 ?? 5 Ma and 989 ?? 13 Ma, respectively. Conventional multigrain U-Pb isotope analyses of zircon demonstrate isotopic disturbance (discordance) and the preservation of inherited older zircons of several different ages and thus yield little about the ages of Sn-granite magmatism. SHRIMP U-Pb ages for the Santa Ba??rbara facies association yielded a 207Pb/206Pb weighted-mean age of 978 ?? 13 Ma. The textural complexity of the zircon crystals of the Santa Ba??rbara facies association, the variable concentrations of U, Th and Pb, as well as the mixed inheritance of zircon populations are major obstacles to using conventional multigrain U-Pb isotopic analyses. Sm-Nd model ages and ??Nd (T) values reveal anomalous isotopic data, attesting to the complex isotopic behaviour within these highly fractionated granites. Thus, SHRIMP U-Pb zircon and conventional U-Pb monazite dating methods are the most appropriate to constrain the crystallization age of the Sn-bearing granite systems in the Rondo??nia Tin Province.

Geologia USP - Serie Cientifica

Lead isotope compositions of Late Cretaceous and early Tertiary igneous rocks and sulfide minerals in Arizona: Implications for the sources of plutons and metals in porphyry copper deposits

Porphyry copper deposits in Arizona are genetically associated with Late Cretaceous and early Tertiary igneous complexes that consist of older intermediate volcanic rocks and younger intermediate to felsic intrusions. The igneous complexes and their associated porphyry copper deposits were emplaced into an Early Proterozoic basement characterized by different rocks, geologic histories, and isotopic compositions. Lead isotope compositions of the Proterozoic basement rocks define, from northwest to southeast, the Mojave, central Arizona, and southeastern Arizona provinces. Porphyry copper deposits are present in each Pb isotope province. Lead isotope compositions of Late Cretaceous and early Tertiary plutons, together with those of sulfide minerals in porphyry copper deposits and of Proterozoic country rocks, place important constraints on genesis of the magmatic suites and the porphyry copper deposits themselves. The range of age-corrected Pb isotope compositions of plutons in 12 Late Cretaceous and early Tertiary igneous complexes is 206 Pb/ 204 Pb = 17.34 to 22.66, 207 Pb/ 204 Pb = 15.43 to 15.96, and 208 Pb/ 204 Pb = 37.19 to 40.33. These Pb isotope compositions and calculated model Th/U are similar to those of the Proterozoic rocks in which the plutons were emplaced, thereby indicating that Pb in the younger rocks and ore deposits was inherited from the basement rocks and their sources. No Pb isotope differences distinguish Late Cretaceous and early Tertiary igneous complexes that contain large economic porphyry copper deposits from less rich or smaller deposits that have not been considered economic for mining. Lead isotope compositions of Late Cretaceous and early Tertiary plutons and sulfide minerals from 30 metallic mineral districts, furthermore, require that the southeastern Arizona Pb province be divided into two subprovinces. The northern subprovince has generally lower 206 Pb/ 204 Pb and higher model Th/U, and the southern subprovince has higher 206 Pb/ 204 Pb and lower model Th/U. These Pb isotope differences are inferred to result from differences in their respective post-1.7 Ga magmatic histories. Throughout Arizona, Pb isotope compositions of Late Cretaceous and early Tertiary plutons and associated sulfide minerals are distinct from those of Jurassic plutons and also middle Tertiary igneous rocks and sulfide minerals. These differences most likely reflect changes in tectonic setting and magmatic sources. Within Late Cretaceous and early Tertiary igneous complexes that host economic porphyry copper deposits, there is commonly a decrease in Pb isotope composition from older to younger plutons. This decrease in Pb isotope values with time suggests an increasing involvement of crust with lower U/Pb than average crust in the source(s) of Late Cretaceous and early Tertiary magmas. Lead isotope compositions of the youngest porphyries in the igneous complexes are similar to those in most sulfide minerals within the associated porphyry copper deposit. This Pb isotope similarity argues for a genetic link between them. However, not all Pb in the sulfide minerals in porphyry copper deposits is magmatically derived. Some sulfide minerals, particularly those that are late stage, or distal to the main orebody, or in Proterozoic or Paleozoic rocks, have elevated Pb isotope compositions displaced toward the gross average Pb isotope composition of the local country rocks. The more radiogenic isotopic compositions argue for a contribution of Pb from those rocks at the site of ore deposition. Combining the Pb isotope data with available geochemical, isotopic, and petrologic data suggests derivation of the young porphyry copper-related plutons, most of their Pb, and other metals from a hybridized lower continental crustal source. Because of the likely involvement of subduction-related mantle-derived basaltic magma in the hybridized lower crustal source, an indiscernible mantle contribution is probable in the porphyry magmas. Clearly, in addition, Pb was contributed from the local country rocks. This is most evident in sulfide minerals in veins that are late stage, hosted in Proterozoic gneiss, and/or peripheral to the porphyry copper deposit.

Economic Geology

Triassic plutonism in southern California: Southward younging of arc initiation along a truncated continental margin

Earliest Cordilleran magmatism in the southwestern United States is recorded by a belt of Triassic plutons that intrude Proterozoic basement of the Mojave crustal province and its cratonal/miogeoclinal cover. The belt extends from the western Mojave Desert through the Transverse Ranges to the Colorado River trough. Triassic plutons are predominantly alkali-calcic, Fe- and Sr-enriched quartz monzodiorites and monzonites. The northern part of the belt is composed of two older plutonic suites (241–231 Ma) which are high K to shoshonitic; the southern part of the belt is a younger (218–213 Ma), sodic-alkalic suite. The plutonic record in southern California suggests a short-lived, southward younging continental margin arc setting for emplacement of Triassic plutons, superimposed on a continental margin modified by sinistral transform faulting. Triassic plutonism in this region was followed by a magmatic lull prior to the onset of voluminous Middle to Late Jurassic Cordilleran arc magmatism.

California

The Amazon-Laurentian connection as viewed from the Middle Proterozoic rocks in the central Andes, western Bolivia and northern Chile

Middle Proterozoic rocks underlying the Andes in western Bolivia, western Argentina, and northern Chile and Early Proterozoic rocks of the Arequipa massif in southern Perú form the Arequipa-Antofalla craton. These rocks are discontinuously exposed beneath Mesozoic and Cenozoic rocks, but abundant crystalline clasts in Tertiary sedimentary rocks in the western altiplano allow indirect samples of the craton. Near Berenguela, western Bolivia, the Oligocene and Miocene Mauri Formation contains boulders of granodiorite augen gneiss (1171±20 Ma and 1158±12 Ma; U-Pb zircon), quartzose gneiss and granofels that are inferred to have arkosic protoliths (1100 Ma source region; U-Pb zircon), quartzofeldspathic and mafic orthogneisses that have amphibolite- and granulite-facies metamorphic mineral assemblages (∼1080 Ma metamorphism; U-Pb zircon), and undeformed granitic rocks of Phanerozoic(?) age. The Middle Proterozoic crystalline rocks from Berenguela and elsewhere in western Bolivia and from the Middle Proterozoic Belén Schist in northern Chile generally have present-day low 206 Pb/ 204 Pb (<18.0), elevated 207 Pb/ 204 Pb (>15.57), and elevated 208 Pb/ 204 Pb (37.2 to 50.7) indicative of high time-averaged Th/U values. The Middle Proterozoic rocks in general have higher present-day 206 Pb/ 204 Pb values than those of the Early Proterozoic rocks of the Arequipa massif ( 206 Pb/ 204 Pb between 16.1 and 17.1) but lower than rocks of the southern Arequipa-Antofalla craton ( 206 Pb/ 204 Pb> 18.5), a difference inferred to reflect Grenvillian granulite metamorphism. The Pb isotopic compositions for the various Proterozoic rocks lie on common Pb isotopic growth curves, implying that Pb incorporated in rocks composing the Arequipa-Antofalla craton was extracted from a similar evolving Pb isotopic reservoir. Evidently, the craton has been a coherent terrane since the Middle Proterozoic. Moreover, the Pb isotopic compositions for the Arequipa-Antofalla craton overlap those of the Amazon craton, thereby supporting a link between these cratons and seemingly precluding part of the Arequipa-Antofalla craton from being a detached fragment of another craton such as eastern Laurentia, which has been characterized by a different U/Pb history. Pb isotopic compositions for the Arequipa-Antofalla craton are, furthermore, distinct from those of the Proterozoic basement in the Precordillera terrane, western Argentina, indicating a Pb isotopic and presumably a tectonic boundary between them. The Pb isotopic compositions for the Precordillera basement are similar to those of eastern Laurentia, and support other data indicating that these rocks are a detached fragment of North America. Finally, the distinct Pb isotopic evolution history of the Arequipa-Antofalla craton and eastern Laurentia require minor modification to tectonic models linking eastern North America-Scotland to the oroclinal bend in western South America.

central Andes

Alteration of basalt hyaloclastite at the off-axis Sea Cliff hydrothermal field, Gorda Ridge

The Sea Cliff hydrothermal field on the northern segment of the Gorda Ridge is situated along a rift-bounding normal fault about 2.6 km east of the neovolcanic zone and approximately 300 m above the spreading axis. The structural setting of this hydrothermal field differs from that of most other active seafloor hydrothermal sites investigated to date, which are typically situated in the neovolcanic zone. Mineralization occurs in basaltic talus covering a large normal-fault scarp. Hydrothermal crusts cover much of the seafloor in the area of the active hydrothermal field. These crusts form by extensive alteration of basaltic hyaloclastite in a zone of mixing between ascending hydrothermal fluid and entrained seawater. The initial stage of alteration is magnesian metasomatism of both crystalline basalt and basaltic glass, converting the rock to Mg-rich smectite and smectite/chlorite. Further alteration removes nearly all cations and ultimately leads to silicification. Preservation of basaltic texture in the silicified rocks provides evidence that even such sparingly soluble elements as A1 and Ti have been removed. Oxygen-isotopic ratios of the altered rocks constrain initial alteration to temperatures near 220°C, close to the maximum measured vent temperatures of 247°C. Silicification proceeded to much lower temperatures, and most amorphous silica deposition occurred at temperatures below 100°C. Sulfur-, strontium-, and lead-isotopic data all indicate a predominantly basaltic source, with important contributions from seawater but no significant contribution from sedimentary sources. Comparison with ophiolite-hosted massive sulfide deposits shows that the structural setting, alteration sequence, and depositional environment are all similar and suggests that mineralization and replacement of basaltic breccia in the Sea Cliff hydrothermal field likely occur in the subsurface beneath a capping layer of silicified hyaloclastite.

California, Oregon

Sources of the Early Cretaceous plutons in the Turtle and West Riverside Mountains, California

Ages and initial isotopic ratios of Early Cretaceous (˜100 Ma) plutons of the Cordilleran Interior in the southern Turtle and West Riverside mountains distinguish them from Late Cretaceous plutons in surrounding ranges in the eastern Mojave Desert. Furthermore, the studied plutons have isotopic and geochemical characteristics more similar to plutons of Cretaceous age in the coastal batholiths (Peninsular Ranges and Sierra Nevada) than to most Mesozoic plutons in the Cordilleran Interior. The studied plutons are calcic, in contrast to the mostly cak-alkaline Mesozoic plutons of the eastern Mojave Desert. Distinctive isotopic signatures of the granitoids include lower initial 87 Sr/ 86 Sr of 0⋅705–0⋅710, δ 18 O of +6⋅3 to +7⋅7‰, 208 Pb/ 204 Pb of 38⋅3–39⋅5, and higher ε Nd of −3⋅86 to −9⋅60 than the Late Cretaceous plutons in the region. The distinctive characteristics of these Early Cretaceous plutons are probably both location and time specific and result from: (1) emplacement in a cold, untapped ‘Mojave-type’ Proterozoic upper crust, (2) a significant component of basaltic magmas partially melted from the asthenosphere or subcontinental lithosphere and (3) a magmatic component derived from Proterozoic, mafic, lower crust. They interacted less with their crustal hosts than did the later, more voluminous Late Cretaceous plutons.

California

The Conterminous United States Mineral Assessment Program: Background information to accompany folio of geologic, geochemical, geophysical, and mineral resource maps of the Ajo and Lukeville 1° by 2° quadrangles, Arizona

Encompassing about 21,000 km 2 in southwestern Arizona, the Ajo and Lukeville 1° by 2° quadrangles have been the subject of mineral resource investigations utilizing field and laboratory studies in the disciplines of geology, geochemistry, geophysics, and Landsat imagery. The results of these studies are published as a folio of maps, figures, and tables, with accompanying discussions. Past mineral production has been limited to copper from the Ajo Mining District. In addition to copper, the quadrangles contain potentially significant resources of gold and silver; a few other commodities, including molybdenum and evaporites, may also exist in the area as appreciable resources. This circular provides background information on the mineral deposits and on the investigations and integrates the information presented in the folio. The bibliography cites references to the geology, geochemistry, geophysics, and mineral deposits of the two quadrangles.

Arizona