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R. E. Broshears

Publications and source records attributed to R. E. Broshears.

11 recordsLinked to original sources
USGS2002

Coupling of hydrologic transport and chemical reactions in a stream affected by acid mine drainage

Experiments in St. Kevin Gulch, an acid mine drainage stream, examined the coupling of hydrologic transport to chemical reactions affecting metal concentrations. Injection of LiCl as a conservative tracer was used to determine discharge and residence time along a 1497-m reach. Transport of metals downstream from inflows of acidic, metal-rich water was evaluated based on synoptic samples of metal concentrations and the hydrologic characteristics of the stream. Transport of SO 4 and Mn was generally conservative, but in the subreaches most affected by acidic inflows, transport was reactive. Both 0.1-um filtered and particulate Fe were reactive over most of the stream reach. Filtered Al partitioned to the particulate phase in response to high instream concentrations. Simulations that accounted for the removal of SO 4 , Mn, Fe, and Al with first-order reactions reproduced the steady-state profiles. The calculated rate constants for net removal used in the simulations embody several processes that occur on a stream-reach scale. The comparison between rates of hydrologie transport and chemical reactions indicates that reactions are only important over short distances in the stream near the acidic inflows, where reactions occur on a comparable time scale with hydrologic transport and thus affect metal concentrations.

Environmental Science & Technology↗
USGS2001

Simulation of stream discharge and transport of nitrate and selected herbicides in the Mississippi River Basin

Stream discharge and the transport of nitrate, atrazine, and metolachlor in the Mississippi River Basin were simulated using the DAFLOW/BLTM hydrologic model. The simulated domain for stream discharge included river reaches downstream from the following stations in the National Stream Quality Accounting Network: Mississippi River at Clinton, IA; Missouri River at Hermann, MO: Ohio River at Grand Chain, IL: And Arkansas River at Little Rock, AR. Coefficients of hydraulic geometry were calibrated using data from water year 1996; the model was validated by favourable simulation of observed discharges in water years 1992-1994. The transport of nitrate, atrazine, and metolachlor was simulated downstream from the Mississippi River at Thebes, IL, and the Ohio River at Grand Chain. Simulated concentrations compared favourably with observed concentrations at Baton Rouge, LA. Development of this model is a preliminary step in gaining a more quantitative understanding of the sources and fate of nutrients and pesticides delivered from the Mississippi River Basin to the Gulf of Mexico.

Hydrological Processes↗
USGS2001

Hydrogeology and ground-water flow in the Memphis and Fort Pillow aquifers in the Memphis area, Tennessee

On the basis of known hydrogeology of the Memphis and Fort Pillow aquifers in the Memphis area, a three-layer, finite-difference numerical model was constructed and calibrated as the primary tool to refine understanding of flow in the aquifers. The model was calibrated and tested for accuracy in simulating measured heads for nine periods of transient flow from 1886-1985. Testing and sensitivity analyses indicated that the model accurately simulated observed heads areally as well as through time. The study indicates that the flow system is currently dominated by the distribution of pumping in relation to the distribution of areally variable confining units. Current withdrawal of about 200 million gallons per day has altered the prepumping flow paths, and effectively captured most of the water flowing through the aquifers. Ground-water flow is controlled by the altitude and location of sources of recharge and discharge, and by the hydraulic characteristics of the hydrogeologic units. Leakage between the Fort Pillow aquifer and Memphis aquifer, and between the Memphis aquifer and the water-table aquifers (alluvium and fluvial deposits) is a major component of the hydrologic budget. The study indicates that more than 50 percent of the water withdrawn from the Memphis aquifer in 1980 is derived from vertical leakage across confining units, and the leakage from the shallow aquifer (potential source of contamination) is not uniformly distributed. Simulated leakage was concentrated along the upper reaches of the Wolf and Loosahatchie Rivers, along the upper reaches of Nonconnah Creek, and the surficial aquifer of the Mississippi River alluvial plain. These simulations are supported by the geologic and geophysical evidence suggesting relatively thin or sandy confining units in these general locations. Because water from surficial aquifers is inferior in quality and more susceptible to contamination than water in the deeper aquifers, high rates of leakage to the Memphis aquifer may be cause for concern. A significant component of flow (12 percent) discharging from the Fort Pillow aquifer was calculated as upward leakage to the Memphis aquifer. This upward leakage was generally limited to areas near major pumping centers in the Memphis aquifer, where heads in the Memphis aquifer have been drawn significantly below heads in the Fort Pillow aquifer. Although the Fort Pillow aquifer is not capable of producing as much water as the Memphis aquifer for similar conditions, it is nonetheless a valuable resource throughout the area.

Tennessee↗
USGS1996

Reactive solute transport in an acidic stream: Experimental pH increase and simulation of controls on pH, aluminum, and iron

Solute transport simulations quantitatively constrained hydrologic and geochemical hypotheses about field observations of a pH modification in an acid mine drainage stream. Carbonate chemistry, the formation of solid phases, and buffering interactions with the stream bed were important factors in explaining the behavior of pH, aluminum, and iron. The precipitation of microcrystalline gibbsite accounted for the behavior of aluminum; precipitation of Fe(OH)3 explained the general pattern of iron solubility. The dynamic experiment revealed limitations on assumptions that reactions were controlled only by equilibrium chemistry. Temporal variation in relative rates of photoreduction and oxidation influenced iron behavior. Kinetic limitations on ferrous iron oxidation and hydrous oxide precipitation and the effects of these limitations on field filtration were evident. Kinetic restraints also characterized interaction between the water column and the stream bed, including sorption and desorption of protons from iron oxides at the sediment-water interface and post-injection dissolution of the precipitated aluminum solid phase.

Environmental Science & Technology↗
USGS1996

Reactive solute transport in acidic streams

Spatial and temporal profiles of Ph and concentrations of toxic metals in streams affected by acid mine drainage are the result of the interplay of physical and biogeochemical processes. This paper describes a reactive solute transport model that provides a physically and thermodynamically quantitative interpretation of these profiles. The model combines a transport module that includes advection-dispersion and transient storage with a geochemical speciation module based on MINTEQA2. Input to the model includes stream hydrologic properties derived from tracer-dilution experiments, headwater and lateral inflow concentrations analyzed in field samples, and a thermodynamic database. Simulations reproduced the general features of steady-state patterns of observed pH and concentrations of aluminum and sulfate in St. Kevin Gulch, an acid mine drainage stream near Leadville, Colorado. These patterns were altered temporarily by injection of sodium carbonate into the stream. A transient simulation reproduced the observed effects of the base injection.

Water, Air, & Soil Pollution↗
USGS1992

Hydrogeology, water quality, and potential for transport of organochlorine pesticides in ground water at the North Hollywood Dump, Memphis, Tennessee

Geologic, hydrologic, and water-quality data indicate that ground-water contamination is confined to shallow horizons within the unconfined aquifer underlying the North Hollywood Dump in Memphis, Tennessee. The dump is a closed municipal-industrial landfill that has been ranked as Tennessee's potentially most dangerous hazardous-waste site. Toxic constituents of concern at the dump include residues from the manufacture of organochlorine pesticides. The dump overlies an unconfined aquifer of unconsolidated sands, silts, and clays. During average hydrologic conditions, ground waterflows beneath the dump at a mean velocity of approximately 3 feet per day and discharges to the Wolf River. Leachate from the dump mixes with underlying ground water, resulting in increased concentrations of dissolved solids and organic carbon downgradient from the dump. The mobility of chlordane, a representative organochlorine pesticide, is limited by its low solubility and its strong affinity for sand, silt, and clays of the aquifer. Degradation of chlordane may occur slowly, if at all, in the aquifer. Based on estimates of mean ground-water velocity and retardation of the pesticide due to sorption, mean travel times for chlordane migrating from the dump to the ground-water discharge zone are of the order of 50 to 500 years. Simulations of chlordane concentration resulting from the discharge of contaminated ground water and complete mixing in the Wolf River are sensitive to assumptions about chlordane persistence in the unconfined aquifer. If the half life of chlordane in the aquifer is assumed to be 30 years or less, the simulated concentration of chlordane in the Wolf River under average flow conditions is less than the most stringent water-quality criterion.

Tennessee↗
USGS1991

A pilot study for delineation of areas contributing water to wellfields at Jackson, Tennessee

The U.S. Geological Survey, in cooperation with the Tennessee Department of Health and Environment, Division of Groundwater Protection, and the Jackson Utility Division, conducted a pilot study to determine data needs and the applicability of four methods for the delineation of wellhead protection areas. Jackson Utility Division in Jackson, Madison County, Tennessee, pumps about 9 million gallons of ground water daily from two municipal wellfields that tap an unconfined sand aquifer. Under natural hydraulic gradients, ground waterflows southward toward the South Wellfield at approximately 2 to 3 feet per day; natural flow toward the North Wellfield from the east at 1 to 2 feet per day. Water quality generally is suitable for most uses. Concentrations of dissolved solids are low, and excessive iron is the only significant naturally occurring water-quality problem. However, trace concentrations of volatile organic compounds have been detected in water pumps from the South Wellfield; the highest concentration of a single compound has been 23 micrograms per liter of tetrachloroethylene. Potential sources of ground-water contamination in the Jackson area include a hazardous-waste site, municipal and industrial landfill, and underground-storage tanks. Some of the four method for delineating wellhead protection areas did not adequately describe zones contributing flow to the wellfields. Calculations based on a uniform flow equation provided a preliminary delineation of zones of contribution for the wellfields and ground-water time-of-travel contours. Limitations of the applied methods motivated the design of a more rigorous hydrogeologic investigation.

Tennessee↗
USGS1991

Characterization of bottom-sediment, water, and elutriate chemistry at selected stations at Reelfoot Lake, Tennessee

To better-understand and predict the potential effect of dredging on water quality at Reelfoot Lake, chemical analyses were conducted on samples of lake water, bottom sediment, and elutriate water. Chemical analyses were conducted on samples of lake water, bottom sediment, and elutriate water collected at five stations in the lake during November 1988. Lake water was of the calcium magnesium bicarbonate type with an average dissolved-solids concentration of 120 milligrams per liter. Trace constituents were present in bottom sediments at concentrations representative of their average relative abundance in the earth?s crust. Elutriate waters prepared by mixing bottom sediment and lake water had suspended-solids concentrations as high as 2,000 milligrams per liter which exerted significant oxygen demand Trace constituents in the unfiltered elutriate waters were elevated with respect to lake water; elevated concentrations were attributable to the increased suspended-solids concentrations. Concentrations of total-recoverable copper, lead., and zinc in many elutriate waters exceeded U.S. Environmental Protection Agency?s water-quality criteria for the protection of freshwater aquatic life. The toxicity of elutriate waters, as measured by a 48-hour bioassay with Ceriodaphnia dubia, was low.

Tennessee↗