Geology topics

R. Blaine McCleskey

Publications and source records attributed to R. Blaine McCleskey.

3 recordsLinked to original sources

USGS2025

Groundwater salinity: Applying the specific conductance and water type proxy

Groundwater is increasingly needed for water supplies but may have limited utility in some locations because of its salinity. Salinity, often expressed as total dissolved solid (TDS), is frequently estimated using specific conductance (SC) measurements. However, the commonly used proxy (0.65 multiplied by SC to indicate TDS, common in many handheld meters) can result in inaccurate TDS estimates. First, the TDS–SC relationship is not linear over the entire concentration range of groundwater. Furthermore, the TDS (and salinity)–SC relationships vary substantially depending on the major-ion composition. Here we develop a proxy method utilizing SC and major-ion water type to estimate TDS and salinity specifically for groundwaters. Compared to most surface waters, groundwater tends to have a wider range of salinity (fresh to highly saline) and higher concentrations of bedrock-derived solutes such as carbonate ions, silica, and many other ions. The dataset used to develop the proxies includes water chemistry data from 149,059 discrete groundwater samples. The groundwater proxies, which employ nonlinear log–log relations, utilize five water types (HCO 3 , Cl, Ca-Mg-SO 4 , Na-K-SO 4 , and mixed waters), are accurate (median percent difference between TDS and salinity determined using the proxy compared to discrete measurements was <±0.8%) over a wide range of SC (up to 200 mS/cm), rapid, cost-effective, and can be measured on-site.

Groundwater↗

USGS2025

The systematics of stable hydrogen (δ2H) and oxygen (δ18O) isotopes and tritium (3H) in the hydrothermal system of the Yellowstone Plateau volcanic field, USA

To improve our understanding of hydrothermal activity on the Yellowstone Plateau volcanic field, we collected and analyzed a large data set of δ 2 H, δ 18 O, and the 3 H concentrations of circum-neutral and alkaline waters. We find that (a) hot springs are fed by recharge throughout the volcanic plateau, likely focused through fractured, permeable tuff units. Previous work had stressed the need for light δ 2 H water recharge restricted to the northern part of the plateau or recharge during past cold periods. However, new data from the Y-7 drill hole suggests that recharge is not restricted to a certain area or a cold period. (b) δ 18 O values of thermal waters in the geyser basins are shifted from the global meteoric water line by temperature-dependent water-rock reactions with higher subsurface temperatures resulting in a greater shift. (c) Large temporal variations in the isotopic composition of meteoric water recharge and small temporal variability in the isotopic composition of hot spring discharge implies that the volume of groundwater in, and around the Yellowstone caldera is substantially larger than the volume of annual water recharge. (d) Hot springs discharged through different rhyolitic units correlate with identifiable differences in δ 2 H and δ 18 O compositions, 3 H concentrations, and water chemistry that imply equilibration at different temperatures and travel along different flow paths. (e) Based on measured 3 H concentrations, we calculate that hot spring waters in the central part of the geyser basins mostly contain <2% post-1950 meteoric water, whereas waters discharged at the basin margins contain larger fractions of post-1950s meteoric water.

Wyoming↗

USGS2025

Tapwater exposures, residential risk, and mitigation in a PFAS-impacted-groundwater community

Tapwater (TW) safety and sustainability are priorities in the United States. Per/polyfluoroalkyl substance(s) (PFAS) contamination is a growing public-health concern due to prolific use, widespread TW exposures, and mounting human-health concerns. Historically-rural, actively-urbanizing communities that rely on surficial-aquifer private wells incur elevated risks of unrecognized TW exposures, including PFAS, due to limited private-well monitoring and contaminant-source proliferation in urbanizing landscapes. Here, a broad-analytical-scope TW-assessment was conducted in a hydrologically-vulnerable, Mississippi River alluvial-island community, where PFAS contamination of the shallow-alluvial drinking-water aquifer has been documented, but more comprehensive contaminant characterization to inform decision-making is currently lacking. In 2021, we analyzed 510 organics, 34 inorganics, and 3 microbial groups in 11 residential and community locations to assess (1) TW risks beyond recognized PFAS issues, (2) day-to-day and year-to-year risk variability, and (3) suitability of the underlying sandstone aquifer as an alternative source to mitigate TW-PFAS exposures. Seventy-six organics and 25 inorganics were detected. Potential human-health risks of detected TW exposures were explored based on cumulative benchmark-based toxicity quotients ( ∑ TQ ). Elevated risks ( ∑ TQ ≥ 1) from organic and inorganic contaminants were observed in all alluvial-aquifer-sourced synoptic samples but not in sandstone-aquifer-sourced samples. Repeated sampling at 3 sites over 52–55 h indicated limited variability in risk over the short-term. Comparable PFAS-specific ∑ TQ for spatial-synoptic, short-term (3 days) temporal, and long-term (3 years quarterly) temporal samples indicated that synoptic results provided useful insight into the risks of TW-PFAS exposures at French Island over the long-term. No PFAS detections in sandstone-aquifer-sourced samples over a 3 year period indicated no PFAS-associated risk and supported the sandstone aquifer as an alternative drinking-water source to mitigate community TW-PFAS exposures. This study illustrated the importance of expanded contaminant monitoring of private-well TW, beyond known concerns (in this case, PFAS), to reduce the risks of a range of unrecognized contaminant exposures.

Wisconsin↗