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Geology topics

Q. Zhou

Publications and source records attributed to Q. Zhou.

3 recordsLinked to original sources

Understanding CO 2 Plume Behavior and Basin-Scale Pressure Changes during Sequestration Projects through the use of Reservoir Fluid Modeling

Large scale geologic sequestration tests are in the planning stages around the world. The liability and safety issues of the migration of CO 2 away from the primary injection site and/or reservoir are of significant concerns for these sequestration tests. Reservoir models for simulating single or multi-phase fluid flow are used to understand the migration of CO 2 in the subsurface. These models can also help evaluate concerns related to brine migration and basin-scale pressure increases that occur due to the injection of additional fluid volumes into the subsurface. The current paper presents different modeling examples addressing these issues, ranging from simple geometric models to more complex reservoir fluid models with single-site and basin-scale applications. Simple geometric models assuming a homogeneous geologic reservoir and piston-like displacement have been used for understanding pressure changes and fluid migration around each CO 2 storage site. These geometric models are useful only as broad approximations because they do not account for the variation in porosity, permeability, asymmetry of the reservoir, and dip of the beds. In addition, these simple models are not capable of predicting the interference between different injection sites within the same reservoir. A more realistic model of CO 2 plume behavior can be produced using reservoir fluid models. Reservoir simulation of natural gas storage reservoirs in the Illinois Basin Cambrian-age Mt. Simon Sandstone suggest that reservoir heterogeneity will be an important factor for evaluating storage capacity. The Mt. Simon Sandstone is a thick sandstone that underlies many significant coal fired power plants (emitting at least 1 million tonnes per year) in the midwestern United States including the states of Illinois, Indiana, Kentucky, Michigan, and Ohio. The initial commercial sequestration sites are expected to inject 1 to 2 million tonnes of CO 2 per year. Depending on the geologic structure and permeability anisotropy, the CO 2 injected into the Mt. Simon are expected to migrate less than 3 km. After 30 years of continuous injection followed by 100 years of shut-in, the plume from a 1 million tonnes a year injection rate is expected to migrate 1.6 km for a 0 degree dip reservoir and over 3 km for a 5 degree dip reservoir. The region where reservoir pressure increases in response to CO 2 injection is typically much larger than the CO 2 plume. It can thus be anticipated that there will be basin wide interactions between different CO 2 injection sources if multiple, large volume sites are developed. This interaction will result in asymmetric plume migration that may be contrary to reservoir dip. A basin- scale simulation model is being developed to predict CO 2 plume migration, brine displacement, and pressure buildup for a possible future sequestration scenario featuring multiple CO 2 storage sites within the Illinois Basin Mt. Simon Sandstone. Interactions between different sites will be evaluated with respect to impacts on pressure and CO 2 plume migration patterns. ?? 2009 Elsevier Ltd. All rights reserved.

Conference Paper

Population influences on tornado reports in the United States

The number of tornadoes reported in the United States is believed to be less than the actual incidence of tornadoes, especially prior to the 1990s, because tornadoes may be undetectable by human witnesses in sparsely populated areas and areas in which obstructions limit the line of sight. A hierarchical Bayesian model is used to simultaneously correct for population-based sampling bias and estimate tornado density using historical tornado report data. The expected result is that F2-F5 compared with F0-F1 tornado reports would vary less with population density. The results agree with this hypothesis for the following population centers: Atlanta, Georgia; Champaign, Illinois; and Des Moines, Iowa. However, the results indicated just the opposite in Oklahoma. It is hypothesized that the result is explained by the misclassification of tornadoes that were worthy of F2-F5 rating but were classified as F0-F1 tornadoes, thereby artificially decreasing the number of F2-F5 and increasing the number of F0-F1 reports in rural Oklahoma.

Weather and Forecasting

A comparison of surface water natural organic matter in raw filtered water samples, XAD, and reverse osmosis isolates

This research compared raw filtered waters (RFWs), XAD resin isolates (XAD-8 and XAD-4), and reverse osmosis (RO) isolates of several surface water samples from McDonalds Branch, a small freshwater fen in the New Jersey Pine Barrens (USA). RO and XAD-8 are two of the most common techniques used to isolate natural organic matter (NOM) for studies of composition and reactivity; therefore, it is important to understand how the isolates differ from bulk (unisolated) samples and from one another. Although, any comparison between the isolation methods needs to consider that XAD-8 is specifically designed to isolate the humic fraction, whereas RO concentrates a broad range of organic matter and is not specific to humics. The comparison included for all samples: weight average molecular weight ( M w ), number average molecular weight ( M n ), polydispersity ( ρ ), absorbance at 280 nm normalized to moles C ( ε 280 ) (RFW and isolates); and for isolates only: elemental analysis, % carbon distribution by 13 C NMR, and aqueous FTIR spectra. As expected, RO isolation gave higher yield of NOM than XAD-8, but also higher ash content, especially Si and S. M w decreased in the order: RO>XAD-8>RFW>XAD-4. The M w differences of isolates compared with RFW may be due to selective isolation (fractionation), or possibly in the case of RO to condensation or coagulation during isolation. 13 C NMR results were roughly similar for the two methods, but the XAD-8 isolate was slightly higher in ‘aromatic’ C and the RO isolate was slightly higher in heteroaliphatic and carbonyl C. Infrared spectra indicated a higher carboxyl content for the XAD-8 isolates and a higher ester:carboxyl ratio for the RO isolates. The spectroscopic data thus are consistent with selective isolation of more hydrophobic compounds by XAD-8, and also with potential ester hydrolysis during that process, although further study is needed to determine whether ester hydrolysis does indeed occur. Researchers choosing between XAD and RO isolation methods for NOM need to consider first the purpose of the isolation; i.e., whether humic fractionation is desirable. Beyond that, they should consider the C yield and ash content, as well as the potential for alteration of NOM by ester hydrolysis (XAD) or condensation/coagulation (RO). Furthermore, the RO and XAD methods produce different fractions or isolates so that researchers should be careful when comparing the compositions and reactivities of NOM samples isolated by these two different techniques.

Water Research