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Peter W. Swarzenski

Publications and source records attributed to Peter W. Swarzenski.

At least 37 records · Page 2Linked to original sources

Nitrogen deposition effects on diatom communities in lakes from three National Parks in Washington State

The goal of this study was to document if lakes in National Parks in Washington have exceeded critical levels of nitrogen (N) deposition, as observed in other Western States. We measured atmospheric N deposition, lake water quality, and sediment diatoms at our study lakes. Water chemistry showed that our study lakes were ultra-oligotrophic with ammonia and nitrate concentrations often at or below detection limits with low specific conductance (−1 year −1 and were variable both within and across the parks. Diatom assemblages in a single sediment core from Hoh Lake (Olympic National Park) displayed a shift to increased relative abundances of Asterionella formosa and Fragilaria tenera beginning in the 1969–1975 timeframe, whereas these species were not found at the remaining (nine) sites. These diatom species are known to be indicative of N enrichment and were used to determine an empirical critical load of N deposition, or threshold level, where changes in diatom communities were observed at Hoh Lake. However, N deposition at the remaining nine lakes does not seem to exceed a critical load at this time. At Milk Lake, also in Olympic National Park, there was some evidence that climate change might be altering diatom communities, but more research is needed to confirm this. We used modeled precipitation for Hoh Lake and annual inorganic N concentrations from a nearby National Atmospheric Deposition Program station, to calculate elevation-corrected N deposition for 1980–2009 at Hoh Lake. An exponential fit to this data was hindcasted to the 1969–1975 time period, and we estimate a critical load of 1.0 to 1.2 kg N ha −1 year −1 for wet deposition for this lake.

Washington

Alpha-emitting isotopes and chromium in a coastal California aquifer

The unadjusted 72-h gross alpha activities in water from two wells completed in marine and alluvial deposits in a coastal southern California aquifer 40 km north of San Diego were 15 and 25 picoCuries per liter (pCi/L). Although activities were below the Maximum Contaminant Level (MCL) of 15 pCi/L, when adjusted for uranium activity; there is concern that new wells in the area may exceed MCLs, or that future regulations may limit water use from the wells. Coupled well-bore flow and depth-dependent water-quality data collected from the wells in 2011 (with analyses for isotopes within the uranium, actinium, and thorium decay-chains) show gross alpha activity in marine deposits is associated with decay of naturally-occurring 238 U and its daughter 234 U. Radon activities in marine deposits were as high as 2230 pCi/L. In contrast, gross alpha activities in overlying alluvium within the Piedra de Lumbre watershed, eroded from the nearby San Onofre Hills, were associated with decay of 232 Th, including its daughter 224 Ra. Radon activities in alluvium from Piedra de Lumbre of 450 pCi/L were lower than in marine deposits. Chromium VI concentrations in marine deposits were less than the California MCL of 10 μg/L (effective July 1, 2014) but δ 53 Cr compositions were near zero and within reported ranges for anthropogenic chromium. Alluvial deposits from the nearby Las Flores watershed, which drains a larger area having diverse geology, has low alpha activities and chromium as a result of geologic and geochemical conditions and may be more promising for future water-supply development.

California

Using lead isotopes and trace element records from two contrasting Lake Tanganyika sediment cores to assess watershed – Lake exchange

Lead isotopic and trace element records of two contrasting sediment cores were examined to reconstruct historic, industrial contaminant inputs to Lake Tanganyika, Africa. Observed fluxes of Co, Cu, Mn, Ni, Pb, and Zn in age-dated sediments collected from the lake varied both spatially and temporally over the past two to four centuries. The fluxes of trace elements were lower (up to 10-fold) at a mid-lake site (MC1) than at a nearshore site (LT-98-58), which is directly downstream from the Kahama and Nyasanga River watersheds and adjacent to the relatively pristine Gombe Stream National Park. Trace element fluxes at that nearshore site did not measurably change over the last two centuries (1815&ndash;1998), while the distal, mid-lake site exhibited substantial changes in the fluxes of trace elements &ndash; likely caused by changes in land use &ndash; over that period. For example, the flux of Pb increased by &sim;300% from 1871 to 1991. That apparent accelerated weathering and detrital mobilization of lithogenic trace elements was further evidenced by (i) positive correlations (r = 0.77&ndash;0.99, p < 0.05) between the fluxes of Co, Cu, Mn, Ni, Pb, and Zn and those of iron (Fe) at both sites, (ii) positive correlations (r = 0.82&ndash;0.98, p < 0.01, n = 9) between the fluxes of elements (Al, Co, Cu, Fe, Mn, Ni, Pb, and Zn) and the mass accumulation rates at the offshore site, (iii) the low enrichment factors (EF < 5) of those trace elements, and (iv) the temporal consistencies of the isotopic composition of Pb in the sediment. These measurements indicate that accelerated weathering, rather than industrialization, accounts for most of the increases in trace element fluxes to Lake Tanganyika in spite of the development of mining and smelting operations within the lake&rsquo;s watershed over the past century. The data also indicate that the mid-lake site is a much more sensitive and useful recorder of environmental changes than the nearshore site. Furthermore, the lead isotopic compositions of sediment at the sites differed spatially, indicating that the Pb (and other trace elements by association) originated from different natural sources at the two locations.

Lake Tanganyika

Mercury dynamics in a coastal aquifer: Maunalua Bay, Oʻahu, Hawaiʻi

We evaluated the influence of groundwater–seawater interaction on mercury dynamics in Maunalua Bay, a coral reef ecosystem located on the south shore of Oʻahu, Hawaiʻi, by combining geochemical data with submarine groundwater discharge (SGD) rates. During a rising tide, unfiltered total mercury (U-HgT) concentrations in seawater increased from ∼6 to 20 pM at Black Point (west Bay) and from ∼2.5 to 8 pM at Niu (central Bay). We attribute this change to an increase in suspended particulate matter at high tide. Approximately 90% of mercury in groundwater at Niu was in the filtered (<0.45 μm) fraction, with a concentration of ∼4 pM. Groundwater discharge during a period of amplified SGD at Niu appeared to contribute to an increase in total mercury concentrations in filtered seawater (F-HgT; 1.2 to 2.4 pM) and in unfiltered seawater (U-HgT; 2.5 to 3.2 pM). The larger magnitude of change in F-HgT relative to U-HgT suggests mercury complexation and/or solubility dynamics in seawater were altered by the addition of groundwater. We used site specific 222 Rn derived SGD flux estimates and groundwater F-HgT concentrations to calculate mercury loadings at Black Point (∼3 nmol m −2 d −1 ) and at Niu (∼1 nmol m −2 d −1 ). We calculated a weighted average Maunalua Bay groundwater mercury flux of 0.68 ± 0.67 mol yr −1 by combining the proportional flux of F-HgT from three distinct SGD zones, and place these results into a broader context by comparing and contrasting flux estimates from locations around the world. Results from existing SGD studies should be evaluated to develop future sampling strategies that address more targeted questions about mercury biogeochemical cycling at the groundwater–seawater interface.

Hawai'i

Editorial for Journal of Hydrology: Regional Studies

Hydrological regimes and processes show strong regional differences. While some regions are affected by extreme drought and desertification, others are under threat of increased fluvial and/or pluvial floods. Changes to hydrological systems as a consequence of natural variations and human activities are region-specific. Many of these changes have significant interactions with and implications for human life and ecosystems. Amongst others, population growth, improvements in living standards and other demographic and socio-economic trends, related changes in water and energy demands, change in land use, water abstractions and returns to the hydrological system (UNEP, 2008), introduce temporal and spatial changes to the system and cause contamination of surface and ground waters. Hydro-meteorological boundary conditions are also undergoing spatial and temporal changes. Climate change has been shown to increase temporal and spatial variations of rainfall, increase temperature and cause changes to evapotranspiration and other hydro-meteorological variables (IPCC, 2013). However, these changes are also region specific. In addition to these climate trends, (multi)-decadal oscillatory changes in climatic conditions and large variations in meteorological conditions will continue to occur.

Journal of Hydrology: Regional Studies

A geochemical and geophysical assessment of coastal groundwater discharge at select sites in Maui and O’ahu, Hawai’i

This chapter summarizes fieldwork conducted to derive new estimates of coastal groundwater discharge and associated nutrient loadings at select coastal sites in Hawai’i, USA. Locations for this work were typically identified based on pronounced, recent ecosystem degradation that may at least partially be attributable to sustained coastal groundwater discharge. Our suite of tools used to evaluate groundwater discharge included select U/Th series radionuclides, a broad spectrum of geochemical analytes, multi-channel electrical resistivity, and in situ oceanographic observations. Based on the submarine groundwater discharge tracer 222Rn, coastal groundwater discharge rates ranged from about 22–50 cm per day at Kahekili, a site in the Ka’anapali region north of Lahaina in west Maui, while at Black Point in Maunalua Bay along southern O’ahu, coastal groundwater discharge rates ranged up to 700 cm per day, although the mean discharge rate at this site was 60 cm per day. The water chemistry of the discharging groundwater can be dramatically different than ambient seawater at both coastal sites. For example, at Kahekili the average concentrations of dissolved inorganic nitrogen (DIN), dissolved silicate (DSi) and total dissolved phosphorus (TDP) were roughly 188-, 36-, and 106-times higher in the discharging groundwater relative to ambient seawater, respectively. Such data extend our basic understanding of the physical controls on coastal groundwater discharge and provide an estimate of the magnitude and physical forcings of submarine groundwater discharge and associated trace metal and nutrient loads conveyed by this submarine route.

Hawaii

A combined radio- and stable-isotopic study of a California coastal aquifer system

Stable and radioactive tracers were utilized in concert to characterize geochemical processes in a complex coastal groundwater system and to provide constraints on the kinetics of rock/water interactions. Groundwater samples from wells within the Dominguez Gap region of Los Angeles County, California were analyzed for a suite of major cations (Na + , K + , Mg 2+ , Ca 2+ ) and anions (Cl − , SO 4 2− ), silica, alkalinity, select trace elements (Ba, B, Sr), dissolved oxygen, stable isotopes of hydrogen (δD), oxygen (δ 18 O), dissolved inorganic carbon (δ 13 C DIC ), and radioactive isotopes ( 3 H, 222 Rn and 223,224,226,228 Ra). In the study area, groundwater may consist of a complex mixture of native groundwater, intruded seawater, non-native injected water, and oil-field brine water. In some wells, Cl − concentrations attained seawater-like values and in conjunction with isotopically heavier δ 18 O values, these tracers provide information on the extent of seawater intrusion and/or mixing with oil-field brines. Groundwater 3 H above 1 tritium unit (TU) was observed only in a few select wells close to the Dominguez Gap area and most other well groundwater was aged pre-1952. Based on an initial 14 C value for the study site of 90 percent modern carbon (pmc), groundwater age estimates likely extend beyond 20 kyr before present and confirm deep circulation of some native groundwater through multiple aquifers. Enriched values of groundwater δ 13 C DIC in the absence of SO 4 2− imply enhanced anaerobic microbial methanogenesis. While secular equilibrium was observed for 234 U/ 238 U (activity ratios ~1) in host matrices, strong isotopic fractionation in these groundwater samples can be used to obtain information of adsorption/desorption kinetics. Calculated Ra residence times are short, and the associated desorption rate constant is about three orders of magnitude slower than that of the adsorption rate constant. Combined stable- and radio-isotopic results provide unique insights into aquifer characteristics, such as geochemical cycling, rock/water interactions, and subsurface transport and mixing.

California

Short-term variability of 7 Be atmospheric deposition and watershed response in a Pacific coastal stream, Monterey Bay, California, USA

Beryllium-7 is a powerful and commonly used tracer for environmental processes such as watershed sediment provenance, soil erosion, fluvial and nearshore sediment cycling, and atmospheric fallout. However, few studies have quantified temporal or spatial variability of 7 Be accumulation from atmospheric fallout, and parameters that would better define the uses and limitations of this geochemical tracer. We investigated the abundance and variability of 7 Be in atmospheric deposition in both rain events and dry periods, and in stream surface-water samples collected over a ten-month interval at sites near northern Monterey Bay (37°N, 122°W) on the central California coast, a region characterized by a rainy winters, dry summers, and small mountainous streams with flashy hydrology. The range of 7 Be activity in rainwater samples from the main sampling site was 1.3–4.4 Bq L −1 , with a mean (±standard deviation) of 2.2 ± 0.9 Bq L −1 , and a volume-weighted average of 2.0 Bq L −1 . The range of wet atmospheric deposition was 18–188 Bq m −2 per rain event, with a mean of 72 ± 53 Bq m −2 . Dry deposition fluxes of 7 Be ranged from less than 0.01 up to 0.45 Bq m −2 d −1 , with an estimated dry season deposition of 7 Bq m −2 month −1 . Annualized 7 Be atmospheric deposition was approximately 1900 Bq m −2 yr −1 , with most deposition via rainwater (>95%) and little via dry deposition. Overall, these activities and deposition fluxes are similar to values found in other coastal locations with comparable latitude and Mediterranean-type climate. Particulate 7 Be values in the surface water of the San Lorenzo River in Santa Cruz, California, ranged from <0.01 Bq g −1 to 0.6 Bq g −1 , with a median activity of 0.26 Bq g −1 . A large storm event in January 2010 characterized by prolonged flooding resulted in the entrainment of 7 Be-depleted sediment, presumably from substantial erosion in the watershed. There were too few particulate 7 Be data over the storm to accurately model a 7 Be load, but the results suggest enhanced watershed export of 7 Be from small, mountainous river systems compared to other watershed types.

California

Integration of bed characteristics, geochemical tracers, current measurements, and numerical modeling for assessing the provenance of beach sand in the San Francisco Bay Coastal System

Over 150 million m 3 of sand-sized sediment has disappeared from the central region of the San Francisco Bay Coastal System during the last half century. This enormous loss may reflect numerous anthropogenic influences, such as watershed damming, bay-fill development, aggregate mining, and dredging. The reduction in Bay sediment also appears to be linked to a reduction in sediment supply and recent widespread erosion of adjacent beaches, wetlands, and submarine environments. A unique, multi-faceted provenance study was performed to definitively establish the primary sources, sinks, and transport pathways of beach-sized sand in the region, thereby identifying the activities and processes that directly limit supply to the outer coast. This integrative program is based on comprehensive surficial sediment sampling of the San Francisco Bay Coastal System, including the seabed, Bay floor, area beaches, adjacent rock units, and major drainages. Analyses of sample morphometrics and biological composition (e.g., Foraminifera) were then integrated with a suite of tracers including 87 Sr/ 86 Sr and 143 Nd/ 144 Nd isotopes, rare earth elements, semi-quantitative X-ray diffraction mineralogy, and heavy minerals, and with process-based numerical modeling, in situ current measurements, and bedform asymmetry to robustly determine the provenance of beach-sized sand in the region.

California

A Sr-Nd isotopic study of sand-sized sediment provenance and transport for the San Francisco Bay coastal system

A diverse suite of geochemical tracers, including 87 Sr/ 86 Sr and 143 Nd/ 144 Nd isotope ratios, the rare earth elements (REEs), and select trace elements were used to determine sand-sized sediment provenance and transport pathways within the San Francisco Bay coastal system. This study complements a large interdisciplinary effort (Barnard et al., 2012) that seeks to better understand recent geomorphic change in a highly urbanized and dynamic estuarine-coastal setting. Sand-sized sediment provenance in this geologically complex system is important to estuarine resource managers and was assessed by examining the geographic distribution of this suite of geochemical tracers from the primary sources (fluvial and rock) throughout the bay, adjacent coast, and beaches. Due to their intrinsic geochemical nature, 143 Nd/ 144 Nd isotopic ratios provide the most resolved picture of where sediment in this system is likely sourced and how it moves through this estuarine system into the Pacific Ocean. For example, Nd isotopes confirm that the predominant source of sand-sized sediment to Suisun Bay, San Pablo Bay, and Central Bay is the Sierra Nevada Batholith via the Sacramento River, with lesser contributions from the Napa and San Joaquin Rivers. Isotopic ratios also reveal hot-spots of local sediment accumulation, such as the basalt and chert deposits around the Golden Gate Bridge and the high magnetite deposits of Ocean Beach. Sand-sized sediment that exits San Francisco Bay accumulates on the ebb-tidal delta and is in part conveyed southward by long-shore currents. Broadly, the geochemical tracers reveal a complex story of multiple sediment sources, dynamic intra-bay sediment mixing and reworking, and eventual dilution and transport by energetic marine processes. Combined geochemical results provide information on sediment movement into and through San Francisco Bay and further our understanding of how sustained anthropogenic activities which limit sediment inputs to the system (e.g., dike and dam construction) as well as those which directly remove sediments from within the Bay, such as aggregate mining and dredging, can have long-lasting effects

California

An investigation of submarine groundwater—borne nutrient fluxes to the west Florida shelf and recurrent harmful algal blooms

A cross‐shelf, water‐column mass balance of radon‐222 ( 222 Rn) provided estimates of submarine groundwater discharge (SGD), which were then used to quantify benthic nutrient fluxes. Surface water and groundwater were collected along a shore‐normal transect that extended from Tampa Bay, Florida, across the Pinellas County peninsula, to the 10‐m isobath in the Gulf of Mexico. Samples were analyzed for 222 Rn and radium‐223,224,226 ( 223,224,226 Ra) activities as well as inorganic and organic nutrients. Cross‐shore gradients of 222 Rn and 223,224,226 Ra activities indicate a nearshore source for these isotopes, which mixes with water characterized by low activities offshore. Radon‐based SGD rates vary between 2.5 and 15 cm d −1 proximal to the shoreline and decrease offshore. The source of SGD is largely shallow exchange between surface and pore waters, although deeper groundwater cycling may also be important. Enrichment of total dissolved nitrogen and soluble reactive phosphorus in pore water combined with SGD rates results in specific nutrient fluxes comparable to or greater than estuarine fluxes from Tampa Bay. The significance of these fluxes to nearshore blooms of Karenia brevis is highlighted by comparison with prescribed nutrient demands for bloom maintenance and growth. Whereas our flux estimates do not indicate SGD and benthic fluxes as the dominant nutrient source to the harmful algal blooms, SGD‐derived loads do narrow the deficit between documented nutrient supplies and bloom demands.

Florida

Utilizing multichannel electrical resistivity methods to examine the dynamics of the fresh water–seawater interface in two Hawaiian groundwater systems

Multichannel electrical resistivity (ER) measurements were conducted at two contrasting coastal sites in Hawaii to obtain new information on the spatial scales and dynamics of the fresh water&ndash;seawater interface and rates of coastal groundwater exchange. At Kiholo Bay (located on the dry, Kona side of the Big Island) and at a site in Maunalua Bay (Oahu), there is an evidence for abundant submarine groundwater discharge (SGD). However, the hydrologic and geologic controls on coastal groundwater discharge are likely to be different at these two sites. While at Kiholo Bay SGD is predominantly through lava tubes, at the Maunalua Bay site exchange occurs mostly through nearshore submarine springs. In order to calculate SGD fluxes, it is important to understand the spatial and temporal scales of coastal groundwater exchange. From ER time series data, subsurface salinity distributions were calculated using site-specific formation factors. A salinity mass balance box model was then used to calculate rates of point source (i.e., spatially discreet) and total fresh water discharge. From these data, mean SGD rates were calculated for Kiholo Bay (&sim;9,200 m 3 /d) and for the Maunalua Bay site (&sim;5,900 m 3 /d). While such results are on the same order of magnitude to geochemical tracer-derived SGD rates, the ER SGD rates provide enhanced details of coastal groundwater exchange that can enable a more cohesive whole watershed perspective.

Hawai'i

Mercury speciation and transport via submarine groundwater discharge at a southern California coastal lagoon system

We measured total mercury (HgT) and monomethylmercury (MMHg) concentrations in coastal groundwater and seawater over a range of tidal conditions near Malibu Lagoon, California, and used 222Rn-derived estimates of submarine groundwater discharge (SGD) to assess the flux of mercury species to nearshore seawater. We infer a groundwater-seawater mixing scenario based on salinity and temperature trends and suggest that increased groundwater discharge to the ocean during low tide transported mercury offshore. Unfiltered HgT (U-HgT) concentrations in groundwater (2.2–5.9 pM) and seawater (3.3–5.2 pM) decreased during a falling tide, with groundwater U-HgT concentrations typically lower than seawater concentrations. Despite the low HgT in groundwater, bioaccumulative MMHg was produced in onshore sediment as evidenced by elevated MMHg concentrations in groundwater (0.2–1 pM) relative to seawater (∼0.1 pM) throughout most of the tidal cycle. During low tide, groundwater appeared to transport MMHg to the coast, resulting in a 5-fold increase in seawater MMHg (from 0.1 to 0.5 pM). Similarly, filtered HgT (F-HgT) concentrations in seawater increased approximately 7-fold during low tide (from 0.5 to 3.6 pM). These elevated seawater F-HgT concentrations exceeded those in filtered and unfiltered groundwater during low tide, but were similar to seawater U-HgT concentrations, suggesting that enhanced SGD altered mercury partitioning and/or solubilization dynamics in coastal waters. Finally, we estimate that the SGD HgT and MMHg fluxes to seawater were 0.41 and 0.15 nmol m–2 d–1, respectively – comparable in magnitude to atmospheric and benthic fluxes in similar environments.

California

Recent paleorecords document rising mercury contamination in Lake Tanganyika

Recent Lake Tanganyika Hg deposition records were derived using 14 C and excess 210 Pb geochronometers in sediment cores collected from two contrasting depositional environments: the Kalya Platform, located mid-lake and more removed from watershed impacts, and the Nyasanga/Kahama River delta region, located close to the lake’s shoreline north of Kigoma. At the Kalya Platform area, pre-industrial Hg concentrations are 23 ± 0.2 ng/g, increasing to 74 ng/g in modern surface sediment, and the Hg accumulation rate has increased from 1.0 to 7.2 μg/m 2 /a from pre-industrial to present, which overall represents a 6-fold increase in Hg concentration and accumulation. At the Nyasanga/Kahama delta region, pre-industrial Hg concentrations are 20 ± 3 ng/g, increasing to 46 ng/g in surface sediment. Mercury accumulation rate has increased from 30 to 70 μg/m 2 /a at this site, representing a 2–3-fold increase in Hg concentration and accumulation. There is a lack of correlation between charcoal abundance and Hg accumulation rate in the sediment cores, demonstrating that local biomass burning has little relationship with the observed Hg concentration or Hg accumulation rates. Examined using a sediment focusing-corrected mass accumulation rate approach, the cores have similar anthropogenic atmospheric Hg deposition profiles, suggesting that after accounting for background sediment concentrations the source of accumulating Hg is predominantly atmospheric in origin. In summary, the data document an increase of Hg flux to the Lake Tanganyika ecosystem that is consistent with increasing watershed sediment delivery with background-level Hg contamination, and regional as well as global increases in atmospheric Hg deposition.

Tanzania, the Democratic Republic of the Congo , B

Dissolved and colloidal trace elements in the Mississippi River Delta outflow after Hurricanes Katrina and Rita

The Mississippi River delta outflow region is periodically disturbed by tropical weather systems including major hurricanes, which can terminate seasonal bottom water hypoxia and cause the resuspension of shelf bottom sediments which could result in the injection of trace elements into the water column. In the summer of 2005, Hurricanes Katrina and Rita passed over the Louisiana Shelf within a month of each other. Three weeks after Rita, we collected water samples in the Mississippi River delta outflow, examining the distributions of trace elements to study the effect of Hurricanes Katrina and Rita. We observed limited stratification on the shelf and bottom waters that were no longer hypoxic. This resulted, for instance, in bottom water dissolved Mn being lower than is typically observed during hypoxia, but with concentrations still compatible with Mn–O2 trends previously reported. Interestingly, for no element were we able to identify an obvious effect of sediment resuspension on its distribution. In general, elemental distributions were compatible with previous observations in the Mississippi outflow system. Co and Re, which have not been reported for this system previously, showed behavior consistent with other systems: input for Co likely from desorption and conservative mixing for Re. For Cs, an element for which there is little information regarding its estuarine behavior, conservative mixing was also observed. Our filtration method, which allowed us to distinguish the dissolved (<0.02 μm) from colloidal (0.02–0.45 μm) phase, revealed significant colloidal fractions for Fe and Zn, only. For Fe, the colloidal phase was the dominant fraction and was rapidly removed at low salinity. Dissolved Fe, in contrast, persisted out to mid-salinities, being removed in a similar fashion to nitrate. This ability to distinguish the smaller Fe (likely dominantly organically complexed) from larger colloidal suspensates may be useful in better interpreting the bioavailablity of the Fe in estuarine systems.

Mississippi River

Atmospheric deposition, water-quality, and sediment data for selected lakes in Mount Rainer, North Cascades, and Olympic National Parks, Washington, 2008-10

To evaluate the potential effect from atmospheric deposition of nitrogen to high-elevation lakes, the U.S. Geological Survey partnered with the National Park Service to develop a "critical load" of nitrogen for sediment diatoms. A critical load is defined as the level of a given pollutant (in this case, nitrogen) at which detrimental effects to a target endpoint (sediment diatoms) result. Because sediment diatoms are considered one of the "first responders" to ecosystem changes from nitrogen, they are a sensitive indicator for nitrogen deposition changes in natural areas. This report presents atmospheric deposition, water quality, sediment geochronology, and sediment diatom data collected from July 2008 through August 2010 in support of this effort.

Washington

Nearshore morphology, benthic structure, hydrodynamics, and coastal groundwater discharge near Kahekili Beach Park, Maui, Hawaii

This report presents a brief summary of recent fieldwork conducted off Kahekili Beach Park, Maui, Hawaii, the site of the newly established U.S. Coral Reef Task Force priority study area at Kaanapali and the Hawaii Department of Land and Natural Resources, Division of Aquatic Resources, Kahekili Herbivore Fisheries Management Area (HFMA). The goals of this fieldwork are to provide new baseline information to help guide future studies and to provide first insights into rates and drivers of coastal groundwater discharge and associated constituent loadings into the priority study area's coastal waters. This study presents the first swath acoustic mapping information, in situ oceanographic instrument measurements, and coastal groundwater discharge estimates at this site based on the submarine groundwater discharge tracer radon-222 ( 222 Rn). Coastal groundwater discharge rates ranged from about 22 to 50 centimeters per day, depending on proximity of the sampling mooring to the primary discharge vent. The water chemistry of the discharging groundwater was at times dramatically different than ambient seawater. For example, at the primary vent site at Kahekili, the concentrations of total dissolved nitrogen (TDN), dissolved silicate (DSi), and total dissolved phosphorus (TDP) in the discharging groundwater were 43.75 micromolar (&mu;M), 583.49 &mu;M, and 12.04 &mu;M, respectively. These data extend our basic understanding of the morphology, benthic structure, and oceanographic setting of this vent site and provide a first estimate of the magnitude and physical forcings of submarine groundwater discharge and associated trace metals and nutrient loads here.

Hawai'i

Coastal circulation and sediment dynamics in Pelekane and Kawaihae Bays, Hawaii--measurements of waves, currents, temperature, salinity, turbidity, and geochronology: November 2010--March 2011

Coral reef communities on the Island of Hawaii have been heavily affected by the construction of Kawaihae Harbor in the 1950s and by subsequent changes in land use in the adjacent watershed. Sedimentation and other forms of land-based pollution have led to declines in water quality and coral reef health over the past two decades (Tissot, 1998). Erosion mitigation efforts are underway on land, and there is a need to evaluate the impact of these actions on the adjacent coastal ecosystem. The Kohala Center and Kohala Watershed Partnership was awarded $2.69 million from the National Oceanographic and Atmospheric Administration’s (NOAA) Restoration Center as part of the American Recovery and Reinvestment Act of 2009 to stabilize soil and improve land-use practices in the Pelekane Bay watershed. The grant allowed the Kohala Watershed Partnership to implement various upland watershed management activities to reduce land-based sources of pollution into Pelekane Bay. However, a number of questions must be answered in order to: (1) evaluate the effectiveness of the terrestrial watershed remediation efforts; (2) understand the potential of the local marine ecosystem to recover; and (3) understand the potential threat that existing mud deposits in the bay pose to adjacent, relatively pristine coral reef ecosystems. The goal of this experiment was to help address these questions and establish a framework to evaluate the success of the Kohala Watershed Partnership restoration efforts. This research program will also provide resource managers with information relevant to other watershed restoration efforts currently being planned in neighboring watersheds. This project involved an interdisciplinary team of coral reef biologists from the University of Hawaii Coral Reef Assessment and Monitoring Program, who focused on the impact of sedimentation on the biota of Pelekane Bay, and a team of geologists and oceanographers from the U.S. Geological Survey (USGS), who focused on the circulation and sediment dynamics in Pelekane and Kawaihae Bays. The initial findings from the USGS research program are described in this report. These measurements support the ongoing studies being conducted as part of the USGS Coastal and Marine Geology Program’s Pacific Coral Reef Project to better understand the effect of geologic and oceanographic processes on coral reef systems.

Hawai'i