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Peter Schultheiss

Publications and source records attributed to Peter Schultheiss.

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Proceedings of the Deepwater Hydrate Coring Expedition UT-GOM2-2

This report was the result of a scientific collaboration between the following institutions The University of Texas at Austin (UT), DOE, NETL, the United States Geological Survey (USGS), the Bureau of Ocean Energy Management (BOEM), The Ohio State University, Columbia University, University of New Hampshire, Oregon State University, University of Washington, Tufts University, Colorado School of Mines, and Geotek Ltd. In the summer and fall of 2023, the University of Texas (UT) Deepwater Hydrate Coring Expedition (UT-GOM2-2) drilled, cored, made downhole measurements, and analyzed samples from the seafloor to the base of the gas hydrate stability zone at Site H in the Walker Ridge Protracted Area Block 313 (Site H, WR313) in the Terrebonne basin, deepwater Gulf of America (Gulf of Mexico), herein the Gulf. This report is made up of a series of files as listed below that represents the “expedition report” of the 2023 UT-GOM2-2 Expedition.

Report

Terrebonne Basin northern Gulf of Mexico, 30 July-28 September 2023

In the summer and fall of 2023, the Gulf of Mexico Deepwater Hydrate Coring Expedition (UT-GOM2-2) drilled, cored, made downhole measurements, and analyzed samples from the seafloor to the base of the gas hydrate stability zone in one location (Site H, WR313) in the Terrebonne basin, deepwater Gulf of Mexico. Analyses of data and samples from the expedition will inform biological, geochemical, and geomechanical models to constrain the role of gas hydrates in the carbon cycle and the potential for gas hydrates as an energy resource. Pressure and conventional cores were collected continuously to a depth of 155.1 meters below the seafloor (mbsf). At deeper depths, cores were taken periodically from hydrate-bearing sands and their bounding muds to a total depth of 861.3 mbsf. 162.6 m of conventional core and 54.8 m of pressure core were obtained. Twelve temperature measurements were made between 27.1 and 144.5 mbsf to determine the geothermal gradient. At the seafloor, more than 4 m of sandy silt of unknown origin was encountered. Beneath this sand, to a depth of ~200 mbsf, the section was composed of interbedded mud and biogenic carbonate ooze. The biogenic ooze correlated to low density and high porosity intervals observed in the previously acquired logging while drilling (LWD) data and as measured. Calcareous nannofossil biostratigraphy constrains the entire record to the Pleistocene (< 0.91 million years) with a pronounced increase in sedimentation rate with depth. Beneath 200 mbsf, the section was predominantly composed of mud with two thicker, hydrate-bearing coarse-grained intervals, which are commonly known as the Blue and Orange sands. The dissolved gas concentration was quantified from pressure cores. In the shallow section, dissolved methane concentration increased below the sulfate-methane transition zone (SMTZ) and reaches saturation (the limit of solubility for methane) at 147 mbsf. Gas expansion was very common in conventional and depressurized pressure (conventionalized) cores below the SMTZ. At deeper depths, the methane concentration within muds bounding the Blue and Orange reservoirs was generally found to be less than saturation. The dissolved and hydrate gas composition is consistent with a microbial source, containing greater than 99.99% methane and only trace concentrations of ethane, propane, and butane. The methane to ethane ratio (C 1 /C 2 ) and the methane to ethane plus propane (C 1 /(C 2 +C 3 )) decrease with depth down to at least 678 mbsf, mainly driven by the increase in ethane with depth. It is unclear if this trend continues through the Orange sand interval. The δ 13 C isotopic signature of methane ranges between -69.9 and -78.5 ‰ Vienna Pee Dee Belemnite (VPDB). Pressure core recovery of all sandy intervals was poor. However, pressure core logs of the Orange sand show intervals of low density and high velocity, which are indicative of high hydrate saturation. One core from within the Orange sand was composed of interbedded graded sandy silt and mud. The sandy silts from this core are composed of mainly quartz and feldspar with some lithics. Most of the recovered pressure core samples are maintained at near in-situ pressure and temperature (within the hydrate stability field) at the University of Texas Pressure Core Center awaiting analysis. In the shallow section, samples will be used to determine the flux of organic carbon through the basin system, find the rate at which that carbon was consumed, and understand the microbial population responsible for these processes. In the deeper section, samples from in and around the hydrate reservoirs will be used to determine the petrophysical properties of the reservoir and bounding seals in these systems.

Gulf of Mexico, Terrebonne Basin

High concentration methane hydrate in a silt reservoir from the deep-water Gulf of Mexico

We present results from 30 quantitative degassing experiments of pressure core sections collected during The University of Texas-Gulf of Mexico 2-1 (UT-GOM2-1) Hydrate Pressure Coring Expedition at Green Canyon Block 955 in the deep-water Gulf of Mexico as part of The University of Texas at Austin–US Department of Energy Deepwater Methane Hydrate Characterization and Scientific Assessment. The hydrate saturation ( S h ), the volume fraction of the pore space occupied by hydrate, is 79% to 93% within sandy silt beds (centimeters to meters in thickness) between 413 and 442 m below seafloor in 2032 m water depth. Sandy silt intervals are characterized by high compressional wave velocity ( V p ) (2515–3012 m s −1 ) and are interbedded with clayey silt sections that have lower S h (2%–35%) and lower V p (1684–2023 m s −1 ). Clayey silt intervals are composed of thin laminae of silts with high S h within clay-rich intervals containing little to no hydrate. Degassing of single-lithofacies sections reveals higher-resolution variation in S h than is possible to observe in well logs; however, the average S h of 64% through the reservoir is similar to well log estimates. Gas recovered from the hydrates during these experiments is composed almost entirely of methane (99.99% CH 4 , <100 ppm C 2 H 6 on average), with an isotopic composition (δ 13 C: −60.4‰ and −63.6‰ Vienna Peedee belemnite and δ 2 H: −178.2‰ and −179.0‰ Vienna standard mean ocean water) that suggests the methane is primarily from a microbial source. A subset of six degassing experiments performed using very small pressure decrements indicates that the salinity within these samples is close to the average seawater concentration, suggesting that hydrate either formed slowly or formed during a rapid event at least tens of thousands of years before present.

Texas, Louisiana

Pressure coring operations during The University of Texas-Gulf of Mexico 2-1 (UT-GOM2-1) Hydrate Pressure Coring Expedition in Green Canyon Block 955, northern Gulf of Mexico

In May 2017, The University of Texas Hydrate Pressure Coring Expedition Gulf of Mexico 2-1 (UT-GOM2-1) drilled two adjacent holes in Green Canyon Block 955 in the deep-water Gulf of Mexico as part of The University of Texas at Austin and US Department of Energy Deepwater Methane Hydrate Characterization and Scientific Assessment. Expedition operations included testing two configurations of a rotary pressure-coring tool in a gas hydrate–bearing formation. In the first hole, an extended core barrel (cutting shoe) configuration of the Pressure Coring Tool with Ball Valve (PCTB-CS) was deployed, and in the second hole, the PCTB face bit configuration (PCTB-FB) was deployed. The PCTB-CS successfully recovered and maintained pressure for only one core out of eight deployments. A series of incremental modifications were made during and after the PCTB-CS deployment period that impacted the operations of the subsequent PCTB-FB deployments. Thus, in the second hole, the PCTB-FB successfully recovered and maintained pressure within the hydrate stability zone for 11 cores out of 13 deployments. The PCTB cored gas hydrate–bearing sandy silt interbedded with non–hydrate-bearing clayey silt within the main reservoir. The PCTB also recovered long intervals of unbroken, high-quality core with preserved sedimentary structures. We recovered one pressure core 130 m (437 ft) above the main hydrate reservoir in the silty clay. Pressure coring is the only available technology for recovering intact cores from sediment that is normally disturbed by gas expansion, dissolution, or dissociation; this allows a wide range of scientific measurements to be obtained with minimal disturbance to the core sediment fabric. Analysis of pressure cores has the potential to illuminate the in situ properties, gas saturation, and gas composition of a wide range of reservoirs including unconventional shale systems.

AAPG Bulletin

Pressure coring a Gulf of Mexico deep-water turbidite gas hydrate reservoir: Initial results from The University of Texas–Gulf of Mexico 2-1 (UT-GOM2-1) Hydrate Pressure Coring Expedition

The University of Texas Hydrate Pressure Coring Expedition (UT-GOM2-1) recovered cores at near in situ formation pressures from a gas hydrate reservoir composed of sandy silt and clayey silt beds in Green Canyon Block 955 in the deep-water Gulf of Mexico. The expedition results are synthesized and linked to other detailed analyses presented in this volume. Millimeter- to meter-scale beds of sandy silt and clayey silt are interbedded on the levee of a turbidite channel. The hydrate saturation (the volume fraction of the pore space occupied by hydrate) in the sandy silts ranges from 79% to 93%, and there is little to no hydrate in the clayey silt. Gas from the hydrates is composed of nearly pure methane (99.99%) with less than 400 ppm of ethane or heavier hydrocarbons. The δ 13 C values from the methane are depleted (−60‰ to −65‰ Vienna Peedee belemnite), and it is interpreted that the gases were largely generated by primary microbial methanogenesis but that low concentrations of propane or heavier hydrocarbons record at least trace thermogenic components. The in situ pore-water salinity is very close to that of seawater. This suggests that the excess salinity generated during hydrate formation diffused away because the hydrate formed slowly or because it formed long ago. Because the sandy silt deposits have high hydrate concentration and high intrinsic permeability, they may represent a class of reservoir that can be economically developed. Results from this expedition will inform a new generation of reservoir simulation models that will illuminate how these reservoirs might be best produced.

Texas, Louisiana