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Peter S. Murdoch

Publications and source records attributed to Peter S. Murdoch.

At least 37 records · Page 2Linked to original sources
USGS2005

Effects of a clearcut on the net rates of nitrification and N mineralization in a northern hardwood forest, Catskill Mountains, New York, USA

The Catskill Mountains of southeastern New York receive among the highest rates of atmospheric nitrogen (N) deposition in eastern North America, and ecosystems in the region may be sensitive to human disturbances that affect the N cycle. We studied the effects of a clearcut in a northern hardwood forest within a 24-ha Catskill watershed on the net rates of N mineralization and nitrification in soil plots during 6 years (1994-1999) that encompassed 3-year pre- and post-harvesting periods. Despite stream NO3- concentrations that increased by more than 1400 ??mol l-1 within 5 months after the clearcut, and three measures of NO3- availability in soil that increased 6- to 8-fold during the 1st year after harvest, the net rates of N mineralization and nitrification as measured by in situ incubation in the soil remained unchanged. The net N-mineralization rate in O-horizon soil was 1- 2 mg N kg-1 day-1 and the net nitrification rate was about 1 mg N kg-1 day-1, and rates in B-horizon soil were only one-fifth to one-tenth those of the O-horizon. These rates were obtained in single 625 m2 plots in the clearcut watershed and reference area, and were confirmed by rate measurements at 6 plots in 1999 that showed little difference in N-mineralization and nitrification rates between the treatment and reference areas. Soil temperature increased 1 ?? 0.8??C in a clearcut study plot relative to a reference plot during the post-harvest period, and soil moisture in the clearcut plot was indistinguishable from that in the reference plot. These results are contrary to the initial hypothesis that the clearcut would cause net rates of these N-cycling processes to increase sharply. The in situ incubation method used in this study isolated the samples from ambient roots and thereby prevented plant N uptake; therefore, the increases in stream NO3- concentrations and export following harvest largely reflect diminished uptake. Changes in temperature and moisture after the clearcut were insufficient to measurably affect the net rates of N mineralization and nitrification in the absence of plant uptake. Soil acidification resulting from the harvest may have acted in part to inhibit the rates of these processes. ?? Springer 2005.

Biogeochemistry↗
USGS2005

Stream acidification and mortality of brook trout (Salvelinus fontinalis) in response to timber harvest in Catskill Mountain watersheds, New York, USA

Effects of clear-cut and timber-stand improvement (TSI) harvests on water chemistry and mortality of caged brook trout (Salvelinus fontinalis) were evaluated in a study of three Catskill Mountain streams, 1994-2000. Harvests removed 73% of tree basal area (BA) from a clearcut subbasin, 5% BA from a TSI subbasin, and 14% BA at a site below the confluence of both streams. A fourth nonharvested site served as a control. Water quality and trout mortality were affected only in the clearcut stream. Acidity and concentrations of nitrate and inorganic monomeric aluminum (Alim) increased sharply during high flows after the first growing season (fall 1997). Acid-Alim episodes were severe during this period and decreased steadily in magnitude and duration thereafter. All trout at this site died within 7 days during spring 1998 and 85% died during spring 1999. Only background mortality was observed in other years at this site and at the other three sites during all tests. The absence of mortality in TSI watersheds indicates that limited harvests should not harm brook trout populations in acid-sensitive streams. Effects of tree harvests on fish communities are of concern, however, because many stream-dwelling species are more sensitive to acidified waters than brook trout. ?? 2005 NRC.

Canadian Journal of Fisheries and Aquatic Sciences↗
USGS2005

Assessing acid deposition: Advances in the state of science

NAPAP has a long history of conducting research related to acid deposition. Throughout the 1980s NAPAP supported a large number of research projects that confirmed the link between SO 2 and NO x emissions and acidic lakes and streams hundreds of miles away. Recent research is confirming the tight link between emissions of SO 2 and the amount of several different forms of sulfur in the atmosphere and in precipitation, and improving our ability to measure acid deposition. Research has continued since 1990, albeit on a smaller scale, to increase our understanding of how acid deposition affects trees, soils, lakes, streams, coastal waters, and building materials such as stone and copper. Some of the areas where the most research has been done include: the importance of calcium in mediating soil and forest response to acidification; the role of nitrogen in acidification and recovery from acidification; and the role of nitrogen deposition in coastal ecosystems. In addition, substantial advances have been made in understanding the human health impacts of fine particles, including sulfates and nitrates, which are briefly mentioned here.

Book chapter↗
USGS2004

The application of an integrated biogeochemical model (PnET-BGC) to five forested watersheds in the Adirondack and Catskill regions of New York

PnET-BGC is an integrated biogeochemical model formulated to simulate the response of soil and surface waters in northern forest ecosystems to changes in atmospheric deposition and land disturbances. In this study, the model was applied to five intensive study sites in the Adirondack and Catskill regions of New York. Four were in the Adirondacks: Constable Pond, an acid-sensitive watershed; Arbutus Pond, a relatively insensitive watershed; West Pond, an acid-sensitive watershed with extensive wetland coverage; and Willy's Pond, an acid-sensitive watershed with a mature forest. The fifth was Catskills: Biscuit Brook, an acid-sensitive watershed. Results indicated model-simulated surface water chemistry generally agreed with the measured data at all five sites. Model-simulated internal fluxes of major elements at the Arbutus watershed compared well with previously published measured values. In addition, based on the simulated fluxes, element and acid neutralizing capacity (ANC) budgets were developed for each site. Sulphur budgets at each site indicated little retention of inputs of sulphur. The sites also showed considerable variability in retention of NO3-. Land-disturbance history and in-lake processes were found to be important in regulating the output of NO3- via surface waters. Deposition inputs of base cations were generally similar at these sites. Various rates of base cation outputs reflected differences in rates of base cation supply at these sites. Atmospheric deposition was found to be the largest source of acidity, and cation exchange, mineral weathering and in-lake processes served as sources of ANC. ?? 2004 John Wiley and Sons, Ltd.

Hydrological Processes↗
USGS2004

Processes affecting the response of sulfate concentrations to clearcutting in a northern hardwood forest, Catskill Mountains, New York, U.S.A.

The effects of disturbance on the biogeochemical processes that affect the sulfur (S) cycle in forested ecosystems are important, but have been studied in only a few locations. In this investigation, the mechanisms that caused large decreases in stream SO42- concentrations after clearcutting a small forested catchment in the Catskill Mountains of southeastern New York in 1997 were identified through an examination of pH and SO42- concentrations in soil solutions, bulk deposition of SO42- in throughfall collectors, adsorbed SO 42- concentrations in buried soil bags, and spatial variations in SO42- concentrations in shallow groundwater. The load of SO42- -S in stream water during the first 2 years after clearcutting was about 2 kg ha-1.year-1 less than the background value of 8-10 kg ha-1 year-1. The 10 and 19% decrease in net throughfall flux of SO42- -S during the 2nd and 3rd year after the clearcut, respectively, reflects reduced dry deposition of S after removal of the canopy, but this decrease accounts for 0 and 43%, respectively, of the decrease in SO42- load in streamflow for these 2 years. The pH of B-horizon soil water decreased from 4.5 to 4.0 within 8 months after the clearcut, and SO42- concentrations decreased from 45 ??mol L-1 to less than 20 ??mol L-1 during this time. A strong correlation between SO 42- concentrations and pH values (r2=0.71, p<0.01) in B-horizon soil water during the post-harvest period (1997-1999) reflects increased SO42- adsorption in response to soil acidification. Sulfate concentrations in groundwater from 21 spatially distributed wells were inversely related to a topographic index that served as a surrogate for soil wetness; thus, providing additional evidence that SO 42- adsorption was the dominant cause of the decreased SO42- concentrations in the stream after clearcutting. These results are consistent with those from a 1985 whole-tree harvest at the Hubbard Brook Experimental Forest in New Hampshire in which increased SO 42- adsorption resulting from decreased soil pH was the primary cause of decreased SO42- concentrations in stream water.

Biogeochemistry↗
USGS2001

Controls of stream chemistry and fish populations in the Neversink watershed, Catskill Mountains, New York

The Neversink Watershed Study was initiated in 1991 to develop an understanding of the key natural processes that control water quality within the forested, 166 km 2 (64 mi 2 ), Neversink River watershed; part of the New York City drinking water supply system, in the Catskill Mountain region of New York. The study entailed (1) hydrological investigations of water movement from the atmosphere to streams, (2) biogeochemical investigations of nitrogen and calcium, important nutrients in forest and aquatic ecosystems whose availability has been altered by acidic deposition, (3) an investigation of elevational patterns in atmospheric deposition, and (4) fisheries investigations to determine the relative importance of physical habitat and acidic deposition in controlling the abundance and diversity of fish species in the watershed. This report summarizes the results of these investigations, which have also been presented, in detail, in peer-reviewed technical articles and reports that are cited throughout the text.

New York↗
USGS1999

Component flow processes at four streams in the Catskill Mountains, New York, analysed using episodic concentration/discharge relationship

Plots of solute concentration against discharge have been used to relate stream hydrochemical variations to processes of flow generation, using data collected at four streams in the Catskill Mountains, New York, during the Episodic Response Project of the US Environmental Protection Agency. Results suggest that a two-component system of shallow and deep saturated subsurface flow, in which the two components respond simultaneously during hydrologic events, may be applicable to the study basins. Using a large natural sea-salt sodium input as a tracer for precipitation, it is argued that an additional distinction can be made between pre-event and event water travelling along the shallow subsurface flow path. Pre-event water is thought to be displaced by infiltrating event water, which becomes dominant on the falling limb of the hydrograph. Where, as appears to be the case for sulfate, a solute equilibrates rapidly within the soil, the pre-event-event water distinction is unimportant. However, for some solutes there are clear and consistent compositional differences between water from the two sources, evident as a hysteresis loop in concentration-discharge plots. Nitrate and acidity, in particular, appear to be elevated in event water following percolation through the organic horizon. Consequently, the most acidic, high nitrate conditions during an episode generally occur after peak discharge. A simple conceptual model of episode runoff generation is presented on the basis of these results.Plots of solute concentration against discharge have been used to relate stream hydrochemical variations to processes of flow generation, using data collected at four streams in the Catskill Mountains, New York, during the Episodic Response Project of the US Environmental Protection Agency. Results suggest that a two-component system of shallow and deep saturated subsurface flow, in which the two components respond simultaneously during hydrologic events, may be applicable to the study basins. Using a large natural sea-salt sodium input as a tracer for precipitation, it is argued that an additional distinction can be made between pre-event and event water travelling along the shallow subsurface flow path. Pre-event water is thought to be displaced by infiltrating event water, which becomes dominant on the falling limb of the hydrograph. Where, as appears to be the case for sulfate, a solute equilibrates rapidly within the soil, the pre-event - event water distinction is unimportant. However, for some solutes there are clear and consistent compositional differences between water from the two sources, evident as a hysteresis loop in concentration-discharge plots. Nitrate and acidity, in particular, appear to be elevated in event water following percolation through the organic horizon. Consequently, the most acidic, high nitrate conditions during an episode generally occur after peak discharge. A simple conceptual model of episode runoff generation is presented on the basis of these results.

Hydrological Processes↗
USGS1999

Prediction of episodic acidification in North-eastern USA: An empirical/mechanistic approach

Observations from the US Environmental Protection Agency's Episodic Response Project (ERP) in the North-eastern United States are used to develop an empirical/mechanistic scheme for prediction of the minimum values of acid neutralizing capacity (ANC) during episodes. An acidification episode is defined as a hydrological event during which ANC decreases. The pre-episode ANC is used to index the antecedent condition, and the stream flow increase reflects how much the relative contributions of sources of waters change during the episode. As much as 92% of the total variation in the minimum ANC in individual catchments can be explained (with levels of explanation >70% for nine of the 13 streams) by a multiple linear regression model that includes pre-episode ANC and change in discharge as independent variable. The predictive scheme is demonstrated to be regionally robust, with the regional variance explained ranging from 77 to 83%. The scheme is not successful for each ERP stream, and reasons are suggested for the individual failures. The potential for applying the predictive scheme to other watersheds is demonstrated by testing the model with data from the Panola Mountain Research Watershed in the South-eastern United States, where the variance explained by the model was 74%. The model can also be utilized to assess 'chemically new' and 'chemically old' water sources during acidification episodes.Observations from the US Environmental Protection Agency's Episodic Response Project (ERP) in the Northeastern United States are used to develop an empirical/mechanistic scheme for prediction of the minimum values of acid neutralizing capacity (ANC) during episodes. An acidification episode is defined as a hydrological event during which ANC decreases. The pre-episode ANC is used to index the antecedent condition, and the stream flow increase reflects how much the relative contributions of sources of waters change during the episode. As much as 92% of the total variation in the minimum ANC in individual catchments can be explained (with levels of explanation >70% for nine of the 13 streams) by a multiple linear regression model that includes pre-episode ANC and change in discharge as independent variables. The predictive scheme is demonstrated to be regionally robust, with the regional variance explained ranging from 77 to 83%. The scheme is not successful for each ERP stream, and reasons are suggested for the individual failures. The potential for applying the predictive scheme to other watersheds is demonstrated by testing the model with data from the Panola Mountain Research Watershed in the South-eastern United States, where the variance explained by the model was 74%. The model can also be utilized to assess `chemically new' and `chemically old' water sources during acidification episodes.

Hydrological Processes↗
USGS1999

Regional trends in aquatic recovery from acidification in North America and Europe

Rates of acidic deposition from the atmosphere ('acid rain') have decreased throughout the 1980s and 1990s across large portions of North America and Europe. Many recent studies have attributed observed reversals in surface-water acidification at national and regional scales to the declining deposition. To test whether emissions regulations have led to widespread recovery in surface-water chemistry, we analysed regional trends between 1980 and 1995 in indicators of acidification (sulphate, nitrate and base-cation concentrations, and measured (Gran) alkalinity) for 205 lakes and streams in eight regions of North America and Europe. Dramatic differences in trend direction and strength for the two decades are apparent. In concordance with general temporal trends in acidic deposition, lake and stream sulphate concentrations decreased in all regions with the exception of Great Britain all but one of these regions exhibited stronger downward trends in the 1990s than in the 1980s. In contrast, regional declines in lake and stream nitrate concentrations were rare and, when detected, were very small. Recovery in alkalinity, expected wherever strong regional declines in sulphate concentrations have occurred, was observed in all regions of Europe, especially in the 1990s, but in only one region (of five) in North America. We attribute the lack of recovery in three regions (south/central Ontario, the Adirondack/Catskill mountains and midwestern North America) to strong regional declines in base-cation concentrations that exceed the decreases in sulphate concentrations.

Nature↗
USGS1999

Soil calcium status and the response of stream chemistry to changing acidic deposition rates

Despite a decreasing trend in acidic deposition rates over the past two to three decades, acidified surface waters in the northeastern United States have shown minimal changes. Depletion of soil Ca pools has been suggested as a cause, although changes in soil Ca pools have not been directly related to long-term records of stream chemistry. To investigate this problem, a comprehensive watershed study was conducted in the Neversink River Basin, in the Catskill Mountains of New York, during 1991–1996. Spatial variations of atmospheric deposition, soil chemistry, and stream chemistry were evaluated over an elevation range of 817–1234 m to determine whether these factors exhibited elevational patterns. An increase in atmospheric deposition of SO 4 with increasing elevation corresponded with upslope decreases of exchangeable soil base concentrations and acid-neutralizing capacity of stream water. Exchangeable base concentrations in homogeneous soil incubated within the soil profile for one year also decreased with increasing elevation. An elevational gradient in precipitation was not observed, and effects of a temperature gradient on soil properties were not detected. Laboratory leaching experiments with soils from this watershed showed that (1) concentrations of Ca in leachate increased as the concentrations of acid anions in added solution increased, and (2) the slope of this relationship was positively correlated with base saturation. Field and laboratory soil analyses are consistent with the interpretation that decreasing trends in acid-neutralizing capacity in stream water in the Neversink Basin, dating back to 1984, are the result of decreases in soil base saturation caused by acidic deposition.

Ecological Applications↗
USGS1998

Relation of climate change to the acidification of surface waters by nitrogen deposition

Abrupt increases and decreases in mean seasonal and annual stream NO3- concentrations during the period of record (1983-1995) at Biscuit Brook, a headwater stream in the Catskill Mountains of New York, have provided an opportunity to study the biogeochemical processes that control NO3- movement through forested watersheds. The Catskills receive the highest rate of NO3- deposition in the New York and New England region of the United States, and many streams have measurable NO3- concentrations throughout the growing season. Correlations between deposition and stream NO3- concentrations are not statistically significant. Stream NO3- concentrations are positively correlated with mean annual air temperature, suggesting that on a year-to-year basis rates of N mineralization and nitrification rather than deposition or vegetation uptake are the primary factors controlling nitrogen leaching from forests where nitrogen in excess of the biological demand is available. Results from nitrification and stable isotope studies are consistent with this conclusion. These data suggest that the release of NO3- to Catskill surface waters and the associated acidification would be enhanced in the short term through increases in mean annual air temperature.Abrupt increases and decreases in mean seasonal and annual stream NO3- concentrations during the period of record (1983-1995) at Biscuit Brook, a headwater stream in the Catskill Mountains of New York, have provided an opportunity to study the biogeochemical processes that control NO3- movement through forested watersheds. The Catskills receive the highest rate of NO3- deposition in the New York and New England region of the United States, and many streams have measurable NO3- concentrations throughout the growing season. Correlations between deposition and stream NO3- concentrations are not statistically significant. Stream NO3- concentrations are positively correlated with mean annual air temperature, suggesting that on a year-to-year basis rates of N mineralization and nitrification rather than deposition or vegetation uptake are the primary factors controlling nitrogen leaching from forests where nitrogen in excess of the biological demand is available. Results from nitrification and stable isotope studies are consistent with this conclusion. These data suggest that the release of NO3- to Catskill surface waters and the associated acidification would be enhanced in the short term through increases in mean annual air temperature.

Environmental Science & Technology↗
USGS1998

Controls on denitrification in riparian soils in headwater catchments of a hardwood forest in the Catskill Mountains, U.S.A.

Denitrification in riparian soils is thought to be an important factor that reduces hydrologic export of nitrate from forested and agricultural catchments. A 2-y study to identify the soil factors most closely associated with denitrification in riparian soils in headwater catchments within the Catskill Mountains of New York, included field surveys of surface and subsurface denitrification rates, and an amendment experiment to assess the relative effects of increases in available carbon and substrate NO-/3 on denitrification rates. Denitrification rates were measured by acetylene inhibition during incubation of intact soil cores from eight soil types representing a range of drainage classes. Soil cores were analyzed for organic matter, total P, extractable NO-/3-N and NH+/4-N, organic N, pH, moisture, porosity, and water-filled pore space, to determine which of these factors were most closely associated with denitrification. The distribution of denitrification rates found during the field surveys was highly skewed, with many low or zero values and few high values. Denitrification rates were positively associated with high soil organic matter, total P, and water-filled pore space, and were highest in seep (poorly-drained) soils, toeslope (seasonally-drained) soils, and stream-edge (poorly- to moderately well-drained) soils in which these three soil characteristics were typically high. Denitrification rates in these wet locations were also positively associated with soil NH+/4-N concentration and pH, but not with NO-/3-N concentration, suggesting that the rate of NO-/3 supply (via nitrification or hydrologic transport) was more important than the instantaneous concentration of NO-/3-N in the soils. The amendment experiment indicated that denitrification in soil types studied was most responsive to added glucose alone or with NO-/3. Thus, in these soils, a combination of slow rates of NO-/3 supply and low available carbon appears to limit denitrification. Annual denitrification rates in spring-fed soils (0.74 to 1.43 kg N ha-1 y-1) were up to 5 times greater than in other surface soils, yet these soils accounted for only 1.8% of the catchment's N loss through denitrification because they represent less than 3% of the catchment area. Dry upland soils constituted 71% of the catchment area and accounted for 91% of the catchment's N loss through denitrification. Annual denitrification in the catchment equaled about 65% of stream NO-/3-N and NH+/4-N export and 14% of precipitation NO-/3-N and NH+/4-N inputs. Denitrification appears to be important relative to N input and export in these Catskill catchments.

Soil Biology and Biochemistry↗
USGS1998

Effect of groundwater springs on NO3− concentrations during summer in Catskill Mountain streams

Groundwater and stream water data collected at three headwater catchments in the Neversink River watershed indicate that base flow is sustained by groundwater from two sources: a shallow flow system within the till and soil and a deep flow system within bedrock fractures and bedding planes that discharges as perennial springs. Data from eight wells finished near the till/bedrock interface indicate that saturated conditions are not maintained in the shallow flow system during most summers. In contrast, the discharge of a perennial spring remained constant during two summer rainstorms, providing evidence that the deep flow system is disconnected from the shallow flow system in summer. Discharge from perennial springs was the principal source of streamflow in a headwater reach during low flow. Mean NO 3 − concentrations were 20–25 μmol L −1 in five perennial springs during the summer but only 5–10 μmol L −1 in shallow groundwater. Thus the deep flow system does not reflect typical NO 3 − concentrations in the soil during summer. A hydrologic budget at a headwater drainage reveals that March and late fall are the principal groundwater recharge periods. Residence time modeling based on analyses of 18 O and 35 S indicates that groundwater in the deep flow system is 6–22 months old. These data indicate that summer base flow largely originates from previous dormant seasons when available soil NO 3 − is greater. In these Catskill watersheds, high base flow concentrations of NO 3 − during summer do not provide sufficient evidence that the atmospheric N deposition rate exceeds the demand of terrestrial vegetation.

Water Resources Research↗
USGS1997

Potential effects of climate change on freshwater ecosystems of the New England/Mid-Atlantic Region

Numerous freshwater ecosystems, dense concentrations of humans along the eastern seaboard, extensive forests and a history of intensive land use distinguish the New England/Mid-Atlantic Region. Human population densities are forecast to increase in portions of the region at the same time that climate is expected to be changing. Consequently, the effects of humans and climatic change are likely to affect freshwater ecosystems within the region interactively. The general climate, at present, is humid continental, and the region receives abundant precipitation. Climatic projections for a 2 × CO 2 atmosphere, however, suggest warmer and drier conditions for much of this region. Annual temperature increases ranging from 3–5°C are projected, with the greatest increases occurring in autumn or winter. According to a water balance model, the projected increase in temperature will result in greater rates of evaporation and evapotranspiration. This could cause a 21 and 31% reduction in annual stream flow in the southern and northern sections of the region, respectively, with greatest reductions occurring in autumn and winter. The amount and duration of snow cover is also projected to decrease across the region, and summer convective thunderstorms are likely to decrease in frequency but increase in intensity.

Hydrological Processes↗
USGS1997

Effect of stream acidification and inorganic aluminum on mortality of brook trout (Salvelinus fontinalis) in the Catskill Mountains, New York

Juvenile brook trout (Salvelinus fontinalis) were exposed in cages to fluctuating chemical conditions in four Catskill Mountain streams during the spring and fall of 1989 and the spring of 1990. Specific chemical constituents and characteristics of acidic episodes that correlated with increased fish mortality were identified. Mortality increased during acidic episodes in one poorly buffered stream when inorganic monomeric aluminum (Al(im)) concentrations increased; mortality was low in three other streams during acidic episodes of shorter duration and smaller magnitude than measured in the poorly buffered stream. Variation in mortality was attributed primarily to differences in concentrations of both Al(im) and dissolved organic carbon. Linear and logistic regression analyses indicate that either mean or median Al(im) concentrations could account for 73-99% of the variability in mortality. Regression analyses suggest that mortality was highly related (in order of importance) to Al(im), pH, dissolved organic carbon, calcium, and chloride concentration. Brook trout mortality was also highly related to durations of exposure above 0.225 and 0.250 mg/L Al(im) during test periods. Characteristics of acidic-Al(im) episodes that are critical to mortality of caged brook trout appear to be (i) Al(im) concentrations of at least 0.225 ?? 0.025 mg/L and (ii) exposure to these toxic Al(im) concentrations for at least 2 days.

Canadian Journal of Fisheries and Aquatic Sciences↗