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Paul M. Mayer

Publications and source records attributed to Paul M. Mayer.

5 recordsLinked to original sources
USGS2026

Watershed Continuum Monitoring Approach: Combining multiple water quality patterns along stream and river flowpaths to track sources, pathways, and processing of pollutants

There is a growing need to improve and expand water quality monitoring approaches to more accurately track the sources, fate, and transport of multiple chemicals and pollutants holistically and quantify the effects of best management practices (BMPs) at the watershed scale. An overarching question raised by scientists, environmental managers, and the general public is: how far can water quality impacts from disturbances or benefits from watershed management and restoration propagate along stream and river flowpaths? Many studies using the classic watershed approach focus on analyzing changes in water quality over time at one or a few sampling stations, whereas theories such as the River Continuum Concept focus on predicting shifts in energy sources and biological communities along rivers but have not been directly applied to water quality. We propose to merge these concepts to create a Watershed Continuum Monitoring Approach (WCMA) that combines both spatial and temporal monitoring in order to better detect and quantify trends and transitions in multiple water quality indicators along flowpaths. Specifically, an array of multiple water quality indicators are analyzed at multiple downstream points along a watershed flowpath over time. These multiple water quality indicators are analyzed together for making comparisons to infer hydrological, biological, and geochemical processes controlling sources, transport, and attenuation of pollutants ( e.g. , analagous to stream tracer studies at the watershed scale). The WCMA leverages the natural expansion of watershed areas along a flowpath, which reflect transitions in land use, land cover, and environmental management across spatial and temporal dimensions for making direct comparisons across different stream reaches and spatial trend analysis. WCMA facilitates monitoring of multiple water quality indicators together, and identifcation of hot spots in sources and attenuation of pollutants or mixtures of pollutants. We illustrate practical applications of the WCMA to analyze water quality trends, transitions, and tradeoffs ( i.e. , a tradeoff occurs when one pollutant is reduced but another is directly or indirectly increased downstream). We explore case studies that quantify: (1) downstream reductions in concentrations of multiple pollutants along a stream flowing to a major drinking water source due to engineered and nature-based solutions, (2) downstream reductions in multiple pollutants and water quality tradeoffs along streams experiencing stormwater BMPs and stream restoration, (3) comparisons in downstream reductions of multiple pollutants and nutrient uptake along streams draining into major drinking water sources based on types of stream restoration, (4) comparisons of downstream pollutant reductions along streams experiencing riparian forest conservation vs. stream restoration, and (5) mapping and visualizing hot spots of increasing water quality problems such as hypoxia, contaminant mobilization, and freshwater salinization that extend downstream to tidal rivers of the Chesapeake Bay. We explore future applications of WCMA for tracking decreasing trends in salinity, E. coli , and other pollutants of emerging concern. WCMA can holistically inform progress towards achieving multiple water quality goals and also be used as a screening tool for selecting monitoring sites and targeting management in strategic locations. Overall, WCMA enables the simultaneous quantification and comparison of sources and transport and attenuation rates for different chemicals and pollutants across a broader range of watershed sizes and flowpath lengths, which is critical for understanding ecological, hydrological, geochemical, and biogeochemical processes along human-impacted streams and rivers.

Ecological Engineering↗
USGS2020

Making ‘chemical cocktails’ – Evolution of urban geochemical processes across the periodic table of elements

Urbanization contributes to the formation of novel elemental combinations and signatures in terrestrial and aquatic watersheds, also known as ‘chemical cocktails.’ The composition of chemical cocktails evolves across space and time due to: (1) elevated concentrations from anthropogenic sources, (2) accelerated weathering and corrosion of the built environment, (3) increased drainage density and intensification of urban water conveyance systems, and (4) enhanced rates of geochemical transformations due to changes in temperature, ionic strength, pH, and redox potentials. Characterizing chemical cocktails and underlying geochemical processes is necessary for: (1) tracking pollution sources using complex chemical mixtures instead of individual elements or compounds; (2) developing new strategies for co-managing groups of contaminants; (3) identifying proxies for predicting transport of chemical mixtures using continuous sensor data; and (4) determining whether interactive effects of chemical cocktails produce ecosystem-scale impacts greater than the sum of individual chemical stressors. First, we discuss some unique urban geochemical processes which form chemical cocktails, such as urban soil formation, human-accelerated weathering, urban acidification-alkalinization, and Freshwater Salinization Syndrome. Second, we review and synthesize global patterns in concentrations of major ions, carbon and nutrients, and trace elements in urban streams across different world regions and make comparisons with reference conditions. In addition to our global analysis, we highlight examples from watersheds in the Baltimore-Washington DC area, USA, which show increased transport of major ions, trace metals, and nutrients across streams draining a well-defined land-use gradient. Urbanization increased the concentrations of multiple major and trace elements in streams draining human-dominated watersheds compared to reference conditions. Chemical cocktails of major and trace elements were formed over diurnal cycles coinciding with changes in streamflow, dissolved oxygen, pH, and other variables measured by high-frequency sensors. Some chemical cocktails of major and trace elements were also significantly related to specific conductance (p < 0.05), which can be measured by sensors. Concentrations of major and trace elements increased, peaked, or decreased longitudinally along streams as watershed urbanization increased, which is consistent with distinct shifts in chemical mixtures upstream and downstream of other major cities in the world. Our global analysis of urban streams shows that concentrations of multiple elements along the periodic table significantly increase when compared with reference conditions. Furthermore, similar biogeochemical patterns and processes can be grouped among distinct mixtures of elements of major ions, dissolved organic matter, nutrients, and trace elements as chemical cocktails. Chemical cocktails form in urban waters over diurnal cycles, decades, and throughout drainage basins. We conclude our global review and synthesis by proposing strategies for monitoring and managing chemical cocktails using source control, ecosystem restoration, and green infrastructure. We discuss future research directions applying the watershed chemical cocktail approach to diagnose and manage environmental problems. Ultimately, a chemical cocktail approach targeting sources, transport, and transformations of different and distinct elemental combinations is beneficial to more holistically monitor and manage the emerging impacts of chemical mixtures in the world's fresh waters.

Applied Geochemistry↗
USGS2007

Pre-Restoration Geomorphic Characteristics of Minebank Run, Baltimore County, Maryland, 2002-04

Data collected from 2002 through 2004 were used to assess geomorphic characteristics and geomorphic changes over time in a selected reach of Minebank Run, a small urban watershed near Towson, Maryland, prior to its physical restoration in 2004 and 2005. Longitudinal profiles of the channel bed, water surface, and bank features were developed from field surveys. Changes in cross-section geometry between field surveys were documented. Grain-size distributions for the channel bed and banks were developed from pebble counts and laboratory analyses. Net changes in the elevation of the channel bed over time were documented at selected locations. Rosgen Stream Classification was used to classify the stream channel according to morphological measurements of slope, entrenchment ratio, width-to-depth ratio, sinuosity, and median-particle diameter of the channel materials. An analysis of boundary shear stress in the vicinity of the streamflow-gaging station was conducted by use of hydraulic variables computed from cross-section surveys and slope measurements derived from crest-stage gages in the study reach. Analysis of the longitudinal profiles indicated noticeable changes in the percentage and distribution of riffles, pools, and runs through the study reach between 2002 and 2004. Despite major changes to the channel profile as a result of storm runoff events, the overall slope of the channel bed, water surface, and bank features remained constant at about 1 percent. The cross-sectional surveys showed net increases in cross-sectional area, mean depth, and channel width at several locations between 2002 and 2004, which indicate channel degradation and widening. Two locations were identified where significant amounts of sediment were being stored in the study reach. Data from scour chains identified several locations where maximum scour ranged from 1.0-1.4 feet during storm events. Bank retreat varied widely throughout the study reach and ranged from 0.2 feet to as much as 7.9 feet. Sequential measurements of bed elevation in selected locations indicated as much as 2 feet of channel degradation in one location during a storm event in May 2004 and identified pulses of sediment that were gradually transported through the study reach during the monitoring period. Particle-size analyses of channel bed materials indicated a median particle diameter of 20.5 millimeters (coarse gravel) for the study reach, with more than 24 percent being sand particles (greater than 0.062 millimeters). Analyses of bank samples showed finer-grained material composing the channel banks, predominantly silt/clay or a mixture of silt/clay (less than 0.062 millimeters) and very fine to coarse sand. The Minebank Run stream channel was classified as a B4c channel, based on morphological descriptions from the Rosgen Stream Classification System. The B4c classification describes a single-thread stream channel with a moderate entrenchment ratio of 1.4 to 2.2; a width-to-depth ratio greater than 12; moderate sinuosity of 1.2 or greater; a water-surface slope of less than 2 percent; and a median-particle diameter in the gravel range of 2 to 64 millimeters. Analysis of boundary shear stress indicated larger mean velocities and boundary shear stress values for Minebank Run when compared to relations for non-urban B channel types developed by Rosgen. The slope of the regression line for mean velocity versus boundary shear stress at Minebank Run was considerably less than slopes developed by Rosgen for non-urban channel types. This indicates that relatively small increases in mean velocity can result in large increases in boundary shear stress in stream channels with highly developed watersheds, such as Minebank Run.

Scientific Investigations Report↗
USGS2006

Watershed characteristics and pre-restoration surface-water hydrology of Minebank Run, Baltimore County, Maryland, water years 2002-04

Stream restoration efforts have been ongoing in Maryland since the early 1990s. Physical stream restoration often involves replacement of lost sediments to elevate degraded streambeds, re-establishment of riffle-pool sequences along the channel profile, planting vegetation in riparian zones, and re-constructing channel banks, point bars, flood plains, and stream-meanders. The primary goal of many restoration efforts is to re-establish geomorphic stability of the stream channel and reduce erosive energy from urban runoff. Monitoring streams prior to and after restoration could help quantify other possible benefits of stream restoration, such as improved water quality and biota. This report presents general watershed characteristics associated with the Minebank Run watershed; a small, urban watershed in the south-central section of Baltimore County, Maryland that was physically restored in phases during 1999, 2004, and 2005. The physiography, geology, hydrology, land use, soils, and pre-restoration geomorphic setting of the unrestored stream channel are discussed. The report describes a reach of Minebank Run that was selected for the purpose of collecting several types of environmental data prior to restoration, including continuous-record and partial-record stage and streamflow data, precipitation, and ground-water levels. Examples of surface-water data that were collected in and near the study reach during water years 2002 through 2004, including continuous-record streamflow, partial-record stage and discharge, and precipitation, are described. These data were used in analyses of several characteristics of surface-water hydrology in the watershed, including (1) rainfall totals, storm duration, and intensity, (2) instantaneous peak discharge and daily mean discharge, (3) stage-discharge ratings, (4) hydraulic-geometry relations, (5) water-surface slope, (6) time of concentration, (7) flood frequency, (8) flood volume, and (9) rainfall-runoff relations. Several hydrologic characteristics that are typical of urban environments were quantified by these analyses. These include (1) large ratios of peak discharge to daily mean discharge as an indicator of flashiness, (2) consistent shifting of the stage-discharge rating over short periods of time that indicates instability of the stream channel, (3) analyses of hydraulic-geometry relations that indicate mean velocities of 11 feet per second or more while the flow is contained in the stream channel, (4) discharges that are 4 to 5 times larger in Minebank Run for corresponding flood frequency recurrence intervals than in Slade Run, which is a Piedmont watershed of similar size with smaller percentages of urban development, and (5) flood waves that can travel through the stream channel at a velocity of 412 feet per minute, or 6.9 feet per second.

Maryland↗