Geology topics

Paul Capel

Publications and source records attributed to Paul Capel.

4 recordsLinked to original sources

USGS2021

Atmospheric nitrogen deposition in the Chesapeake Bay watershed: A history of change

The Chesapeake Bay watershed has been the focus of pioneering studies of the role of atmospheric nitrogen (N) deposition as a nutrient source and driver of estuarine trophic status. Here, we review the history and evolution of scientific investigations of the role of atmospheric N deposition, examine trends from wet and dry deposition networks, and present century-long (1950–2050) atmospheric N deposition estimates. Early investigations demonstrated the importance of atmospheric deposition as an N source to the Bay, providing 25%–40% among all major N sources. These early studies led to the unprecedented inclusion of targeted decreases in atmospheric N deposition as part of the multi-stakeholder effort to reduce N loads to the Bay. Emissions of nitrogen oxides (NO x ) and deposition of wet nitrate, oxidized dry N, and dry ammonium (NH 4 + ) sharply and synchronously declined by 60%–73% during 1995–2019. These decreases largely resulted from implementation of Title IV of the 1990 Clean Air Act Amendments, which began in 1995. Wet NH 4 + deposition shows no significant trend during this period. The century-long atmospheric N deposition estimates indicate an increase in total atmospheric N deposition in the Chesapeake watershed from 1950 to a peak of ~15 kg N/ha/yr in 1979, trailed by a slight decline of <10% through the mid-1990s, and followed by a sharp decline of about 40% thereafter through 2019. An additional 21% decline in atmospheric N deposition is projected from 2015 to 2050. A comparison of the Potomac River and James River watersheds indicates higher atmospheric N deposition in the Potomac, likely resulting from greater emissions from higher proportions of agricultural and urban land in this basin. Atmospheric N deposition rose from 30% among all N sources to the Chesapeake Bay watershed in 1950 to a peak of 40% in 1973, and a decline to 28% by 2015. These data highlight the important role of atmospheric N deposition in the Chesapeake Bay watershed and present a potential opportunity for decreases in deposition to contribute to further reducing N loads and improving the trophic status of tidal waters.

New York, New Jersey, Delaware, Maryland, Pennsylv↗

USGS2019

Monitoring the Riverine Pulse: Applying high-frequency nitrate data to advance integrative understanding of biogeochemical and hydrological processes

Widespread deployment of sensors that measure river nitrate (NO3-) concentrations has led to many recent publications in water resources journals including review papers focused on data quality assurance, improved load calculations, and better nutrient management. The principal objective of this paper is to review and synthesize studies of high-frequency NO3- data that have aimed to improve understanding of the hydrologic and biogeochemical processes underlying episodic, diel, and long-term stream NO3- dynamics. Investigations have provided unprecedented detail on hysteresis and flushing patterns during high flow, seasonal variation during baseflow, and responses to multi-year climate variation. Analyses of high-frequency data have led to notable advances in understanding how climate variation affects spatial and temporal NO3- patterns, especially dry-wet cycles and antecedent moisture. Further advances have been limited by few investigations that include high-frequency measurements outside the channel and the short duration of many records. High-frequency data for multiple constituents have provided new insight to the relative roles of hydrology and biogeochemistry as highlighted by studies of the roles of autotrophic uptake, denitrification, riparian evapotranspiration, and temperature-driven changes in viscosity as drivers of diel patterns. Comparisons of short-duration high-frequency data with long-duration low frequency data have described similarities and differences in concentration – discharge patterns and highlighted the role of legacy stores. Investigators have applied innovative analysis approaches not previously possible with low-frequency or temporally-irregular data. Future availability of long-duration high-frequency data will provide new insight to processes, resulting in improved conceptual models and a deeper understanding of the role of climate variation.

WIREs Water↗

USGS2012

Concentrations, loads, and yields of organic carbon in streams of agricultural watersheds

Carbon is cycled to and from large reservoirs in the atmosphere, on land, and in the ocean. Movement of organic carbon from the terrestrial reservoir to the ocean plays an important role in the global cycling of carbon. The transition from natural to agricultural vegetation can change the storage and movement of organic carbon in and from a watershed. Samples were collected from 13 streams located in hydrologically and agriculturally diverse watersheds, to better understand the variability in the concentrations and loads of dissolved organic carbon (DOC) and particulate organic carbon (POC) in the streams, and the variability in watershed yields. The overall annual median concentrations of DOC and POC were 4.9 (range: 2.1–6.8) and 1.1 (range: 0.4–3.8) mg C L −1 , respectively. The mean DOC watershed yield (± SE) was 25 ± 6.8 kg C ha −1 yr −1 . The yields of DOC from these agricultural watersheds were not substantially different than the DOC yield from naturally vegetated watersheds in equivalent biomes, but were at the low end of the range for most biomes. Total organic carbon (DOC + POC) annually exported from the agricultural watersheds was found to average 0.03% of the organic carbon that is contained in the labile plant matter and top 1 m of soil in the watershed. Since the total organic carbon exported from agricultural watersheds is a relatively small portion of the sequestered carbon within the watershed, there is the great potential to store additional carbon in plants and soils of the watershed, offsetting some anthropogenic CO2 emissions.

California;Indiana;Iowa;Maryl;Mississippi;Nebraska↗

USGS2005

Bogue Phalia watershed in Mississippi selected for a national water-quality study

The U.S. Geological Survey (USGS) is studying seven watersheds across the Nation to better understand how natural factors and agricultural management practices (AMPs) affect the transport of water and chemicals. Natural factors include climate and landscape (soil type, topography, geology), and AMPs include practices related to tillage, irrigation, and chemical application. The study approach is similar in each watershed so that we can compare and contrast the results and more accurately predict conditions in other agricultural settings.

Mississippi↗