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Pamela A. Reilly

Publications and source records attributed to Pamela A. Reilly.

At least 19 recordsLinked to original sources

Baseline water-quality inventory and summary for the Paterson Great Falls National Historical Park, New Jersey

The Paterson Great Falls National Historical Park (PAGR), established in 2011 in the City of Paterson, New Jersey, contains many cultural, historical, and natural resources. Because of the PAGR’s young age and limited resources, a long record of natural resource data is not available for use to guide future park management and planning decisions. A detailed natural resource inventory was identified as an immediate need in the “Foundation Document—Paterson Great Falls National Historical Park,” given the history of extensive industrial activity throughout the PAGR and the Passaic River Basin. The U.S. Geological Survey, in cooperation with the National Park Service and the Urban Waters Federal Partnership for the Lower Passaic River, inventoried water-quality monitoring efforts and compiled historical water-quality data from secondary data sources to define baseline conditions in the PAGR and the surrounding study area. This report documents the methods used to harmonize water-quality data aggregated from multiple sources for the PAGR study area. Procedures implemented during data harmonization include compiling data from multiple sources, assessing the dataset for completeness, addressing metadata concerns, and creating a consistent and quality-assured dataset for future analysis. The harmonized dataset contains 14 aggregated surface-water sites, 1,103 individual sampling days, and 32,000 water-quality records throughout the period of record defined for this study (1952–2021). Summary statistics and comparison to water-quality criteria are provided for focus parameters that can support PAGR management, including field properties, suspended material, total dissolved solids, specific conductance, chloride, sulfate, Escherichia coli, nutrients, contaminants of concern related to fish consumption advisories, and litter and floatable debris. A spatial data gap was identified for the recreational area near the base of the Great Falls and immediately downstream from a known combined sewer overflow discharge location. Analytic data gaps were identified for continuous streamflow and water-quality parameters, floatable debris characterization, and harmful algal blooms identification. Continuous collection of contaminants of concern was identified as a temporal data gap, as these parameters were not consistently collected within the study area. The water-quality data synthesis and summary presented in this report can assist PAGR staff in understanding the complex baseline water resources within the study area and can serve as a baseline to design future water-quality monitoring efforts and evaluate changes in water quality over time. The harmonized dataset, as well as future New Jersey Department of Environmental Protection and New Jersey Harbor Discharge Group monitoring data and assessments, can also be used to examine the status and trends in surface-water quality, support compliance with the Clean Water Act (33 U.S.C. 1251 et seq.), and further investigate changes to park water resources that can affect ecological and human health.

New Jersey↗

Opportunities and challenges in using Solid Phase Adsorption Toxin Tracking (SPATT) samplers for monitoring cyanotoxins in freshwater and estuarine environments

Cyanobacterial toxins (cyanotoxins) represent a substantial threat to drinking water supplies and safe recreational uses of freshwater resources in watersheds worldwide. Monitoring cyanotoxins can be difficult because toxin events are variable in both space and time, are not always persistent, can be moved easily by wind and currents, and may be degraded biotically or abiotically. Thus, monitoring programs that collect discrete samples on a monthly or even bimonthly interval can miss key events and underestimate cyanotoxin risk or if they capture a high-concentration event, can give a false impression that cyanotoxins are a widespread health hazard. The use of Solid Phase Adsorption Toxin Tracking (SPATT) samplers helps address this issue by providing a time-weighted average estimate of dissolved cyanotoxin occurrence and relative concentrations. SPATT samplers have been used as a complement to traditional monitoring programs and can help elucidate cyanotoxin dynamics. SPATT samplers have been used by six U.S. Geological Survey (USGS) Water Science Centers (New York, California, Oregon, Upper Midwest, New Jersey, and Lower Mississippi-Gulf) to monitor various cyanotoxins in waterbodies such as streams, rivers, lakes, waterfalls, estuaries, and drinking-water intakes. Despite their use across the USGS, there is little guidance available to ensure consistent approaches and data quality across the Bureau. This report summarizes best practices for SPATT deployment and analysis, synthesizes data and describes lessons learned from USGS studies, identifies priority knowledge gaps, and offers considerations for future targeted experiments to help improve data collection and interpretation.

Scientific Investigations Report↗

Occurrence of cyanobacteria and associated cyanotoxins in the Raritan Basin Water Supply Complex, New Jersey, August 2020 to August 2021

Harmful algal blooms, particularly cyanobacteria harmful algal blooms (cyanoHABs), have emerged as a substantial global concern because of their detrimental effects on water quality and aquatic ecosystem health. CyanoHABs can produce cyanotoxins, which pose serious health risks to humans and wildlife, such as liver failure and respiratory distress. This is particularly concerning for water bodies that serve as drinking-water sources. Recent trends indicate an increase in the frequency and intensity of cyanoHABs globally. This study focuses on the Raritan Basin Water Supply Complex in New Jersey, where extensive monitoring was conducted from August 2020 to August 2021 to assess the presence of cyanobacteria and associated cyanotoxins. The research utilized a combination of discrete water-quality sampling, continuous monitoring, and solid phase adsorption toxin tracking (SPATT) to capture the dynamics of cyanotoxin occurrence and potential transport. Findings revealed a widespread presence of cyanobacteria and potential for cyanotoxin production, although actual cyanotoxin concentrations remained below drinking water and recreational thresholds. The study, conducted by the U.S. Geological Survey (USGS) in collaboration with the New Jersey Water Supply Authority (NJWSA) and the New Jersey Department of Environmental Protection (NJDEP), highlighted the limitations of traditional sampling methods and emphasized that continuous monitoring can support better understanding of how cyanoHAB conditions change over time and in different places. Genetic testing included quantitative polymerase chain reaction (qPCR) analyses, which demonstrated higher sensitivity, or increased findings of cyanobacteria compared to microscopy, indicating the potential for use in early warning systems. This research underscores that integrating various detection methods and hydrological data can enhance understanding of cyanotoxin dynamics in river systems.

New Jersey↗

Downstream persistence of cyanobacteria in New Jersey's Raritan River basin

Few studies have examined cyanobacteria persistence starting from lacustrine cyanobacteria harmful algal blooms (HABs) downstream. Multiple lakes and reservoirs within New Jersey's Raritan Basin Water Supply Complex (RBWSC) feature recurrent HABs and discharge water into the Raritan River. As the RBWSC provides drinking water to 1.5 million people, these HABs create drinking water treatment and human health concerns. This study quantitatively reviews the persistence of cyanobacteria communities across the RBWSC from cyanobacteria-dominated lacustrine sources to downstream drinking water and qualitatively assess what, if any, water chemistry parameters influenced the persistence, growth, or decline of cyanobacteria during downstream transport. Statistical tests showed there was a lack of continuity between cyanobacteria communities along the Raritan River, except for periods of higher streamflow and higher releases from the Spruce Run Reservoir. Results along the Millstone River suggested the potential for in-river cyanobacteria growth, which overlapped with periods of low streamflow and high nutrient concentrations in the summer and fall. A permutational analysis of variance (PERMANVOA) test found significantly dissimilar ( p < 0.01) cyanobacteria communities between lake and reservoir outlet sites and downstream sites in the Raritan, but not the Millstone River ( p = 0.928). A similarity percentage (SIMPER) analysis found cyanobacteria communities changed from high densities of bloom forming cyanobacteria ( Aphanocapsa, Aphanizomenon, Microcystis) at the lake outlet sites to low densities of non-bloom forming cyanobacteria ( Synechcoccus, Chroococcus) along the Raritan mainstem, with Aphanocapsa the most notable bloom forming genera overlapping between sites. Investigating cyanobacteria on a watershed-specific basis could enhance understanding of the site-specific transport mechanisms and water chemistry parameters that facilitate community persistence.

New Jersey↗

Capturing the transient hydrological response in sandy soils during a rare cloudburst associated with shallow slope failures; A case study in the Atlantic Highlands, New Jersey, USA

A cloudburst on 7 August 2018 in the coastal bluffs of the Atlantic Highlands, New Jersey, induced flooding, erosion and multiple shallow slope failures that adversely affected the surrounding hillside residential area. Historically, short-duration deluges are rare in the New York Bay region, with only eight cloudbursts of greater magnitude documented since 1948. The coastal bluffs consist of a variably thick, sandy surficial material overlying flat-lying, mostly non-indurated Cretaceous and Tertiary sediments, including some low-permeability glauconitic units. The bluffs have been affected by both historical deep-seated and shallow landslide movement, the latter typically related to heavy, relatively long-duration rainfall associated with tropical cyclones and nor'easters. The shallow hydrological response during the rare cloudburst was captured at two hydrological monitoring sites and yielded insights into rapidly changing moisture conditions resulting in slope failure. Additional information is provided on historical cloudbursts that have affected the region, antecedent moisture conditions, and documented landslide types and processes.

New Jersey↗

Virginia flow-ecology modeling results—An initial assessment of flow reduction effects on aquatic biota

Background The U.S. Geological Survey (USGS), in cooperation with the Virginia Department of Environmental Quality (DEQ), reviewed a previously compiled set of linear regression models to assess their utility in defining the response of the aquatic biological community to streamflow depletion. As part of the 2012 Virginia Healthy Watersheds Initiative (HWI) study conducted by Tetra Tech, Inc., for the U.S. Environmental Protection Agency (EPA) and Virginia DEQ, a database with computed values of 72 hydrologic metrics, or indicators of hydrologic alteration (IHA), 37 fish metrics, and 64 benthic invertebrate metrics was compiled and quality assured. Hydrologic alteration was represented by simulation of streamflow record for a pre-water-withdrawal condition (baseline) without dams or developed land, compared to the simulated recent-flow condition (2008 withdrawal simulation) including dams and altered landscape to calculate a percent alteration of flow. Biological samples representing the existing populations represent a range of alteration in the biological community today. For this study, all 72 IHA metrics, which included more than 7,272 linear regression models, were considered. This extensive dataset provided the opportunity for hypothesis testing and prioritization of flow-ecology relations that have the potential to explain the effect(s) of hydrologic alteration on biological metrics in Virginia streams.

Virginia↗

Landslide monitoring in the Atlantic Highlands area, New Jersey

Shallow and deep-seated landslides have occurred episodically on the steep coastal bluffs of the Atlantic Highlands area (Boroughs of Atlantic Highlands and Highlands) in New Jersey. The oldest documented deep-seated landslide occurred in April 1782 and significantly changed the morphology of the bluff. However, recent landslides have been mostly shallow in nature and have occurred during large storms with exceptionally heavy rainfall. These shallow landslides have resulted in considerable damage to residential property and local infrastructure and threatened human safety. The recent shallow landslides in the area (locations modified from New Jersey Department of Environmental Protection) consist primarily of slumps and flows of earth and debris within areas of historical landslides or on slopes modified by human activities. Such landslides are typically triggered by increases in shallow soil moisture and pore-water pressure caused by sustained and intense rainfall associated with spring nor’easters and late summer–fall tropical cyclones. However, the critical relation between rainfall, soil-moisture conditions, and landslide movement has not been fully defined. The U.S. Geological Survey is currently monitoring hillslopes within the Atlantic Highlands area to better understand the hydrologic and meteorological conditions associated with shallow landslide initiation.

New Jersey↗

Characterizing meteorological and hydrologic conditions associated with shallow landslide initiation in the coastal bluffs of the Atlantic Highlands, New Jersey

Meteorological and hydrologic conditions associated with shallow landslide initiation in the coastal bluffs of the Atlantic Highlands, New Jersey remain undocumented despite a history of damaging slope movement extending back to at least 1903. This study applies an empirical approach to quantify the rainfall conditions leading to shallow landsliding based on analysis of overlapping historical precipitation data and records of landslide occurrence, and uses continuous monitoring to quantify antecedent soil moisture and hydrologic response to rainfall events at two failure-prone hillslopes. Analysis of historical rainfall data reveals that both extended duration and cumulative rainfall amounts are critical characteristics of many landslide-inducing storms, and is consistent with current monitoring results that show notable increases in shallow soil moisture and pore-water pressure in continuous rainfall periods. Monitoring results show that shallow groundwater levels and soil moisture increase from annual lows in late summer-early fall to annual highs in late winter-early spring, and historical data indicate that shallow landslides occur most commonly from tropical cyclones in late summer through fall and nor’easters in spring. Based on this seasonality, we derived two provisional rainfall thresholds using a limited dataset of documented landslides and rainfall conditions for each season and storm type. A lower threshold for landslide initiation in spring corresponds with high antecedent moisture conditions, and higher rainfall amounts are required to induce shallow landslides during the drier soil moisture conditions in late summer-early fall.

New Jersey↗

Urban development and stream ecosystem health—Science capabilities of the U.S. Geological Survey

Urban development creates multiple stressors that can degrade stream ecosystems by changing stream hydrology, water quality, and physical habitat. Contaminants, habitat destruction, and increasing streamflow variability resulting from urban development have been associated with the disruption of biological communities, particularly the loss of sensitive aquatic biota. Understanding how algal, invertebrate, and fish communities respond to these physical and chemical stressors can provide important clues as to how streams should be managed to protect stream ecosystems as a watershed becomes increasingly urbanized. The U.S. Geological Survey continues to lead monitoring efforts and scientific studies on the effects of urban development on stream ecosystems in metropolitan areas across the United States.

Fact Sheet↗

An assessment of mercury in estuarine sediment and tissue in Southern New Jersey using public domain data

Mercury (Hg) is considered a contaminant of global concern for coastal environments due to its toxicity, widespread occurrence in sediment, and bioaccumulation in tissue. Coastal New Jersey, USA, is characterized by shallow bays and wetlands that provide critical habitat for wildlife but share space with expanding urban landscapes. This study was designed as an assessment of the magnitude and distribution of Hg in coastal New Jersey sediments and critical species using publicly available data to highlight potential data gaps. Mercury concentrations in estuary sediments can exceed 2 &mu;g/g and correlate with concentrations of other metals. Based on existing data, the concentrations of Hg in mussels in southern New Jersey are comparable to those observed in other urbanized Atlantic Coast estuaries. Lack of methylmercury data for sediments, other media, and tissues are data gaps needing to be filled for a clearer understanding of the impacts of Hg inputs to the ecosystem.

New Jersey↗

Biogeochemical environments of streambed-sediment pore waters with and without arsenic enrichment in a sedimentary rock terrain, New Jersey Piedmont, USA

Release of arsenic (As) from sedimentary rocks has resulted in contamination of groundwater in aquifers of the New Jersey Piedmont Physiographic Province, USA; the contamination also may affect the quality of the region's streamwater to which groundwater discharges. Biogeochemical mechanisms involved in the release process were investigated in the streambeds of Six Mile Run and Pike Run, tributaries to the Millstone River in the Piedmont. At Six Mile Run, streambed pore water and shallow groundwater were low or depleted in oxygen, and contained As at concentrations greater than 20 μg/L. At Pike Run, oxidizing conditions were present in the streambed, and the As concentration in pore water was 2.1 μg/L. The 16S rRNA gene and the As(V) respiratory reductase gene, arrA , were amplified from DNA extracted from streambed pore water at both sites and analyzed, revealing that distinct bacterial communities that corresponded to the redox conditions were present at each site. Anaerobic enrichment cultures were inoculated with pore water from gaining reaches of the streams with acetate and As(V). As(V) was reduced by microbes to As(III) in enrichments with Six Mile Run pore water and groundwater, whereas no reduction occurred in enrichments with Pike Run pore water. Cloning and sequencing of the arrA gene indicated 8 unique operational taxonomic units (OTUs) at Six Mile Run and 11 unique OTUs at Pike Run, which may be representative of the arsenite oxidase gene arxA . Low-oxygen conditions at Six Mile Run have favored microbial As reduction and release, whereas release was inhibited by oxidizing conditions at Pike Run.

New Jersey↗

Variable contributions of mercury from groundwater to a first-order urban coastal plain stream in New Jersey, USA

Filtered total mercury (FTHg) concentrations in a rapidly urbanizing area ranged from 50 to 250 ng/L in surface waters of the Squankum Branch, a tributary to a major river (Great Egg Harbor River (GEHR)) traversing both urban and forested/wetland areas in the Coastal Plain of New Jersey. An unsewered residential area with Hg-contaminated well water (one of many in the region) is adjacent to the stream’s left bank. Although the region’s groundwater contains total Hg (THg) at background levels of <10 ng/L, water from about 700 domestic wells in urbanized areas completed in the acidic, quartzose unconfined aquifer typically at depths 20 to 30 m below land surface has been found to exceed 2,000 ng/L (the USEPA maximum contaminant level). Within urbanized areas, THg concentrations in shallow groundwater (<20 m below land surface at or near the water table) and the potential for Hg transport were not well known, representing a considerable knowledge gap. Sampling of streamwater in, and groundwater discharge to, the Squankum Branch watershed revealed that concentrations of THg generally were in the range of 1 to 10 ng/L, but narrow plumes (“plumelets”) of shallow groundwater discharging to the stream from the opposing banks contained FTHg at a concentration > 5,000 ng/L (left bank) and nearly 2,000 ng/L (right bank). The Hg content of bankside soils and sediments was high (up to 12 mg/kg) and mostly acid leachable where groundwater with high Hg concentrations discharged, indicating contributions of Hg by both runoff and shallow groundwater. Elevated concentrations of nutrients and chloride in some groundwater plumelets likely indicated inputs from septic-system effluent and (or) fertilizer applications. The Hg probably derives mainly from mercurial pesticide applications to the former agricultural land being urbanized. The study results show that soil disturbance and introduction of anthropogenic substances can mobilize Hg from soils to shallow groundwater and the Hg contamination travels in narrow plumelets to discharge points such as stream tributaries. In the entire GEHR watershed, THg concentrations in groundwater discharging to streams in urban areas tended to be higher than concentrations in water discharging to streams of forested areas, consistent with the results from this small watershed. Other areas with similar quartzose coastal aquifers, land-use history, and hydrogeology may be similarly vulnerable to Hg contamination of shallow groundwater and associated surface water.

New Jersey↗

Arsenic in groundwater: a summary of sources and the biogeochemical and hydrogeologic factors affecting arsenic occurrence and mobility

Arsenic (As) is a metalloid element (atomic number 33) with one naturally occurring isotope of atomic mass 75, and four oxidation states (-3, 0, +3, and +5) (Smedley and Kinniburgh, 2002). In the aqueous environment, the +3 and +5 oxidation states are most prevalent, as the oxyanions arsenite (H 3 AsO 3 or H 2 AsO 3 - at pH ~9-11) and arsenate (H 2 AsO 4 - and HAsO 4 2- at pH ~4-10) (Smedley and Kinniburgh, 2002). In soils, arsine gases (containing As 3- ) may be generated by fungi and other organisms (Woolson, 1977). The different forms of As have different toxicities, with arsine gas being the most toxic form. Of the inorganic oxyanions, arsenite is considered more toxic than arsenate, and the organic (methylated) arsenic forms are considered least toxic (for a detailed discussion of toxicity issues, the reader is referred to Mandal and Suzuki (2002)). Arsenic is a global health concern due to its toxicity and the fact that it occurs at unhealthful levels in water supplies, particularly groundwater, in more than 70 countries (Ravenscroft et al., 2009) on six continents.

Book chapter↗

Method to support Total Maximum Daily Load development using hydrologic alteration as a surrogate to address aquatic life impairment in New Jersey streams

More than 300 ambient monitoring sites in New Jersey have been identified by the New Jersey Department of Environmental Protection (NJDEP) in its integrated water-quality monitoring and assessment report (that is, the 305(b) Report on general water quality and 303(d) List of waters that do not support their designated uses) as being impaired with respect to aquatic life; however, no unambiguous stressors (for example, nutrients or bacteria) have been identified. Because of the indeterminate nature of the broad range of possible impairments, surrogate measures that more holistically encapsulate the full suite of potential environmental stressors need to be developed. Streamflow alteration resulting from anthropogenic changes in the landscape is one such surrogate. For example, increases in impervious surface cover (ISC) commonly cause increases in surface runoff, which can result in “flashy” hydrology and other changes in the stream corridor that are associated with streamflow alteration. The NJDEP has indicated that methodologies to support a hydrologically based Total Maximum Daily Load (hydro-TMDL) need to be developed in order to identify hydrologic targets that represent a minimal percent deviation from a baseline condition (“minimally altered”) as a surrogate measure to meet criteria in support of designated uses. The primary objective of this study was to develop an applicable hydro-TMDL approach to address aquatic-life impairments associated with hydrologic alteration for New Jersey streams. The U.S. Geological Survey, in cooperation with the NJDEP, identified 51 non- to moderately impaired gaged streamflow sites in the Raritan River Basin for evaluation. Quantile regression (QR) analysis was used to compare flow and precipitation records and identify baseline hydrographs at 37 of these sites. At sites without an appropriately long period of record (POR) or where a baseline hydrograph could not be identified with QR, a rainfall-runoff model was used to develop simulated baseline hydrographs. The hydro-TMDL approach provided an opportunity to evaluate proportional differences in flow attributes between observed and baseline hydrographs and to develop complementary flow-ecology response relations at a subset of Raritan River Basin sites where available flow and ecological information overlapped. The New Jersey Stream Classification Tool (NJSCT) was used to determine the stream class of all 51 study sites by using either an observed or a simulated baseline hydrograph. Two New Jersey stream classes (A and C) were evaluated to help characterize the unique hydrology of the Raritan River Basin. In general, class C streams (1.99–40.7 square miles) had smaller drainage areas than class A streams (0.7–785 square miles). Many of the non-impaired and moderately impaired class A and C streams in the Raritan River Basin were found to have significant hydrologic alteration as indicated by numerous flow values that fell outside the established 25th-to-75th- and the more conservative 40th-to-60th-percentile boundaries. However, percent deviations for the class C streams (defined as moderately stable streams with moderately high base-flow contributions) were, in general, much larger than those for the class A streams (defined as semiflashy streams characterized by moderately low base flow). The greater deviations for class C streams in the hydro-TMDL assessments likely resulted from comparisons that were based solely on simulated baseline hydrographs, which were developed without considering any anthropogenic influences in the basin. In contrast, comparisons for many of the class A streams were made by using an observed baseline, which already includes an implicit level of ISC and other human influences on the landscape. By using the hydro-TMDL approach, numerous flow deviations were identified that were indicative of streams that are highly regulated by reservoirs or dams, streams that are affected by increasing amounts of surface runoff resulting from ISC, and streams that are affected by water abstraction (that is, groundwater or surface-water withdrawals used for agricultural and human supply). Eight of the reservoir- and (or) dam-affected sites showed flow deviations that are indicative of flow-managed systems. For example, indices that account for the timing and magnitude of high and low flows were often found to fall outside the 25th-to-75th-percentile range. In general, at regulated class C streams, annual summer low flows are arriving later and tend to be lower, and high flows are arriving earlier with higher magnitudes of longer duration. At class A streams, high and low flows are arriving later with an overall increase in discharge with respect to the prereservoir baseline conditions. The drainage basins of eight of the study sites had large values of ISC (>10 percent), most likely as a result of expanding urban development. In general, the magnitude and frequency of high flows at class A and C sites with high ISC are increasing and were commonly found to fall outside the 25th-to-75th-percentile range. Additionally, magnitudes of low flows are becoming lower and, although the timing of high flows was highly variable, low-flow events appeared to be arriving earlier than would be expected under normal low-flow conditions. Three of the study sites appeared to be affected by hydrologic changes associated with water abstraction. At these sites, the timing of flows appeared to be altered. For example, low flows tended to arrive earlier and high flows arrived later at two of the three sites. Additionally, the magnitude and duration of low flows were commonly less than the 25th-percentile value and the duration of high flows appeared to increase. A reduced set of hydrologic and ecological variables was used to develop univariate and multivariate flow-ecology response models for the aquatic-invertebrate assemblage. Many hydrologic variables accounting for the duration, magnitude, frequency, and timing of flows were significantly correlated with ecological response. Multiple linear regression (MLR) models were developed to provide a more holistic evaluation of the combined effects of hydrologic alteration and to identify models with two or three hydrologic variables that account for a significant proportion of the variability in invertebrate-assemblage condition as represented by assemblage metric scores. MLR models, derived on the basis of hydrologic attributes, accounted for 35 to 75 percent of the variability in assemblage condition. The hydro-TMDL method developed herein for non- to moderately impaired Raritan River Basin streams utilizes a “surrogate” approach in place of the traditional “pollutant of concern” approach commonly used for TMDL development. Managers can use the results obtained by using the hydro-TMDL method to offset the effects of impervious-surface runoff and altered streamflow and to implement measures designed to achieve the necessary load reductions for the “pollutant of concern” (that is, percentage deviations of stream-class-specific flow-index values outside the established 25th-to-75th-percentile range). In this case, such deviations could represent all or a subset of the altered flow indices that prevent the stream from meeting designated aquatic-life criteria. This hydro-TMDL uses a reference, or attainment stream approach for developing the TMDL endpoint. That is, either observed or simulated baseline hydrographs were selected as appropriate reference conditions on the basis of results of QR analysis and watershed modeling procedures, respectively. For any stream in the Raritan River Basin evaluated as part of this study, the hydro-TMDL can be expressed as the greatest amount of deviation in flow a stream can exhibit without violating the stream’s designated aquatic-life criteria. Use of this surrogate approach is appropriate because flows that fall outside the established percentile ranges are ultimately a function of many anthropogenic modifications of the landscape, including the amount of stormwater runoff generated from impervious surfaces within a given basin, the presence of manmade structures designed to retain or divert water, the magnitude of ground- and surface-water abstraction, and the presence of water-supply processes implemented to support human needs. In addition, the stream-type-specific flow indices used as the basis for the hydro-TMDL approach are useful for representing the hydrologic conditions of class A and C streams/basins because they incorporate the full spectrum of flow conditions (very low to very high) that occur in the stream system over a long period of time, as well as those flow properties that change as a result of seasonal variation. Ultimately, an estimate of the maximum percentage flow reduction that could be allowed will be needed to address the aquatic-life impairments in many of the study streams in the Raritan River Basin and will be necessary for identifying appropriate target flow conditions for hydro-TMDL implementation. As described in this report, a target flow value equal to the 25th- or 75th-percentile flow rate could be selected as the point useful for setting specific hydrologic targets. This selection, however, is a management decision that could vary depending on the designated use of the stream or other regulatory factors (for example, water-supply protection, trout production, antidegradation policies, or special protection designations). In New Jersey streams where no unambiguous stressors can be identified, State monitoring agencies, such as the NJDEP, could choose to require the implementation of a flow-based TMDL that not only supports designated uses, but meets the regulatory requirements under the Clean Water Act, and represents a balance between water supply intended to meet human needs and the conservation of ecosystem integrity.

New Jersey↗

Arsenic in New Jersey Coastal Plain streams, sediments, and shallow groundwater: effects from different geologic sources and anthropogenic inputs on biogeochemical and physical mobilization processes

Arsenic (As) concentrations in New Jersey Coastal Plain streams generally exceed the State Surface Water Quality Standard (0.017 micrograms per liter (&micro;g/L)), but concentrations seldom exceed 1 &micro;g/L in filtered stream-water samples, regardless of geologic contributions or anthropogenic inputs. Nevertheless, As concentrations in unfiltered stream water indicate substantial variation because of particle inputs from soils and sediments with differing As contents, and because of discharges from groundwater of widely varying chemistry. In the Inner Coastal Plain, streams draining to lower reaches of the Delaware River traverse As-rich glauconitic sediments of marine origin in which As contents typically are about 20 milligrams per kilogram (mg/kg) or greater. In some of these sedimentary units, As concentrations exceed the New Jersey drinking-water maximum contaminant level (5 &micro;g/L) in shallow groundwater that discharges to streams. Microbes, fueled by organic carbon beneath the streambed, reduce iron (Fe) and As, releasing As and Fe into solution in the shallow groundwater from geologic materials that likely include (in addition to glauconite) other phyllosilicates, apatite, and siderite. When the groundwater discharges to the stream, the dissolved Fe and As are oxidized, the Fe precipitates as a hydroxide, and the As sorbs or co-precipitates with the Fe. Because of the oxidation/precipitation process, dissolved As concentrations measured in filtered stream waters of the Inner Coastal Plain are about 1 &micro;g/L, but the total As concentrations (and loads) are greater, substantially amplified by As-bearing suspended sediment in stormflows. In the Outer Coastal Plain, streams draining to the Atlantic Ocean traverse quartz-rich sediments of mainly deltaic origin where the As content generally is low (<8 mg/kg). In unfiltered and filtered water samples, As concentrations typically are less than 1 &micro;g/L in the acidic stream water and groundwater of the Outer Coastal Plain, but are greater in waters from urban areas. Despite the generally small geologic contributions to Outer Coastal Plain groundwater, where wastewater inputs were indicated, concentrations of As in unfiltered shallow groundwater discharging to small urban streams exceeded the maximum contaminant level. With a history of agriculture in the New Jersey Coastal Plain, anthropogenic inputs of As, such as residues from former pesticide applications in soils, can amplify any geogenic As in runoff. Such inputs contribute to an increased total As load to a stream at high stages of flow. As a result of yet another anthropogenic influence, microbes that reduce and mobilize As beneath the streambeds are stimulated by inputs of dissolved organic carbon (DOC). Although DOC is naturally occurring, anthropogenic contributions from wastewater inputs may deliver increased levels of DOC to subsurface soils and ultimately groundwater. Arsenic concentrations may increase with the increases in pH of groundwater and stream water in developed areas receiving wastewater inputs, as As mobilization caused by pH-controlled sorption and desorption reactions are likely to occur in waters of neutral or alkaline pH (for example, Nimick and others, 1998; Barringer and others, 2007b). Because of the difference in As content of the geologic materials in the two sub-provinces of the Coastal Plain, the amount of As that is mobile in groundwater and stream water is, potentially, substantially greater in the Inner Coastal Plain than in the Outer Coastal Plain. In turn, streams within the Inner and Outer Coastal Plain can receive substantially more As in groundwater discharge from developed areas than from environments where DOC appears to be of natural origin.

New Jersey↗

Occurrence and mobility of mercury in groundwater: Chapter 5

1. Introduction 1.1. FORMS, TOXICITY, AND HEALTH EFFECTS Mercury (Hg) has long been identified as an element that is injurious, even lethal, to living organisms. Exposure to its inorganic form, mainly from elemental Hg (Hg(0)) vapor ( Fitzgerald & Lamborg, 2007 ) can cause damage to respiratory, neural, and renal systems ( Hutton, 1987 ; USEPA, 2012 ; WHO, 2012 ). The organic form, methylmercury (CH 3 Hg + ; MeHg), is substantially more toxic than the inorganic form ( Fitzgerald & Lamborg, 2007 ). Methylmercury attacks the nervous system and exposure can prove lethal, as demonstrated by well-known incidents such as those in 1956 in Minimata, Japan ( Harada, 1995 ), and 1971 in rural Iraq ( Bakir et al., 1973 ), where, in the former, industrial release of MeHg into coastal waters severely tainted the fish caught and eaten by the local population, and in the latter, grain seed treated with an organic mercurial fungicide was not planted, but eaten in bread instead. Resultant deaths are not known with certainty but have been estimated at about 100 and 500, respectively ( Hutton, 1987 ). Absent such lethal accidents, human exposure to MeHg comes mainly from ingestion of piscivorous fish in which MeHg has accumulated, with potential fetal damage ascribed to high fish diets during their mothers&rsquo; pregnancies ( USEPA, 2001 ). Lesser human exposure occurs through ingestion of drinking water (USEPA, 2001), where concentrations of total Hg (THg; inorganic plus organic forms) typically are in the low nanograms-per-liter range [1] - , particularly from many groundwater sources, and concentrations at the microgram-per-liter level are rare.

Book chapter↗

Microbial transformations of arsenic: Mobilization from glauconitic sediments to water

In the Inner Coastal Plain of New Jersey, arsenic (As) is released from glauconitic sediment to carbon- and nutrient-rich shallow groundwater. This As-rich groundwater discharges to a major area stream. We hypothesize that microbes play an active role in the mobilization of As from glauconitic subsurface sediments into groundwater in the Inner Coastal Plain of New Jersey. We have examined the potential impact of microbial activity on the mobilization of arsenic from subsurface sediments into the groundwater at a site on Crosswicks Creek in southern New Jersey. The As contents of sediments 33&ndash;90 cm below the streambed were found to range from 15 to 26.4 mg/kg, with siderite forming at depth. Groundwater beneath the streambed contains As at concentrations up to 89 &mu;g/L. Microcosms developed from site sediments released 23 &mu;g/L of As, and active microbial reduction of As(V) was observed in microcosms developed from site groundwater. DNA extracted from site sediments was amplified with primers for the 16S rRNA gene and the arsenate respiratory reductase gene, arrA , and indicated the presence of a diverse anaerobic microbial community, as well as the presence of potential arsenic-reducing bacteria. In addition, high iron (Fe) concentrations in groundwater and the presence of iron-reducing microbial genera suggests that Fe reduction in minerals may provide an additional mechanism for release of associated As, while arsenic-reducing microorganisms may serve to enhance the mobility of As in groundwater at this site.

New Jersey↗

Mercury in waters, soils, and sediments of the New Jersey Coastal Plain: A comparison of regional distribution and mobility with the mercury contamination at the William J. Hughes Technical Center, Atlantic County, New Jersey

Mercury in soils, surface water, and groundwater at the William J. Hughes Technical Center , Atlantic County, New Jersey, has been found at levels that exceed established background concentrations in Coastal Plain waters, and, in some cases, New Jersey State standards for mercury in various media. As of 2012, it is not known whether this mercury is part of regional mercury contamination or whether it is related to former military activities. Regionally, groundwater supplying about 700 domestic wells in the New Jersey Coastal Plain is contaminated with mercury that appears to be derived from anthropogenic inputs, such as agricultural pesticide use and atmospheric deposition. High levels of mercury occasionally are found in Coastal Plain soils, but disturbance during residential development on former agricultural land is thought to have mobilized any mercury applied during farming, a hypothesis borne out by experiments leaching mercury from soils. In the unsewered residential areas with mercury-contaminated groundwater, septic-system effluent is believed to create reducing conditions in which mercury sorbed to subsoils is mobilized to groundwater. In comparing the levels of mercury found in soils, sediments, streamwater, and groundwater at the William J. Hughes Technical Center site with those found regionally, mercury concentrations in groundwater in the region are, in some cases, substantially higher than those found in groundwater at the William J. Hughes Technical Center site. Nevertheless, concentrations of mercury in streamwater at the site are, in some instances, higher than most found regionally. The mercury contents in soils and sediment at the William J. Hughes Technical Center site are substantially higher than those found to date (2012) in the region, indicating that a source other than regional sources may be present at the site.

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