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P. C. Mills

Publications and source records attributed to P. C. Mills.

7 recordsLinked to original sources

Herbicides and degradates in shallow aquifers of Illinois: Spatial and temporal trends

During the fall of 2000, the occurrence was examined of 16 herbicides and 13 herbicide degradates in samples from 55 wells in shallow aquifers underlying grain producing regions of Illinois. Herbicide compounds with concentrations above 0.05 μg/L were detected in 56 percent of the samples. No concentrations exceeded regulatory drinking water standards. The six most frequently detected compounds were degradates. Water age was an important factor in determining vulnerability of ground water to transport of herbicide compounds. Unconsolidated aquifers, which were indicated to generally contain younger ground water than bedrock aquifers, had a higher occurrence of herbicides (73 percent of samples) than bedrock aquifers (22 percent). Temporal analysis to determine if changes in concentrations of selected herbicides and degradates could be observed over a near decadal period indicated a decrease in detection frequency (25 to 18 percent) between samplings in 1991 and 2000. Over this period, significant differences in concentrations were observed for atrazine (decrease) and total acetochlor (increase). The increase in acetochlor compound concentrations corresponds to an increase in acetochlor use during the study period, while the decrease in atrazine concentrations corresponds to relatively consistent use of atrazine. Changes in frequency of herbicide detection and concentration do not appear related to changes in land use near sampled wells.

Illinois

Geology, hydrology, and ground-water quality of the upper part of the Galena-Platteville aquifer at the Parson's Casket Hardware Superfund site in Belvidere, Illinois

The geology, hydrology, hydraulic properties, and distribution of contaminants in the upper part of the Galena-Platteville aquifer at the Parson's Casket Hardware Superfund site in Belvidere, Illinois, were characterized on the basis of data collected from boreholes by use of packer assemblies, flowmeter logging, and borehole ground-penetrating radar. Four permeable intervals were identified in the upper part of the Galena-Platteville aquifer: (1) a shallow, subhorizontal fracture from 37 to 40 feet below land surface; (2) an inclined fracture from 75 to 85 feet; (3) a shallow, vuggy interval from 90 to 100 feet; and (4) a deep, vuggy interval from about 140 to 180 feet. The calculated horizontal hydraulic conductivity of the two fractured intervals exceeds 50 feet per day and is more than an order of magnitude greater than that of the vuggy intervals. Water levels in the Galena-Platteville aquifer respond to pumping cycles in the Belvidere municipal-supply wells below a depth of at least 180 feet. Results of flowmeter logging and constant discharge aquifer testing indicate that the shallow, subhorizontal fracture is hydraulically connected to the overlying unconsolidated aquifer. Discrete inclined fractures are the primary conduits for vertical ground-water flow between the permeable units within the upper part of the Galena-Platteville aquifer, and perhaps for flow to the deeper parts of the aquifer. The inclined fractures may become less permeable with depth. A maximum effective porosity in the deep, vuggy interval of 8.8 percent was calculated from hydrologic and borehole radar-tomography data collected during tracer testing. The average maximum horizontal ground-water velocity through this interval was calculated at 21.4 feet per day using cross-hole radar tomography under a hydraulic gradient of 1.25 feet per foot. Trichloroethene, trichloroethane, and tetrachloroethene are the primary volatile organic compounds detected in the aquifer. There is no distinct pattern of the concentration of volatile organic compounds with depth; however, the highest concentrations tend to be present in the shallow part of the aquifer at the site. Movement of organic compounds through vertical fractures may account for their presence in the deeper parts of the aquifer.

Illinois

Geologic, hydrologic, and water-quality data from selected boreholes and wells in and near Belvidere, Illinois, 1989-96

This report presents selected geologic, hydrologic, and water-quality data collected in and near Belvidere, Ill., during 1989-96. The data were collected primarily by the U.S. Geological Survey and U.S. Environmental Protection Agency in support of an ongoing ground-water study of the glacial drift aquifer and bedrock aquifers of Ordovician and Cambrian age underlying the area. These data were collected from 8 boreholes and 52 wells within a 4 square-mile urbanized part of the 80 square-mile study area. Data include stratigraphic, lithologic, and physical descriptions of rock cores from 5 boreholes; geophysical logs of 23 boreholes; surface-geophysical surveys at 3 sites; ground-water levels at 46 wells; horizontal hydraulic conductivity estimated from slug tests at 32 boreholes and wells; and ground-water-quality information at 26 boreholes and wells. Ground-water-quality information include field characteristics and laboratory analyses of inorganic constituents, tritium, volatile organic compounds, and semivolatile organic compounds. Also included are construction logs for 11 monitoring wells and descriptions of the methods used for data collection.

Illinois

Rock-stratigraphic nomenclature, lithology, and subcrop area of the Galena-Platteville bedrock unit in Illinois and Wisconsin

The Galena-Platteville bedrock unit is a dependable source of ground water for many private well owners and some municipal-water-supply systems in northern Illinois (Hackett, 1960) and in Wisconsin. The carbonate lithology of the unit contributes to the availability of ground water and also to the susceptibility of the unit to ground-water contamination. Susceptibility to contamination is greatest in areas where the unit is overlain by only a thin layer (less than 50 feet) of soil or unconsolidated glacial deposits. Within the study area in Illinois and Wisconsin (fig. 1), volatile organic compounds and other contaminants have been detected in groundwater samples from various sites (Kay and others, 1989; Mills, 1993a, 1993b; Kay and others, 1994). Known and suspected sources of contaminants are numerous, including landfills and industrial facilities. To determine the possible effects of contamination on the ground-water supply, an understanding of the regional hydrogeologic framework of the Galena-Platteville bedrock unit is needed. Published map and point data describing the geologic and hydrologic properties of the Galena-Platteville bedrock unit are available from many sources. The U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, Region 5, has selected and compiled pertinent data. The objective of this study is to publish these data in a series of concise map reports and a bibliographic report listing available sources of information by county for the Galena-Platteville bedrock unit. Investigators involved in site-specific studies within the subcrop area will be able to utilize these reports to design effective site investigations. This report presents the rock-stratigraphic nomenclature of the lithologic units that make up the Galena-Platteville bedrock unit (fig.2) and provides a brief, generalized description of the lithologic characteristics of each unit. Sources with more detailed descriptions of lithology can be found below in SELECTED REFERENCES. Figure 3 is a map, created from published maps of various scales, showing the areal extent of the Galena-Platteville subcrop and major known geologic structural features in Illinois and Wisconsin. The subcrop area of the Galena-Platteville bedrock unit is that area where the unit crops out, or is the uppermost bedrock unit and is overlain by soil or glacial deposits. The unit is present at depth under younger bedrock units south and east of the subcrop area and is absent north and west of the subcrop area. Data sources used to prepare the map are included in SELECTED REFERENCES.

Illinois, Wisconsin

Hydrogeology and water quality of the Galena-Platteville aquifer at the Parson's Casket Hardware Superfund site, Belvidere, Illinois, 1991-92

The purpose of this letter is to describe the results of the final phase (phase 3) of the U.S. Geological Survey's (USGS) ground-water investigation at the Parson's Casket Hardware site, Belvidere, Ill. (figs. 1 and 2), for the U.S. Environmental Protection Agency (USEPA). Included in this letter are brief descriptions of (1) study methods employed in the phase 3 investigation that have not been previously described in earlier reports, and (2) results of the phase 3 investigation as they relate to the results of the previous phases of the investigation. The data from the phase 3 investigation that are presented and described herein were collected during November 1991-January 1992. The Galena-Platteville aquifer is the uppermost bedrock aquifer beneath the site. The Glenwood Formation of Ordovician age, a potential confining unit, separates the Galena-Platteville aquifer from the underlying St. Peter Sandstone aquifer (fig. 3). The St. Peter Sandstone aquifer is an important source of ground water to Belvidere and other cities in the region. The phase 3 investigation was done (1) to determine the lithology of the Glenwood Formation; (2) to determine the vertical distribution of horizontal hydraulic conductivity (K) and concentrations of volatile organic compounds (VOC's) in the upper 150 ft (feet) of the Galena-Platteville aquifer at an existing monitoring location, borehole G127GP (figs. 2 and 3) ; and (3) to confirm the presence or absence of VOC's in the St. Peter Sandstone aquifer at a new monitoring location, well G127SP (figs. 2 and 3). Additional components of the site investigation described in this letter include determination of vertical hydraulic gradients between the Galena-Platteville and St. Peter Sandstone aquifers and in situ measurement of selected water-quality characteristics (pH, temperature, specific conductance, Eh, and dissolved oxygen) in borehole G127GP. The results of the first and second phases of the USGS investigation at the Parson's Casket Hardware site are presented in two previous USGS Open-File Reports prepared for the USEPA (Mills, 1993a, 1993b) . These reports describe the hydrogeology of the study site, principally the Galena-Platteville aquifer, and the distribution of VOC concentrations in the Galena-Platteville aquifer. (The stratigraphic nomenclature used in this report is that of the Illinois State Geological Survey (Willman and others, 1975, p. 47-87) and does not necessarily follow the usage of the USGS. The aquifer nomenclature is that generally used by the Illinois State Geological Survey and the U.S. Environmental Protection Agency.) The previous two reports also describe most of the study methods employed in the phase 3 investigation.

Open-File Report