Geology topics

Nora K. Foley

Publications and source records attributed to Nora K. Foley.

At least 37 records · Page 2Linked to original sources

USGS2012

Remarkable isotopic and trace element trends in potassic through sodic Cretaceous plutons of the Yukon-Koyukuk Basin, Alaska, and the nature of the lithosphere beneath the Koyukuk terrane

During the period from 110 to 80 m.y. ago, a 450-km-long magmatic belt was active along the northern margin of Yukon-Koyukuk basin and on eastern Seward Peninsula. The plutons intruded Upper Jurassic(?) and Lower Cretaceous volcanic arc rocks and Cretaceous sedimentary rocks in Yukon-Koyukuk basin and Proterozoic and lower Paleozoic continental rocks in Seward Peninsula. Within Yukon-Koyukuk basin, the plutons vary in composition from calc-alkalic plutons on the east to potassic and ultrapotassic alkalic plutons on the west. Plutons within Yukon-Koyukuk basin were analyzed for trace element and isotopic compositions in order to discern their origin and the nature of the underling lithosphere. Farthest to the east, the calc-alkalic rocks of Indian Mountain pluton are largely tonalite and sodic granodiorite, and have low Rb (average 82 ppm), high Sr (>600 ppm), high chondrite-normalized (cn) Ce/Yb (16–37), low δ 18 O (+6.5 to +7.1), low initial 87 Sr/ 86 Sr (SIR) (0.704), and high initial 143 Nd/ 144 Nd (NIR) (0.5126). These rocks resemble those modelled elsewhere as partial melts and subsequent fractionates of basaltic or gabbroic metaigneous rocks, and may be products of melting in the deeper parts of the Late Jurassic(?) and Early Cretaceous volcanic arc. Farthest to the west, the two ultrapotassic bodies of Selawik and Inland Lake are high in Cs (up to 93 ppm), Rb (up to 997 ppm), Sr, Ba, Th, and light rare earth elements, have high (Ce/Yb)cn (30, 27), moderate to low δ 18 O (+8.4, +6.9), high SIR (0.712, 0.710), and moderate NIR (0.5121–0.5122). These rocks resemble rocks of Australia and elsewhere that were modelled as melts of continental mantle that had been previously enriched in large cations. This mantle may be Paleozoic or older. The farthest west alkalic pluton of Selawik Hills is largely monzonite, quartz monzonite, and granite; has moderate Rb (average 284 ppm), high Sr (>600 ppm), high (Ce/Yb)cn (15–25), moderate δ 18 O (+8.3 to +8.6), high SIR (0.708–0.712), and moderate NIR (0.5121–0.5122). These rocks may be the product of interaction of magma derived from old continental mantle and magma derived from old continental crust. Plutons between eastern and western extremes show completely gradational variations in the concentration of K and Rb and in the isotopic compositions of Sr, Nd, and O. These plutons probably originated either by melting in a mixed source composed of a Paleozoic or older continental section (mantle + crust) overlain by Mesozoic mafic arc rocks, or by mixing of ultrapotassic to potassic magmas from continental sources (mantle + crust), and tonalitic magmas from arc sources. We infer from these results that the northwest portion of Yukon-Koyukuk basin is underlain by a substantial continental basement of Paleozoic or greater age. This basement probably thins out to the east. There is no geochemical evidence for continental basement east of about longitude 157°, or along a belt of at least 50 km width flanking Ruby Geanticline as far to the southwest as about longitude 161°. These areas are probably underlain by oceanic and Mesozoic arc rocks.

Alaska↗

USGS2012

Gold deposits of the Carolina Slate Belt, southeastern United States--Age and origin of the major gold producers

Gold- and iron sulfide-bearing deposits of the southeastern United States have distinctive mineralogical and geochemical features that provide a basis for constructing models of ore genesis for exploration and assessment of gold resources. The largest (historic) deposits, in approximate million ounces of gold (Moz Au), include those in the Haile (~ 4.2 Moz Au), Ridgeway (~1.5 Moz Au), Brewer (~0.25 Moz Au), and Barite Hill (0.6 Moz Au) mines. Host rocks are Late Proterozoic to early Paleozoic (~553 million years old) metaigneous and metasedimentary rocks of the Carolina Slate Belt that share a geologic affinity with the classic Avalonian tectonic zone. The inferred syngenetic and epithermal-subvolcanic quartz-porphyry settings occur stratigraphically between sequences of metavolcanic rocks of the Persimmon Fork and Uwharrie Formations and overlying volcanic and epiclastic rocks of the Tillery and Richtex Formations (and regional equivalents). The Carolina Slate Belt is highly prospective for many types of gold ore hosted within quartz-sericite-pyrite altered volcanic rocks, juvenile metasedimentary rocks, and in associated shear zones. For example, sheared and deformed auriferous volcanogenic massive sulfide deposits at Barite Hill, South Carolina, and in the Gold Hill trend, North Carolina, are hosted primarily by laminated mudstone and felsic volcanic to volcaniclastic rocks. The high-sulfidation epithermal style of gold mineralization at Brewer and low-sulfidation gold ores of the Champion pit at Haile occur in breccias associated with subvolcanic quartz porphyry and within crystal-rich tuffs, ash flows, and subvolcanic rhyolite. The Ridgeway and Haile deposits are primarily epithermal replacements and feeder zones within (now) metamorphosed crystal-rich tuffs, volcaniclastic sediments, and siltstones originally deposited in a marine volcanic-arc basinal setting. Recent discoveries in the region include (1) extensions of known deposits, such as at Haile where drilling has identified an extensive gold-rich feeder system; and (2) newly discovered prospects like the porphyry-style gold-copper-molybdenum occurrence reported at Deep River, N.C. Gold ores at Ridgeway and Haile represent the low-sulfidation, disseminated, shallow subaqueous tuffaceous equivalents of intrusion-related high-sulfidation ores such as those at Brewer. Haile also has mineralogical features that support a stockwork disseminated model of pyrite-gold-sericite mineralization in which a significant amount of ore was deposited in sediments at or near the surface. The potential is high for gold-rich ore at depth in the funnel-shaped feeder zones that likely underlie such surface variants of high sulfidation–low sulfidation epithermal systems and for new discoveries of similar deposits in areas undercover. Exploration strategies for large-scale gold-mineralizing systems applied to rocks of the Carolina Slate Belt, and by extension, the Carolinian-Avalonian tectonic zone of North America, benefit from applying subvolcanic and basinal epithermal models for gold mineralization.

North Carolina;South Carolina;Virginia;Georgia↗

USGS2012

Occurrence model for volcanogenic beryllium deposits

Current global and domestic mineral resources of beryllium (Be) for industrial uses are dominated by ores produced from deposits of the volcanogenic Be type. Beryllium deposits of this type can form where hydrothermal fluids interact with fluorine and lithophile-element (uranium, thorium, rubidium, lithium, beryllium, cesium, tantalum, rare earth elements, and tin) enriched volcanic rocks that contain a highly reactive lithic component, such as carbonate clasts. Volcanic and hypabyssal high-silica biotite-bearing topaz rhyolite constitutes the most well-recognized igneous suite associated with such Be deposits. The exemplar setting is an extensional tectonic environment, such as that characterized by the Basin and Range Province, where younger topaz-bearing igneous rock sequences overlie older dolomite, quartzite, shale, and limestone sequences. Mined deposits and related mineralized rocks at Spor Mountain, Utah, make up a unique economic deposit of volcanogenic Be having extensive production and proven and probable reserves. Proven reserves in Utah, as reported by the U.S. Geological Survey National Mineral Information Center, total about 15,900 tons of Be that are present in the mineral bertrandite (Be 4 Si 2 O 7 (OH) 2 ). At the type locality for volcanogenic Be, Spor Mountain, the tuffaceous breccias and stratified tuffs that host the Be ore formed as a result of explosive volcanism that brought carbonate and other lithic fragments to the surface through vent structures that cut the underlying dolomitic Paleozoic sedimentary rock sequences. The tuffaceous sediments and lithic clasts are thought to make up phreatomagmatic base surge deposits. Hydrothermal fluids leached Be from volcanic glass in the tuff and redeposited the Be as bertrandite upon reaction of the hydrothermal fluid with carbonate clasts in lithic-rich sections of tuff. The localization of the deposits in tuff above fluorite-mineralized faults in carbonate rocks, together with isotopic evidence for the involvement of magmatic water in an otherwise meteoric water-dominated hydrothermal system, indicate that magmatic volatiles contributed to mineralization. At the type locality, hydrothermal alteration of dolomite clasts formed layered nodules of calcite, opal, fluorite, and bertrandite, the latter occurring finely intergrown with fluorite. Alteration assemblages and elemental enrichments in the tuff and surrounding volcanic rocks include regional diagenetic clays and potassium feldspar and distinctive hydrothermal halos of anomalous fluorine, lithium, molybdenum, niobium, tin, and tantalum, and intense potassium feldspathization with sericite and lithium-smectite in the immediate vicinity of Be ore. Formation of volcanogenic Be deposits is due to the coincidence of multiple factors that include an appropriate Be-bearing source rock, a subjacent pluton that supplied volatiles and heat to drive convection of meteoric groundwater, a depositional site characterized by the intersection of normal faults with permeable tuff below a less permeable cap rock, a fluorine-rich ore fluid that facilitated Be transport (for example, BeF 4 2- complex), and the existence of a chemical trap that caused fluorite and bertrandite to precipitate at the former site of carbonate lithic clasts in the tuff.

Scientific Investigations Report↗

USGS2011

Whole-rock and sulfide-mineral geochemical data for samples from volcanogenic massive sulfide deposits of the Bonnifield district, east-central Alaska

This Open-File Report presents geochemical data for outcrop and drill-core samples from volcanogenic massive sulfide deposits and associated metaigneous and metasedimentary rocks in the Wood River area of the Bonnifield mining district, northern Alaska Range, east-central Alaska. The data consist of major- and trace-element whole-rock geochemical analyses, and major- and trace-element analyses of sulfide minerals determined by electron microprobe and laser ablation—inductively coupled plasma—mass spectrometry (LA-ICP-MS) techniques. The PDF consists of text, appendix explaining the analytical methods used for the analyses presented in the data tables, a sample location map, and seven data tables. The seven tables are also available as spreadsheets in several file formats. Descriptions and discussions of the Bonnifield deposits are given in Dusel-Bacon and others (2004, 2005, 2006, 2007, 2010).

Alaska↗

USGS2010

An occurrence model for the national assessment of volcanogenic beryllium deposits

The general occurrence model summarized here is intended to provide a descriptive basis for the identification and assessment of undiscovered beryllium deposits of a type and style similar to those found at Spor Mountain, Juab County, Utah. The assessment model is restricted in its application in order to provide a coherent basis for assessing the probability of the occurrence of similar economic deposits using the current U.S. Geological Survey methodology. The model is intended to be used to identify tracts of land where volcanogenic epithermal replacement-type beryllium deposits hosted by metaluminous to peraluminous rhyolite are most likely to occur. Only a limited number of deposits or districts of this type are known, and only the ores of the Spor Mountain district have been studied in detail. The model highlights those distinctive aspects and features of volcanogenic epithermal beryllium deposits that pertain to the development of assessment criteria and puts forward a baseline analysis of the geoenvironmental consequences of mining deposits of this type.

Open-File Report↗

USGS2010

The principal rare earth elements deposits of the United States: A summary of domestic deposits and a global perspective

The rare earth elements (REE) are fifteen elements with atomic numbers 57 through 71, from lanthanum to lutetium ('lanthanides'), plus yttrium (39), which is chemically similar to the lanthanide elements and thus typically included with the rare earth elements. Although industrial demand for these elements is relatively small in tonnage terms, they are essential for a diverse and expanding array of high-technology applications. REE-containing magnets, metal alloys for batteries and light-weight structures, and phosphors are essential for many current and emerging alternative energy technologies, such as electric vehicles, energy-efficient lighting, and wind power. REE are also critical for a number of key defense systems and other advanced materials. Section 843 of the National Defense Authorization Act for Fiscal Year 2010, Public Law 111-84, directs the Comptroller General to complete a report on REE materials in the defense supply chain. The Office of Industrial Policy, in collaboration with other U.S. Government agencies, has initiated (in addition to this report) a detailed study of REE. This latter study will assess the Department of Defense's use of REE, as well as the status and security of domestic and global supply chains. That study will also address vulnerabilities in the supply chain and recommend ways to mitigate any potential risks of supply disruption. To help conduct this study, the Office of Industrial Policy asked the U.S. Geological Survey (USGS) to report on domestic REE reserves and resources in a global context. To this end, the enclosed report is the initial USGS contribution to assessing and summarizing the domestic REE resources in a global perspective. In 2009, the Mineral Resources Program of the USGS organized a new project under the title Minerals at Risk and For Emerging Technologies in order to evaluate mineral resource and supply issues of rare metals that are of increasing importance to the national economy. Leaders and members of this project, with the assistance of the USGS National Minerals Information Center, prepared the enclosed USGS report on domestic REE resources. The USGS Mineral Resources Program has investigated domestic and selected foreign REE resources for many decades, and this report summarizes what has been learned from this research. The USGS National Minerals Information Center (formerly Minerals Information Team) has monitored global production, trade, and resources for an equally long period and is the principal source of statistics used in this report. The objective of this study is to provide a nontechnical overview of domestic reserves and resources of REE and possibilities for utilizing those resources. At the present time, the United States obtains its REE raw materials from foreign sources, almost exclusively from China. Import dependence upon a single country raises serious issues of supply security. In a global context, domestic REE resources are modest and of uncertain value; hence, available resources in traditional trading partners (such as Canada and Australia) are of great interest for diversifying sources of supply. This report restates basic geologic facts about REE relevant to assessing security of supply, followed by a review of current United States consumption and imports of REE, current knowledge of domestic resources, and possibilities for future domestic production. Further detail follows in a deposit-by-deposit review of the most significant domestic REE deposits (see index map). Necessary steps to develop domestic resources are discussed in a separate section, leading into a review of current domestic exploration and a discussion of the value of a future national mineral resource assessment of REE. The report also includes an overview of known global REE resources and discusses the reliability of alternative foreign sources of REE.

Scientific Investigations Report↗

USGS2009

The role of ridge subduction in determining the geochemistry and Nd–Sr–Pb isotopic evolution of the Kodiak batholith in southern Alaska

The Paleocene Kodiak batholith, part of the Sanak–Baranof belt of Tertiary near-trench intrusive rocks, forms an elongate body (~ 150 km long) that transects Kodiak Island from SW to NE. The batholith consists of three zones (Southern, Central, and Northern) of kyanite-, muscovite-, and garnet-bearing biotite tonalite and granodiorite and less abundant granite that intruded an accretionary prism (Kodiak Formation, and Ghost Rocks Formation). Small and likely coeval bodies (Northern, Western, and Eastern satellite groups) of quartz gabbro, diorite, tonalite, granodiorite, and leucogranite flank the batholith. The batholith is calc-alkalic, has an aluminum saturation index of > 1.1, FeO t /(FeO t + MgO) ~ 0.65 (at SiO 2 = 65 wt.%), and increases in SiO 2 (~ 61 wt.%–73 wt.%) and decreases in TiO 2 (~ 0.9 wt.%–0.3 wt.%) from SW to NE. As a group, the granitic rocks have light REE-enriched chondrite-normalized patterns with small or no negative Eu anomalies, primitive mantle-normalized negative anomalies for Nb and Ti, and positive anomalies for Pb. Small to large negative anomalies for Th are also distinctive. The quartz gabbros and diorites are generally characterized by generally flat to light REE chondrite-normalized patterns (no Eu anomalies), and mantle-normalized negative anomalies for Nb, Ti, and P. Pb isotopic compositions ( 206 Pb/ 204 Pb = 18.850–18.960; 207 Pb/ 204 Pb = 15.575–15.694; 208 Pb/ 204 Pb = 38.350–39.039) are intermediate between depleted mantle and average continental crust. The Southern zone and a portion of the Central zone are characterized by negative ε Nd values of − 3.7 to − 0.3 and T DM ages ranging from ~ 838 Ma to 1011 Ma. Other granitic rocks from the Central and Northern zones have higher ε Nd values of − 0.4 to + 4.7 and younger T DM ages of ~ 450 to 797 Ma. Granitic and mafic plutons from the Eastern satellites show a wide range of ε Nd values of − 2.7 to + 6.4, and T DM ages from 204 Ma to 2124 Ma. 87 Sr/ 86 Sr values of the Southern and Central zones overlap and tend to be slightly more radiogenic ( 87 Sr/ 86 Sr > 0.70426) than the Northern zone ( 87 Sr/ 86 Sr < 0.70472). 206 Pb/ 204 Pb values increase slightly from the Southern and Central zones toward the Northern zone. There is no clear correlation of the major or trace elements with ε Nd , Pb or Sr isotopic values. Kodiak Formation and the Ghost Rocks Formation overlap the isotopic compositions (e.g., 206 Pb/ 204 Pb = 18.978 to 19.165, 87 Sr/ 86 Sr of 0.705715 to 0.707118, and ε Nd of − 6.7 to − 1.5 at 59 Ma) and T DM values (959 to 1489 Ma) of the batholith. Production of large volumes of granitic rocks in the Sanak–Baranof belt, and particularly on Kodiak Island, reflects a sequence of processes that includes underplating of mantle-derived mafic (possibly from the mantle wedge) and intermediate rocks under the accretionary flysch, interlayering of mantle-derived and flyschoid rocks, and partial melting of the mixed lithologic assemblages. Limited degrees of fractional crystallization or assimilation and fractional crystallization influenced compositions of the granitic rocks. The contribution of mantle-derived rocks that resided in the accretionary prism for only a short period of time prior to partial melting likely exceeds 40% (up to 80%). The balance (60 to 20%) is from a recently recycled crustal component represented by the Kodiak Formation. This type of progressive intracrustal melting from mixed sources controlled the geochemical character of the batholith and is most consistent with the hypothesis that the granitic rocks are associated with a slab-window produced by collision of a spreading oceanic center and a subduction zone and migration beneath the accretionary prism.

Gulf of Alaska↗

USGS2007

Geological assessment of cores from the Great Bay National Wildlife Refuge, New Hampshire

Geological sources of metals (especially arsenic and zinc) in aquifer bedrock were evaluated for their potential to contribute elevated values of metals to ground and surface waters in and around Rockingham County, New Hampshire. Ayotte and others (1999, 2003) had proposed that arsenic concentrations in ground water flowing through bedrock aquifers in eastern New England were elevated as a result of interaction with rocks. Specifically in southeastern New Hampshire, Montgomery and others (2003) established that nearly one-fifth of private bedrock wells had arsenic concentrations that exceed the U.S. Environmental Protection Agency (EPA) maximum contamination level for public water supplies. Two wells drilled in coastal New Hampshire were sited to intersect metasedimentary and metavolcanic rocks in the Great Bay National Wildlife Refuge. Bulk chemistry, mineralogy, and mineral chemistry data were obtained on representative samples of cores extracted from the two boreholes in the Kittery and Eliot Formations. The results of this study have established that the primary geologic source of arsenic in ground waters sampled from the two well sites was iron-sulfide minerals, predominantly arsenic-bearing pyrite and lesser amounts of base-metal-sulfide and sulfosalt minerals that contain appreciable arsenic, including arsenopyrite, tetrahedrite, and cobaltite. Secondary minerals containing arsenic are apparently limited to iron-oxyhydroxide minerals. The geologic source of zinc was sphalerite, typically cadmium-bearing, which occurs with pyrite in core samples. Zinc also occurred as a secondary mineral in carbonate form. Oxidation of sulfides leading to the liberation of acid, iron, arsenic, zinc, and other metals was most prevalent in open fractures and vuggy zones in core intervals containing zones of high transmissivity in the two units. The presence of significant calcite and lesser amounts of other acid-neutralizing carbonate and silicate minerals, acting as a natural buffer to reduce acidity, forced precipitation of iron-oxyhydroxide minerals and the removal of trace elements, including arsenic and lead, from ground waters in the refuge. Zinc may have remained in solution to a greater extent because of complexing with carbonate and its solubility in near-neutral ground and surface waters. The regional link between anomalously high arsenic contents in ground water and a bedrock source as established by Ayotte and others (1999, 2003) and Montgomery and others (2003) was confirmed by the presence of some arsenic-bearing minerals in rocks of the Kittery and Eliot Formations. The relatively low amounts of arsenic and metals in wells in the Great Bay National Wildlife Refuge as reported by Ayotte and others (U.S. Geological Survey Water Resources Data, 2005) were likely controlled by local geochemical environments in partially filled fractures, fissures, and permeable zones within the bedrock formations. Carbonate and silicate gangue minerals that line fractures, fissures, and permeable zones likely limited the movement of arsenic from bedrock to ground water. Sources other than the two geologic formations might have been required to account for anomalously high arsenic contents measured in private bedrock aquifer wells of Rockingham County.

New Hampshire↗

USGS2006

Ultramafic-Hosted Talc-Magnesite Deposits

This presentation on the geology of ultramafic-hosted talc-magnesite deposits was given at the 42nd Forum on the Geology of Industrial Minerals, May 7-13, 2006, in Asheville, North Carolina (USA). Talc is a soft inert industrial mineral commodity commonly used as a component or filler in ceramic, paint, paper, plastic, roofing, and electrical applications. Ultramafic-hosted talc-magnesite deposits are important sources of talc.

Open-File Report↗

USGS2005

U-Pb zircon ages and Pb isotope geochemistry of gold deposits in the Carolina slate belt of South Carolina

Volcanic rocks of the Persimmon Fork Formation host the largest known gold mines of the Carolina slate belt. U-Pb (SHRIMP) zircon ages have been obtained from rocks closely associated with pyrite-enargite-gold deposits at Brewer (quartz-topaz rhyolite breccia from the argillic alteration zone in the Brewer pit and felsic ash-flow tuff from the quartz sericite alteration zone), from the disseminated and semimassive pyrite-gold deposits at Haile (crystal lithic rhyolitic ash-flow tuffs from the Champion pit), and from the Ridgeway deposit (felsic ash-flow tuff from the stratigraphic host of the North pit gold deposit). Generally, the zircons are fine grained, fractured, and contain crystal imperfections (corrosion, inclusions, and pits). 206 Pb/ 238 U zircon spot ages for all deposits span a wide range, mostly from 400 to 760 Ma. Inclusions and cores indicative of inherited domains in the zircons were not found, and only a few analyses range from 1.1 to 1.8 Ga. A distinct xenocrystic zircon population was not identified. The 206 Pb/ 238 U weighted age averages of zircon indicate the following crystallization dates for the volcanic and volcaniclastic rocks closely associated with the gold deposits: 550 ± 3 Ma for Brewer, 553 ± 2 Ma for Haile, and 556 ± 2 Ma for the Ridgeway deposit. These zircon crystallization ages represent close estimates of the age of the original gold mineralizing events. Younger zircon spot ages can be attributed to the effects of Paleozoic regional metamorphism. Pb isotope compositions of sulfide minerals (galena, pyrite, enargite, sphalerite, chalcopyrite, and molybdenite) and silicate minerals (K-feldspar, and sericite) in the gold deposits help to constrain the sources of fluids and metals during the mineralizing events. The deposits are pyrite rich, containing multiple generations of pyrite, including early-crystallized pyrite that is closely associated with the original gold mineralizing event, as well as recrystallized pyrite formed in response to Paleozoic metamorphism. Pb isotope compositions of pyrite span a wide range, including the most radiogenic values for the sulfides. Galena and K-feldspar are not abundant but where present they are typically the least radiogenic minerals. Galena has a limited range of Pb isotope compositions that are representative of the gold deposits as a group ( 206 Pb/ 204 Pb = 18.020–18.326, 207 Pb/ 204 Pb = 15.550–15.639, 208 Pb/ 204 Pb = 37.605–38.286). Values of 207 Pb/ 204 Pb straddle the average crustal Pb growth curve, consistent with contributions involving the mantle and continental crust. Whole-rock Pb isotope compositions of volcanic and volcaniclastic rocks of the Persimmon Fork Formation nearly match the range for sulfides in the gold deposits. Subtle regional contrasts in Pb isotope compositions exist among the deposits. Sulfide minerals from Barite Hill (e.g., galena 206 Pb/ 204 Pb < 18.077) in southern South Carolina are generally less radiogenic than sulfides from Ridgeway ( 206 Pb/ 204 Pb > 18.169), Haile ( 206 Pb/ 204 Pb > 18.233), and Brewer ( 206 Pb/ 204 Pb > 18.311) in northern South Carolina. Because Pb isotope compositions of basement rocks from Grenville massifs in the southern Appalachians and sulfide minerals from the gold deposits do not match, a direct genetic connection cannot be established. Diversity in values of 206 Pb/ 204 Pb and the relatively high values of 207 Pb/ 204 Pb suggest that the deposits evolved adjacent to or closely related to continental blocks, perhaps linked to a back-arc tectonic setting. Among potential younger analogues of the slate belt gold deposits are the sulfide deposits of the Okinawa trough in the western Pacific. Mantle-derived isotopic contributions were more important at Barite Hill in southern South Carolina, the least radiogenic among the deposits where oceanic crust had developed, than at Brewer, Haile, and Ridgeway in northern South Carolina where rifting thinned the continental crust.

Georgia, North Carolina, South Carolina, Virginia↗

USGS2004

Bedrock geology and mineral resources of the Knoxville 1° x 2° quadrangle, Tennessee, North Carolina, and South Carolina

The Knoxville 1°x 2° quadrangle spans the Southern Blue Ridge physiographic province at its widest point from eastern Tennessee across western North Carolina to the northwest corner of South Carolina. The quadrangle also contains small parts of the Valley and Ridge province in Tennessee and the Piedmont province in North and South Carolina. Bedrock in the Valley and Ridge consists of unmetamorphosed, folded and thrust-faulted Paleozoic miogeoclinal sedimentary rocks ranging in age from Cambrian to Mississippian. The Blue Ridge is a complex of stacked thrust sheets divided into three parts: (1) a west flank underlain by rocks of the Late Proterozoic and Early Cambrian Chilhowee Group and slightly metamorphosed Late Proterozoic Ocoee Supergroup west of the Greenbrier fault; (2) a central part containing crystalline basement of Middle Proterozoic age (Grenville), Ocoee Supergroup rocks east of the Greenbrier fault, and rocks of the Murphy belt; and (3) an east flank containing the Helen, Tallulah Falls, and Richard Russell thrust sheets and the amphibolitic basement complex. All of the east flank thrust sheets contain polydeformed and metamorphosed sedimentary and igneous rocks of mostly Proterozoic age. The Blue Ridge is separated by the Brevard fault zone from a large area of rocks of the Inner Piedmont to the east, which contains the Six Mile thrust sheet and the ChaugaWalhalla thrust complex. All of these rocks are also polydeformed and metamorphosed sedimentary and igneous rocks. The Inner Piedmont rocks in this area occupy both the Piedmont and part of the Blue Ridge physiographic provinces. The intensity of deformation and metamorphism increases from west to east in the Blue Ridge. The west flank is mostly chlorite grade or relatively unmetamorphosed, and the central part of the Blue Ridge is mostly staurolite, garnet, or biotite grade, although sillimanite grade rocks occur along the eastern part of the central Blue Ridge in the vicinity of the leading edge of the Hayesvil Ie fault. The east flank of the Blue Ridge and much of the Inner Piedmont are at kyanite or silli manite grade of Manuscript approved for publication February 22, 1991. regional metamorphism except for a zone of retrograde rocks in the Brevard fault zone and a small area of biotite-grade rocks in the extreme southwest part of the Grandfather Mountain window in the northeast corner of the quadrangle. The major mineral resources in the Knoxville 1°x2° quadrangle are construction materials and a variety of industrial minerals mostly related to either granite and pegmatite or ultramafic rocks. Past production in the quadrangle of metals, which are of secondary importance relative to construction materials and industrial minerals, include copper in massive sulfides of the Besshi type, gold-bearing quartz veins, and residual iron and manganese deposits. Resources are discussed in relation to the Valley and Ridge, Blue Ridge, and Piedmont provinces. The following resources are the most important: A. Construction materials: Dimension stone of the Tennessee marble district in the Valley and Ridge. Limestone and dolomite of the Valley and Ridge. Sand and gravel and crushed stone, widespread throughout the quadrangle. B. Industrial minerals: Feldspar, flake mica, and quartz produced by flotation methods from the Spruce Pine Alaskite (muscovite granodiorite) in the east flank of the Blue Ridge. The district produces about half of the U.S. feldspar and significant amounts of the U.S. flake mica. Olivine produced from alpine-type dunite bodies in the east flank of the Blue Ridge. Talc and marble from the Murphy belt in the central part of the Blue Ridge, Vermiculite produced from a large deposit near Tigerville, S.C-, in the Inner Piedmont. Deposit worked out and mine backfilled. Smaller deposits associated with ultramafic rocks in the east flank of the Blue Ridge are now uneconomic and have not been worked in the past 20 years. C. Metals: Copper in three deposits, the Fontana and Hazel Creek mines in the Great Smoky Mountains Abstract Figure 1. Location of the Knoxville 1ºx2º quadrangle, with state and county boundaries National Park in the Central Blue Ridge, and the Cullowhee mine in the east flank of the Blue Ridge. D. Organic fuels: The rocks of the quadrangle contain no coal and probably lie outside the maximum range in thermal maturity permitting the survival of oil. The rocks in the Valley and Ridge and for a short distance eastward below the west flank of the Blue Ridge probably lie within a zone of thermal maturity permitting the survival of natural gas. Consequently the western part of the quadrangle is an area of high risk for hydrocarbon exploration. No exploration drilling has been done in this belt.

North Carolina, South Carolina, Tennessee↗

USGS2003

Arsenic in New England: Mineralogical and geochemical studies of sources and enrichment pathways

Detailed mineralogical, geochemical and radiogenic isotopic studies of iron-sulfide and secondary iron oxy-hydroxide minerals in natural bedrock in coastal Maine and New Hampshire test the link between arsenic-rich sulfide minerals in bedrock and secondary oxy-hydroxide minerals. Samples were selected from over 70 bedrock localities, including 22 within the regionally extensive and sulfide-mineral-rich Penobscot Formation and 10 associated with mineral deposits from coastal New Hampshire and Maine, and coupled with data from drill core collected at several sites including areas where well waters contain anomalous As abundances (e.g., Northport, ME). The data were used to establish a diversity of primary and secondary mineralogical hosts for arsenic in bedrock of this part of New England. The studies show that bedrock mineralogy is critical to contributing arsenic to groundwater and suggest a number of mineralogical pathways for arsenic that define weathering processes. The studies show that lead isotopic compositions of the sulfides and iron oxy-hydroxides overlap and establish a genetic link between the sulfides and secondary minerals. The data and interpretive results were presented at Arsenic in New England -- A multidisciplinary Scientific Conference, Manchester, New Hampshire, May 29-31, 2002, sponsored by the New Hampshire Consortium on Arsenic, are available in abstract and poster (full size = 84 by 36 inch sheet) formats.

Maine, New Hampshire↗

USGS1999

Environmental characteristics of clays and clay mineral deposits

Clays and clay minerals have been mined since the Stone Age; today they are among the most important minerals used by manufacturing and environmental industries. The U.S. Geological Survey (USGS) supports studies of the properties of clays, the mechanisms of clay formation, and the behavior of clays during weathering. These studies can tell us how and where these minerals form and provide industry and land-planning agencies with the information necessary to decide how and where clay and clay mineral deposits (fig. 1) can be developed safely with minimal effects on the environment. The term "clay" is applied both to materials having a particle size of less than 2 micrometers (25,400 micrometers = 1 inch) and to the family of minerals that has similar chemical compositions and common crystal structural characteristics (Velde, 1995) described in the next section. Clay minerals have a wide range of particle sizes from 10's of angstroms to millimeters. (An angstrom ( ) is a unit of measure at the scale of atoms.) Thus, clays may be composed of mixtures of finer grained clay minerals and clay-sized crystals of other minerals such as quartz, carbonate, and metal oxides. Clays and clay minerals are found mainly on or near the surface of the Earth.

Information Handout↗

USGS1995

Geologic, geochemical, and isotopic studies of a carbonate- and siliciclastic-hosted Pb-Zn deposit at Lion Hill, Vermont

Zn-, Pb-, Cu-, and Fe-bearing rocks of the Lion Hill area in western Vermont formed during the Early Cambrian by syngenetic sedimentary-exhalative and diagenetic replacement processes. Sphalerite, galena, chalcopyrite, pyrite, and, locally, magnetite form stratabound and broadly stratiform lenticular zones, -300 meters long and 25-50 meters thick, which are uneconomic at the present time. The lenses are structurally disrupted and metamorphosed to greenschist facies, probably due to the Taconic orogeny. Textural evidence suggests that mineralizing fluids permeated the sediments prior to lithification and that a dilatant fracture zone, possibly a feeder zone, contains some of the discordant veins at Lion Hill. The veins may have formed when the sediments were in a plastic, semiconsolidated state. The association of layered iron formation containing base-metal sulfide minerals provides possible lithologic evidence for syngenetic mineralization by submarine exhalative activity. Sand bars and tidal channels present in the sedimentary section could have acted as permeable pathways for movement of mineralizing fluids. The complex interlayering in the sedimentary sequence of carbonate and siliciclastic rock types having widely varying permeabilities created numerous fluid traps. Homogenization temperatures of primary and secondary inclusions in vein sphalerite range from 152°C to 196°C; salinities range from 11.5 to 14.0 equivalent weight percent NaCl. δ 34 S values of sulfides from Lion Hill vary from -25.9 to +10.0 per mil, and fall within the expected range for sulfide produced from bacteriogenic reduction of sulfate with δ 34 S values of 25 to 30 per mil. In addition, some pyrite probably formed from sulfate in trapped pore fluid that resulted in heavier isotopic values characteristic of more closed-system behavior. Three sphalerite samples that have heavier sulfur isotopic values may reflect a change in the source of sulfur during a later episode of mineralization, perhaps a change to a deep-seated source. Lead isotopic compositions of galenas from mineralized zones at Lion Hill range from 18.351 to 18.632 for 206 Pb/ 204 Pb, from 15.546 to 15.618 for 207 Pb/ 204 Pb, and from 38.126 to 38.496 for 208 Pb/ 204 Pb. The lead isotopic compositions of galena from Lion Hill and fluid inclusion and sulfur isotopic values for the Lion Hill sulfides are more like those of Pb-Zn-Ag deposits of Ireland than those of MVT or Appalachian-type Zn deposits. The prospect of an Irish-type sedimentary-exhalative origin for stratabound Pb-Zn deposits of the Paleozoic shelf of North America is of considerable importance to understanding the timing of mineralization relative to platform evolution and for evaluating the mineral resource potential of the region. Our study of the Lion Hill deposit indicates a potential for Irish-type Pb-Zn deposits in platform rocks of western Vermont; however, at Lion Hill they contain enrichments of Pb, Zn, and Cu rather than a Pb, Zn, and Ag association.

Vermont↗

USGS1994

Lead isotope compositions as guides to early gold mineralization: The North Amethyst vein system, Creede district, Colorado

The North Amethyst vein system, which is hosted by approximately 27 Ma Carpenter Ridge Tuff and approximately 26 Ma Nelson Mountain Tuff, has two mineral associations separated by brecciation and sedimentation in the veins. The early association consists of quartz, rhodonite, hematite, magnetite, electrum (Au (sub 0.3-0.5) Ag (sub 0.7-0.5)) , and Mn carbonate, Au-Ag sulfide, Ag sulfosalt, and base metal sulfide minerals. The later mineral association cuts the Mn- and Au-bearing assemblages and consists of quartz, calcite, sericite, chlorite, hematite, adularia, fluorite, base metal sulfides, and Ag-bearing tetrahedrite.Our detailed studies show that the Pb isotope compositions of paragenetically early galenas associated with Au-rich mineralization in the North Amethyst vein system are relatively unradiogenic ( 206 Pb/ 204 Pb: 18.826-18.881, 207 Pb/ 204 Pb: 15.588-15.602, and 208 Pb/ 204 Pb: 37.790-37.926) compared to Pb isotope compositions of galenas formed later at about 25 Ma during Ag and base metal mineralization ( 206 Pb/ 204 Pb: 19.041-19.115, 207 Pb/ 204 Pb: 15.627- 15.672, and 208 Pb/ 204 Pb: 37.829-38.057). New Pb isotope data for the central and southern parts of the Creede district, which are located 5 to 7 km south of the North Amethyst area, agree with the results of a regional study by Doe et al. (1979) that included five samples from the main part of the Creede district. Galenas and adularia from the central and southern Creede district and galenas from the Bondholder district, 7 km north of the North Amethyst area, are similar to the Pb isotope compositions of galenas formed later in the North Amethyst area during Ag and base metal mineralization. Galenas from the Alpha-Corsair vein, which was mined for Ag prior to 1910, are isotopically similar to galenas associated with North Amethyst Au-stage mineralization. This isotopic similarity suggests that unexplored segments of the Alpha-Corsair structure may have the same mineralogy as the North Amethyst Au stage; thus, the Alpha-Corsair structure has the potential for high gold contents.Pb isotope compositions from the late stage of the North Amethyst vein system and from the Bondholder and central and southern Creede mining districts are more radiogenic than the host volcanic rocks of the central cluster of the San Juan volcanic field. Our Pb isotope results indicate that early Au mineralization of the North Amethyst area may represent the product of an older and relatively local hydrothermal system distinct from that of the younger base metal and Ag mineralization found throughout the region. Fluids that deposited Au minerals may have derived their Pb isotope composition by a greater degree of interaction with shallow, relatively less radiogenic volcanic wall rocks. The younger, base metal and Ag-rich mineralization that overprints the Au mineralization in the North Amethyst area clearly has a more radiogenic isotopic signature, which implies that the later mineralization derived a greater component of its Pb from Proterozoic source rocks, or sediments derived from them.Paragenetically early sulfide-rich vein assemblages have the least radiogenic galenas and generally also have the highest Au contents. Thus, identification of paragenetically early vein assemblages with relatively unradiogenic Pb isotope compositions similar to those of the North Amethyst area provides an additional exploration tool for Au in the central San Juan Mountains area.

Colorado↗

USGS1992

Bedrock geology and mineral resources of the Knoxville 1° x 2° quadrangle, Tennessee, North Carolina, and South Carolina

The Knoxville 1° x 2° quadrangle spans the Southern Blue Ridge physiographic province at its widest point from eastern Tennessee across western North Carolina to the northwest corner of South Carolina. The quadrangle also contains small parts of the Valley and Ridge province in Tennessee and the Piedmont province in North and South Carolina. Bedrock in the Valley and Ridge consists of unmetamorphosed, folded and thrust-faulted Paleozoic miogeoclinal sedimentary rocks ranging in age from Cambrian to Mississippian. The Blue Ridge is a complex of stacked thrust sheets divided into three parts: (1) a west flank underlain by rocks of the Late Proterozoic and Early Cambrian Chilhowee Group and slightly metamorphosed Late Proterozoic Ocoee Supergroup west of the Greenbrier fault; (2) a central part containing crystalline basement of Middle Proterozoic age (Grenville), Ocoee Supergroup rocks east of the Greenbrier fault, and rocks of the Murphy belt; and (3) an east flank containing the Helen, Tallulah Falls, and Richard Russell thrust sheets and the amphibolitic basement complex. All of the east flank thrust sheets contain polydeformed and metamorphosed sedimentary and igneous rocks of mostly Proterozoic age. The Blue Ridge is separated by the Brevard fault zone from a large area of rocks of the Inner Piedmont to the east, which contains the Six Mile thrust sheet and the ChaugaWalhalla thrust complex. All of these rocks are also polydeformed and metamorphosed sedimentary and igneous rocks. The Inner Piedmont rocks in this area occupy both the Piedmont and part of the Blue Ridge physiographic provinces. The intensity of deformation and metamorphism increases from west to east in the Blue Ridge. The west flank is mostly chlorite grade or relatively unmetamorphosed, and the central part of the Blue Ridge is mostly staurolite, garnet, or biotite grade, although sillimanite grade rocks occur along the eastern part of the central Blue Ridge in the vicinity of the leading edge of the Hayesville fault. The east flank of the Blue Ridge and much of the Inner Piedmont are at kyanite or sillimanite grade of regional metamorphism except for a zone of retrograde rocks in the Brevard fault zone and a small area of biotite-grade rocks in the extreme southwest part of the Grandfather Mountain window in the northeast corner of the quadrangle. The major mineral resources in the Knoxville 1° x 2° quadrangle are construction materials and a variety of industrial minerals mostly related to either granite and pegmatite or ultramafic rocks. Past production in the quadrangle of metals, which are of secondary importance relative to construction materials and industrial minerals, include copper in massive sulfides of the Besshi type, gold-bearing quartz veins, and residual iron and manganese deposits. Resources are discussed in relation to the Valley and Ridge, Blue Ridge, and Piedmont provinces. The following resources are the most important: A. Construction materials: Dimension stone of the Tennessee marble district in the Valley and Ridge. Limestone and dolomite of the Valley and Ridge. Sand and gravel and crushed stone, widespread throughout the quadrangle. B. Industrial minerals: Feldspar, flake mica, and quartz produced by flotation methods from the Spruce Pine Alaskite (muscovite granodiorite) in the east flank of the Blue Ridge. The district produces about half of the U.S. feldspar and significant amounts of the U.S. flake mica. Olivine produced from alpine-type dunite bodies in the east flank of the Blue Ridge. Talc and marble from the Murphy belt in the central part of the Blue Ridge. Vermiculite produced from a large deposit near Tigerville, S.C., in the Inner Piedmont. Deposit worked out and mine backfilled. Smaller deposits associated with ultramafic rocks in the east flank of the Blue Ridge are now uneconomic and have not been worked in the past 20 years. C. Metals: Copper in three deposits, the Fontana and Hazel Creek mines in the Great Smoky Mountains National Park in the Central Blue Ridge, and the Cullowhee mine in the east flank of the Blue Ridge. D. Organic fuels: The rocks of the quadrangle contain no coal and probably lie outside the maximum range in thermal maturity permitting the survival of oil. The rocks in the Valley and Ridge and for a short distance eastward below the west flank of the Blue Ridge probably lie within a zone of thermal maturity permitting the survival of natural gas. Consequently the western part of the quadrangle is an area of high risk for hydrocarbon exploration. No exploration drilling has been done in this belt.

North Carolina, South Carolina, Tennessee↗

USGS1989

A reinterpretation of the δD H 2 O of inclusion fluids in contemporaneous quartz and sphalerite, Creede mining district, Colorodo: a generic problem for shallow orebodies?

Water extracted from fluid inclusions in quartz from shallow epithermal ore deposits often has a hydrogen isotope composition (δD) different from that of water extracted from inclusions in associated minerals. This difference is usually attributed to the involvement of primary fluids from multiple sources. Isotopic and homogenization and freezing temperature determinations on fluid inclusions from contemporaneous quartz and sphalerite from the epithermal, silver and base metal orebodies of the OH vein, Creede district, Colorado, suggest an alternative explanation. In near-surface deposits, differences between δD H 2 O of inclusion fluids in ore minerals and quartz may result, instead, from contamination during extraction of the fluids contained in primary inclusions by shallow ground water trapped in pseudosecondary inclusions in quartz. Quartz from the OH vein contains two principal petrographically distinct populations of fluid inclusions: primary and pseudosecondary. The primary inclusions have salinities ranging from 5 to 10 equiv wt percent NaCl, and the salinities of pseudosecondary inclusions cluster between 0 and 1 percent. Primary inclusions in quartz from one locality have a measured δD H 2 O value of -69 per mil, while pseudosecondary inclusions at the same locality have a δD H 2 O value of -102 per mil. Both salinity and isotopic values for primary inclusions in quartz are similar to those for primary inclusions in contemporaneous sphalerite. Homogenization temperatures for primary and pseudosecondary inclusions in quartz range from 191° to 280° C and from 199° to 278° C, respectively. The δD H 2 O value measured on fluid inclusions from bulk crystals ranges between -97 and -85 per mil and represents a mixture of fluids from both primary and pseudosecondary inclusions. We interpret the data to indicate that one or more episodes of abrupt incursion of cooler, overlying ground water into the ore zone caused thermal cracking of the quartz crystals during the time interval of mineralization. Subsequent healing of the fractures trapped heated, low-salinity ground water in pseudosecondary inclusions. The abrupt incursions of overlying ground water are speculated to have resulted from either collapse of a transient vapor-dominated region of the ore zone, or catastrophic venting of the system through hydrothermal eruption(s). The unusually high contrast between the salinities of the ore-depositing fluids and the ground water overlying the ore zone allowed recognition of this phenomenon at Creede. It is likely, however, that Creede is not unique. Similar phenomena may be common in shallow ore zones where rapid fluctuation of an interface between a deep, high-temperature thermal plume and an overlying, cooler ground water may be expected to occur. Careful study of the origins of fluid inclusions, particularly in quartz, is essential to characterize the primary ore fluids and to assess the role of ground water in the hydrology of shallow ore deposits.

Colorado↗

USGS1987

Source of lead and mineralizing brines for rossie-type Pb-Zn veins in the Frontenac axis area, New York ( USA).

Veins composed mainly of calcite and some galena, sphalerite, fluorite, and other minerals are widespread in the Frontenac axis area of New York and Ontario. In New York, the veins (Fig. 1) occur mainly west and northwest of Gouverneur (Brown, 1983). The veins, mined in the 1800s for lead, were first described by Emmons (1838). Smyth (1903) called these the "Rossie lead veins," a name now used locally for all veins of this type. Similar veins in southeastern Ontario were described by Uglow (1916) and Sangster (1970). The steeply dipping veins are aligned along extensional fractures in metamorphic rocks of the Grenville Complex and in Paleozoic sedimentary rocks, including the Potsdam Sandstone of Late Cambrian age, and limestones as young as Middle Ordovician. However, the age of emplacement of Rossie veins is unknown. The veins are mineralogically simple, consisting of calcite (~95%) with minor and approximately equal amounts of sphalerite and galena, and sparse fluorite, barite, celestite, and chalcopyrite (Brown, 1983). Paragenetically early minerals are crushed and granulated; later undeformed minerals fill open spaces (Fig. 2). Sandstone dikes that originated from either the overlying Potsdam Sandstone or stratigraphically higher arenaceous rocks cut into the Rossie veins and occupy all available space. Their unstratified nature suggests that sand was intruded under high hydraulic pressure during tectonic events that reopened the veins. Most veins are vertical and narrow (1-3 cm wide) and those that were mined are as much as 1.7 m wide. The veins trend mainly northwest-southeast but have a local east-west orientation. The fractures and veins show evidence of strike-slip faulting with a right-lateral offset due to late reactivation of north-east-trending faults that originally formed during the Proterozoic Grenville orogeny. Relatively rare inclined veins, termed gash veins (Brown, 1983), occur in proximity to some of the regional northeast-trending faults. These veins contain open spaces lined with large, undeformed crystals of calcite (~90%) and green fluorite (~5%). The minerals of the northeast-trending gash veins, which dip to the northwest, are believed to be paragenetically late results of the same mineralization and tectonic event that produced the Rossie veins. For example, the green fluorite in the gash veins is similar in color and occurrence to small fluorite crystals in vugs in the vertical Rossie veins. Associated with the fluorite in both occurrences is coarse crystalline calcite containing tiny tetrahedra of chalcopyrite aligned along crystallographic planes. The present study of fluid inclusions and lead isotopes was done to understand better the nature and possible source of the mineralizing solutions for both vertical and gash veins and the possible origin of the lead and zinc mineralization. Large deposits of essentially syngenetic sphalerite with minor to trace galena occur in the Proterozoic rocks of this region (e.g., Balmat-Edwards, New York). Although none of these deposits are known in the immediate vicinity of Rossie veins, the possibility that Rossie veins contain remobilized metals from these older deposits was considered.

New York↗