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USGS2019

Authigenic mineral texture in submarine 1979 basalt drill core, Surtsey volcano, Iceland

Micrometer-scale maps of authigenic microstructures in submarine basaltic tuff specimens from a 1979 Surtsey volcano, Iceland, drill core acquired 15 years after eruptions terminated provide fresh perspectives for deciphering the initial alteration of oceanic basalt in a low temperature hydrothermal system. A novel investigative approach integrates synchrotron source X-ray microdiffraction (µXRD), X-ray microfluoresence (µXRF), micro-computed tomography (µCT), and scanning transmission electron microscopy (S/TEM) coupled with Raman spectroscopy to create finely resolved spatial frameworks that record a continuum of alteration in glass and olivine. Micro-analytical maps of vesicular and fractured lapilli in specimens from 157.1, 137.9, and 102.6 m depth, and borehole temperatures of 83, 93.9 and 141.3 °C measured in 1980, respectively, record the production of nanocrystalline clay mineral, zeolites, and Al-tobermorite in diverse microenvironments. Nanocrystalline clay mineral (nontronite) and zeolite (amicite) texture in linear microstructures have concentrically-oriented crystallographic preferred orientation. Raman spectra indicating degraded organic carbonaceous matter are associated with nanocrystalline clay mineral in 10–25 nm, sub-circular nanoscale cavities in altered glass at 137.9 m depth and in a concentrically-layered, crystallographically-oriented linear microstructure in altered olivine at 102.6 m. These features have little resemblance to previously described alteration features in basalt. Irregular alteration fronts between fresh and altered glass at 157.1 depth, however, show a resemblance to microchannels in older basalts. The integrated analyses describe the complex organization of previously unrecognized mineral textures in very young basalt and provide a foundational mineralogical reference for longitudinal, time-lapse characterizations of palagonitized basalt in oceanic environments.

Geochemistry, Geophysics, Geosystems↗

USGS2007

Spectroscopic evidence for uranium bearing precipitates in vadose zone sediments at the Hanford 300-area site

Uranium (U) solid-state speciation in vadose zone sediments collected beneath the former North Process Pond (NPP) in the 300 Area of the Hanford site (Washington) was investigated using multi-scale techniques. In 30 day batch experiments, only a small fraction of total U (???7.4%) was released to artificial groundwater solutions equilibrated with 1% pCO2. Synchrotron-based micro-X-ray fluorescence spectroscopy analyses showed that U was distributed among at least two types of species: (i) U discrete grains associated with Cu and (ii) areas with intermediate U concentrations on grains and grain coatings. Metatorbernite (Cu[UO2]2[PO 4]2??8H2O) and uranophane (Ca[UO 2]2[SiO3(OH)]2?? 5H 2O) at some U discrete grains, and muscovite at U intermediate concentration areas, were identified in synchrotron-based micro-X-ray diffraction. Scanning electron microscopy/energy dispersive X-ray analyses revealed 8-10 ??m size metatorbernite particles that were embedded in C-, Al-, and Si-rich coatings on quartz and albite grains. In ??- and bulk-X-ray absorption structure (??-XAS and XAS) spectroscopy analyses, the structure of metatorbernite with additional U-C and U-U coordination environments was consistently observed at U discrete grains with high U concentrations. The consistency of the ??- and bulk-XAS analyses suggests that metatorbernite may comprise a significant fraction of the total U in the sample. The entrapped, micrometer-sized metatorbernite particles in C-, Al-, and Si-rich coatings, along with the more soluble precipitated uranyl carbonates and uranophane, likely control the long-term release of U to water associated with the vadose zone sediments. ?? 2007 American Chemical Society.

Environmental Science & Technology↗