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Miya N. Barr

Publications and source records attributed to Miya N. Barr.

17 recordsLinked to original sources

General water-quality conditions, long-term trends, and network analysis at selected sites within the Ambient Water-Quality Monitoring Network in Missouri, water years 1993–2017

The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, collects data pertaining to the surface-water resources of Missouri. Established in 1964, the Ambient Water-Quality Monitoring Network (AWQMN) consisted of 69 sites in 2017. Two additional sites from the National Water-Quality Program are included with the AWQMN sites for the analyses in this report. The sites are sampled typically from 2 to 12 times per year for physical properties, total suspended solids, nutrients, fecal indicator bacteria, and trace elements. The period of analysis for this study was from 1993 through 2017 and data analysis included 71 sites and 15 water-quality constituents plus discharge. Data analysis involved retrieving the data, conditioning the data for analysis, analyzing the data for trends, and analyzing the monitoring network to determine if potential data gaps or data redundancies exist in the network. Results from these analyses can be used to help manage the monitoring network into the future. Water-quality data were analyzed using several software packages to provide graphical and statistical information for interpretation of trends in the data at selected sites. Discharge data at selected sites were analyzed to determine the general trends during the analysis period and how the water-quality samples represented the range of daily mean discharges at each site. Water-quality data also were analyzed at selected sites to determine the relative sensitivity of selected sites and constituents to changes in data collection frequency. Trend analysis at selected sites using a simulated reduction in sampling frequency was completed to compare to trends obtained using monthly data to determine the potential degradation in the ability of determining trends from a reduced sampling frequency. The viability of using estimated discharge to evaluate long-term trends for sites with no continuous discharge was investigated. Data from sites were statistically compared in groups to determine the relative similarity (or difference) between sites for each water-quality constituent to identify potentially redundant sites in the monitoring network. Discharge-weighted long-term trends during 1993 through 2017 were analyzed for 15 water-quality constituents at 58 sites and results indicated there were significant single- or two-period trends in about 17 percent of the analyses. Some trends indicated improvement and some trends indicated deterioration of the general water quality at some sites in the AWQMN. No trend was indicated in about 31 percent of the analyses. The constituents pH, specific conductance, and total phosphorus showed the most frequent significant trends, and each of the 15 constituents examined had a significant trend at one or more sites. A total of 42 sites indicated at least 1 constituent with a significant single- or two-period trend, and 10 sites indicated 6 or more significant trends. Potential data gaps identified for computing discharge-weighted long-term trends in the monitoring network included the lack of collection of continuous discharge at 23 sites, insufficient sampling frequency for some constituents (dissolved chloride and total and dissolved lead and zinc) at some sites, insufficient temporal sample distribution (lack of at least one sample in each season per year) at some sites, and insufficient sampling frequency for some highly censored constituents (nutrients and total and dissolved lead and zinc) at some sites. Potential data gaps based on site spatial distribution were identified in 7 basins greater than 800 square miles. Potential site redundancies were identified in 4 basins that had an area greater than 500 square miles with a site density greater than 2 sites per 1,000 square miles. Potential site redundancies also were identified for nine site pairs by observing statistical similarities in the constituent data distributions. Sampling frequency was investigated to determine if reducing the sampling frequency of select constituents could provide a statistically similar data distribution. At 28 of 71 sites, 11 constituents had sufficient data collection frequency (approximately monthly) to allow for the creation of simulated datasets of various reduced data collection frequency. For the selected monitoring network sites analyzed, the data distribution of a simulated sampling frequency of four times per year or greater, roughly evenly distributed over the year, was not significantly different than the data distribution of the original monthly sampling frequency. Sites analyzed using varying simulated sampling frequencies tended to be more sensitive to sampling frequency changes if they were in basins classified as large or very large size and tended to be least sensitive in basins classified as small and medium size in the Ozark Plateaus Province. Simulated reduced frequency sampling analysis indicated that the constituents and measurements most sensitive to changes in sampling frequencies were water temperature, dissolved oxygen, discharge, and dissolved nitrate, and least sensitive were pH, total suspended solids, dissolved phosphorus, and total phosphorus. Discharge-weighted long-term trend analysis was repeated at 22 sites for 11 constituents using a simulated quarterly sampling frequency, and matched about 46 percent of the significant single-period trends identified using monthly data and about 65 percent of the analyses that indicated no trend using the monthly data.

Missouri

Water-quality trends of urban streams in Independence, Missouri, 2005–18

The U.S. Geological Survey and the city of Independence, Missouri, Water Pollution Control Department has studied the water quality and ecological condition of urban streams within Independence since 2005. Selected physical properties, nutrients, chloride, fecal indicator bacteria (Escherichia coli and total coliform), total dissolved solids, and suspended-sediment concentration data for base-flow and stormflow samples were used to document temporal trends in concentrations and flow-weighted concentrations; and annual loads were computed and investigated for selected nutrients, chloride, and suspended sediment. The six study sites included in this report are located on five urban streams: Rock Creek, a tributary in the city that drains to the Missouri River; three tributaries of the Little Blue River within the city (East Fork Little Blue River, Adair Creek, and Spring Branch Creek); and two sites on the main stem of the Little Blue River (one upstream from the city and one downstream from the three tributaries). Many factors such as population, land use, and climate, and combinations of these factors contributed to the significant changes in the concentrations and transport of nutrients, chloride, fecal indicator bacteria, and suspended sediment in the urban streams within Independence. The population of Independence and the amount of developed land in the urban watersheds remained unchanged during the 2005–18 study. Differences were noted in precipitation and in streamflow during the study. Annual precipitation and streamflow were separated into two time periods within the study—period 1 (2006–10), having greater annual streamflow and precipitation, and period 2 (2011–18), having about 30 percent lower annual streamflow and less precipitation. Streamflow was an important factor in the transport of nitrogen, phosphorus, chloride, and suspended sediment from the urban watersheds. Changes in data collection methodology during the study period and improvements to the city stormwater and wastewater infrastructure also could have contributed to some of the trends. Between 2009 and 2015, more than 35 million dollars of improvements were made to stormwater and wastewater infrastructure within the city. These improvements, such as additional sewage overflow holding tanks, removal of septic tanks, and improved and expanded sanitary sewer lines and storm overflows, also could have affected the decreased nutrients and fecal indicator bacteria trends among the urban streams in the study area. Models were used for analyzing streamflow-related variability in constituent concentrations and loads to determine if the water quality changed significantly during the study period. Trends in concentration data at four sites were analyzed using a statistical package called R–QWTREND and trends in load data were analyzed at six sites using a statistical package called Weighted Regressions on Time, Discharge, and Season-Kalman filter (WRTDS–K); both developed by the U.S. Geological Survey and publicly available for use. Statistically significant trends in flow-weighted nutrient concentrations and loads generally were downward during the study period. The only nutrient compound with a statistically significant upward trend in flow-weighted concentration was dissolved orthophosphate as phosphorus at the Rock Creek site and the upstream site on the Little Blue River. A statistically significant downward trend in annual dissolved ammonia load was identified at the downstream Little Blue River site. A significant upward linear trend in annual orthophosphate as phosphorus load was identified on Adair Creek. A statistically significant upward trend in dissolved chloride concentrations was identified at the downstream Little Blue River site. Road salt application near the site during the winter could have resulted in higher concentrated runoff during wet weather conditions. Annual chloride loads significantly decreased in Adair Creek and Spring Branch Creek. The mean annual chloride load transported in the drier (2011–18) period 2 was significantly less than during the wetter (2006–10) period 1, indicating that trends in precipitation runoff are an important factor in trends in annual transport of chloride. Statistically significant downward trends in flow-weighted fecal indicator bacteria Escherichia coli (E. coli) population densities were noted for Rock Creek and the down-stream site on the Little Blue River. However, no trend was identified in E. coli population density at the upstream Little Blue River site. The downward trend in E. coli population density at the downstream site could be a result of decreased streamflow and precipitation over the study period, storage of fecal indicator bacteria in the Little Blue River streambed within the study area, die-off of fecal indicator bacteria during travel from upstream to downstream, changes in the sample collection methodology, improvements to the city’s storm-water and wastewater infrastructures, or a combination of these factors. The statistically significant downward trend in suspended-sediment concentration identified at the upstream Little Blue River site could be affected by the decreased streamflow and precipitation during the study period, by changes in sampling methods within the study period, and by the decrease in construction and urban land development upstream from the city. No statistically significant change was indicated in the annual suspended-sediment load transported from Independence to the Little Blue River during the study period. More than one-half the suspended sediment transported in the Little Blue River originated in the watershed upstream from Independence. The Little Blue River and many of its tributaries that drain Independence have been designated as recreational waters classified for whole-body contact class B and secondary contact recreation, and some have been listed as impaired for E. coli by the Missouri Department of Natural Resources from urban runoff and storm sewers. Observations were made among the available E. coli population density data for both Little Blue River sites to further understand water-quality conditions over the study period. Both Little Blue River sites had similar medians and geometric means for the recreational season (April through October) and during the full study period, both of which are greater than the regulatory population density for both recreational classes. The Little Blue River drainage area nearly doubles in size from the upstream to downstream site; therefore, the consistent geometric mean and median of E. coli population densities at the upstream and downstream Little Blue River sites could be primarily due to the larger volume of streamflow creating a dilution effect. Other possible factors could be storage of fecal indicator bacteria in stream bed sediments, die-off of fecal indicator bacteria during transport, improvements to the city’s wastewater and stormwater infrastructure, changes to sampling methodology, or a combination of these factors. Specific sources of the E. coli are currently (2019) unknown.

Missouri

Quality of surface water in Missouri, water year 2017

The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, designed and operates a network of monitoring stations on streams and springs throughout Missouri known as the Ambient Water-Quality Monitoring Network. During water year 2017 (October 1, 2016, through September 30, 2017), data presented in this report were collected at 72 stations: 70 Ambient Water-Quality Monitoring Network stations and 2 U.S. Geological Survey National Stream Quality Assessment Network stations. Among the 72 stations in this report, 4 stations have data presented from additional sampling performed in cooperation with the U.S. Army Corps of Engineers. Summaries of the concentrations of dissolved oxygen, specific conductance, water temperature, suspended solids, suspended sediment, Escherichia coli bacteria, fecal coliform bacteria, dissolved nitrate plus nitrite as nitrogen, total phosphorus, dissolved and total recoverable lead and zinc, and selected pesticide compounds are presented. Most of the stations have been classified based on the physiographic province or primary land use in the watershed represented by the station. Some stations have been classified based on the unique hydrology of the waterbodies they monitor. A summary of hydrologic conditions in the State including peak streamflows, monthly mean streamflows, and 7-day low flows also are presented.

Missouri

Evaluation of whole-water churn splitters for suspended-sediment sample collection and analysis

The U.S. Geological Survey (USGS) collects a wide range of whole-water samples to test for the many physical and chemical constituents that represent stream conditions at the time of sampling to assess the quality of the Nation’s waters. During sampling efforts, in which a suspended-sediment concentration is one result among a broader suite of constituents, a sample is sometimes composited into a churn splitter and then subdivided for analysis. Five churn splitters—comprising three sizes and two different materials—used by the USGS were tested for single-withdrawal accuracy from one-half of full capacity and for multiple-withdrawal accuracy at varied volumes of fullness to see if churn splitters introduce bias during the collection of sediment samples. Both tests were similar to previously conducted tests for consistency, but the tests conducted in this report also attempted to answer questions that arose during previous evaluations of churn splitters. The purpose of this report is to inform sediment analysts about the capabilities and limitations of all available churn-splitter sizes and materials used by the USGS for the analysis of suspended sediment. The results indicate that suspended-sediment samples and constituents absorbed into suspended sediment may have substantial bias errors when withdrawn from churn splitters. Results were affected by the settling velocity of sediment particles relative to the resuspension velocities induced by the churning, the effects of prior withdrawals of the water-sediment mixture, and the remaining volume in a churn splitter after samples were withdrawn.

Scientific Investigations Report

Quality of surface water in Missouri, Water Year 2016

The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, designed and operates a series of monitoring stations on streams and springs throughout Missouri known as the Ambient Water-Quality Monitoring Network. During water year 2016 (October 1, 2015, through September 30, 2016), data presented in this report were collected at 71 stations: 69 Ambient Water-Quality Monitoring Network stations and 2 U.S. Geological Survey National Stream Quality Assessment Network stations. Among the 71 stations in this report, 4 stations have data presented for additional cooperative efforts with the U.S. Army Corps of Engineers. Dissolved oxygen, specific conductance, water temperature, suspended solids, suspended sediment, Escherichia coli bacteria, fecal coliform bacteria, dissolved nitrate plus nitrite as nitrogen, total phosphorus, dissolved and total recoverable lead and zinc, and select pesticide compound summaries are presented for these 71 stations. The stations primarily have been classified into groups corresponding to the physiography of the State, primary land use, or unique station types. In addition, a summary of hydrologic conditions in the State including peak streamflows, monthly mean streamflows, and 7-day low flows is presented.

Missouri

Quality of surface water in Missouri, water year 2015

The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, designed and operates a series of monitoring stations on streams and springs throughout Missouri known as the Ambient Water-Quality Monitoring Network. During water year 2015 (October 1, 2014, through September 30, 2015), data were collected at 74 stations—72 Ambient Water-Quality Monitoring Network stations and 2 U.S. Geological Survey National Stream Quality Assessment Network stations. Dissolved oxygen, specific conductance, water temperature, suspended solids, suspended sediment, Escherichia coli bacteria, fecal coliform bacteria, dissolved nitrate plus nitrite as nitrogen, total phosphorus, dissolved and total recoverable lead and zinc, and select pesticide compound summaries are presented for 71 of these stations. The stations primarily have been classified into groups corresponding to the physiography of the State, primary land use, or unique station types. In addition, a summary of hydrologic conditions in the State including peak streamflows, monthly mean streamflows, and 7-day low flows is presented.

Missouri

Surface-water quality and suspended-sediment quantity and quality within the Big River Basin, southeastern Missouri, 2011-13

Missouri was the leading producer of lead in the United States—as well as the world—for more than a century. One of the lead sources is known as the Old Lead Belt, located in southeast Missouri. The primary ore mineral in the region is galena, which can be found both in surface deposits and underground as deep as 200 feet. More than 8.5 million tons of lead were produced from the Old Lead Belt before operations ceased in 1972. Although active lead mining has ended, the effects of mining activities still remain in the form of large mine waste piles on the landscape typically near tributaries and the main stem of the Big River, which drains the Old Lead Belt. Six large mine waste piles encompassing more than 2,800 acres, exist within the Big River Basin. These six mine waste piles have been an available source of trace element-rich suspended sediments transported by natural erosional processes downstream into the Big River. A study was performed by the U.S. Geological Survey in cooperation with U.S. Environmental Protection Agency, Region 7, to calculate and characterize suspended-sediment quantity and quality within the Big River basin after reclamation of the mine waste piles ended in 2012. Streamflow and suspended sediments were quantified and sampled at two locations along a 68-mile reach of the Big River between Bonne Terre and Byrnes Mill, Missouri. The results will help regulatory agencies, such as the U.S. Environmental Protection Agency and U.S. Fish and Wildlife Service, determine impaired reaches and ecosystems for remedial and restoration efforts. Continuous stream stage, water temperature, and turbidity, and discrete suspended-sediment concentration data were collected at the two sites between October 2011 and September 2013. Suspended-sediment samples were collected during various hydrologic conditions to develop a regression model between discrete suspended-sediment concentration and continuous turbidity. Suspended sediments collected during stormflow events were analyzed for concentrations of trace elements such as barium, cadmium, lead, and zinc within two sediment size fractions. Event loads and annual loads of suspended sediment and select trace elements in suspended sediments also were calculated. Suspended-sediment loads computed by the regression model increased downstream from about 201,000 tons at the upstream site to about 355,000 tons at the downstream site during the study period. Stormflow-event-based (hereinafter referred to as “event-based”) suspended-sediment loads ranged from 180 to 32,000 tons at the upstream sampling site and 390 to 53,000 tons at the downstream site along the Big River. Although only seven stormflow events at the upstream site and six at the downstream site were sampled, the event-based suspended-sediment loads accounted for nearly 30 percent of the total suspended-sediment loads computed at both sites, indicating most of the suspended sediment transported through the Big River occurs during higher streamflows. Sediment quality guidelines, known as the threshold effect concentration and the probable effect concentration, used to assess toxicity of trace-element concentrations in sediments were compared to the cadmium, lead, and zinc concentrations in suspended sediment samples collected during stormflow events. All concentrations of cadmium, lead, and zinc in event-based suspended sediment samples exceeded the threshold and probable effect concentrations. Lead and zinc concentrations in the sediment size fraction less than 0.063 millimeters also exceeded the toxic effect threshold, above which sediment is considered to be heavily polluted causing adverse effects on sediment-dwelling organisms. Concentrations of cadmium and zinc in event-based suspended sediment samples were notably higher in samples from the upstream site than samples from the downstream site, indicating the sources of sediments enriched in these trace elements decrease in the downstream area of the watershed. The reduction in concentration of cadmium and zinc could be from dissolution of the constituents during transport or possibly a decrease in downstream source material. The lead concentration exceedance of the probable effects concentration as well as the threshold effects concentration indicates that lead-rich suspended sediments in the fraction less than 0.063 millimeters are readily available within the Big River Basin for transport. These sediments remain in the system from historical mining, and as the reclamation of mine waste piles in the upstream area of the watershed reduce additional sediment loadings, these fine sediments may be continually released as the river scours the streambed and erodes stream banks causing the lead-rich suspended sediment to remain in a state of equilibrium. Barium concentrations in suspended-sediments were nearly twice as high in stormflow event samples collected at the downstream site as compared to samples from the upstream site. The source of barium in the Big River could be from Mineral Fork and Mill Creek, which flow through the historical barite (barium sulfate, also known as tiff) mining district in Washington County, and discharge into the Big River between the two study sites. Total trace-element loads and yields in suspended sediments were computed from the sampled events for each year in the study. The total barium loads in suspended sediments were higher for sampled events collected at the downstream site than the upstream site during both study years. Cadmium and zinc loads in suspended sediments were lower at the downstream site than the upstream site, although the decrease in total load was not substantial during the study period. Lead loads in suspended sediments were lower at the downstream site during the first study year, with a slightly higher load downstream in the second year though the increase from upstream to downstream was small. Event-based yields were higher at the upstream site, indicating that readily available sediment sources are closer to the upstream site where more mining affected areas are located. The estimates determined during large precipitation events indicate that large sources of suspended sediments with large concentrations of trace elements are still available for transport within the Big River.

Missouri

Quality of surface water in Missouri, water year 2014

The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, designed and operates a series of monitoring stations on streams and springs throughout Missouri known as the Ambient Water-Quality Monitoring Network. During the 2014 water year (October 1, 2013, through September 30, 2014), data were collected at 74 stations—72 Ambient Water-Quality Monitoring Network stations and 2 U.S. Geological Survey National Stream Quality Assessment Network stations. Dissolved oxygen, specific conductance, water temperature, suspended solids, suspended sediment, Escherichia coli bacteria, fecal coliform bacteria, dissolved nitrate plus nitrite as nitrogen, total phosphorus, dissolved and total recoverable lead and zinc, and select pesticide compound summaries are presented for 71 of these stations. The stations primarily have been classified into groups corresponding to the physiography of the State, primary land use, or unique station types. In addition, a summary of hydrologic conditions in the State including peak discharges, monthly mean discharges, and 7-day low flow is presented.

Missouri

Quality of surface water in Missouri, water year 2012

The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, designed and operates a series of monitoring stations on streams and springs throughout Missouri known as the Ambient Water-Quality Monitoring Network. During the 2012 water year (October 1, 2011, through September 30, 2012), data were collected at 81 stations—73 Ambient Water-Quality Monitoring Network stations, 6 alternate Ambient Water-Quality Monitoring Network stations, and 2 U.S. Geological Survey National Stream Quality Accounting Network stations. Dissolved oxygen, specific conductance, water temperature, suspended solids, suspended sediment, fecal coliform bacteria, Escherichia coli bacteria, dissolved nitrate plus nitrite as nitrogen, total phosphorus, dissolved and total recoverable lead and zinc, and select pesticide compound summaries are presented for 78 of these stations. The stations primarily have been classified into groups corresponding to the physiography of the State, primary land use, or unique station types. In addition, a summary of hydrologic conditions in the State including peak discharges, monthly mean discharges, and 7-day low flow is presented.

Missouri

Quality of surface water in Missouri, water year 2013

The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, designed and operates a series of monitoring stations on streams and springs throughout Missouri known as the Ambient Water-Quality Monitoring Network. During the 2013 water year (October 1, 2012, through September 30, 2013), data were collected at 79 stations—73 Ambient Water-Quality Monitoring Network stations, 4 alternate Ambient Water-Quality Monitoring Network stations, and 2 U.S. Geological Survey National Stream Quality Accounting Network stations. Dissolved oxygen, specific conductance, water temperature, suspended solids, suspended sediment, Escherichia coli bacteria, fecal coliform bacteria, dissolved nitrate plus nitrite as nitrogen, total phosphorus, dissolved and total recoverable lead and zinc, and select pesticide compound summaries are presented for 76 of these stations. The stations primarily have been classified into groups corresponding to the physiography of the State, primary land use, or unique station types. In addition, a summary of hydrologic conditions in the State including peak discharges, monthly mean discharges, and 7-day low flow is presented.

Missouri

Quality of surface water in Missouri, water year 2011

The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, designed and operates a series of monitoring stations on streams throughout Missouri known as the Ambient Water-Quality Monitoring Network. During the 2011 water year (October 1, 2010, through September 30, 2011), data were collected at 75 stations—72 Ambient Water-Quality Monitoring Network stations, 2 U.S. Geological Survey National Stream Quality Accounting Network stations, and 1 spring sampled in cooperation with the U.S. Forest Service. Dissolved oxygen, specific conductance, water temperature, suspended solids, suspended sediment, fecal coliform bacteria, Escherichia coli bacteria, dissolved nitrate plus nitrite, total phosphorus, dissolved and total recoverable lead and zinc, and select pesticide compound summaries are presented for 72 of these stations. The stations primarily have been classified into groups corresponding to the physiography of the State, primary land use, or unique station types. In addition, a summary of hydrologic conditions in the State including peak discharges, monthly mean discharges, and 7-day low flow is presented.

Missouri

Hydrologic and sediment data collected from selected basins at the Fort Leonard Wood Military Reservation, Missouri--2010-11

Commercial and residential development within a basin often increases the amount of impervious area, which changes the natural hydrologic response to storm events by increasing runoff. Land development and disturbance combined with increased runoff from impervious areas potentially can increase sediment transport. At the Fort Leonard Wood Military Reservation in Missouri, there has been an increase in population and construction activities in the recent past, which has initiated an assessment of the hydrology in selected basins. From April 2010 to December 2011, the U.S. Geological Survey, in cooperation with the U.S. Army Maneuver Support Center at the Fort Leonard Wood Military Reservation, collected hydrologic and suspended-sediment concentration data in six basins at Fort Leonard Wood. Storm-sediment concentration, load, and yield varied from basin to basin and from storm to storm. In general, storm-sediment yield, in pounds per square mile per minute, was greatest from Ballard Hollow tributary (06928410) and Dry Creek (06930250), and monthly storm-sediment yield, in tons per square mile, estimates were largest in Ballard Hollow tributary (06928410), East Gate Hollow tributary (06930058), and Dry Creek (06930250). Sediment samples, collected at nine sites, primarily were collected using automatic samplers and augmented with equal-width-increment cross-sectional samples and manually collected samples when necessary. Storm-sediment load and yield were computed from discharge and suspended-sediment concentration data. Monthly storm-sediment yields also were estimated from the total storm discharge and the mean suspended-sediment concentration at each given site.

Missouri

Quality of surface water in Missouri, water year 2010

The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, designs and operates a series of monitoring stations on streams throughout Missouri known as the Ambient Water-Quality Monitoring Network. During the 2010 water year (October 1, 2009 through September 30, 2010), data were collected at 75 stations-72 Ambient Water-Quality Monitoring Network stations, 2 U.S. Geological Survey National Stream Quality Accounting Network stations, and 1 spring sampled in cooperation with the U.S. Forest Service. Dissolved oxygen, specific conductance, water temperature, suspended solids, suspended sediment, fecal coliform bacteria, Escherichia coli bacteria, dissolved nitrate plus nitrite, total phosphorus, dissolved and total recoverable lead and zinc, and select pesticide compound summaries are presented for 72 of these stations. The stations primarily have been classified into groups corresponding to the physiography of the State, primary land use, or unique station types. In addition, a summary of hydrologic conditions in the State including peak discharges, monthly mean discharges, and 7-day low flow is presented.

Data Series

Quality of surface water in Missouri, water year 2009

The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, designs and operates a series of monitoring stations on streams throughout Missouri known as the Ambient Water-Quality Monitoring Network. During the 2009 water year (October 1, 2008, through September 30, 2009), data were collected at 75 stations-69 Ambient Water-Quality Monitoring Network stations, 2 U.S. Geological Survey National Stream Quality Accounting Network stations, 1 spring sampled in cooperation with the U.S. Forest Service, and 3 stations sampled in cooperation with the Elk River Watershed Improvement Association. Dissolved oxygen, specific conductance, water temperature, suspended solids, suspended sediment, fecal coliform bacteria, Escherichia coli bacteria, dissolved nitrate plus nitrite, total phosphorus, dissolved and total recoverable lead and zinc, and select pesticide compound summaries are presented for 72 of these stations. The stations primarily have been classified into groups corresponding to the physiography of the State, primary land use, or unique station types. In addition, a summary of hydrologic conditions in the State including peak discharges, monthly mean discharges, and seven-day low flow is presented.

Open-File Report

Surface-Water Quality Conditions and Long-Term Trends at Selected Sites within the Ambient Water-Quality Monitoring Network in Missouri, Water Years 1993-2008

The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, collects data pertaining to the surface-water resources of Missouri. These data are collected as part of the Missouri Ambient Water-Quality Monitoring Network and constitute a valuable source of reliable, impartial, and timely information for developing an improved understanding of water resources in the State. Six sites from the Ambient Water-Quality Monitoring Network, with data available from the 1993 through 2008 water years, were chosen to compare water-quality conditions and long-term trends of dissolved oxygen, selected physical properties, total suspended solids, dissolved nitrate plus nitrite as nitrogen, total phosphorous, fecal indicator bacteria, and selected trace elements. The six sites used in the study were classified in groups corresponding to the physiography, main land use, and drainage basin size, and represent most stream types in Missouri. Long-term trends in this study were analyzed using flow-adjusted and non-flow adjusted models. Highly censored datasets (greater than 5 percent but less than 50 percent censored values) were not flow-adjusted. Trends that were detected can possibly be related to changes in agriculture or urban development within the drainage basins. Trends in nutrients were the most prevalent. Upward flow-adjusted trends in dissolved nitrate plus nitrite (as nitrogen) concentrations were identified at the Elk River site, and in total phosphorus concentrations at the South Fabius and Grand River sites. A downward flow-adjusted trend was identified in total phosphorus concentrations from Wilson Creek, the only urban site in the study. The downward trend in phosphorus possibly was related to a phosphorus reduction system that began operation in 2001 at a wastewater treatment plant upstream from the sampling site. Total suspended solids concentrations indicated an upward non-flow adjusted trend at the two northern sites (South Fabius and Grand Rivers). The increase in total suspended solids concentrations could be because of soil erosion from land cultivated for row crops. Most trace element data examined in the study were highly censored and could not be used for flow-adjusted trend analyses. Water-quality conditions were assessed to explore relations between data from sites and to the State water-quality standards where applicable for selected constituents. Streamflow varied at each site because of drainage area, land use, and groundwater inputs. Dissolved oxygen and water temperature were similar at all sites except the urban site located on Wilson Creek. Specific conductance was similar between the most northern (South Fabius and Grand River sites) and the most southern sites (Current and Elk River sites). Total suspended solids concentrations were near the method reporting level at all sites, except the northern sites. Streams in northern Missouri are more turbid than streams in southern Missouri and are affected by large volumes of sediment deposition because of soil erosion from land cultivated for row crops. Geometric means of Escherichia coli were calculated from the recreational seasons within the study period. Only the Grand River site exceeded the whole-body-contact standard for frequently used waters. The South Fabius and Grand River sites and the Wilson Creek site had statistically larger densities of both fecal indicator bacteria types than the remaining sites.

Scientific Investigations Report

Effects of the upper Taum Sauk Reservoir embankment breach on the surface-water quality and sediments of the East Fork Black River and the Black River, southeastern Missouri–2006–07

On December 14, 2005, a 680-foot wide section of the upper reservoir embankment of the Taum Sauk pump-storage hydroelectric powerplant located in Reynolds County, Missouri, suddenly failed. This catastrophic event sent approximately 1.5 billion gallons of water into the Johnson's Shut-Ins State Park and into the East Fork Black River, and deposited enormous quantities of rock, soil, and vegetation in the flooded areas. Water-quality data were collected within and below the impacted area to study and document the changes to the riverene system. Data collection included routine, event-based, and continuous surface-water quality monitoring as well as suspended- and streambed-sediment sampling. Surface water-quality samples were collected and analyzed for a suite of physical and chemical constituents including: turbidity; nutrients; major ions such as calcium, magnesium, and potassium; total suspended solids; total dissolved solids; trace metals such as aluminum, iron, and lead; and suspended-sediment concentrations. Suspended-sediment concentrations were used to calculate daily sediment discharge. A peculiar blue-green coloration on the water surface of the East Fork Black River and Black River was evident downstream from the lower reservoir during the first year of the study. It is possible that this phenomenon was the result of 'rock flour' occurring when the upper reservoir embankment was breached, scouring the mountainside and producing extremely fine sediment particles, or from the alum-based flocculent used to reduce turbidity in the lower reservoir. It also was determined that no long-term effects of the reservoir embankment breach are expected as the turbidity and concentrations of trace metals such as total recoverable aluminum, dissolved aluminum, dissolved iron, and suspended-sediment concentration graphically decreased over time. Larger concentrations of these constituents during the beginning of the study also could be a direct result of the alum-based flocculent used in the lower reservoir. Suspended-sediment concentrations and turbidity measurements were largest at the site downstream from the lower reservoir. This is because of the large amounts of debris deposited in the lower reservoir from the breach, which in turn were redeposited into the East Fork Black River during releases. When these constituents were plotted over time, the concentrations decreased and were similar to the other two sites in the study. Trend analyses were studied at one site with historical data. No major trends were discovered for streamflow, turbidity, suspended-sediment concentrations, or suspended-sediment discharges before or after the event. Although long-term effects of the elevated turbidity, major trace metals, and suspended sediments in the study area as a result of the reservoir embankment breach are not expected, there could possibly be other effects not measured during this study that could potentially affect the surface-water quality, such as loss of riparian habitat, changes in biological ecosystems, and large-scale reworking of sediments.

Missouri

Assessment of possible sources of microbiological contamination in the water column and streambed sediment of the Jacks Fork, Ozark National Scenic Riverways, Missouri — Phase III

In 1998, a 5 river-mile reach of the Jacks Fork was included on Missouri's list of impaired waters as required by Section 303(d) of the Federal Clean Water Act. The identified pollutant on the Jacks Fork was fecal coliform bacteria. The length of the impaired reach was changed to 7 miles on the Missouri 2002 303(d) list because of data indicating the fecal coliform bacteria problem existed over a broader area. The U.S. Geological Survey, in cooperation with the National Park Service, conducted a study to better understand the extent and sources of microbiological contamination within the Jacks Fork from Alley Spring to the mouth, which includes the 7-mile 303(d) reach. Ten sites were sampled from June 2003 through October 2003 and from June 2004 through October 2004. Water-column and streambed sediment samples were collected from main-stem and tributary sites mostly during base-flow conditions during a variety of recreational season river uses and analyzed for fecal coliform and Escherichia coli bacteria. Isolates of Escherichia coli obtained from water samples collected at five sites were submitted for rep-PCR analysis to identify presumptive sources of fecal indicator bacteria in the Jacks Fork. Results indicate that recreational users (including boaters and swimmers) are not the primary source of fecal coliform bacteria in the Jacks Fork; rather, the presence of fecal coliform bacteria is associated with other animals, of which horses are the primary source. Increases in fecal coliform bacteria densities in the Jacks Fork are associated with cross-country horseback trail-riding events.

Missouri