Geology topics

Michelle R. Plampin

Publications and source records attributed to Michelle R. Plampin.

13 recordsLinked to original sources

USGS2025

Estimation of dynamic geologic CO2 storage resources in the Illinois Basin, including effects of brine extraction, anisotropy, and hydrogeologic heterogeneity

Since the vast majority of carbon dioxide (CO 2 ) storage resources in the United States are in deep saline aquifers, optimizing the use of these saline storage resources could be crucial for efficient development of geologic CO 2 storage (GCS) resources and basin- or larger-scale deployment of GCS in the country. Maximum CO 2 injection rates can be enhanced by extracting brine from the CO 2 storage unit. However, disposal of the extracted brine is both a technological and economic challenge. The lowest-cost option would likely be reinjection of the extracted brine into another formation above or below the CO 2 storage unit. Therefore, it is important to estimate brine injectivity as it will constrain the potential to increase CO 2 injectivity at an injection site that has access to multiple geologic storage units where either CO 2 or brine can be injected. Using a simulation-optimization framework, coupled with a non-isothermal, multiphase CO 2 -water-salt equation-of-state module, we developed a computationally efficient method for evaluating optimization of simultaneous CO 2 injection, brine extraction, and brine (re)injection at hypothetical injection sites deployed across a geologic basin. The Illinois basin is ideal for testing our methodology because it contains multiple geologic storage units with seals in between them to isolate injection of CO 2 in one unit from interfering with the injection of either brine or CO 2 in another unit above or below it. In addition, we investigated the relative effects of variation in key geologic parameters as well as two reservoir structures (hydrogeologic heterogeneity/anisotropy and homogeneity/isotropy) on CO 2 injectivities and enhancement of CO 2 injectivity through extracting brine. Results suggest that permeability, depth, and especially thickness of the storage unit could be the most influential parameters determining CO 2 injectivity. They also suggest that only injecting CO 2 into the storage unit with the greatest injectivity, enhancing that unit’s injectivity by extracting brine, and disposing of the produced brine in other suitable units could maximize total CO 2 injectivity in limited regions of the basin. At the majority of simulated injection sites, however, we found that injecting CO 2 into all of the accessible and suitable storage units was more likely to maximize the CO 2 storage resource.

Illinois, Kentucky, Indiana↗

USGS2024

Hypothetical CO2 leakage into, and hydrological plume management within, an underground source of drinking water at a proposed CO2 storage facility, Kemper County, Mississippi, USA

A large Geologic Carbon Sequestration (GCS) hub has been proposed in Kemper County, Mississippi. The target injection interval consists of numerous Cretaceous-aged deep saline aquifers overlain by a competent and extensive regional sealing layer. Above the seal, the deepest Underground Source of Drinking Water (USDW) at the site is the Eutaw aquifer of the Eutaw Group and McShan Formation, undifferentiated. To assess potential risks of leakage from the deep sequestration reservoir, a model of a portion of the Cretaceous Eutaw Group was constructed in this study. Simulations tested various permeabilities, hypothetical leakage rates, and plume mitigation strategies utilizing existing wells. Results suggest that, under the influence of regional groundwater flow fields, leaking CO 2 would effectively bypass the existing wells, and to influence this migration would require very large water extraction rates. Therefore, to ensure plume detection, monitoring for leakage at the injection wells themselves is very important.

Mississippi↗

USGS2023

Geologic energy storage

Introduction As the United States transitions away from fossil fuels, its economy will rely on more renewable energy. Because current renewable energy sources sometimes produce variable power supplies, it is important to store energy for use when power supply drops below power demand. Battery storage is one method to store power. However, geologic (underground) energy storage may be able to retain vastly greater quantities of energy over much longer durations compared to typical battery storage. Geologic energy storage also has high flexibility; many different types of materials can be used to store chemical, thermal, or mechanical energy in a variety of underground settings. The U.S. Geological Survey (USGS) has the capability to research and assess possible domestic geologic energy storage resources to help prepare the United States for the future of renewable energy.

Fact Sheet↗

USGS2022

Dynamic estimates of geologic CO2 storage resources in the Illinois Basin constrained by reinjectivity of brine extracted for pressure management

Geologic carbon storage (GCS) is likely to be an important part of global efforts to decarbonize the energy industry. Widespread deployment of GCS relies on strategies to maximize CO 2 injection rates while minimizing reservoir pressurization that could induce seismicity and/or fluid leakage into groundwater resources. Brine extraction from CO 2 storage formations with subsurface reinjection elsewhere could mitigate pressure buildup associated with GCS. Therefore, evaluation of CO 2 storage resources should consider the injectivity of produced brine in geologic layers above or below the CO 2 storage formation. For this study, a methodology was developed to estimate brine injectivity from formation depth and thickness using flow modeling and optimization techniques. The methodology was demonstrated in the Illinois Basin, where GCS in the Mt. Simon Sandstone is ongoing. Based on pressure constraints and considering only regions of the shallower units where salinity and sealing conditions were met, maximum brine injection rates were estimated within the Mt. Simon and three overlying hydrostratigraphic layers. Results indicate that a large area exists where CO 2 injectivity could be optimized by brine extraction and reinjection.

Illinois, Indiana↗

USGS2022

Possible effects of multiphase methane evolution during a glacial cycle on underpressure development in sedimentary basins: An analysis with application to the northeast Michigan Basin

In low-permeability systems, groundwater may be accompanied by separate-phase fluids, and measured pore water pressures may deviate from those expected in steady-state, single-phase systems. These same systems may be of interest for storage of nuclear waste in Deep Geologic Repositories. Therefore, it is important to understand the relationship between the presence of a separate phase and anomalous pressure development. At the Bruce site in Southern Ontario, a significant underpressure was observed, and there is evidence for the presence of gas-phase methane in situ. This study used a one-dimensional (vertical) numerical model of the subsurface down to a depth of 844 m beneath the Bruce site to evaluate possible effects of hydromechanical coupling with multiphase flow on pressure evolution during glacial loading and unloading. The simulated pressure conditions were affected strongly by the amount of methane initially present in the system, and the maximum simulated underpressure varied nonmonotonically with increasing initial methane content. When the initial methane content was below the solubility limit, exsolution led to underpressures that briefly exceeded those that formed in the single-phase case. At intermediate initial methane contents (sufficient to produce an immobile gas phase), the gas phase dampened the hydromechanical effects of the glacial cycle. At large initial methane contents (when a mobile gas phase was present), gas migration caused a large decrease in relative liquid permeability, which further contributed to underpressure development in the pore water. Multiple scenarios that spanned a range of initial methane contents yielded underpressures like those observed at the Bruce site.

Journal of Geophysical Research - Solid Earth↗

USGS2021

Potential Pb+2 mobilization, transport, and sequestration in shallow aquifers impacted by multiphase CO2 leakage: A natural analogue study from the Virgin River Basin in Southwest Utah

Geological carbon sequestration (GCS) is necessary to help meet emissions reduction goals, but groundwater contamination may occur if CO 2 and/or brine were to leak out of deep storage formations into the shallow subsurface. For this study, a natural analogue was investigated: in the Virgin River Basin of southwest Utah, water with moderate salinity and high CO 2 concentrations is leaking upward into shallow aquifers that contain heavy metal-bearing concretions. The aquifer system is comprised of the Navajo and Kayenta formations, which are pervasive across southern Utah and have been considered as a potential GCS injection unit where they are sufficiently deep. Numerical models of the site were constructed based on measured water chemistry and head distributions from previous studies. Simulations were used to improve understanding of the rate and distribution of the upwelling flow into the aquifers, and to assess the reactive transport processes that may occur if the upwelling fluids were to interact with a zone of iron oxide and other heavy metals, representing the concretions that are common in the area. Various mineralogies were tested, including one in which Pb +2 was adsorbed onto ferrihydrite, and another in which it was bound within a solid mixture of litharge (PbO) and hematite (Fe 2 O 3 ). Results indicate that metal mobilization depends strongly on the source zone composition and that Pb +2 transport can be naturally attenuated by gas phase formation and carbonate mineral precipitation. These findings could be used to improve risk assessment and mitigation strategies at geological carbon sequestration sites.

Utah↗

USGS2021

Rapid-response unsaturated zone hydrology: Small-scale data, small-scale theory, big problems

The unsaturated zone (UZ) extends across the Earth’s terrestrial surface and is central to many problems related to land and water resource management. Flow of water through the UZ is typically thought to be slow and diffusive, such that it could attenuate fluxes and dampen variability between atmospheric inputs and underlying aquifer systems. This would reduce water resource vulnerability to contaminants and water-related hazards. Reducing or negating that effect, however, spatially concentrated and rapid flow and transport through the unsaturated zone is surprisingly common and becoming more so with the increasing frequency and magnitude of extreme hydroclimatic events. Arising from the wide range in the rates and complex modes of nonlinear flow processes, these effects are among the most poorly characterized hydrologic phenomena. Issues of scale present additional difficulties. Equations representing unsaturated processes have been developed and tested on the basis of field and laboratory measurements typically made at scales from pore size to plot size. In contrast, related problems of significant interest to society, including floods, aquifer recharge, landslides, and groundwater contamination, range from watershed to regional scales. The disparity between the scale of our understanding and the scale of interest for societal problems has spurred application of these model equations at increasingly coarse resolutions over larger areas than can be justified by existing measurements or theory. This mismatch in scales requires an assumption that spatially averaging slow diffusive flow and rapid preferential flow can effectively represent the influence of both processes across vast areas. Given the currently inadequate recognition and quantitative characterization of focused and rapid processes in unsaturated flow, these phenomena are critically in need of expanded attention and effort.

Frontiers in Earth Science↗

USGS2021

Computational methodology to analyze the effect of mass transfer rate on attenuation of leaked carbon dioxide in shallow aquifers

Exsolution and re-dissolution of CO 2 gas within heterogeneous porous media are investigated using experimental data and mathematical modeling. In a set of bench-scale experiments, water saturated with CO 2 under a given pressure is injected into a 2-D water-saturated porous media system, causing CO 2 gas to exsolve and migrate upwards. A layer of fine sand mimicking a heterogeneity within a shallow aquifer is present in the tank to study accumulation and trapping of exsolved CO 2 . Then, clean water is injected into the system and the accumulated CO 2 dissolves back into the flowing water. Simulated exsolution and dissolution mass transfer processes are studied using both nearequilibrium and kinetic approaches and compared to experimental data under conditions that do and do not include lateral background water flow. The mathematical model is based on the mixed hybrid finite element method that allows for accurate simulation of both advection- and diffusion- dominated processes.

Acta Polytechnica↗

USGS2020

Compositional analysis of formation water geochemistry and microbiology of commercial and carbon dioxide-rich wells in the southwestern United States

Studies of naturally occurring subsurface carbon dioxide (CO 2 ) accumulations can provide useful information for potential CO 2 injection projects; however, the microbial communities and formation water geochemistry of most reservoirs are understudied. Formation water and microbial biomass were sampled at four CO 2 -rich reservoir sites: two within Bravo Dome, a commercial CO 2 field in New Mexico; one northwest of Bravo Dome in Colorado (Oakdale Field); and one southwest of Bravo Dome in New Mexico (Rafter “K” Ranch). Aside from the Rafter “K” Ranch site, minor differences were observed in the geochemistry of formation water collected from these sites compared to historical data. No organisms were significantly associated with Oakdale Field compared to the other three sites, nor were any hydrogeochemical or gas geochemical parameters (for example, CO 2 concentration) found to have significant associations with the microbial ecology of these four sites. Microorganisms from these sites were metabolically diverse and had the potential to (1) generate methane, (2) produce corrosive hydrogen sulfide (H 2 S), and (3) rapidly biofoul and (or) clog pore spaces by shifting microbial communities with changes in salinity or nutrient supply. This study demonstrates that high concentrations of CO 2 in subsurface reservoirs apparently have not imparted a distinct geochemical or microbiological signature on the associated formation waters and that the microorganisms in these reservoirs are metabolically diverse and could adapt to geochemical changes in the subsurface.

Colorado, New Mexico, Texas, Oklahoma↗

USGS2020

Dimensional effects of inter-phase mass transfer on attenuation of structurally trapped gaseous carbon dioxide in shallow aquifers

Based on experimental evidence and using mathematical modeling, inter-phase mass transfer processes of CO 2 exsolving from and dissolving into water in heterogeneous porous media are investigated under two fundamentally different flow conditions: in a quasi one dimensional vertical column and in a two-dimensional tank with a lateral background water flow, both at laboratory scale. In both cases, the CO 2 dissolved in water under a given overpressure is injected for a certain period at the bottom of the tank, exsolves, and migrates upwards. A layer of fine sand is present in the tanks designed to mimic geological scenarios of accumulation and trapping of exsolved CO 2 in shallow aquifers. Then, clean water is injected and the accumulated CO 2 is dissolved back into the flowing water. The study aims to point out the differences in the mass transfer processes between the quasi-1D and 2D cases using a mathematical model of two-phase compositional flow in heterogeneous porous media calibrated to the experimental datasets, and expose strategies that should be explored in future research. Additionally, temperature variations observed during the 2D experiments allow for analysis of isothermal versus non-isothermal effects on the processes of multiphase CO 2 evolution. The mathematical model is discretized and solved using the mixed hybrid finite element method in 2D that allows for the simulation of both advection- and diffusion-dominated processes accurately.

Journal of Computational Physics↗

USGS2019

Glacially-induced hydromechanical coupling in shale may have caused underpressured water in the eastern Michigan Basin despite the possible presence of gas phase methane

When glacial cycles occur above low-permeability geologic formations, such as the shale and limestone units being considered for nuclear waste disposal in Canada, pressures may differ greatly from normal hydrostatic conditions. Although shale also often has the propensity to generate separate phase fluids like natural gas, it is largely uncertain how the processes that control this behavior might affect water pressure evolution during loading cycles. Therefore, this study investigates the relationships among these fundamental system components via an example site that exhibits both a dramatic underpressure and potential evidence for gas phase methane in situ. A simple 1-D representation of the site was constructed, and hydromechanical coupling during a glacial cycle was simulated with and without gas phase methane present. Results indicate that, while the presence of gas phase dampened the effects of the loading cycle due to its higher compressibility compared to water, it did not preclude underpressure development.

Ontario↗

USGS2018

Multiphase flow and underpressured shale at the Bruce nuclear site, Ontario, Canada

Hydraulic testing has revealed dramatic underpressures in Paleozoic shales and carbonates at the Bruce nuclear site in Ontario. Although evidence from both laboratory and field studies suggests that a small amount of gas-phase methane could be present in the shale, previous studies examining causal linkages between the gas phase and the underpressure have been inconclusive. To better elucidate processes in such a system, we used a highly simplified 1D representation of the site to test, by using iTOUGH2-EOS7C, the effects of various factors on the evolution of gas-phase methane and pressures within the system. Heterogeneity was represented by three stratigraphic regions with slightly different capillary pressure characteristics and, in one case, three thin distinct zones with very different characteristics. Underpressure occurred only when gas pressures set as an initial condition required it, and even in this case it was geologically short-lived. We conclude that the presence of multiple fluid phases is unlikely to explain the underpressure at the site; we suggest that the influence of gas-phase methane on porewater flow is minimal. This is consistent with prior conceptualizations of the underpressured section as a thick aquiclude, in which solute transport occurs extremely slowly, bounded by aquifers of significantly higher permeability.

Ontario↗

USGS2018

Multiphase hydromechanical iTOUGH2-EOS7C modeling study of underpressure development in shale during glacial loading cycles at the Bruce Nuclear Site, Ontario, Canada

A deep geologic repository (DGR) for low- and intermediate-level radioactive waste has been proposed at the Bruce nuclear site on the eastern flank of the Michigan Basin in southeastern Ontario, Canada. The repository would be placed at a depth of ~680 m, within a ~450 m-thick sequence of geologic media with extremely low porosity and permeability. The water in this section is significantly underpressured, which previous modeling work has shown could be the result of hydromechanical coupling during geologically recent glacial cycles. However, questions have been raised about whether gas phase methane is present in situ, and if so, how it relates to the generation and persistence of the underpressure here, as well as those in numerous other shale- and gas-rich sedimentary basins around the world. The primary goal of this study is to investigate, using the hydromechanical multiphase flow simulator iTOUGH2-EOS7C, what impact separate phase methane may have on coupled hydromechanical processes during glacial cycles. This was done by observing pressure evolution in a one-dimensional iTOUGH2-EOS7C model designed as a simplified representation of the Bruce site and its geologically recent history. Results indicate that, although gas phase generally dampens pressure changes in response to glacial loading, a similar underpressure to the one observed at the Bruce site could feasibly occur in a multiphase system.

Ontario↗