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Michael P. Doukas

Publications and source records attributed to Michael P. Doukas.

At least 19 recordsLinked to original sources
USGS2013

Evaluation of Redoubt Volcano's sulfur dioxide emissions by the Ozone Monitoring Instrument

The 2009 eruption of Redoubt Volcano, Alaska, provided a rare opportunity to compare satellite measurements of sulfur dioxide (SO 2 ) by the Ozone Monitoring Instrument (OMI) with airborne SO 2 measurements by the Alaska Volcano Observatory (AVO). Herein we: (1) compare OMI and airborne SO 2 column density values for Redoubt's tropospheric plume, (2) calculate daily SO 2 masses from Mount Redoubt for the first three months of the eruption, (3) develop simple methods to convert daily measured SO 2 masses into emission rates to allow satellite data to be directly integrated with the airborne SO 2 emissions dataset, (4) calculate cumulative SO 2 emissions from the eruption, and (5) evaluate OMI as a monitoring tool for high-latitude degassing volcanoes. A linear correlation (R 2 ~ 0.75) is observed between OMI and airborne SO 2 column densities. OMI daily SO 2 masses for the sample period ranged from ~ 60.1 kt on 24 March to below detection limit, with an average daily SO 2 mass of ~ 6.7 kt. The highest SO 2 emissions were observed during the initial part of the explosive phase and the emissions exhibited an overall decreasing trend with time. OMI SO 2 emission rates were derived using three methods and compared to airborne measurements. This comparison yields a linear correlation (R 2 ~ 0.82) with OMI-derived emission rates consistently lower than airborne measurements. The comparison results suggest that OMI's detection limit for high latitude, springtime conditions varies from ~ 2000 to 4000 t/d. Cumulative SO 2 masses calculated from daily OMI data for the sample period are estimated to range from 542 to 615 kt, with approximately half of this SO 2 produced during the explosive phase of the eruption. These cumulative masses are similar in magnitude to those estimated for the 1989–90 Redoubt eruption. Strong correlations between daily OMI SO 2 mass and both tephra mass and acoustic energy during the explosive phase of the eruption suggest that OMI data may be used to infer relative eruption size and explosivity. Further, when used in conjunction with complementary datasets, OMI daily SO 2 masses may be used to help distinguish explosive from effusive activity and identify changes in lava extrusion rates. The results of this study suggest that OMI is a useful volcano monitoring tool to complement airborne measurements, capture explosive SO 2 emissions, and provide high temporal resolution SO 2 emissions data that can be used with interdisciplinary datasets to illuminate volcanic processes.

Alaska↗
USGS2013

Airborne filter pack measurements of S and Cl in the plume of Redoubt Volcano, Alaska February–May 2009

Filter pack data from six airborne campaigns at Redoubt Volcano, Alaska are reported here. These measurements provide a rare constraint on Cl output from an andesitic eruption at high emission rate (> 10 4 t d − 1 SO 2 ). Four S/Cl ratios measured during a period of lava dome growth indicate a depth of last magma equilibration of 2–5 km. The S/Cl ratios in combination with COSPEC SO 2 emission rate measurements indicate HCl emission rates of 1500–3600 t d − 1 during dome growth. SO 2 and HCl emission rates at Redoubt Volcano correlate with each other and were low prior to the eruption, high during the eruption, and low after the eruption. S/Cl ratios measured by filter pack at andesitic volcanoes have a small range of variance, with no clear trends seen for eruptive versus passive activity. The very few S/Cl ratio measurements by filter pack at andesitic volcanoes are not as predictive of future volcanic activity as has been demonstrated for basaltic volcanoes. This may be because there are so few of these measurements. We have demonstrated it is possible to collect these samples by air between explosions during lava dome-building eruptions. We recommend more filter pack sampling be performed at andesitic volcanoes to determine the technique's utility for volcano monitoring. Filter pack data has been demonstrated to be useful for calculating the depth of magma equilibration at volcanoes including Redoubt Volcano.

Alaska↗
USGS2013

Degassing of CO2, SO2, and H2S associated with the 2009 eruption of Redoubt Volcano, Alaska

The 2009 eruption of Redoubt Volcano, Alaska was particularly well monitored for volcanic gas emissions. We report 35 airborne measurements of CO 2 , SO 2 , and H 2 S emission rates that span from October 2008 to August 2010. The magmatic system degassed primarily as a closed system although minor amounts of open system degassing were observed in the 6 months prior to eruption on March 15, 2009 and over 1 year following cessation of dome extrusion. Only 14% of the total CO 2 was emitted prior to eruption even though high emissions rates (between 3630 and 9020 t/d) were observed in the final 6 weeks preceding the eruption. A minor amount of the total SO 2 was observed prior to eruption (4%), which was consistent with the low emission rates at that time (up to 180 t/d). The amount of the gas emitted during the explosive and dome growth period (March 15–July 1, 2009) was 59 and 66% of the total CO 2 and SO 2 , respectively. Maximum emission rates were 33,110 t/d CO 2 , 16,650 t/d SO 2 , and 1230 t/d H 2 S. Post-eruptive passive degassing was responsible for 27 and 30% of the total CO 2 and SO 2 , respectively. SO 2 made up on average 92% of the total sulfur degassing throughout the eruption. Magmas were vapor saturated with a C- and S-rich volatile phase, and regardless of composition, the magmas appear to be buffered by a volatile composition with a molar CO 2 /SO 2 ratio of ~ 2.4. Primary volatile contents calculated from degassing and erupted magma volumes range from 0.9 to 2.1 wt.% CO 2 and 0.27–0.56 wt.% S; whole-rock normalized values are slightly lower (0.8–1.7 wt.% CO 2 and 0.22–0.47 wt.% S) and are similar to what was calculated for the 1989–90 eruption of Redoubt. Such contents argue that primary arc magmas are rich in CO 2 and S. Similar trends between volumes of estimated degassed magma and observed erupted magma during the eruptive period point to primary volatile contents of 1.25 wt.% CO 2 and 0.35 wt.% S. Assuming these values, up to 30% additional unerupted magma degassed in the year following final dome emplacement.

Alaska↗
USGS2012

Deep magmatic degassing versus scrubbing: Elevated CO2 emissions and C/S in the lead-up to the 2009 eruption of Redoubt Volcano, Alaska

We report CO 2, SO 2 , and H 2 S emission rates and C/S ratios during the five months leading up to the 2009 eruption of Redoubt Volcano, Alaska. CO 2 emission rates up to 9018 t/d and C/S ratios ≥30 measured in the months prior to the eruption were critical for fully informed forecasting efforts. Observations of ice-melt rates, meltwater discharge, and water chemistry suggest that surface waters represented drainage from surficial, perched reservoirs of condensed magmatic steam and glacial meltwater. These fluids scrubbed only a few hundred tonnes/day of SO 2 , not the >2100 t/d SO 2 expected from degassing of magma in the mid- to upper crust (3–6.5 km), where petrologic analysis shows the final magmatic equilibration occurred. All data are consistent with upflow of a CO 2 -rich magmatic gas for at least 5 months prior to eruption, and minimal scrubbing of SO 2 by near-surface groundwater. The high C/S ratios observed could reflect bulk degassing of mid-crustal magma followed by nearly complete loss of SO 2 in a deep magmatic-hydrothermal system. Alternatively, high C/S ratios could be attributed to decompressional degassing of low silica andesitic magma that intruded into the mid-crust in the 5 months prior to eruption, thereby mobilizing the pre-existing high silica andesite magma or mush in this region. The latter scenario is supported by several lines of evidence, including deep long-period earthquakes (−28 to −32 km) prior to and during the eruption, and far-field deformation following the onset of eruptive activity.

Alaska↗
USGS2011

The reawakening of Alaska's Augustine volcano

Augustine volcano, in south central Alaska, ended a 20-year period of repose on 11 January 2006 with 13 explosive eruptions in 20 days. Explosive activity shifted to a quieter effusion of lava in early February, forming a new summit lava dome and two short, blocky lava flows by late March (Figure 1). The eruption was heralded by eight months of increasing seismicity, deformation, gas emission, and small phreatic eruptions, the latter consisting of explosions of steam and debris caused by heating and expansion of groundwater due to an underlying heat source.

Alaska↗
USGS2010

Emission of SO 2 , CO 2 , and H 2 S from Augustine Volcano, 2002-2008: Chapter 26 in The 2006 eruption of Augustine Volcano, Alaska

Airborne surveillance of gas emissions from Augustine Volcano and other Cook Inlet volcanoes began in 1990 to identify baseline emission levels during noneruptive conditions. Gas measurements at Augustine for SO 2 , CO 2 , and H 2 S showed essentially no evidence of anomalous degassing through spring 2005. Neither did a measurement on May 10, 2005, right after the onset of low level seismicity and inflation. The following measurement, on December 20, 2005, showed Augustine to be degassing about 600 metric tons per day (t/d) of SO 2 , and by January 4, 2006, only 7 days before the first explosive event, SO 2 emissions had climbed to ten times that amount. Maximum emission rates measured during the subsequent eruption were: 8,930 t/d SO 2 (February 24, 2006), 1,800 t/d CO 2 (March 9, 2006), and 4.3 t/d H 2 S (January 19, 2006). In total, 45 measurements for SO 2 were made from December 2005 through the end of 2008, with 19 each for CO 2 and H 2 S during the same period. Molar CO 2 /SO 2 ratios averaged about 1.6. In general, SO 2 emissions appeared to increase during inflation of the volcanic edifice, whereas CO 2 emissions were at their highest during the period of deflation associated with the vigorous effusive phase of the eruption in March. High SO 2 was probably associated with degassing of shallow magma, whereas high CO 2 likely reflected deep (>4 km) magma recharge of the sub-volcanic plumbing system, For the 2005–6 period, the volcano released a total of about 1.5×10 6 tons of CO 2 to the atmosphere, a level similar to the annual output of a medium-sized natural-gas-fired powerplant. Augustine also emitted about 8×10 5 tons of SO 2 , similar to that produced by the 1976 and 1986 eruptions of the volcano.

Alaska↗
USGS2008

Emission rates of CO2, SO2, and H2S, scrubbing, and preeruption excess volatiles at Mount St. Helens, 2004-2005

Airborne surveillance of gas emissions began at Mount St. Helens on September 27, 2004. Reconnaissance measurements--SO 2 column abundances and CO 2 , SO 2 , and H 2 S concentrations--showed neither a gas plume downwind of the volcano nor gas sources within the crater. Subsequent measurements taken during the period of unrest before the eruption began on October 1 and for several days after October 1 showed only small point sources of gas within the crater. These sources defined a pattern of scrubbed degassing that evolved from near-zero emissions, to scattered CO 2 -only sources, to growing sources of CO 2 with minor H 2 S and SO 2 , and finally to myriad sources of CO 2 with increasingly SO 2 - dominant sulfur gases. Scrubbing strongly hydrolyzed SO 2 but also affected CO 2 and H 2 S.

Washington↗
USGS2008

Chlorine degassing during the lava dome-building eruption of Mount St. Helens, 2004-2005

Remote measurements of volcanic gases from the Mount St. Helens lava dome were carried out using OpenPath Fourier-Transform Infrared spectroscopy on August 31, 2005. Measurements were performed at a site ~1 km from the lava dome, which was used as a source of IR radiation. On average, during the period of measurement, the volcanic gas contained 99 mol percent H 2 O, 0.78 percent CO 2 , 0.095 percent HCl, 0.085 percent SO 2 , 0.027 percent HF, 4.8×10 -4 percent CO, and 2.5×10 -4 percent COS close to the active vent. The fluxes of these species, constrained by synchronous measurements of SO 2 flux, were 7,200 t/d H 2 O, 140 t/d CO 2 , 22 t/d SO 2 , 14 t/d HCl, 2.0 t/d HF, 54 kg/d CO, and 59 kg/d COS, ±20 percent. Observations of H 2 O/Cl in the vapor and melt are compared to models of closed- and open-system degassing and to models where a closed system dominates to depths as shallow as ~1 km, and gases are then allowed to escape through a permeable bubble network. Although several features are consistent with this model--for example, (1) H 2 O/Cl in the gases emitted from stagnant parts of the lava dome, (2) the concentration of Cl in the matrix glass of erupted dacite, and (3) the glass H 2 O/Cl--the gases emitted from the active part of the lava dome have much higher H 2 O/ Cl than expected. These higher H 2 O/Cl levels result from a combination of two factors (1) the addition of substantial amounts of ground water or glacier-derived H 2 O to the gases at shallow depths, such that only ~10 mol percent of the measured H 2 O is magmatic, and (or) (2) some Cl present as alkali chloride (NaCl and KCl) in the gas phase. The mean molar Cl/S is similar to gases measured at other silicic subductionzone volcanoes during effusive activity; this may be due to the influence of Cl in the vapor on S solubility in the melt, which produces a solubility maximum for S at vapor Cl/S ~1.

Washington↗
USGS2007

A Compilation of Gas Emission-Rate Data from Volcanoes of Cook Inlet (Spurr, Crater Peak, Redoubt, Iliamna, and Augustine) and Alaska Peninsula (Douglas, Fourpeaked, Griggs, Mageik, Martin, Peulik, Ukinrek Maars, and Veniaminof), Alaska, from 1995-2006

INTRODUCTION This report presents gas emission rates from data collected during numerous airborne plume-measurement flights at Alaskan volcanoes since 1995. These flights began in about 1990 as means to establish baseline values of volcanic gas emissions during periods of quiescence and to identify anomalous levels of degassing that might signal the beginning of unrest. The primary goal was to make systematic measurements at the major volcanic centers around the Cook Inlet on at least an annual basis, and more frequently during periods of unrest and eruption. A secondary goal was to measure emissions at selected volcanoes on the Alaska Peninsula. While the goals were not necessarily met in all cases due to weather, funding, or the availability of suitable aircraft, a rich dataset of quality measurements is the legacy of this continuing effort. An earlier report (Doukas, 1995) presented data for the period from 1990 through 1994 and the current report provides data through 2006. This report contains all of the available measurements for SO2, CO2, and H2S emission rates in Alaska determined by the U. S. Geological Survey from 1995 through 2006; airborne measurements for H2S began in Alaska in 2001. The results presented here are from Cook Inlet volcanoes at Spurr, Crater Peak, Redoubt, Iliamna, and Augustine and cover periods of unrest at Iliamna (1996) and Spurr (2004-2006) as well as the 2006 eruption of Augustine. Additional sporadic measurements at volcanoes on the Alaska Peninsula (Douglas, Martin, Mageik, Griggs, Veniaminof, Ukinrek Maars, Peulik, and Fourpeaked during its 2006 unrest) are also reported here.

Open-File Report↗
USGS2005

Reconnaissance gas measurements on the East Rift Zone of Kilauea Volcano, Hawai'i by Fourier transform infrared spectroscopy

We report the results of a set of measurements of volcanic gases on two small ground level plumes in the vicinity of Pu`u `O`o cone on the middle East Rift Zone (ERZ) of Kilauea volcano, Hawai`i on 15 June 2001 using open-path Fourier transform infrared (FTIR) spectroscopy. The work was carried out as a reconnaissance survey to assess the monitoring and research value of FTIR measurements at this volcano. Despite representing emissions of residual volatiles from lava that has undergone prior degassing, the plumes contained detectable amounts of CO2, CO, SO2, HCl, HF and SiF4. Various processes, including subsurface cooling, condensation of water in the atmospheric plume, oxidation, dissolution in water, and reactions with wall rocks at plume vents affect the abundance of these gases. Low concentrations of volcanic CO2 measured against a high ambient background are not well constrained by FTIR spectroscopy. Although there appear to be some differences between these gases and Pu`u `O`o source gases, ratios of HCl/SO2, HF/SO2 and CO/SO2 determined by FTIR measurements of these two small plumes compare reasonably well with earlier published analyses of ERZ vent samples. The measurements yielded emission rate estimates of 4, 11 and 4 t d-1

Hawaii↗
USGS2002

A new method for GPS-based wind speed determinations during airborne volcanic plume measurements

Begun nearly thirty years ago, the measurement of gases in volcanic plumes is today an accepted technique in volcano research. Volcanic plume measurements, whether baseline gas emissions from quiescent volcanoes or more substantial emissions from volcanoes undergoing unrest, provide important information on the amount of gaseous output of a volcano to the atmosphere. Measuring changes in gas emission rates also allows insight into eruptive behavior. Some of the earliest volcanic plume measurements of sulfur dioxide were made using a correlation spectrometer (COSPEC). The COSPEC, developed originally for industrial pollution studies, is an upward-looking optical spectrometer tuned to the ultraviolet absorption wavelength of sulfur dioxide (Millán and Hoff, 1978). In airborne mode, the COSPEC is mounted in a fixed-wing aircraft and flown back and forth just underneath a volcanic plume, perpendicular to the direction of plume travel (Casadevall and others, 1981; Stoiber and others, 1983). Similarly, for plumes close to the ground, the COSPEC can be mounted in an automobile and driven underneath a plume if a suitable road system is available (Elias and others, 1998). The COSPEC can also be mounted on a tripod and used to scan a volcanic plume from a fixed location on the ground, although the effectiveness of this configuration declines with distance from the plume (Kyle and others, 1990). In the 1990’s, newer airborne techniques involving direct sampling of volcanic plumes with infrared spectrometers and electrochemical sensors were developed in order to measure additional gases such as CO2 and H2S (Gerlach and others, 1997; Gerlach and others, 1999; McGee and others, 2001). These methods involve constructing a plume cross-section from several measurement traverses through the plume in a vertical plane. Newer instruments such as open-path Fourier transform infrared (FTIR) spectrometers are now being used to measure the gases in volcanic plumes mostly from fixed locations on the ground. Most FTIR studies to date measure only gas compositions or ratios of gas species (Love and others, 1998; Francis and others, 1998; Horrocks and others, 1999). What all of these methods have in common, however, is the necessity to know plume velocities if accurate gas emission rates are to be calculated. Even open-path FTIR studies done in tandem with a COSPEC require knowledge of plume velocity in order to compute emission rates.

Open-File Report↗
USGS1997

Impacts of volcanic gases on climate, the environment, and people

Gases from volcanoes give rise to numerous impacts on climate, the environment, and people. U.S. Geological Survey (USGS) scientists are inventorying gas emissions at many of the almost 70 active volcanoes in the United States. This effort helps build a better understanding of the dynamic processes at work on the Earth's surface and is contributing important new information on how volcanic emissions affect global change.

Open-File Report↗
USGS1996

Volcanic activity in Alaska: Summary of events and response of the Alaska Volcano Observatory 1993

During 1993, the Alaska Volcano Observatory (AVO) responded to episodes of eruptive activity or false alarms at nine volcanic centers in the state of Alaska. Additionally, as part of a formal role in KVERT (the Kamchatkan Volcano Eruption Response Team), AVO staff also responded to eruptions on the Kamchatka Peninsula, details of which are summarized in Miller and Kurianov (1993). In 1993, AVO maintained seismic instrumentation networks on four volcanoes of the Cook Inlet region--Spurr, Redoubt, Iliamna, and Augustine--and two stations at Dutton Volcano near King Cove on the Alaska Peninsula. Other routine elements of AVO's volcano monitoring program in Alaska include periodic airborne measurement of volcanic SO 2 and CO 2 at Cook Inlet volcanoes (Doukas, 1995) and maintenance of a lightning detection system in Cook Inlet (Paskievitch and others, 1995).

Alaska↗
USGS1995

Volcanic activity in Alaska: Summary of events and response of the Alaska Volcano Observatory 1994

During 1994, the Alaska Volcano Observatory (AVO) responded to eruptions, possible eruptions, or false alarms at nine volcanic centers-- Mount Sanford, Iliamna, the Katmai group, Kupreanof, Mount Veniaminof, Shishaldin, Makushin, Mount Cleveland and Kanaga (table 1). Of these volcanoes, AVO has a real time, continuously recording seismic network only at Iliamna, which is located in the Cook Inlet area of south-central Alaska (fig. 1). AVO has dial-up access to seismic data from a 5-station network in the general region of the Katmai group of volcanoes. The remaining unmonitored volcanoes are located in sparsely populated areas of the Wrangell Mountains, the Alaska Peninsula, and the Aleutian Islands (fig. 1). For these volcanoes, the AVO monitoring program relies chiefly on receipt of pilot reports, observations of local residents and analysis of satellite imagery.

Alaska↗
USGS1995

A compilation of sulfur dioxide and carbon dioxide emission-rate data from Cook Inlet volcanoes (Redoubt, Spurr, Iliamna, and Augustine), Alaska during the period from 1990 to 1994

Airborne sulfur dioxide (SO2) gas sampling of the Cook Inlet volcanoes (Mt. Spurr, Redoubt, Iliamna, and Augustine) began in 1986 when several measurements were carried out at Augustine volcano during the eruption of 1986 (Rose and others, 1988). More systematic monitoring for SO2 began in March 1990 and for carbon dioxide (CO2) began in June, 1990 at Redoubt Volcano (Brantley, 1990 and Casadevall and others, 1994) and continues to the present. This report contains all of the available daily SO2 and CO2 emission rates determined by the U.S. Geological Survey (USGS) from March 1990 through July 1994. Intermittent measurements (four to six month intervals) at Augustine and Iliamna began in 1990 and continues to the present. Intermittent measurements began at Mt. Spurr volcano in 1991, and were continued at more regular intervals from June, 1992 through the 1992 eruption at the Crater Peak vent to the present.

Alaska↗