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Michael Jenkins

Publications and source records attributed to Michael Jenkins.

14 recordsLinked to original sources
USGS2026

Origin of the Pd/Pt ratio of the J-M Reef, Stillwater Complex, Montana, USA

The J-M reef of the Stillwater Complex is characterized by a high Pd/Pt ratio (mean ~3.8 with a standard error of 0.03) with a homogeneous geospatial distribution at the deposit scale. In this contribution, we demonstrate that the Pd/Pt ratio of the reef is the product of equilibration of an immiscible sulfide liquid with a silicate melt rich in Pd relative to Pt. Despite the high tenors of the J-M reef sulfides (avg 2,700 ppm Pt and 770 ppm Pt), numerical modeling shows that the parental melts did not have extraordinary Pd and Pt concentrations. Instead, the initial composition of a plausible parental silicate melt can have Pd and Pt contents well within the expected range of a normal, mantle-derived partial melt (i.e., ~10–20 ppb for both Pd and Pt with Pd/Pt of ~1). The relative differences in the partitioning behavior of Pt and Pd between sulfide liquid and silicate melt are unlikely to produce a consistent Pd/Pt ratio across a wide range of silicate melt to sulfide liquid mass ratios (i.e., R factors). Instead, the pre-emplacement fractionation of Pt alloy from S-undersaturated silicate magma accounts for the homogeneous and high Pd/Pt ratio of the J-M reef. We show that batch equilibration of sulfide liquid with silicate melt can produce the high Pd/Pt ratios of the reef if the partition coefficients between sulfide liquid and silicate melt for Pd and Pt are extremely high (>10 6 ). In an alternative model, Pd enrichment could be achieved by sulfide upgrading in resident footwall mush even if the partition coefficients between sulfide liquid and silicate melt are relatively small (between 10 4 and 10 6 ) because the instantaneous mass ratio of silicate melt to sulfide liquid is small (R ≈ 100–700), so the partitioning behavior of Pt and Pd has little impact on the composition of sulfide liquid.

Montana↗
USGS2025

Noble and base metal distribution and processes affecting ore tenors in the disrupted lower stratigraphy of the Stillwater Complex, USA

Exploration continues for contact-style Ni-Cu sulfide and chromitite-associated PGE mineralization in ultramafic rocks of the Stillwater Complex. At the Iron and Chrome Mountain areas, massive sulfides occur along the complex’s footwall contact and anomalous concentrations of PGE+Au are associated with the three lowermost chromitite seams. Southeast of Chrome Mountain, magmatic layering is highly disrupted by the presence of faults, magmatic breccias, serpentinized discordant dunites, pyroxenite pegmatoids, and disaggregated chromitite seams. The bulk rock chemistry, sulfide chemistry, and noble metal mineralogy of samples from this area were examined to determine the deportment of PGE and processes that led to enrichments in PGE, Au, Cu, Co and Ni. Results show that a sulfide liquid was the principal collector of PGE. If sulfide liquid was initially deposited with chromite, it was disaggregated or redistributed by subsequent melt or fluid infiltration, which may have resulted in the offset of peak PGE(+Cu, Ni) from peak Cr 2 O 3 concentrations, and upgraded PGE tenors. Upon cooling, PGE exsolved from sulfides to form discrete bismuth tellurides, arsenides, arsenic sulfides, antimonides, and alloys, commonly along the margins of sulfide globules. Calculated metal tenors are highest in the disseminated sulfides southwest of Chrome Mountain, whereas massive and net-textured sulfides near the Iron Mountain-Camp zone represent monosulfide solid solution cumulates. At progressively shallower levels, higher metal tenors combined with lower S/Se ratios are consistent with increasing R-factors from 100 to 100,000. Serpentinization and talc-tremolite alteration resulted in S loss through partial replacement of sulfides by secondary silicate+carbonate+magnetite+sulfide assemblages, further upgrading Ni-Cu-PGE tenors. The present work shows that processes responsible for the disruption of magmatic layering and post-magmatic fluid alteration along the intrusion’s lower contact led to noble and base metal enrichments.

Montana↗
USGS2025

Assimilation of reduced carbon triggers platinum alloy saturation in mafic and ultramafic magmas

It is generally observed that magmatic sulfide ores have higher ratios of Pd/Pt than the mantle-like values of their parental magmas. This discrepancy has defied simple explanation because the partitioning behavior of both elements between sulfide and silicate liquids is very similar. Assimilation of sulfur- and carbon-rich country rocks by mafic and ultramafic magmas is considered a critical, if not essential, step in the formation of magmatic base metal sulfide deposits. Although there is general consensus that the assimilation of external sulfur and carbon promotes sulfide saturation, the effect of carbon assimilation on the solubilities of platinum-group elements in natural S-bearing silicate melt has been overlooked. In this study, we investigate the variations of platinum and palladium solubilities during assimilation of graphite and methane through thermodynamic modeling, in comparison with data from an array of highly distinctive magmatic sulfide ore systems representing ages from Archean to Paleozoic, melt compositions from komatiite to basalt, and magmatic settings including lavas, hypabyssal intrusions, plutonic continental arc roots, and plutonic layered intrusions, namely: Raglan, Norilsk-Talnakh, Lac des Iles, and the J-M Reef of the Stillwater Complex. We model assimilation-fractional crystallization processes to estimate the reduction of oxygen fugacity ( ⁠fO2⁠ ) of the melt due to incorporation of graphite and methane. The simulations show that although Pd remains highly soluble during the progressive assimilation of reduced carbon, Pt solubility decreases significantly as the silicate melt becomes increasingly reduced. With less than 8 % of sediment assimilation, Pt alloy may saturate and then deviate from sulfide-undersaturated silicate melts, concomitantly increasing the Pd/Pt value of the remaining melts of the Raglan and Norilsk-Talnakh systems. For the Lac des Iles and Stillwater systems, a higher extent of assimilation is needed to reach Pt saturation because of the relatively carbon-poor nature of the lower crustal rocks. The assimilation of methane volatiles is shown to be more effective than graphite assimilation, and it provides a pathway to Pt alloy fractionation in the absence of detectable amounts of bulk host-rock assimilation. High Pd/Pt values have been documented in many world-class magmatic sulfide deposits whose parental magmas have demonstrably experienced crustal contamination. Our model suggests that although anomalous Pd/Pt values may be explained by other mechanisms such as incongruent melting of preexisting sulfide or differences in the diffusivities of the metals within achieving equilibration, the assimilation of graphite or methane may play an important role in the global occurrence of magmatic sulfide ores with elevated Pd/Pt values.

Economic Geology↗
USGS2025

Petrogenesis and mineralization potential of spinifex komatiitic basalts in the Bradley Peak greenstone terrane, Wyoming Province

Komatiitic volcanic rocks are important hosts of Ni sulfide mineralization and record early Earth evolution; however, those in the well-studied Archean Wyoming Province have received little attention. Here, we elucidate the timing and petrogenesis of the Bradley Peak komatiitic volcanic rocks using field and textural observations, geochronology, and geochemistry. Detrital and igneous zircon U-Pb ages for two samples from previously undated units support published age determinations, placing the eruption age at 2.72 Ga. Stratigraphy of the volcanic flows was mapped and 36 samples including cumulates, greenschists, and spinifex-textured rocks were collected. Whole-rock geochemistry was used to classify the spinifex-textured samples as Al-undepleted komatiitic basalts (11–17 wt% MgO). Platinum-group element concentrations (n = 25) are like those in global Al-undepleted komatiitic basalts, and PGE/Ti ratios do not indicate the volcanic flows likely host sulfide mineralization. Initial ε Nd values of −0.5 to +4.7 (n = 16), indicate that these lavas were derived from a depleted mantle source and have negligible evolved crust contamination. The primary magma to the komatiitic basalt flows is estimated to have had 19 wt% MgO and be derived from ∼15 to 25 % mantle partial melting at 3–4 GPa. Trace element chemistry and thermodynamic modeling suggest the primary melt assimilated local banded iron formation. Although the Bradley Peak komatiitic basalts do not contain positive evidence of magmatic sulfide deposits, depleted Au in the flows suggests they could be source rocks for nearby orogenic gold deposits.

Wyoming↗
USGS2025

Origin of the high Pd/Pt ratio of the J-M Reef, Stillwater Complex Montana USA

The J-M Reef of the Stillwater Complex exhibits a high and consistent Pd/Pt ratio (~3.8). This ratio results from the equilibration of an immiscible sulfide liquid with a relatively high Pd/Pt silicate melt rather than an unusually Pd- and Pt-enriched parental melt. Numerical modeling suggests that the original silicate melt contained typical mantle-derived concentrations of Pd and Pt (~10–20 ppb Pd/Pt ~1). The partitioning of Pt and Pd between sulfide liquid and silicate melt alone cannot explain the consistently high Pd/Pt ratio across variable melt-to-sulfide mass ratios (R factors). Instead Pt-depletion caused by the early fractionation of Pt-alloy from S-undersaturated silicate magma likely established the high Pd/Pt signature. High Pd/Pt ratios can form through batch equilibration of sulfide liquid with silicate melt if partition coefficients are extremely high (>10⁶). Alternatively Pd enrichment may result from sulfide upgrading within the resident footwall mush under smaller partition coefficients (10⁴–10⁶) in this model the instantaneous R factors remain low (R ≈ 100–700). This limits the impact of Pt and Pd partitioning on sulfide composition and helps explain the Pd-enriched character of the J-M Reef.

Montana↗
USGS2025

Petrogenesis and mineralization potential of the Bradley Peak komatiitic basalts, Wyoming Province

The ca. 2.72 Ga Bradley Peak greenstone terrane in the Wyoming Province contains spinifex- and cumulate-textured komatiitic volcanic rocks that may host Ni-Cu-PGE sulfide mineralization. New whole rock geochemistry classifies these rocks as Al-undepleted komatiitic basalts derived from a parental melt with ~17 wt. % MgO. Isotopic data (Sm-Nd, Re-Os) and REE profiles suggest a plume source and possible assimilation of juvenile footwall volcanic rocks. Calculated sulfur concentrations at sulfide saturation and low-detection PGE geochemistry indicate these magmas did not saturate a sulfide liquid resulting in sulfide mineralization. Although the Bradley Peak komatiitic basalt flows are unlikely to host magmatic sulfide mineralization, they are likely the source of Au for regional orogenic gold deposits.

Wyoming↗
USGS2024

Layered intrusions in the Precambrian: Observations and perspectives

Layered intrusions are plutonic bodies of cumulates that form by the crystallization of mantle-derived melts. These intrusions are characterized by igneous layering distinguishable by shifts in mineralogy, texture, or composition. Layered intrusions have been fundamental to our understanding of igneous petrology; however, it is their status as important repositories of critical metals – such as platinum-group elements, chromium, and vanadium – that has predominantly driven associated research in recent decades. Many layered intrusions were emplaced during the Precambrian, predominantly at the margins of ancient cratons during intervals of supercontinent accretion and destruction. It appears that large, layered intrusions require rigid crust to ensure their preservation, and their geometry and layering is primarily controlled by the nature of melt emplacement. Layered intrusions are best investigated by integrating observations from various length-scales. At the macroscale, intrusion geometries can be discerned, and their presence understood in the context of the regional geology. At the mesoscale, the layering of an intrusion may be characterized, intrusion-host rock contact relationships studied, and the nature of stratiform mineral occurrences described. At the microscale, the mineralogy and texture of cumulate rocks and any mineralization are elucidated, particularly when novel microtextural and mineral chemical datasets are integrated. For example, here we demonstrate how mesoscale observations and microscale datasets can be combined to understand the petrogenesis of the perplexing snowball oiks outcrop located in the Upper Banded Series of the Stillwater Complex. Our data suggest that the orthopyroxene oikocrysts did not form in their present location, but rather formed in a dynamic magma chamber where crystals were transported either by convective currents or within crystal-rich slurries. Critical metals may be transported to the level of a nascent intrusion as dissolved components in the melt. Alternatively, ore minerals are entrained from elsewhere in a plumbing system, potentially facilitated by volatile-rich phases. There are many ore-forming processes propounded by researchers to occur at the level of emplacement; however, each must address the arrival of the ore mineral, its concentration of metals, and its accumulation into orebodies. In this contribution, several of these processes are described as well as our perspectives on the future of layered intrusion research.

Precambrian Research↗
USGS2022

A novel origin for PGE reefs: A case study of the J-M Reef

The origin of meter scale stratiform layers of disseminated sulfides in enriched platinum group element (PGE) tenors and grades, called reef-type deposits, are the world’s most significant source of PGEs. Their origin in layered mafic intrusions remains debated, but in general, most researchers favor an orthomagmatic origin for reef-type deposits and agree that their formation requires the equilibration of an immiscible sulfide liquid with a significantly larger mass of silicate magma (i.e., silicate:sulfide mass ratios of 104 to 106). However, where, and how this chemical equilibration process takes place in the magmatic system is poorly constrained. In this contribution, we propose a new model for the origin of PGE reef deposits. We demonstrate that finely disseminated, resident sulfide liquid hosted within cumulate mush can be upgraded by incoming batches of S-undersaturated and PGE-undepleted silicate melt. We demonstrate this model through a case study of the J-M Reef deposit of the Stillwater Complex, the world’s highest-grade PGE deposit (14 ppm Pd over 1.8 m).

Conference Paper↗
USGS2021

Origin of the J-M Reef and Lower Banded series, Stillwater Complex, Montana, USA

The origin and parental magma for layered cumulates in the Lower Banded series (LBS) and the J-M Reef Pd-Pt deposit of the Stillwater Complex remains poorly constrained. We present whole-rock lithogeochemistry and mineral chemistry from LBS rocks collected from drill holes and surface samples from the Mountain View area of the complex that in total span nearly the entirety of the LBS stratigraphy. Excess S, Pt, and Pd in the noritic and gabbronoritic cumulates of the LBS indicate that small amounts of high tenor sulfide liquid generated at very low degrees of sulfide oversaturation were ubiquitous parts of the cumulate assemblage. We show that a simple two-stage thermodynamic model of assimilation-batch crystallization of a komatiitic parental magma in the lower crust, produces a close match to a common suite of fine-grained gabbronorite dikes and sills that intrude both the complex and its footwall. After fractionating ultramafic cumulates in the lower crust, the model contaminated komatiitic liquid produces upper crustal cumulates by batch crystallization en route to or at the level of the intrusion. The modeled rocks have compositions and mineral assemblages closely resembling pyroxenite of the Bronzitite zone and both norite and gabbronorite cumulates in the lower LBS. The trends from the Bronzitite zone through Norite zone I and Gabbronorite zone I can be understood as the result of deposition of crystals from successive batches of the same contaminated parental magma, with an upward trend toward greater amounts of cooling before the separation of crystals from liquid. The olivine-bearing suite of Olivine-bearing zone I, which includes the J-M Reef, can be modeled by partial remelting of the same norite and gabbronorite cumulates due to a temporarily increased flux of hot, moderately less contaminated LBS parental magma that infiltrated partially molten cumulates because its density exceeded that of the interstitial liquid. This model suggests that infiltration of hot Mg-rich parental liquid into moderately PGE-enriched footwall cumulates may be fundamental to the formation of the extremely high tenor sulfide mineralization in the J-M Reef ore zone, and perhaps other reef-type deposits worldwide. The same metal tenors that would require silicate/sulfide mass ratios (i.e., R-factors) of 10 5 to 10 6 in a single stage of equilibration would be attained during this second stage of interaction by the incremental infiltration and passage of LBS parental magma through previously sulfide saturated cumulate mush.

Montana↗
USGS2020

The nature and composition of the J-M Reef, Stillwater Complex, Montana, USA

In this contribution, we analyze 30 years of mine development data and quantitatively identify the processes that control the grade and tenor of the mineralized rock. An assay database of more than 60,000 samples was used to examine variations in ore grade and tenor of the sulfide mineralization in the J-M reef horizon of the Stillwater Complex along the strike and down the dip of the deposit in the area of the Stillwater mine. We compare these results with data from the East Boulder mine and whole-rock lithogeochemistry of samples collected along the entire strike length of the complex. We find significant variation in the composition of the reef sulfides in different spatial domains of the Stillwater mine area and between the Stillwater and East Boulder mines. Most of the variation in the grade and tenor can be explained by a variation in the mass of silicate magma with which the sulfide liquid equilibrated (i.e., R factor); however, geochemical and textural evidence suggests that parts of the reef may have experienced significant S loss following initial sulfide melt segregation. Some variability in the reef tenor and grade can be attributed to variable amounts of sulfur loss due to low-temperature hydrothermal fluids and the overestimation or underestimation of metal concentrations in reef assays due to the nugget effect. Furthermore, we address the Pd/Pt ratio of the reef samples and suggest that the lower solubility of Pt in the parental silicate melt may have caused the crystallization and removal of Pt alloys at some point before the melt reached sulfide saturation and Pt could partition into the sulfide liquid. This disparity between the prior evolution of Pt and Pd in the silicate melt resulted in the observed Pd/Pt ratio of ~3.65 across all areas of the reef—a value significantly larger than anticipated for primitive mantle-derived magmas.

Montana↗