40Ar/39Ar age-spectrum data for whole rock samples of the Martinsburg Formation, Lehigh Gap area, Pennsylvania
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Geology topics
Publications and source records attributed to Michael J. Kunk.
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High precision 40 Ar/ 39 Ar laser-microprobe ages of individual sanidines, 40 Ar/ 39 Ar plateau age spectra on bulk sanidine concentrates, U-Pb zircon ages, and zircon and apatite fission-track ages from three bentonites bracketing the Cenomanian-Turonian boundary in the Western Interior of the United States suggest an age for the boundary of 93.1 ± 0.3 (2σ. The lowermost bentonite comes from the Upper Cenomanian Sciponoceras gracile biozone, and gives a weighted mean laser-fusion single-crystal 40 Ar/ 39 Ar age of 93.50 ± 0.52 Ma (2σ, standard error of the mean, n = 14) for sanidine. The middle bentonite comes from the Upper Cenomanian Neocardioceras juddii biozone, accepted in both North America and Europe as the uppermost Cenomanian ammonite zone; it gives an average single-crystal 40 / 39 Ar age of 93.33 ± 0.50 Ma ( n = 29), a bulk-sample 40 Ar/ 39 Ar plateau age of 93.09 ± 0.34 Ma (2σ) for sanidine, and concordant 206 Pb/ 238 U and 207 Pb/ 235 U ages of 93.48 ± 0.32 Ma on zircon. The upper bentonite comes from near the base of the Turonian, immediately above the first occurrence of the basal Turonian bivalve Mytiloides and sanidines from it give an average single-crystal 40 Ar/ 39 Ar age of 93.46 ± 0.60 Ma ( n = 12) and a bulk-sample 40 Ar/ 39 Ar plateau age of 92.87 ± 0.34 Ma. The composition of these Cenomanian-Turonian bentonites from Colorado and Utah, the types of phenocrysts present, and the morphology of included zircons all indicate that the pre-alteration ash was rhyolitic and probably generated in a subduction setting involving a significant crustal component.
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Biotite phenocryst compositions in three thick, widespread Ordovician K-bentonites, the Deicke and Millbrig from Big Ridge, Alabama, and the Kinnekulle from Mossen, Västergötland, Sweden, fall into three distinct groups, and so the proposed intercontinental correlation of the Millbrig and the Kinnekulle is suspect. Because the biotites are nearly pristine compositionally, electron microprobe analyses provide a precise geochemical fingerprint of each bed. Millbrig and Kinnekulle biotites contain more FeO* and MnO and less MgO and TiO 2 than do Deicke biotites. Millbrig biotites contain more MgO and less TiO 2 than Kinnekulle biotites, and Kinnekulle biotites contain appreciably more Al 2 O 3 than either Deicke or Millbrig biotites. Each of these tephras was unmistakably the product of a gigantic explosive volcanic eruption, but the differences in phenocryst chemistry point to derivation from three compositionally different magma batches.
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40 Ar/ 39 Ar plateau age spectra of seven sanidine samples from the Fire Clay tonstein (Middle Pennsylvanian), collected along a 300-km traverse in the Appalachian basin, range from 310.3 to 311.4 Ma. All plateau ages agree, within the limits of analytical precision, with their respective total gas ages. This agreement, together with the reproducibility between samples, suggests the analyzed samples did not contain any significant contaminant feldspar. The mean of these seven plateau ages, 310.9 ± 0.8 Ma, is interpreted to represent a precise numerical estimate of time of eruption and deposition of this tonstein and the coal bed in which it is found. The lack of any discernible difference between the age of two samples of the Fire Clay tonstein collected from east of the Pine Mountain thrust fault, along with the age of five samples from west of this fault, suggests that the Fire Clay tonstein has been reliably correlated with a tonstein on the Cumberland overthrust sheet. This correlation, together with the age data presented in this paper, indicates that the Pine Mountain thrust fault must be younger than the 310.9-Ma age obtained for the Fire Clay tonstein. The Fire Clay tonstein is biostratigraphically correlated with the Trace Creek Shale Member of the Atoka Formation in the Midcontinent of North America and with a position near the Westphalian B-C boundary in Western Europe. Our age of 310.9 ± 0.8 Ma for the Westphalian B-C boundary represents a well-constrained point, useful for the numerical refinement of the geologic time scale.
The Middle Pennsylvanian Fire Clay tonstein, mostly kaolinite and minor accessory minerals, is an altered and lithified volcanic ash preserved as a thin, isochronous layer associated with the Fire Clay coal bed. Seven samples of the tonstein, taken along a 300-km traverse of the central Appalachian basin, contain cogenetic phenocrysts and trapped silicate-melt inclusions of a rhyolitic magma. The phenocrysts include beta-form quartz, apatite, zircon, sanidine, pyroxene, amphibole, monazite, garnet, biotite, and various sulfides. An inherited component of the zircons (determined from U-Pb isotope analyses) provides evidence that the source of the Fire Clay ash was Middle Proterozoic (Grenvillian) continental crust inboard of the active North American margin. 40 Ar/ 39 Ar plateau ages of seven sanidine samples from the tonstein have a mean age of 310.9 ± 0.8 Ma, which suggests that it is the product of a single, large-volume, high-silica, rhyolitic eruption possibly associated with one of the Hercynian granitic plutons in the Piedmont. Biostratigraphic analyses correlate the Fire Clay coal bed with a position just below the top of the Trace Creek Member of the Atoka Formation in the North American Midcontinent and near the Westphalian B-C boundary in western Europe.
Cenozoic strata exposed along the Porcupine River between the Upper Ramparts and Canyon Village, Alaska, can be divided into five unconformity-bounded units (sequences) which are: lower and middle Miocene unit A, the white sandy fluvial sequence with peat beds; middle Miocene unit B, the basalt sequence-part B1 is basalt, and part B2 is organic-rich sedimentary beds; upper Miocene unit C, mudrock-dominated lake sequence; late Miocene or Pliocene to Pleistocene unit D, terrace gravels, detrital organic matter and associated sediments, and Holocene unit E, mixed sand and gravel-rich sediment and other sedimentary material including peat and eolian silt. The sequence (unit A) of lower and middle Miocene fluvial deposits formed in streams and on flood plains, just before the inception of local volanism. Fossil pollen from unit A suggests conifer-dominated regional forests and cool temperate climates. Peat beds and lake deposits from unit B contain pollen that indicates a warmer temperate climate coinciding with the middle Miocene thermal maximum. The lake deposits (unit C) downstream from the basalts accumulated in a small basin which resulted from a hydrologic system that was dammed in the late Miocene but breached soon thereafter. The lower part of the terrace gravels (unit D) expresses breaching of the dammed hydrologic system (of unit C). The Porcupine River became a major tributary of the Yukon River in late Pleistocene time when Laurentide ice blocked drainage from the Yukon interior basins causing meltwater to spill over the low divide separating it from the Porcupine River drainage initiating erosion and capture of the Yukon interior basins. ?? 1994.
40 Ar/ 39 Ar ages of volcanic rocks are used to provide numerical constraints on the age of middle and upper Miocene sedimentary strata collected along the Porcupine River. Intercalated sedimentary rocks north of latitude 67°10′N in the Porcupine terrane of east-central Alaska contain a rich record of plant fossils. The fossils are valuable indicators of this interior region's paleoclimate during the time of their deposition. Integration of the 40 Ar/ 39 Ar 40 Ar 39 Ar "> results with paleomagnetic and sedimentological data allows for refinements in estimating the timing of deposition and duration of selected sedimentary intervals. 40 Ar 39 Ar "> 40Ar39Ar plateau age spectra, from whole rock basalt samples, collected along the Upper Ramparts and near Half-way Pillar on the Porcupine River, range from 15.7 ± 0.1 Ma at site 90-6 to 14.4 ± 0.1 Ma at site 90-2. With exception of the youngest basalt flow at site 90-2, all of the samples are of reversed magnetic polarity, and all 40 Ar/ 39 Ar age spectrum results are consistent with the deposition of the entire stratigraphic section during a single interval of reversed magnetic polarity. The youngest flow at site 90-2 was emplaced during an interval of normal polarity. With age, paleomagnetic and sedimentological data, the ages of the Middle Miocene sedimentary rocks between the basalt flows at sites 90-1 and 90-2 can be assigned to an interval within the limits of analytical precision of 15.2 ± 0.1 Ma; thus, the sediments were deposited during the peak of the Middle Miocene thermal maximum. Sediments in the upper parts of sites 90-1 and 90-2 were probably deposited during cooling from the Middle Miocene thermal maximum. 40 Ar/ 39 Ar results of plagioclase and biotite from a single tephra, collected at sites 90-7 and 90-8 along the Canyon Village section of the Porcupine River, indicate an age of 6.57 ± 0.02 Ma for its time of eruption and deposition. These results, together with sedimentological and paleomagnetic data, suggest that all of the Upper Miocene lacustrine sedimentary rocks at these sites were deposited during a single interval of reversed magnetic polarity and may represent a duration of only about 40,000 years. The age of this tephra corresponds with a late late Miocene warm climatic interval. The results from the Upper Ramparts and Half-way Pillar sites are used to estimate a minimum interval of continental flood basalt activity of 1.1–1.5 million years, and to set limits for the timing and duration of Tertiary extensional tectonic activity in the Porcupine terrane. Our data indicate that the oroclinal flexure that formed before the deposition of the basalts at the eastern end of the Brooks Range was created prior to 15.7 ± 0.1 Ma.
Field studies and 40 Ar/ 39 Ar dating reveal that silicic volcanism in the Davis Mountains part of the Trans-Pecos Texas volcanic field occurred in six episodes at 0.3 m.y. intervals between 36.8 and 35.3 Ma. Additionally, two groups of silicic intrusions were emplaced at 34.6 and 32.8 Ma. This episodicity is similar to that determined for volcanic fields dominated by ash-flow tuffs, yet voluminous, extensive silicic lavas are considerably more abundant than tuffs in the Davis Mountains, by number of flows and by volume. The preponderance of voluminous silicic lavas over tuffs most likely reflects low water contents and high temperatures of the alkalic and commonly peralkaline Davis Mountains magmas. The earliest episode, at 36.8 Ma, included a widespread and voluminous (possibly >1,000 km 3 ) suite of rhyolite and quartz trachyte lavas, several rhyolite domes, and a strongly rheomorphic, peralkaline ash-flow tuff erupted from a caldera in the northern Davis Mountains. The lava suite extends well beyond the Davis Mountains. Silicic lavas of all episodes probably erupted from widespread, fissure vents. The 36.5 Ma episode consisted of rhyolite to quartz trachyte lavas, also extensive and voluminous (∼200 km 3 ). The 36.3 Ma episode consisted of rhyolite to trachyte tuffs and lavas erupted from a central vent volcano in the southern Davis Mountains. The 35.9 Ma episode consisted of a single, moderately large (∼50 km 3 ) rhyolite lava and a small-volume ash-flow tuff erupted from a caldera in the western Davis Mountains. Rocks emplaced during the 35.6 Ma episode were also rhyolites, including an enigmatic rock that may be strongly rheomorphic ash-flow tuff or a combination of tuff and lava, followed by definite lavas. The 35.3 Ma episode consisted of two ash-flow tuffs, one of which is strongly rheomorphic, and additional voluminous rhyolite lavas (∼120 km 3 ). The rheomorphic tuff erupted from a caldera in the southwestern Davis Mountains. The source of the other tuff is probably in the western Davis Mountains. Intermediate and mafic rocks are minor, except around the southeastern flank of the Davis Mountains, where basalt is abundant. Mafic lavas erupted only during gaps in the silicic activity and on the flanks of the Davis Mountains. Nevertheless, basaltic magma probably drove the silicic magmatism, either by differentiation or by crustal melting, and was present throughout the time of Davis Mountains activity but could not penetrate the low-density silicic magma chambers until they cooled and solidified. The time required for cooling and solidification appears to be 0.1-0.2 m.y.
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The 40 Ar/ 39 Ar ages of a sanidine clast from a melt-matrix breccia of the Manson, Iowa, impact structure (MIS) indicate that the MIS formed 73.8 ± 0.3 million years ago (Ma) and is not coincident with the Cretaceous-Tertiary boundary (64.43 ± 0.05 Ma). The MIS sanidine is 9 million years older than 40 Ar/ 39 Ar age spectra of MIS shock-metamorphosed microcline and melt-matrix breccia interpreted earlier to be 64 to 65 Ma. Grains of shock-metamorphosed quartz, feldspar, and zircon were found in the Crow Creek Member (upper Campanian) at a biostratigraphic level constrained by radiometric ages in the Pierre Shale of South Dakota that are consistent with the 40 Ar/ 39 Ar age of 73.8 ± 0.3 Ma for MIS reported herein.
40 Ar/ 39 Ar age spectra of hornblende, muscovite, and microcline, and total fusion ages of biotite from metamorphic rocks of the Inner Piedmont, Pine Mountain, and Uchee belts are reported. Mineral cooling ages from the eastern part of the Inner Piedmont are as follows: hornblende, 320 Ma; muscovite, 296 Ma; biotite, 293 Ma; and microcline (diffusional release patterns) Tmax = 267 Ma, Tmin = 234 Ma. A 347 Ma hornblende spectrum from the highest Inner Piedmont structural level sampled is the oldest date determined and implies earlier passage of this level through the 500 °C isotherm. Most release spectra from Pine Mountain belt units are discordant with little or no apparent geologic meaning. Modified saddle-shaped release patterns for hornblende indicate extraneous argon with a maximum age of ∼358 Ma. Muscovite from the Pine Mountain belt cover sequence is 286 Ma (plateau age), and one from the underlying Grenville basement is 277 Ma (correlation age), indicating cooling below the 350 °C isotherm. Plateau ages on Uchee belt rocks are as follows: hornblende, from 297 to 288 Ma; muscovite, 285 Ma; biotite, 276 Ma; and microcline Tmax = 261 Ma, Tmin 230 Ma. Muscovite fish from a Bartletts Ferry fault zone phyllonite have a plateau age of 283 Ma. The 40 Ar/ 39 Ar results combined with other geologic data indicate that (1) a large part of the southern and Inner Piedmonts of Alabama and southwest Georgia experienced a late Paleozoic amphibolite-facies thermal and deformational event contemporaneous with the Alleghanian orogeny observed in the foreland; (2) the tectonic development of this event, characterized by initial crustal thickening followed by right-slip and normal-slip movements, is grossly similar to that described for the amphibolite-facies Alleghanian belt in the eastern Piedmont of South Carolina and Georgia; and (3) extensional movements along the flanks of the Pine Mountain window occurred between ca. 277 Ma and the Late Triassic-Early Jurassic and thus may reflect latest Alleghanian extensional collapse or Mesozoic rifting.
Pb concentrations and isotopic compositions have been determined for authigenic over-growths and detrital cores of K-feldspar from Cambrian sedimentary rocks in Texas, Tennessee, and Pennsylvania (referred to as group 1) and southeastern Missouri (referred to as group 2). Overgrowths and cores were separated by abrasion and analyzed separately. In three group 1 samples, cores have Pb isotopic ratios similar to initial ratios in K-feldspar from nearby Middle Proterozoic basement rocks ( 206 Pb/ 204 Pb =16.7-17.0). Pb ratios in overgrowths are radiogenic ( 206 Pb/ 204 Pb up to 19.3) and mostly are distinct from those in ore deposits in the southern Appalachians. Pb isotopic data for two samples of K-feldspar from southeastern Missouri are scattered; in one sample, cores and overgrowths contain radiogenic Pb, suggesting at least two periods of authigenic replacement, in agreement with petrographic evidence. Proterozoic material must still be present because 40 Ar/ 39 Ar stepwise analysis of a total (cores plus overgrowths) sample yields incremental ages ranging from about 500 to 750 Ma. The disparity in Pb isotopic ratios of group 1 overgrowths and Pb in nearby Mississippi Valley-type deposits implies that the regional authigenic K-feldspar event was not synchronous with ore deposition in the southeastern United States. In contrast, Pb isotopic ratios from group 2 authigenic K-feldspar are similar to ratios in ores of southeastern Missouri, suggesting a genetic relation in late Paleozoic time.
A Variscan,deep-crustal-level (eclogite-facies),continental basement massif in western Poland, the Snieznik complex, was tectonically exhumed. Crustal-penetrating mylonite zones record three main kinematic events: early top-to-the-north-directed thrusting, right-slip transpression-tension, and late top-to-the-south and -east normal faulting. Thrusting resulted in extreme crustal thickening and associated eclogite-facies metamorphism. Right-slip movements produced retrogressive crystal-plastic simple-shear zones. Normal faults flank Carboniferous to Early Permian terrigenous sedimentary basins, documenting tectonic and erosional denudation of the Snieznik complex during lithospheric extension. Sm/Nd isotopic dates previously reported for the in situ eclogite-facies metamorphic mineral assemblages are 341, 337, and 329 Ma (Brueckner et al., 1991). 40 Ar/ 39 Ar isotopic dates for metamorphic hornblende (338, 333, and 332 Ma), muscovite (329 and 329 Ma), and biotite (328 Ma) reflect times of cooling through the ∼500, 350, and 300 °C isotherms, respectively. These nearly concordant mineral dates document rapid cooling from ∼850 °C (eclogue-facies temperatures) to ∼300 °C. Rapid denudation of these deep-crustal rocks (∼19-22 kbar pressures, >70 km depth) is attributed to processes, similar to those of metamorphic-core complexes, that operated during lithospheric delamination and gravitational collapse. The sequence of late Paleozoic (Alleghanian) crustal thickening followed by right-slip transpression-tension followed by normal faulting recognized in the U.S. Appalachians implies that this tectonic pattern may exist throughout the Afleghanian-Variscan belt.