Search USGS⌕ Search

Geology topics

Maryse Delevaux

Publications and source records attributed to Maryse Delevaux.

3 recordsLinked to original sources

Variations in lead-isotopic compositions in Mesozoic granitic rocks of California: A preliminary investigation

Six alkali feldspar and two whole-rock samples of granitic rocks from the Sierra Nevada batholith and adjacent Klamath Mountains were analyzed for their lead-isotope compositions. The samples represented each of three 87 Sr/ 86 Sr groupings (< 0.704, 0.704 to 0.706, and > 0.706) for granitic rocks north of the Garlock fault in California. The isotopic compositions of lead in the samples from the Sierra Nevada batholith range from 18.73 to 19.37 for 206 Pb/ 204 Pb, 15.61 to 15.71 for 207 Pb/ 204 Pb, and 38.44 to 39.10 for 208 Pb/ 204 Pb. A crude parallel correspondence was found between lead and strontium isotopes, in that the specimens with the most radiogenic strontium also tend to have the most radiogenic lead similar to the previously studied Boulder batholith of Montana. A parallel correspondence is thought to imply characteristics of the source rocks for the plutons rather than consequences of partial melting or natural contamination. Lead-isotopic compositions for the Sierra Nevada batholith and the Boulder batholith differ, average values of 206 Pb/ 204 Pb being at least 18.8 for the Sierra Nevada batholith and about 18 for the Boulder batholith. In the Late Cretaceous part of the Sierra Nevada batholith, the secondary isochron “age” for the lead data in these rocks is about 2,900 m.y., far older than known Precambrian in California. Sources are proposed for these plutons from the lower continental crust and upper continental mantle or dominantly recycled continental materials, probably of intermediate composition and possibly carried down to the zone of melting by subduction. This source material may have been formed in Pre-cambrian times but did not undergo a Precambrian metamorphism greater than upper amphibolite facies which would have reduced the values of 238 U/ 204 Pb in the source rocks and resulted in Mesozoic leads like those found in the Boulder batholith and elsewhere in the Rocky Mountain region. A trondhjemite from the Klamath Mountains has a lead-isotope composition ( 206 Pb/ 204 Pb, 18.57; 207 Pb/ 204 Pb, 15.50; 208 Pb/ 204 Pb, 38.08) similar to that of oceanic volcanic rocks, particularly like those of island volcanics on oceanic ridges. Derivation of this trondhjemite from an oceanic mantle or recycled mantle material is indicated by this observation and supports the conclusion of Kistler and Peterman (1973) based on its alkali abundances and 87 Sr/ 86 Sr value.

California↗

Occurrence of selenium in sulfides from some sedimentary rocks of the western United States

Investigations of the minor- and trace-element content of sulfides associated with uranium ore deposits from sandstone-type deposits have shown that selenium commonly substitutes for sulfur. The Morrison formation and Entrada sandstone of Jurassic age and the Wind River formation of Eocene age seem to be seleniferous stratigraphic zones; sulfides deposited within these formations generally contain abnormal amounts of selenium. The selenium content of the pyrite, marcasite, and chalcocite is much greater than that reported in previously published data. Under the prevailing temperatures and pressures of formation of the Colorado Plateau uranium deposits the maximum amount of Se substituting for S in the pyrite structure was found to be 3 percent by weight. Ferroselite, the iron selenide (FeSe 2 ), was found in two deposits on the Colorado Plateau and it was also established that galena (PbS) forms an isomorphous series with clausthalite (PbSe) in nature. During oxidation of the selenium-bearing sulfides and selenides in the Colorado Plateau and Wyoming, the selenium forms pinkish crusts of either monoclinic or hexagonal native selenium intergrown with soluble sulfates, suggesting that under "normal" oxidizing conditions native selenium is more stable than selenites or selenates. The above-normal selenium content of these sulfides from sedimentary rocks of Mesozoic and Tertiary age is significant. The high selenium in these sulfides is related to periods of volcanic and intrusive activity penecontemporaneous with the formation of the containing sediments.

Arizona;Colorado;New Mexico;Utah;Wyoming↗