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Mark M. Dornblaser

Publications and source records attributed to Mark M. Dornblaser.

24 records · Page 2Linked to original sources

Carbon dioxide and methane emissions from the Yukon River system

Carbon dioxide (CO 2 ) and methane (CH 4 ) emissions are important, but poorly quantified, components of riverine carbon (C) budgets. This is largely because the data needed for gas flux calculations are sparse and are spatially and temporally variable. Additionally, the importance of C gas emissions relative to lateral C exports is not well known because gaseous and aqueous fluxes are not commonly measured on the same rivers. We couple measurements of aqueous CO 2 and CH 4 partial pressures ( p CO 2 , p CH 4 ) and flux across the water-air interface with gas transfer models to calculate subbasin distributions of gas flux density. We then combine those flux densities with remote and direct observations of stream and river water surface area and ice duration, to calculate C gas emissions from flowing waters throughout the Yukon River basin. CO 2 emissions were 7.68 Tg C yr −1 (95% CI: 5.84 −10.46), averaging 750 g C m −2 yr −1 normalized to water surface area, and 9.0 g C m −2 yr −1 normalized to river basin area. River CH 4 emissions totaled 55 Gg C yr −1 or 0.7% of the total mass of C emitted as CO 2 plus CH 4 and ∼6.4% of their combined radiative forcing. When combined with lateral inorganic plus organic C exports to below head of tide, C gas emissions comprised 50% of total C exported by the Yukon River and its tributaries. River CO 2 and CH 4 derive from multiple sources, including groundwater, surface water runoff, carbonate equilibrium reactions, and benthic and water column microbial processing of organic C. The exact role of each of these processes is not yet quantified in the overall river C budget.

Yukon River Basin

Biodegradability of dissolved organic carbon in the Yukon River and its tributaries: Seasonality and importance of inorganic nitrogen

Northern high-latitude rivers transport large amounts of terrestrially derived dissolved organic matter (DOM) from boreal and arctic ecosystems to coastal areas and oceans. Current knowledge of the biodegradability of DOM in these rivers is limited, particularly for large rivers discharging to the Arctic Ocean. We conducted a seasonally comprehensive study of biodegradable dissolved organic carbon (BDOC) dynamics in the Yukon River and two of its tributaries in Alaska, USA. Distinct seasonal patterns of BDOC, consistent across a wide range of watershed size, indicate BDOC is transported year-round. Relative biodegradability (%BDOC) was greatest during winter, and decreased into spring and summer. Due to large seasonal differences in DOC concentration, the greatest concentrations of BDOC (mg C L −1 ) occurred during spring freshet, followed by winter and summer. While chemical composition of DOM was an important driver of BDOC, the overriding control of BDOC was mineral nutrient availability due to wide shifts in carbon (C) and nitrogen (N) stoichiometry across seasons. We calculated seasonal and annual loads of BDOC exported by the Yukon River by applying measured BDOC concentrations to daily water discharge values, and also by applying an empirical correlation between %BDOC and the ratio of DOC to dissolved inorganic N (DIN) to total DOC loads. The Yukon River exports ∼0.2 Tg C yr −1 as BDOC that is decomposable within 28 days. This corresponds to 12–18% of the total annual DOC export. Furthermore, we calculate that the six largest arctic rivers, including the Yukon River, collectively export ∼2.3 Tg C yr −1 as BDOC to the Arctic Ocean.

Global Biogeochemical Cycles

Suspended sediment and carbonate transport in the Yukon River Basin, Alaska: Fluxes and potential future responses to climate change

Loads and yields of suspended sediment and carbonate were measured and modeled at three locations on the Yukon, Tanana, and Porcupine Rivers in Alaska during water years 2001–2005 (1 October 2000 to 30 September 2005). Annual export of suspended sediment and carbonate upstream from the Yukon Delta averaged 68 Mt a −1 and 387 Gg a −1 , respectively, with 50% of the suspended sediment load originating in the Tanana River Basin and 88% of the carbonate load originating in the White River Basin. About half the annual suspended sediment export occurred during spring, and half occurred during summer‐autumn, with very little export in winter. On average, a minimum of 11 Mt a −1 of suspended sediment is deposited in floodplains between Eagle, Alaska, and Pilot Station, Alaska, on an annual basis, mostly in the Yukon Flats. There is about a 27% loss in the carbonate load between Eagle and Yukon River near Stevens Village, with an additional loss of about 29% between Stevens Village and Pilot Station, owing to a combination of deposition and dissolution. Comparison of current and historical suspended sediment loads for Tanana River suggests a possible link between suspended sediment yield and the Pacific decadal oscillation.

Water Resources Research

Carbon export and cycling by the Yukon, Tanana, and Porcupine rivers, Alaska, 2001-2005

Loads and yields of dissolved and particulate organic and inorganic carbon (DOC, POC, DIC, PIC) were measured and modeled at three locations on the Yukon River (YR) and on the Tanana and Porcupine rivers (TR, PR) in Alaska during 2001–2005. Total YR carbon export averaged 7.8 Tg C yr −1 , 30% as OC and 70% as IC. Total C yields (0.39–1.03 mol C m −2 yr −1 ) were proportional to water yields (139–356 mm yr −1 ; r 2 = 0.84) at all locations. Summer DOC had an aged component (fraction modern (FM) = 0.94–0.97), except in the permafrost wetland‐dominated PR, where DOC was modern. POC had FM = 0.63–0.70. DOC had high concentration, high aromaticity, and high hydrophobic content in spring and low concentration, low aromaticity, and high hydrophilic content in winter. About half of annual DOC export occurred during spring. DIC concentration and isotopic composition were strongly affected by dissolution of suspended carbonates in glacial meltwater during summer.

Water Resources Research

Water and sediment quality in the Yukon River and its tributaries between Atlin, British Columbia, Canada, and Eagle, Alaska, USA, 2004

The Yukon River basin is the fourth largest watershed in North America at 855,300 square kilometers (km 2 ). Approximately 126,000 people live within the basin and depend on the Yukon River and its tributaries for drinking water, commerce, subsistence and recreational fish and game resources. Climate warming in the Arctic and Sub arctic regions encompassing the Yukon basin has recently become a concern because of possible far-reaching effects on the ecosystem. Large amounts of carbon and nutrients are stored in permafrost and have potential for release in response to this warming. These changes in carbon and nutrient cycling may result in changes in stream chemistry and productivity, including salmon populations, and ultimately changes in the chemistry and productivity of the Bearing Sea. To address these concerns, the U.S. Geological Survey (USGS) conducted a 5-year comprehensive water-quality study of the Yukon River and its major tributaries starting in 2000. The study included frequent water-quality sampling at a fixed site network as well as intensive sampling along the Yukon River and its major tributaries. This report contains observations of water and sediment quantity and quality of the Yukon River and its tributaries in Canada during 2004. Chemical, biological, physical, and discharge data are presented for the reach of river between Atlin, British Columbia, Canada, and Eagle, Alaska, USA.

Alaska, British Columbia, Yukon

Mercury loading and methylmercury production and cycling in high-altitude lakes from the Western United States

Studies worldwide have shown that mercury (Hg) is a ubiquitous contaminant, reaching even the most remote environments such as high-altitude lakes via atmospheric pathways. However, very few studies have been conducted to assess Hg contamination levels of these systems. We sampled 90 mid-latitude, high-altitude lakes from seven national parks in the western United States during a four-week period in September 1999. In addition to the synoptic survey, routine monitoring and experimental studies were conducted at one of the lakes (Mills Lake) to quantify MeHg fluxrates and important process rates such as photo-demethylation. Results show that overall, high-altitude lakes have low total mercury (HgT) and methylmercury (MeHg) levels (1.07 and 0.05 ng L -1 , respectively), but a very good correlation of Hg to MeHg (r 2 = 0.82) suggests inorganic Hg(II) loading is a primary controlling factor of MeHg levels in dilute mountain lakes. Positive correlations were also observed for dissolved organic carbon (DOC) and both Hg and MeHg, although to a much lesser degree. Levels of MeHg were similar among the seven national parks, with the exception of Glacier National Park where lowerconcentrations were observed (0.02 ng L -1 ), and appear to be related to naturally elevated pH values there. Measured rates ofMeHg photo-degradation at Mills Lake were quite fast, and this process was of equal importance to sedimentation and stream flow for removing MeHg. Enhanced rates of photo-demethylation are likely an important reason why high-altitude lakes, with typically high water clarity and sunlight exposure, are low in MeHg.

California, Colorado, Montana, Wyoming