Geology topics
Publications and source records attributed to Mark J. Pawlewicz.
Using a geology-based assessment methodology, the U.S. Geological Survey estimated a mean of 8.5 trillion cubic feet of undiscovered natural gas, a mean of 5.9 million barrels of undiscovered oil, and a mean of 7.6 million barrels of undiscovered natural gas liquids in the Black Warrior Basin Province.
The Greater Green River Basin is a large Laramide (Late Cretaceous through Eocene) structural and sedimentary basin that encompasses about 25,000 square miles in southwestern Wyoming, northwestern Colorado, and northeastern Utah (fig. 1). Important conventional oil and gas resources have been discovered and produced from reservoirs ranging in age from Cambrian through Tertiary (Law, 1996). In addition, an extensive overpressured basin - centered gas accumulation has also been identified in Cretaceous and Tertiary reservoirs by numerous researchers including Law (1984a, 1996), Law and others (1980, 1989), McPeek (1981), and Spencer (1987). The purpose of this report is to present new vitrinite reflectance data to be used in support of the U.S Geological Survey assessment of undiscovered oil and gas resources of the Greater Green River Basin. One hundred eighty-six samples were collected from Cretaceous and Tertiary coalbearing strata (figs. 1 and 2) in an effort to better understand and characterize the thermal maturation and burial history of potential source rocks. Two samples were from core, one from outcrop, and the remainder from well cuttings. These data were collected to supplement previously published data by Law (1984b), Pawlewicz and others (1986), Merewether and others (1987), and Garcia-Gonzalez and Surdam (1995) and are presented in table 1.
The results of ROCK-EVAL and vitrinite reflectance analyses of a large sample base from more than 70 wells located in three oil-rich California petroleum basins are reported. The cores from these wells have a wide range of present-day burial temperatures (40 ? to 220 ? C). The rocks in these basins were deposited under highly variable conditions, sometimes resulting in substantially different organic matter (OM) types in rocks tens of meters vertically apart from each other in one well. The kinetic response of these different OM types to equivalent wellknown burial histories is a pivotal point of this study. In the Los Angeles and Ventura Basins, rock organic-richness significantly increased with depth, as did kerogen hydrogen content, and the percentage of fine-grained versus coarsegrained rocks. The shales in these basins are perceived as containing primarily hydrogen-rich amorphous OM. In actuality, the shallowest 2,000 to 3,000 m of rocks in the basins, and at least the upper 6,000 m of rocks in parts of the Los Angeles Basin central syncline, are dominated by type III/IV OM. In the Los Angeles Basin, mainstage hydrocarbon (HC) generation commences in the type III/IV OM at present-day burial temperatures of 85 ? to 110 ? C, most likely around 100 ? C, and is largely complete by 220 ? C. In the Southern San Joaquin Valley Basin, mainstage HC generation commences in type III/IV OM at 150 ? C and is also largely complete by 220 ? C. In the Ventura Basin, mainstage HC generation commences above 140 ? C in type III/IV OM. The apparent lower temperatures for commencement of HC generation in the Los Angeles Basin are attributed to the fact that parts of the basin were cooled from maximal burial temperatures by increased meteoric water flows during the last glaciations. All aspects of organic metamorphism, including mainstage HC generation, are strongly suppressed in rocks with hydrogenrich OM in these basins. For example, ROCK-EVAL data suggest that mainstage HC generation has not commenced in rocks with hydrogen-rich OM at present-day temperatures of 198?C. This observation is attributed to much stronger bonds in hydrogen- rich OM compared to types III and IV OM and, therefore, significantly higher burial temperatures are required to break these bonds. This difference in OM kinetics has profound ramifications for petroleum-geochemical exploration models. Organic-matter characteristics inherited from original depositional conditions were overlaid on, and at times confused interpretation of, characteristics from organic metamorphism in all study areas. In all the basins examined in this study, immature fine-grained rocks occasionally had high to very high carbon-normalized concentrations of pre-generation indigenous bitumen. This unusual characteristic may be due to unique depositional conditions in these basins.
No abstract available.
In coal samples, published recommendations based on statistical methods suggest 100 measurements are needed to estimate the mean random vitrinite reflectance ( R v−r ) to within ±2%. Our survey of published thermal maturation studies indicates that those using dispersed organic matter (DOM) mostly have an objective of acquiring 50 reflectance measurements. This smaller objective size in DOM versus that for coal samples poses a statistical contradiction because the standard deviations of DOM reflectance distributions are typically larger indicating a greater sample size is needed to accurately estimate R v−r in DOM. However, in studies of thermal maturation using DOM, even 50 measurements can be an unrealistic requirement given the small amount of vitrinite often found in such samples. Furthermore, there is generally a reduced need for assuring precision like that needed for coal applications. Therefore, a key question in thermal maturation studies using DOM is how many measurements of R v−r are needed to adequately estimate the mean. Our empirical approach to this problem is to compute the reflectance distribution statistics: mean, standard deviation, skewness, and kurtosis in increments of 10 measurements. This study compares these intermediate computations of R v−r statistics with a final one computed using all measurements for that sample. Vitrinite reflectance was measured on mudstone and sandstone samples taken from borehole M-25 in the Cerro Prieto, Mexico geothermal system which was selected because the rocks have a wide range of thermal maturation and a comparable humic DOM with depth. The results of this study suggest that after only 20–30 measurements the mean R v−r is generally known to within 5% and always to within 12% of the mean R v−r calculated using all of the measured particles. Thus, even in the worst case, the precision after measuring only 20–30 particles is in good agreement with the general precision of one decimal place recommended for mean R v−r measurements on DOM. The coefficient of variation ( V = standard deviation/mean) is proposed as a statistic to indicate the reliability of the mean R v−r estimates made at n ⪡ 20. This preliminary study suggests a V < 0.1 indicates a reliable mean and a V > 0.2 suggests an unreliable mean in such small samples.