Geology topics

Mark D. Kozar

Publications and source records attributed to Mark D. Kozar.

At least 19 recordsLinked to original sources

USGS2025

Reconnaissance of potential alternate water supply sources for the City of Gary, West Virginia

Seven potential sources of water, consisting of free-flowing discharge from abandoned coal mines at six locations and one abandoned flooded underground coal mine air shaft, were sampled for chemical analysis to assess the quality of the groundwater emanating from the seven mine sources. The six free-flowing mine discharge sources were also assessed for discharge by current-meter measurements on two separate occasions. The U.S. Geological Survey assessed these seven sources to provide information to the City of Gary, West Virginia (W. Va.), and the City of Gary’s consulting engineer with groundwater-quality and flow data to allow them to assess the seven sites as potential alternate sources of water for the City of Gary to augment its existing supply. For the six sites where discharge could be measured, discharge ranged from a minimum of 0.082 cubic feet per second (ft 3 /s) to a maximum of 3.685 ft 3 /s. Of the six sites measured, only two, Harmon Branch at Thorpe, W. Va. (USGS site 372201081303501) and the abandoned public-supply water wells near Havaco, W. Va. (USGS site 372358081344601), had discharge in excess of 1.00 ft 3 /s. Discharge from the abandoned public supply wells was 3.685 ft 3 /s on September 20, 2023, and 2.888 ft 3 /s on October 16, 2023, and discharge from Harmon Branch at Thorpe, W. Va., was 1.049 ft 3 /s on September 22, 2023, and 1.038 ft 3 /s on October 17, 2023. Discharge in the abandoned underground mine air shaft (USGS site 372224081340901) could not be assessed, but the air shaft drains an abandoned mine that likely contains water stored in approximately 1.7 square miles (mi 2 ) of abandoned underground coal mines in the Pocahontas No. 3 coal seam, and possibly an additional 0.9 mi 2 of leakage from the overlying Pocahontas No. 4 coal seam. Discharge for the six sites measured for the study was measured during a period between September 20 and October 18, 2023, and corresponded to the 12th to the 15th percentile of flow-duration statistics for the Tug Fork downstream of Elkhorn Creek at Welch, W. Va. streamgage (USGS site 03212750). Water-quality data for the seven sites sampled overall were acceptable with respect to drinking water standards. Of the 203 constituents analyzed, only a few failed to meet applicable U.S. Environmental Protection Agency (EPA) drinking water standards. Iron exceeded the 300 micrograms per liter (μg/L) secondary maximum contaminant level (SMCL) at only 1 of the 7 sites (14.3 percent) sampled. Iron concentrations ranged from a minimum of less than (<) 5.00 μg/L to a maximum of 724 μg/L with a median concentration of 7.62 μg/L. Manganese exceeded the 50.0 μg/L SMCL at 2 of the 7 sites (28.6 percent) sampled. Manganese concentrations ranged from a minimum of 1.93 μg/L to a maximum of 271 μg/L with a median concentration of 4.03 μg/L. No sites sampled exceeded the arsenic maximum contaminant level (MCL) of 10 μg/L. Arsenic concentrations ranged from a minimum of <0.100 μg/L to a maximum of 2.35 μg/L with a median arsenic concentration of 0.200 μg/L. None of the seven sites sampled for selenium for this study exceeded the EPA MCL of 50.0 μg/L. Selenium concentrations ranged from a minimum of <0.050 μg/L to a maximum of 5.26 μg/L with a median concentration of 3.21 μg/L. All seven sites were sampled for volatile organic compounds (VOCs), semivolatile organic compounds (SVOCs), and polychlorinated biphenyls (PCBs), but most had concentrations below the detection limit. Of the 10 PCB compounds analyzed for the seven sites sampled, none contained detectable concentrations of PCBs or Aroclor compounds. Of the 44 SVOCs analyzed at each of the seven sites sampled, only 1 SVOC, acenaphthene, was detected, at a concentration of 0.02 μg/L. Of the 96 VOCs analyzed, from each of the seven sites sampled, only two were found at detectable concentrations. Trichloromethane was detected only at 1 of the 7 (14.3 percent) sites sampled at a concentration of 0.027 μg/L, and benzene was detected at the same site and 3 additional sites (4 of the 7 sites or 57.1 percent of the sites sampled) at concentrations of 0.028, 0.029, 0.021, and 0.035 μg/L, but none exceeded the EPA MCL for benzene of 5.00 μg/L. Total coliform bacteria are ubiquitous in the environment, and their presence only suggests the potential for contamination by near-surface processes. Escherichia coli ( E. coli ) bacteria are derived from either human or animal fecal material and can be an indicator of potential contamination by pathogenic bacteria or viruses. Total coliform bacteria were detected at all 7 sites sampled at concentrations ranging from 17.5 to greater than (>) 2,420 most probable number per 100 mL (MPN/100 mL) of sample, with a median total coliform concentration of 1,553 MPN/100 mL. Escherichia coli bacteria were detected at 4 of the 7 sites sampled at concentrations ranging from <1 to 11.9 MPN/100 mL, with a median E. coli concentration of 5.1 MPN/100 mL.

West Virginia↗

USGS2025

Factors affecting the distribution of water-bearing fractures in the bedrock aquifers of West Virginia

Bedrock aquifers cover 23,601 square miles within the State of West Virginia and comprise 97.4 percent of the surficial area within the State; the remaining 2.6 percent (621 square miles) consists of alluvial sand-and-gravel and glacial outwash aquifers bordering the State’s major rivers. While West Virginia’s alluvial aquifers have been studied extensively, bedrock aquifers have only been characterized for studies completed in a few areas in Jefferson, McDowell, and Monroe Counties. Bedrock aquifers are water supplies for public supply, agriculture, industry, and residential homeowner use. In this study, the U.S. Geological Survey, in cooperation with the West Virginia Department of Environmental Protection Division of Water and Waste Management, provides a statewide assessment of the occurrence and distribution of fractures within bedrock aquifers of the State and the various topographic, physiographic, and lithologic influences controlling the occurrence and distribution of bedrock fractures. The results of this study provide an increased understanding of the distribution of fractures in bedrock aquifers in West Virginia and help to verify trends that have been suspected for many years but were never well documented or verified by data. The results confirmed that the density of fractures and those that were determined to be water bearing decrease significantly with depth. A statistically significant difference in the density of fractures was observed at a depth of 215 feet for wells in the Appalachian Plateaus Physiographic Province’s and in the Valley and Ridge Physiographic Province’s aquifers; a higher density of fractures and water-bearing fractures were above a depth of 215 feet than below that depth. This is an important consideration when drilling wells for residential, commercial, industrial, or agricultural water supply. Abandoned underground coal mines are commonly believed to form large pools of water in the interconnected mine entries in abandoned room and pillar coal mines. Such pools of water can and do exist in abandoned underground coal mines, but many mines lack open entries and are held up by overburden strata and pillars that can collapse and form aquifers comprised of vast interconnected rubble zones (gob), especially in older mines. Data assessed for this study showed that shale-corrected values of effective porosity for limestone aquifers in West Virginia had a median value of 2 percent and an average value of 4 percent and generally are mineralized with low effective porosity. Argillaceous or sandy limestone has a median shale-corrected porosity of 4 percent and an average shale-corrected porosity of 5 percent. The median and average shale-corrected porosity of sandstone aquifers was estimated to be 14 percent, but the median shale-corrected porosity for argillaceous or calcareous sandstone was 5 percent and the average shale-corrected porosity for argillaceous or calcareous sandstone was 6 percent. Even though shale has a relatively high total sonic porosity compared to other lithologies, shale and siltstone had relatively low shale-corrected porosity, ranging from 0 to 2 percent. Well yields were previously documented to be highest in valley settings, lowest on hilltops, and intermediate on hillsides. Transmissivity data provided by this study confirm this general pattern within the Appalachian Plateaus Province; however, the Valley and Ridge Province does not follow this pattern. While still lowest on hilltop settings, the highest well yields were in hillside settings. The trend for the Valley and Ridge Province was likely skewed because of 9 high-yield wells specifically targeting deeper thin limestone units, such as the Tonoloway and Helderberg Limestones, at depths with transmissivity in excess of 2,000 feet squared per day in Mineral County, West Virginia, or targeting karst aquifers in Berkeley, Jefferson, or Greenbrier Counties, West Virginia. Finally, water-bearing fractures have been hypothesized to comprise a small number of all fractures within a typical bedrock well in West Virginia. Data collected for this study support this theory. A total of 3,403 fractures were identified during this study; 3,151 (92.6 percent) of those fractures are low-transmissive, and only 252 (7.4 percent) fractures are water-bearing. Even though a well may contain many fractures, less than 8 percent are considered water-bearing fractures.

West Virginia↗

USGS2023

Hydrogeology, karst, and groundwater availability of Monroe County, West Virginia

Monroe County is in southeastern West Virginia, encompassing an area of 474 square miles. The area consists of karst and siliciclastic aquifers of Ordovician, Silurian, Devonian, and Mississippian age and is in parts of two physiographic provinces: the Valley and Ridge Province to the east of Peters Mountain, and the Appalachian Plateau Province to the west of Peters Mountain. This study was developed in response to inquiries from the Monroe County Commission requesting assessment of the water resources of the county to better understand the quantity of the county’s groundwater resources, for both current [2023] and future demand, and to provide information to support protection and management of the county’s valuable groundwater resources. Various products were developed for this study that provide knowledge with respect to water availability and contamination susceptibility of the karst aquifers within the county. U.S. Geological Survey (USGS) geologists conducted extensive geologic mapping in support of the project, producing (1) a countywide bedrock geologic map, (2) a countywide hydrogeologic map, and (3) a light detection and ranging (lidar)-derived countywide digital elevation model and associated sinkhole map. A significant part of this work was to map in detail the Greenbrier Group at the formation level, which prior to this study had only partially been completed. The report also includes (4) a description of the lithologic units identified as part of the geologic mapping process. U.S. Geological Survey hydrologists completed several additional products for the hydrology part of the effort, including development of (1) a countywide potentiometric surface (water-table) map, (2) a countywide base-flow stream assessment, (3) countywide water-budget estimates, (4) well log surveys for 15 wells to better understand subsurface controls on groundwater flow within the study area, (5) two groundwater tracer tests to better refine the groundwater divide from the northern and southern parts of the karst aquifer in Monroe County; and finally, based on all available data collected for the study including the potentiometric surface map, geologic map, current [2023] and legacy fluorometric groundwater tracer tests, and base-flow stream assessments, (6) groundwater-basin delineations were reassessed for principal groundwater basins within the Greenbrier aquifer. In Monroe County, four principal hydrogeologic settings produce large yields of water for residential, agricultural, and other uses. The most relied upon water-bearing zone with respect to current [2023] public water supply is from springs along Peters Mountain. These springs are derived from intervals of fractured sandstone and resultant alluvial deposits. Groundwater flows downslope through these permeable alluvial deposits and discharges at the contact with less permeable strata, such as the Reedsville Shale. The second most relied upon water-bearing zone in Monroe County is within the karstic Greenbrier Group aquifer, in which the basal Hillsdale Limestone overlies the less permeable Maccrady Shale. This geologic contact between the Hillsdale Limestone and Maccrady Shale is not only targeted as a source of water for agricultural supply but also is targeted as a source of water for residential supply. The third most relied upon water-bearing zone is composed of shallow perched aquifers within the Greenbrier Group. The discontinuous nature of these perched aquifers makes mapping their extent impossible, but they are related to permeable geologic strata, such as karstified limestones with solutionally enhanced permeability that overlies less permeable shale or chert bedrock. During geologic mapping of the county, several of these perched aquifers were documented in the Pickaway, Union, and Alderson Limestones. A fourth zone consists of springs from Ordovician carbonates at the base of Peters Mountain, which are influenced by sinking streams as well as upwelling along faults. In terms of water quantity, the most sustainable springs are those having deeper-sourced flows. Public supplies are a principal source of water used for residential and commercial supply in the region, accounting for 0.49 million gallons per day (Mgal/d) of fresh-water withdrawals (0.14 Mgal/d of groundwater and 0.35 Mgal/d of surface water) for residential and commercial use and serving 6,645 individuals (49.2 percent of the population). An estimated 6,861 people, (50.8 percent of the population) primarily rely on private wells or other unregulated sources, such as springs, and withdraw 0.55 Mgal/d of groundwater for their residential use. Public water supply in the region is primarily (71.4 percent) derived from springs and augmented by stream withdrawals (backup sources mainly during low-flow periods), with the remaining portion (28.6 percent) derived from groundwater withdrawals from wells. For rural residents, however, 100 percent of their withdrawals are derived from groundwater (wells or springs).

West Virginia↗

USGS2023

Groundwater quality in abandoned underground coal mine aquifers across West Virginia

Abandoned underground coal mine aquifers cover a large part of West Virginia and could supply substantial quantities of water for agricultural, industrial, residential, and public use. Several Federal, State, and academic institutions have studied the availability and quality of water stored in abandoned underground coal mine aquifers for a variety of applications, such as economic development, geothermal energy, aquaculture, and wastewater disposal. However, the spatial and stratigraphic controls on water quality produced from abandoned underground coal mine aquifers are still poorly constrained on a state-wide basis. In response to these knowledge gaps, the U.S. Geological Survey initiated a study, in cooperation with the West Virginia Department of Environmental Protection, to understand the applicability of using existing secondary source data for understanding water quality in abandoned underground coal mine aquifers across the State. Results from the calculation of net alkalinity indicated that Upper Pennsylvanian coal beds primarily produce net acidic waters and Lower Pennsylvanian coal beds primarily produce net alkaline waters. Multivariate statistical analysis of elemental data supports the conclusion that abandoned underground coal mine aquifers in the northern part of the State generally produce poor water quality and abandoned underground coal mine aquifers in southern West Virginia primarily produce good water quality. These results substantiate the potential benefits of leveraging abandoned underground coal mine aquifers as a multifaceted resource in West Virginia and can be used as a reconnaissance tool for water managers to characterize abandoned underground coal mine aquifers on a local scale.

West Virginia↗

USGS2022

Groundwater quality and geochemistry of the western wet gas part of the Marcellus Shale Oil and Gas Play in West Virginia

Thirty rural residential water wells in the wet gas region of the Marcellus Shale oil and gas play in northwestern West Virginia were sampled by the U.S. Geological Survey (USGS) in 2018, in cooperation with West Virginia State agencies, to analyze for a range of water-quality constituents, including major ions, trace metals, radionuclides, bacteria, and methane and other dissolved hydrocarbon gases. The groundwater-quality data collected for this study were used to assess the overall quality of groundwater in the study area in relation to public drinking-water standards. The groundwater-quality data were also evaluated with respect to geology, well depth, topographic setting, and proximity to oil and gas wells to identify possible relations to these factors. The presence of total coliform bacteria in groundwater is a potential indicator of surface contamination. The presence of Escherichia coli bacteria is indicative of fecal contamination of groundwater from either human or animal sources and may be considered an indicator of other related pathogens such as viruses. Total coliforms were detected in 26 of the 30 (87 percent) wells sampled. Eleven of the 30 (37 percent) wells sampled had detections of Escherichia coli bacteria. Sodium concentrations in 24 of 30 (80 percent) samples exceeded the U.S. Environmental Protection Agency (EPA) 20-milligram per Liter (mg/L) health-based value (HBV). Manganese, aluminum, and iron concentrations exceeded the EPA 50, 2.0, and 300 micrograms per liter (μg/L) secondary maximum contaminant level (SMCL) drinking-water standards at 14 (47 percent), 7 (23 percent), and 5 (17 percent) of the 30 wells sampled. Two of the 30 (7 percent) wells sampled had concentrations of manganese that exceeded the 300-μg/L USGS health-based screening level (HBSL). Arsenic concentrations at 7 of 30 (23 percent) wells sampled exceeded the 10-μg/L EPA maximum contaminant level (MCL) health-based drinking water standard. The EPA maximum contaminant level goal (MCLG) for arsenic is 0 μg/L and 29 of 30 wells sampled contained detectable concentrations of arsenic. None of the 30 wells sampled exceeded the U.S. Office of Surface Mining Reclamation and Enforcement (OSMRE) 28-mg/L immediate action level (IAL) for methane in groundwater and only 1 of 30 (3 percent) sites exceeded the 10-mg/L OSMRE level of concern (LOC) for methane in groundwater. Of the 28 wells sampled for radon-222 all 28 (100 percent) exceeded the EPA proposed 300-picocuries per liter (pCi/L) MCL for radon. None of the samples exceeded the 4,000-pCi/L alternate maximum contaminant level (AMCL) which is applicable to public drinking water systems that have adopted radon mitigation programs. Wilcoxon Signed Rank Tests indicated statistically significant differences at a 95 percent confidence interval (p less than 0.05) in radium-226, barium, and ethane groundwater concentrations with respect to the density of oil and gas wells present within a 500-meter (m) radius around the rural residential wells sampled for the study. Samples from residential wells that had four or fewer oil and gas wells in the surrounding 500-m radius had statistically lower concentrations of radium-226, bromide, and ethane than samples from residential wells sampled that had five or more oil and gas wells in the surrounding 500-m radius. Given the available data, the relationship between concentrations of radium-226, bromide, and ethane for wells sampled in this study and oil and gas development or natural geochemical processes is not clear. Groundwater-age tracers (chlorofluorocarbons, tritium, and sulfur hexafluoride) were sampled at 17 of the 30 wells. All 17 samples contained a fraction of young, post-1950s groundwater. Many of the groundwater samples collected for this study have high calcium to sodium ratios and low total dissolved solids concentrations, indicating they are dominated by recently recharged water. A subset of samples had chloride to bromide mass ratios between 70 and 200, indicating that deep Appalachian basin brines mixed with the shallow groundwater. For most of the samples in this study, the C 1 through C 6 hydrocarbons have characteristics that reflect a biogenic gas signature that has, to varying degrees, undergone oxidation processes during transport. None of the samples show a characteristic thermogenic cracking pattern among the hydrocarbon ratios.

West Virginia↗

USGS2020

Groundwater quality and geochemistry of West Virginia’s southern coal fields

Coal mining has been the dominant industry and land use in West Virginia’s southern coal fields since the mid-1800s. Mortality rates for a variety of serious chronic conditions, such as diabetes, heart disease, and some forms of cancer in Appalachian coal mining regions, are higher than in areas lacking substantial coal mining activity within the Appalachian Region or elsewhere in the United States. Causes of the increased mortality and morbidity are not clear, but poor diet, high rates of smoking, socioeconomic factors, and the quality of groundwater used by area residents are all possible contributing factors. This study was conducted by the U.S. Geological Survey in cooperation with the West Virginia Department of Health and Human Resources and the West Virginia Department of Environmental Protection, with grant support from the Centers for Disease Control and Prevention (CDC) to assess the quality of groundwater in southern West Virginia. The data from this assessment of groundwater quality may be used by the CDC and other agencies to potentially investigate the role or lack thereof of groundwater quality with respect to mortality and morbidity rates in the region. The study was conducted in a region where a high density of current or past coal mining combined with a lack of advanced sewage treatment could affect concentrations of commonly occurring constituents plus contaminants, including nitrate, trace metals, major ions, indicator bacteria, radon, hydrogen sulfide, and dissolved hydrocarbons. Because rural residential wells and mine outfalls are considered private sources of water in the region, and are therefore unregulated and unmonitored, water-quality data are sparse. To fill the data gap and assess the groundwater quality in the region, water-quality samples were collected from 60 sites in a 10-county area. The 60 sites sampled included 46 rural residential homeowner wells and 14 mine outfall discharges used for residential supply. For this study, all samples were collected prior to any filtration or other treatments, typically at the pressure tank, and are indicative of total and dissolved constituents in the untreated water. Generally, data for the 60 sites indicate that most waters sampled do not exceed thresholds for most U.S. Environmental Protection Agency (EPA) drinking-water standards and U.S. Geological Survey (USGS) drinking-water screening criteria. However, there were several notable exceptions. Turbidity exceeded the 5-Nephelometric Turbidity Unit (NTU) EPA treatment technique (TT) drinking-water standard in 14 of 60 (23 percent) sites sampled and exceeded the 1-NTU TT standard in 51 of 60 (85 percent) sites sampled. Turbidity is common in many wells in southern West Virginia and may be attributed to iron oxyhydroxide precipitates, sediment carried into the aquifers from the shallow soil zone due to improperly constructed or cased wells or transported to the aquifer in shallow stress-relief fracture zones or through permeable bedding-plane partings. For the sites sampled, 31 of 60 (52 percent) had pH values at, above, or below the upper and lower range of the EPA Secondary Maximum Contaminant Level (SMCL, 6.5–8.5 standard units). Of those 31 sites, 28 (90 percent) were indicative of acidic corrosive water and 3 (10 percent) were indicative of alkaline water. The Langelier Saturation Index (LSI), which is a measure of the corrosivity of the water, was computed for all sites sampled for the study. Eighty-two percent of the sites sampled had waters that were classified as corrosive, based on a LSI less than −0.5. Corrosive water has the potential to leach lead, copper, and other metals from lead, copper, galvanized, or lead-tin soldered connections in water lines. The chloride to sulfate mass ratio also was assessed with the alkalinity to indicate the potential to promote galvanic corrosion (PPGC) of water lines and plumbing fixtures. Only one of the sites (1.7 percent) classified as a corrosive water site, had a PPGC considered high; the remaining sites were classified as having either a moderate (53.3 percent) or low (45 percent) PPGC. Therefore, the type of plumbing systems sampled for this study may be affected by corrosive water, but the potential for leaching trace metals and other constituents from residential plumbing systems containing older galvanized pipes or lead-tin soldered copper pipes is moderate to low. The indicator bacteria total coliform and Escherichia coli ( E. coli ) also were detected in groundwater samples to varying degrees. Total coliforms, which are a broad class of indicator bacteria, are common in groundwater in southern West Virginia and were detected in 39 of the 60 sites (65 percent) sampled. The presence of total coliform bacteria is a potential indicator of surface contamination, due to improperly constructed or cased wells, or infiltration of soil or other surface contaminants into the aquifer or well bore. E. coli bacteria, however, are much more indicative of fecal contamination of groundwater from either human or animal sources, and 14 of the 60 (23 percent) sites sampled had detections of E. coli . Although only a few strains of E. coli are known pathogens, their presence in groundwater may be an indicator of other related pathogens such as viruses and should be regarded as a serious potential issue. Water treatment such as chlorination, ozonation, or ultraviolet light may be appropriate to kill potential pathogenic bacteria or viruses in the source water. Manganese and iron were prevalent contaminants in the groundwater samples collected for this study, with 30 of 60 (50 percent) sites analyzed for manganese and 25 of 60 (42 percent) sites analyzed for iron exceeding the proposed 50- and 300-micrograms per liter (µg/L) SMCL drinking-water standards, respectively, for aesthetic criteria such as taste, odor, or staining of plumbing fixtures. Fourteen of the 60 sites sampled (23 percent) had concentrations of manganese that exceeded the 300-µg/L USGS health-based screening level, and 1 site exceeded the 1,600-µg/L EPA drinking-water equivalent level, which is based on a lifetime exposure level. Sodium is another common constituent in groundwater within the study area. Sodium has an EPA health-based value (HBV) of 20 milligrams per liter (mg/L) for individuals who are on a sodium-restricted diet for blood pressure or other health reasons. Sodium concentrations exceeded the 20-mg/L EPA HBV in 27 of 60 (45 percent) samples. Radon, a naturally occurring carcinogenic radioactive gas known to cause lung cancer, was detected at concentrations at or exceeding the proposed 300-picocuries per liter (pCi/L) EPA Maximum Contaminant Level (MCL) in 12 of the 60 (20 percent) sites sampled. Sites with radon gas concentrations exceeding the 300-pCi/L proposed MCL have the potential for airborne concentrations of radon to exceed the 4-pCi/L indoor air standard. Inhalation of radon can cause lung cancer, and the 4-pCi/L indoor air standard is based on an inhalation standard. Therefore, homeowners whose wells have radon gas concentrations exceeding 300 pCi/L may be advised to have their indoor air tested to determine if indoor air concentrations exceed the 4-pCi/L indoor air standard established by the EPA. Various factors were analyzed statistically and graphically to determine whether they have an influence on groundwater quality within the study area, including topographic setting, well depth, type of mining (surface or underground), type of site (well or mine outfall), and geologic formation. Only geologic formation and the type of site sampled had strong statistical correlations with one or more of the constituents of concern for this study. The overall chemistry of outfalls (mine outfalls) and wells was significantly different, with a much higher dissolved oxygen content in outfalls than in wells. The dissolved oxygen content is the primary component driving the oxidation and reduction of minerals, and the precipitation of minerals that are saturated or super saturated with respect to various cations and anions. Median dissolved oxygen concentrations for the outfalls sampled was 8.75 mg/L, and only 0.4 mg/L for the wells sampled. Median concentrations of sulfate and selenium were much higher in waters from the outfalls sampled, with median concentrations of 73.75 mg/L and 2.35 µg/L, respectively, compared to the wells sampled, which had median concentrations of 18.3 mg/L and less than (<) the 0.05-µg/L method detection limit, respectively. The maximum selenium concentration was for a well, with a concentration of 16.6 µg/L. The geochemical processes that control sulfate and selenium concentrations in groundwater are similar and are the result of the oxidation of sulfide minerals such as pyrite and ferroselite. Iron and manganese concentrations were elevated in most of the wells sampled, with median concentrations of 269.5 and 124.5 µg/L, respectively, but were rarely detected in the outfalls sampled, with median concentrations of < 4.0 and < 0.4 µg/L, respectively. The difference in iron and manganese between wells and outfalls is indicative of the role of dissolved oxygen on processes controlling groundwater chemistry in the region. Three principal geologic formations were assessed for the study, and the overall chemistry for the Pocahontas, New River, and Kanawha Formations varied substantially with respect to several constituents. Concentrations of calcium, magnesium, and total dissolved solids were highest for sites sampled in the Pocahontas Formation, with median concentrations of 41.9, 18.6, and 312 mg/L, respectively. For constituents that are commonly associated with mining activity, the highest concentrations were for sites sampled in the New River Formation, with median concentrations of iron and manganese of 2,450 µg/L and 482 µg/L, respectively, and a median pH of 6.35 standard units. Concentrations of barium also were elevated in samples collected from sites in the New River Formation, with a median barium concentration of 184 µg/L. The source of the barium is not fully known but may be associated with commingling of shallow groundwater with deeper brines or dissolution of the mineral barite. The highest median sulfate concentrations were from sites sampled in the Pocahontas Formation, with a median concentration of 64.0 mg/L. Of the 12 sites at or exceeding the 300-pCi/L proposed drinking-water standard for radon, 8 (67 percent of MCL exceedances) were for sites deriving water from the Kanawha Formation, 3 (25 percent of MCL exceedances) were for sites deriving water from the New River Formation, and only 1 site was for water from the Pocahontas Formation (8 percent of proposed MCL exceedances). Dissolved hydrocarbons, including methane, ethane, propane, propene, n - and i -butane, 1-butene, n - and i -pentane, pentane, 2- and 3-ethyl pentane, hexane, and benzene were analyzed in samples collected from 59 of the 60 sites to assess the potential occurrence and sources of these trace gases in groundwater within the study area. Results of the analysis indicate that most of the gas is of shallow biogenic origin, possibly associated with coal-bed methane, but a subset of samples has a gas signature and a chloride to bromide ratio indicative of potential mixing with deeper thermogenic gases. Only 2 of the 59 (3.3 percent) sites sampled had concentrations of methane gas, which is a highly combustible and explosive gas, exceeding the 10 milligrams per kilogram level of concern established by the U.S. Office of Surface Mining Reclamation and Enforcement. Principal components analysis was used to assess the primary geochemical processes occurring in the aquifers sampled. The first principal component had significant positive loadings for bromide, chloride, silica, ammonia, barium, iron, manganese, and arsenic, and significant negative loadings for dissolved oxygen, potassium, nitrate, and uranium, and reflects reduction and oxidation (redox) processes occurring in deeper anoxic groundwater or shallow oxic groundwater. The strong positive loadings for iron, manganese, barium, and arsenic are correlated with reducing conditions often found deeper in the aquifer. More oxic water is correlated with oxidation of nitrogen species to nitrate and environmental mobilization of uranium and sulfate in shallow wells and mine outfalls.

West Virginia↗

USGS2017

Groundwater-quality data associated with abandoned underground coal mine aquifers in West Virginia, 1973-2016: Compilation of existing data from multiple sources

This report describes a compilation of existing water-quality data associated with groundwater resources originating from abandoned underground coal mines in West Virginia. Data were compiled from multiple sources for the purpose of understanding the suitability of groundwater from abandoned underground coal mines for public supply, industrial, agricultural, and other uses. This compilation includes data collected for multiple individual studies conducted from July 13, 1973 through September 7, 2016. Analytical methods varied by the time period of data collection and requirements of the independent studies.This project identified 770 water-quality samples from 294 sites that could be attributed to abandoned underground coal mine aquifers originating from multiple coal seams in West Virginia.

West Virginia↗

USGS2017

Hydrogeology, groundwater flow, and groundwater quality of an abandoned underground coal-mine aquifer, Elkhorn Area, West Virginia

The Pocahontas No. 3 coal seam in southern West Virginia has been extensively mined by underground methods since the 1880’s. An extensive network of abandoned mine entries in the Pocahontas No. 3 has since filled with good-quality water, which is pumped from wells or springs discharging from mine portals (adits), and used as a source of water for public supplies. This report presents results of a three-year investigation of the geology, hydrology, geochemistry, and groundwater flow processes within abandoned underground coal mines used as a source of water for public supply in the Elkhorn area, McDowell County, West Virginia. This study focused on large (> 500 gallon per minute) discharges from the abandoned mines used as public supplies near Elkhorn, West Virginia. Median recharge calculated from base-flow recession of streamflow at Johns Knob Branch and 12 other streamflow gaging stations in McDowell County was 9.1 inches per year. Using drainage area versus mean streamflow relationships from mined and unmined watersheds in McDowell County, the subsurface area along dip of the Pocahontas No. 3 coal-mine aquifer contributing flow to the Turkey Gap mine discharge was determined to be 7.62 square miles (mi2), almost 10 times larger than the 0.81 mi2 surface watershed. Results of this investigation indicate that groundwater flows down dip beneath surface drainage divides from areas up to six miles east in the adjacent Bluestone River watershed. A conceptual model was developed that consisted of a stacked sequence of perched aquifers, controlled by stress-relief and subsidence fractures, overlying a highly permeable abandoned underground coal-mine aquifer, capable of substantial interbasin transfer of water. Groundwater-flow directions are controlled by the dip of the Pocahontas No. 3 coal seam, the geometry of abandoned mine workings, and location of unmined barriers within that seam, rather than surface topography. Seven boreholes were drilled to intersect abandoned mine workings in the Pocahontas No. 3 coal seam and underlying strata in various structural settings of the Turkey Gap and adjacent down-dip mines. Geophysical logging and aquifer testing were conducted on the boreholes to locate the coal- mine aquifers, characterize fracture geometry, and define permeable zones within strata overlying and underlying the Pocahontas No. 3 coal-mine aquifer. Water levels were measured monthly in the wells and showed a relatively static phreatic zone within subsided strata a few feet above the top of or within the Pocahontas No. 3 coal-mine aquifer (PC3MA). A groundwater-flow model was developed to verify and refine the conceptual understanding of groundwater flow and to develop groundwater budgets for the study area. The model consisted of four layers to represent overburden strata, the Pocahontas No. 3 coal-mine aquifer, underlying fractured rock, and fractured rock below regional drainage. Simulation of flow in the flooded abandoned mine entries using highly conductive layers or zones within the model, was unable to realistically simulate interbasin transfer of water. Therefore it was necessary to represent the coal-mine aquifer as an internal boundary condition rather than a contrast in aquifer properties. By representing the coal-mine aquifer with a series of drain nodes and optimizing input parameters with parameter estimation software, model errors were reduced dramatically and discharges for Elkhorn Creek, Johns Knob Branch, and other tributaries were more accurately simulated. Flow in the Elkhorn Creek and Johns Knob Branch watersheds is dependent on interbasin transfer of water, primarily from up dip areas of abandoned mine workings in the Pocahontas No. 3 coal-mine aquifer within the Bluestone River watershed to the east. For the 38th, 70th, and 87th percentile flow duration of streams in the region, mean measured groundwater discharge was estimated to be 1.30, 0.47, and 0.39 cubic feet per square mile (ft3/s/mi2

West Virginia↗

USGS2016

Assessment of hydrogeologic terrains, well-construction characteristics, groundwater hydraulics, and water-quality and microbial data for determination of surface-water-influenced groundwater supplies in West Virginia

In January 2014, a storage tank leaked, spilling a large quantity of 4-methylcyclohexane methanol into the Elk River in West Virginia and contaminating the water supply for more than 300,000 people. In response, the West Virginia Legislature passed Senate Bill 373, which requires the West Virginia Department of Health and Human Resources (WVDHHR) to assess the susceptibility and vulnerability of public surface-water-influenced groundwater supply sources (SWIGS) and surface-water intakes statewide. In response to this mandate for reassessing SWIGS statewide, the U.S. Geological Survey (USGS), in cooperation with the WVDHHR, Bureau of Public Health, Office of Environmental Health Services, compiled available data and summarized the results of previous groundwater studies to provide the WVDHHR with data that could be used as part of the process for assessing and determining SWIGS. Existing geologic, hydrologic, well-construction, water-quality, and other related data and information from previous U.S. Geological Survey (USGS) hydrogeologic studies and the USGS National Water Information System (NWIS) database, in conjunction with data from the West Virginia Bureau for Public Health (WVBPH) Department of Health and Human Resources (WVDHHR) and the West Virginia Department of Environmental Protection database and files, were collected, compiled, and analyzed to help the WVDHHR to better assess public groundwater supply wells that may meet the definition of a surface-water-influenced- groundwater supply (SWIGS). In this study, measures of intrinsic susceptibility, which are characterized by the physical properties that affect the ease with which water moves through the unsaturated zone and, subsequently, into the saturated zone within an aquifer, showed that karst limestone aquifers are the aquifers most intrinsically susceptible to contamination within the State of West Virginia. Karst limestone aquifers are present within Cambrian- and Ordovician-age formations within West Virginia’s eastern panhandle and in Mississippian-age limestones within the Greenbrier River valley. Solution development within these limestone aquifers allows rapid recharge and flow of groundwater within the aquifer, both of which allow surface contaminants to easily enter the aquifer and travel long distances in a short period of time. Alluvial aquifers bordering the Ohio River in western West Virginia are also potentially highly susceptible to contamination because these alluvial aquifers can receive significant recharge from the adjacent Ohio River. Any potential contaminants that may be present in the river have the potential to enter the aquifer and contaminate wells completed within the sand and gravel alluvial sediments within which the wells are completed. These same alluvial sediments, however, help to retard the movement of bacteria and other potentially pathogenic organisms, such as Cryptosporidia and Giardia lamblia , into the aquifer. As a result, samples from alluvial aquifers bordering the Ohio River and elsewhere within the State do not commonly test positive for indicator bacteria, such as total coliform, fecal coliform, or Escherichia coli ( E. coli ). The alluvial sediments do not, however, provide assimilative capacity with respect to water soluble compounds such as nitrate and certain volatile and semi-volatile organic compounds. Therefore, the Ohio River alluvial aquifers are highly susceptible to organic compounds present in the river or on the land surface near a well. These aquifers are also susceptible to nitrate contamination from fertilizers, pesticides, and manure, which are commonly used on the fertile agricultural soils present on terraces along the Ohio River. Abandoned-coal-mine aquifers, which are typically used as a source of groundwater in southern West Virginia, are moderately susceptible to contamination. The vast network of voids from mine entries provide vast storage for groundwater in abandoned mine aquifers, and fracturing of overburden strata, which is common in areas of past or current mining, can allow rapid infiltration of contaminants to the aquifer. Where streams cross over below-drainage underground coal mines, there is an increased potential for contamination of coal-mine aquifers. As a result, above-drainage underground coal mines, those mines that are present at an elevation above local tributary drainage, are probably less susceptible to contamination than are below-drainage underground coal mines. Public groundwater supplies in abandoned coal mines need to be evaluated on a case-by-case basis to assess the potential for recharge of contaminated surface water to enter below-drainage underground coal-mine aquifers and to assess potential hydraulic conductivity to nearby surface-water bodies, such as lakes, ponds, rivers, or streams. Fractured-rock aquifers compose an additional major type of aquifer within the State of West Virginia. Owing to their low permeability and their typically small groundwater capture areas, fractured-rock aquifers within the State of West Virginia typically have low susceptibility to contamination. However, there are exceptions, and wells completed in fractured-rock aquifers that are in close proximity to streams may be adversely affected by induced recharge from the stream. Where such systems are present, frequent bacterial testing of the source water can be used to ascertain the potential for microbial contamination of the aquifer. Intrinsic susceptibility alone does not fully predict whether or not a well is vulnerable to contamination, only that the hydrogeologic terrain is suitable for rapid transport of pathogenic organisms or chemical compounds to and within the aquifer. However, contaminants may or may not be present in the recharge water to an individual well or well field. Therefore, an assessment of potential contaminant sources, such as nearby gas wells, landfills, underground storage tanks, above ground storage tanks, major transportation corridors, surface or underground coal mines, and flood plains, is needed to assess vulnerability. The assessments need to be conducted on a case-by-case basis or, as has been done in this study, by collecting and compiling the number of potential contaminant sources that may be present in the source-water-protection area for an individual public groundwater supply source. Groundwater public-supply systems in areas of high intrinsic susceptibility and with a large number of potential contaminant sources within the recharge or source-water-protection area of individual wells or well fields are potentially vulnerable to contamination and probably warrant further evaluation as potential SWIGS. However, measures can be taken to educate the local population and initiate safety protocols and protective strategies to appropriately manage contaminant sources to prevent release of contaminants to the aquifer, therefore, reducing vulnerability of these systems to contamination. However, each public groundwater supply source needs to be assessed on an individual basis. Data presented in this report can be used to categorize and prioritize wells and springs that have a high potential for intrinsic susceptibility or vulnerability to contamination.

West Virginia↗

USGS2015

Hydrologic budget and conditions of Permian, Pennsylvanian, and Mississippian aquifers in the Appalachian Plateaus physiographic province

In response to challenges to groundwater availability posed by historic land-use practices, expanding development of hydrocarbon resources, and drought, the U.S. Geological Survey Groundwater Resources Program began a regional assessment of the Appalachian Plateaus aquifers in 2013 that incorporated a hydrologic landscape approach to estimate all components of the hydrologic system: surface runoff, base flow from groundwater, and interaction with atmospheric water (precipitation and evapotranspiration). This assessment was intended to complement other Federal and State investigations and provide foundational groundwater-related datasets in the Appalachian Plateaus. A regional Soil-Water-Balance model was constructed for a 160,000-square-mile study area that extended to the topographic divide of all streams originating outside but flowing into areas underlain by Appalachian Plateaus aquifers. The model incorporated soil, landscape, and climate variables to estimate an annual water budget for the 32-year period from 1980 to 2011 and was calibrated using base-flow data estimated by hydrograph separation techniques from 20 streamflow gaging stations across the study area. Over this period, an average of 47 inches per year (in/yr) of precipitation fell on Appalachian Plateaus aquifers. Simulations from the regional Soil-Water-Balance model indicate that only 19 percent of the precipitation or an average 9 in/yr recharged aquifers, and 19 percent resulted in surface runoff to streams. The remaining 62 percent, an average of 27 in/yr of water, was returned to the atmosphere via evapotranspiration. Because withdrawals from aquifers due to pumping equated to less than 1 percent of the water budget, differences in predevelopment and postdevelopment regional water budgets of the Appalachian Plateaus were minimal. Storage changes caused by filling of abandoned coal-mine aquifers and long-term differences in aquifer storage resulting from climate fluctuations constitute a small portion of the overall water budget. The percentage of precipitation that results in recharge, runoff, or evapotranspiration from the landscape varies annually by up to a factor of two depending on temporal changes in prevailing climate conditions and spatial changes in basin characteristics, precipitation patterns, and sources of atmospheric moisture over a large study area. A comparison of water-budget estimates from the regional Soil-Water-Balance model for a dry year (1988) and wet year (2004) showed that evapotranspiration accounts for most of the annual differences in precipitation. As a portion of annual precipitation, evapotranspiration ranged from 69 percent (dry year) to 52 percent (wet year), a range four times greater than the 15 percent (dry year) to 18 percent (wet year) range estimated for recharge. Evapotranspiration as a percentage of precipitation peaks during dry periods, whereas base flow and runoff tend to reach minimum values. During wet periods, this relationship is reversed and base flow and runoff as a percentage of precipitation generally peak while evapotranspiration percentages reach minimum values. Annual recharge in the Appalachian Plateaus reaches a maximum at near 20 percent of annual precipitation, regardless of the severity of wet conditions. Hydrograph separation data from 849 streamflow gaging stations in the study area were used to assess trends in streamflow, base flow, surface runoff, and base-flow index, or ratio of base flow to streamflow, in the Appalachian Plateaus for the period from 1930 to 2011. Annual data anomalies for each of the four variables were individually defined as the annual standard deviation from the mean at all 849 streamflow gaging stations. Annual data anomalies confirm the close relation of annual precipitation to both base flow and runoff components of streamflow, and both components increased during the period of analysis. Around 1970, conditions shifted streamflow from values generally below to above long-term means. At a regional scale, increases in base flow account for most of these observed increases in mean annual streamflow. The independence of the base-flow index to annual climate trends indicate that changes in the components of streamflow of the Appalachian Plateaus are probably in response to shifts in seasonal precipitation or widespread land-use practices. A subset of 77 index streamgages, defined as having 60 or more years of complete record between the years 1930 and 2011 with no more than 20 percent missing data, was selected to show spatial patterns of change in the water budget. Data from the index streamgages showed that the overall trends in base flow are dependent upon the period of evaluation. Long-term (1930–2011) increases in base flow were observed throughout the study area. For two shorter periods (1930–1969 and 1970–2011) trends in base flow were largely negative. In general, spatial patterns of change in streamflow, base flow, and runoff were mixed but generally consistent with prevailing climate patterns and land-use changes.

Alabama, Kentucky, Maryland, Ohio, Pennslyvania, V↗

USGS2015

Water quality of groundwater and stream base flow in the Marcellus Shale Gas Field of the Monongahela River Basin, West Virginia, 2011-12

The Marcellus Shale gas field underlies portions of New York, Pennsylvania, Ohio, Virginia, Maryland, Tennessee, and West Virginia. Development of hydraulic fracturing and horizontal drilling technology led to extensive development of gas from the Marcellus Shale beginning about 2007. The need to identify and monitor changes in water-quality conditions related to development of the Marcellus Shale gas field prompted the U.S. Geological Survey, in cooperation with the West Virginia Department of Environmental Protection, Division of Water and Waste Management, to document water quality for comparison with water quality in samples collected at a future date. The identification of change in water-quality conditions over time is more difficult if baseline water-quality conditions have not been documented. U.S. Geological Survey personnel sampled groundwater and surface water in West Virginia’s Monongahela River Basin during 2011–12. A groundwater survey, in which 39 wells and 2 springs were sampled, was conducted during June through September 2011. A base-flow survey was conducted during July through October 2012; 50 stream sites were sampled under base-flow conditions in this survey. Because additives to hydraulic fracturing fluids are variable and decrease in flowback water over a relatively short time, water-quality analyses for this study focused on documenting the water-quality characteristics typical of water from shallow aquifers; water derived from contact with the Marcellus Shale (flowback from hydraulic fracturing or formation water); and water with constituents from conventional oil and gas development, sewage effluent, and coal-mine drainage. All samples were analyzed for field properties (water temperature, pH, specific conductance, dissolved oxygen, and turbidity), major ions, trace elements, naturally occurring radioactive materials, and stable isotopes. In addition to documenting baseline water-quality conditions for an area of shale-gas development, these data were examined for patterns in water quality. Groundwater and base-flow survey data were compared to historical data from the Monongahela River Basin in West Virginia. Additionally, groundwater- and base-flow survey samples were grouped by Marcellus Shale gas production in the subbasin in which that sampling site was located. The comparisons of data collected as part of this study with historical data identified few differences. No significant difference was found in a comparison of groundwater survey data and historical data. Base-flow survey samples differed significantly from historical data for pH, chloride, and strontium, all of which had higher concentrations in the base-flow survey samples. Differences in pH are likely related to changes in mining regulation beginning in 1977. Concentrations of chloride and strontium elevated above background concentrations may be related to saline groundwater; saline water is within 300 feet of the land surface in parts of the study area. In the comparison of base-flow survey samples grouped by shale-gas-production setting, significant differences were found for fluoride and barium. Concentrations of fluoride and barium were higher in stream subbasins with active Marcellus Shale production than in subbasins not near active Marcellus Shale production. Elevated fluoride and barium are associated with deep brines. Generally, naturally occurring radioactive materials were not found in elevated concentrations in either groundwater or base-flow samples. Only 3 samples, 2 from the groundwater survey and one from the base-flow survey, exceeded the U.S. Environmental Protection Agency maximum contaminant level for radium isotopes of 5.0 picocurie per liter for either a single isotope or a combined value of radium-226 and radium-228. Stable isotope composition indicates broad similarity among surface water, shallow groundwater, and precipitation in the region. Neither shallow groundwater nor surface water showed a marked similarity with the deep brines associated with shale gas. In most of the groundwater survey samples, 38 of 41 samples, dissolved gas profiles were similar to those previously found in samples from shallow, domestic wells in the region. This study provides a baseline of water-quality conditions in the Monongahela River Basin in West Virginia during the early phases of development of the Marcellus Shale gas field. Although not all inclusive, the results of this study provide a set of reliable water-quality data against which future data sets can be compared and the effects of shale-gas development may be determined.

West Virginia↗

USGS2013

Quality-assurance plan for groundwater activities, U.S. Geological Survey, Washington Water Science Center

This report documents the standard procedures, policies, and field methods used by the U.S. Geological Survey’s (USGS) Washington Water Science Center staff for activities related to the collection, processing, analysis, storage, and publication of groundwater data. This groundwater quality-assurance plan changes through time to accommodate new methods and requirements developed by the Washington Water Science Center and the USGS Office of Groundwater. The plan is based largely on requirements and guidelines provided by the USGS Office of Groundwater, or the USGS Water Mission Area. Regular updates to this plan represent an integral part of the quality-assurance process. Because numerous policy memoranda have been issued by the Office of Groundwater since the previous groundwater quality assurance plan was written, this report is a substantial revision of the previous report, supplants it, and contains significant additional policies not covered in the previous report. This updated plan includes information related to the organization and responsibilities of USGS Washington Water Science Center staff, training, safety, project proposal development, project review procedures, data collection activities, data processing activities, report review procedures, and archiving of field data and interpretative information pertaining to groundwater flow models, borehole aquifer tests, and aquifer tests. Important updates from the previous groundwater quality assurance plan include: (1) procedures for documenting and archiving of groundwater flow models; (2) revisions to procedures and policies for the creation of sites in the Groundwater Site Inventory database; (3) adoption of new water-level forms to be used within the USGS Washington Water Science Center; (4) procedures for future creation of borehole geophysics, surface geophysics, and aquifer-test archives; and (5) use of the USGS Multi Optional Network Key Entry System software for entry of routine water-level data collected as part of long-term water-level monitoring networks.

Open-File Report↗

USGS2012

Use of modflow drain package for simulating inter-basin transfer in abandoned coal mines

Simulation of groundwater flow in abandoned mines is difficult, especially where flux to and from mines is unknown or poorly quantified, and inter-basin transfer of groundwater occurs. A 3-year study was conducted in the Elkhorn area, West Virginia to better understand groundwater-flow processes and inter-basin transfer in above drainage abandoned coal mines. The study area was specifically selected, as all mines are located above the elevation of tributary receiving streams, to allow accurate measurements of discharge from mine portals and tributaries for groundwater model calibration. Abandoned mine workings were simulated in several ways, initially as a layer of high hydraulic conductivity bounded by lower permeability rock in adjacent strata, and secondly as rows of higher hydraulic conductivity embedded within a lower hydraulic conductivity coal aquifer matrix. Regardless of the hydraulic conductivity assigned to mine workings, neither approach to simulate mine workings could accurately reproduce the inter-basin transfer of groundwater from adjacent watersheds. To resolve the problem, a third approach was developed. The MODFLOW DRAIN package was used to simulate seepage into and through mine workings discharging water under unconfined conditions to Elkhorn Creek, North Fork, and tributaries of the Bluestone River. Drain nodes were embedded in a matrix of uniform hydraulic conductivity cells that represented the coal mine aquifer. Drain heads were empirically defined from well observations, and elevations were based on structure contours for the Pocahontas No. 3 mine workings. Use of the DRAIN package to simulate mine workings as an internal boundary condition resolved the inter-basin transfer problem, and effectively simulated a shift from a topographic- dominated to a dip-dominated flow system, by dewatering overlying unmined strata and shifting the groundwater drainage divide up dip within the Pocahontas No. 3 coal seam several kilometers into the adjacent Bluestone River Watershed. Model simulations prior to use of the DRAIN package for simulating mine workings produced estimated flows of 0.32 to 0.34 m3/s in each of the similar sized Elkhorn Creek and North Fork Watersheds, but failed to estimate inter-basin transfer of groundwater from the adjacent Bluestone River Watershed. The simulation of mine entries and discharge using the MODFLOW DRAIN package produced estimated flows of 0.46 and 0.26 m3/s for the Elkhorn Creek and North Fork watersheds respectively, which matched well measured flows for the respective watersheds of 0.47 and 0.26 m3/s.

West Virginia↗

USGS2012

Groundwater quality in West Virginia, 1993-2008

Approximately 42 percent of all West Virginians rely on groundwater for their domestic water supply. However, prior to 2008, the quality of the West Virginia’s groundwater resource was largely unknown. The need for a statewide assessment of groundwater quality prompted the U.S. Geological Survey (USGS), in cooperation with West Virginia Department of Environmental Protection (WVDEP), Division of Water and Waste Management, to develop an ambient groundwater-quality monitoring program. The USGS West Virginia Water Science Center sampled 300 wells, of which 80 percent were public-supply wells, over a 10-year period, 1999–2008. Sites for this statewide ambient groundwater-quality monitoring program were selected to provide wide areal coverage and to represent a variety of environmental settings. The resulting 300 samples were supplemented with data from a related monitoring network of 24 wells and springs. All samples were analyzed for field measurements (water temperature, pH, specific conductance, and dissolved oxygen), major ions, trace elements, nutrients, volatile organic compounds, fecal indicator bacteria, and radon-222. Sub-sets of samples were analyzed for pesticides or semi-volatile organic compounds; site selection was based on local land use. Samples were grouped for comparison by geologic age of the aquifer, Groups included Cambrian, Ordovician, Silurian, Devonian, Pennsylvanian, Permian, and Quaternary aquifers. A comparison of samples indicated that geologic age of the aquifer was the largest contributor to variability in groundwater quality. This study did not attempt to characterize drinking water provided through public water systems. All samples were of raw, untreated groundwater. Drinking-water criteria apply to water that is served to the public, not to raw water. However, drinking water criteria, including U.S. Environmental Protection Agency (USEPA) maximum contaminant level (MCL), non-enforceable secondary maximum contaminant level (SMCL), non-enforceable proposed MCL, or non-enforceable advisory health-based screening level (HBSL), were used as benchmarks against which to compare analytical results. Constituent concentrations were less than the MCLs in most samples. However, some samples exceeded non-enforceable SMCLs, proposed MCLs, or advisory HBSLs. Radon-222 concentrations exceeded the proposed MCL of 300 pCi/L in 45 percent of samples, and iron concentrations exceeded the SMCL of 300 µg/L in 57 percent of samples. Manganese concentrations were greater than the SMCL (50 µg/L) in 62 percent of samples and greater than the HBSL (300 µg/L) in 25 percent of the samples. Other sampled constituents, including organic compounds and trace elements, exceeded drinking-water criteria at much lower frequencies. The radon-222 median concentrations in samples from Cambrian, Ordovician, Silurian, Permian, and Quaternary aquifers exceeded the proposed 300 pCi/L MCL. Although median radon concentrations for wells in Devonian, Mississippian, and Pennsylvanian aquifers were less than the proposed MCL, radon concentrations greater than the proposed MCL were measured in samples from aquifers of all geologic ages. The median iron concentrations for samples from Devonian and Pennsylvanian aquifers were greater than the 300 µg/L SMCL. Iron concentrations exceeded the SMCL in aquifers of all geologic ages, except Cambrian. Median concentrations of manganese exceeded the SMCL in samples from Devonian, Pennsylvanian, and Quaternary aquifers. As with iron, manganese concentrations were found to exceed the SMCL in at least one sample from aquifers of all geologic ages, except Cambrian. Pesticides were detected most frequently and in higher concentrations in limestone-dominated areas. Most of West Virginia’s agriculture is concentrated in those areas. This study, the most comprehensive assessment of West Virginia groundwater quality to date, indicates the water quality of West Virginia’s groundwater is generally good; in the majority of cases raw-water samples met primary drinking water-criteria. However, some constituents, notably iron and manganese, exceeded the secondary drinking criteria in more than half the samples.

West Virginia↗

USGS2009

Hydrogeologic Factors Affecting Base-Flow Yields in the Jefferson County Area, West Virginia, October-November 2007

Base-flow yields at approximately the annual 75-percent-duration flow were determined for watersheds in the Jefferson County area, WV, from stream-discharge measurements made during October 31 to November 2, 2007. Five discharge measurements of Opequon Creek defined increased flow from 29,000,000 gallons per day (gal/d) at Carters Ford to 51,400,000 gal/d near Vanville. No flow was observed at 45 of 110 additional stream sites inspected, and discharge at the 65 flowing stream sites ranged from 1,940 to 17,100,000 gallons per day (gal/d). Discharge at 28 springs ranged from no flow to 2,430,000 gal/d. Base-flow yields were computed as the change in stream-channel discharge between measurement sites divided by the change in drainage area between the sites. Yields were negative for losing (influent) channel reaches and positive for gaining (effluent) reaches. Channels in 14 watersheds were determined to have lost flow ranging from -9.6 to -1,770 gallons per day per acre (gal/d/acre). Channels in 51 watersheds were determined to have gained flow ranging from 3.4 to 235,000 gal/d/acre. Water temperature at the stream sites ranged from 5.0 to 16.3 deg C (quarry pumpage), and specific conductance ranged from 51 to 881 microsiemens per centimeter (uS/cm). Water temperature at the springs ranged from 11.5 to 15.0 deg C, and specific conductance ranged from 22 to 958 uS/cm. Large springs in some watersheds in western Jefferson County are adjacent to other watersheds with little or no surface-water discharge; this is probably the result of interbasin transfer of groundwater along faults that dissect the area. Most watersheds located adjacent to the Potomac River in northeastern Jefferson County were not flowing during this study; this is most likely because the Potomac River is deeply incised, and groundwater flows directly to it rather than to the local stream systems in these areas. Except for one watershed with a yield of 651 gal/d/acre, no watersheds in northeastern Jefferson County yielded more than 305 gal/d/acre. Base-flow yields of several watersheds in south-central Jefferson County exceeded 400 gal/d/acre, and the effect of the Shenadoah River on base flows in the watershed appears to be less than that of the Potomac River in the northeastern part of the county. In the southeastern part of the county, because of steep relief and low-permeability bedrock, several streams were not flowing at the time of the study, and yields from all flowing streams were all less than 100 gal/d/acre. On the basis of historical data from 1961 through 2008, the mean and median depths to groundwater in 213 wells in western Jefferson County were 33.4 and 29.3 ft, respectively. Mean and median depths to groundwater in 69 wells in the northeastern county area were 56.0 and 55.0 ft below land surface, respectively. However, mean and median depths to groundwater in 28 wells within 1.5 miles of the Potomac River were 70.0 and 71.3 ft below land surface, respectively. Mean and median depths to groundwater in 108 wells in the south-central county area were 53.9 and 52.8 ft below land surface, respectively. Mean and median depths to groundwater of 26 wells in the southeastern county area were 86.6 and 59.5 ft below land surface, respectively.

Scientific Investigations Report↗

USGS2009

Hydrogeology and Ground-Water Flow in the Opequon Creek Watershed area, Virginia and West Virginia

Due to increasing population and economic development in the northern Shenandoah Valley of Virginia and West Virginia, water availability has become a primary concern for water-resource managers in the region. To address these issues, the U.S. Geological Survey (USGS), in cooperation with the West Virginia Department of Health and Human Services and the West Virginia Department of Environmental Protection, developed a numerical steady-state simulation of ground-water flow for the 1,013-square-kilometer Opequon Creek watershed area. The model was based on data aggregated for several recently completed and ongoing USGS hydrogeologic investigations conducted in Jefferson, Berkeley, and Morgan Counties in West Virginia and Clarke, Frederick, and Warren Counties in Virginia. A previous detailed hydrogeologic assessment of the watershed area of Hopewell Run (tributary to the Opequon Creek), which includes the USGS Leetown Science Center in Jefferson County, West Virginia, provided key understanding of ground-water flow processes in the aquifer. The ground-water flow model developed for the Opequon Creek watershed area is a steady-state, three-layer representation of ground-water flow in the region. The primary objective of the simulation was to develop water budgets for average and drought hydrologic conditions. The simulation results can provide water managers with preliminary estimates on which water-resource decisions may be based. Results of the ground-water flow simulation of the Opequon Creek watershed area indicate that hydrogeologic concepts developed for the Hopewell Run watershed area can be extrapolated to the larger watershed model. Sensitivity analyses conducted as part of the current modeling effort and geographic information system analyses of spring location and yield reveal that thrust and cross-strike faults and low-permeability bedding, which provide structural and lithologic controls, respectively, on ground-water flow, must be incorporated into the model to develop a realistic simulation of ground-water flow in the larger Opequon Creek watershed area. In the model, recharge for average hydrologic conditions was 689 m3/d/km2 (cubic meters per day per square kilometer) over the entire Opequon Creek watershed area. Mean and median measured base flows at the streamflow-gaging station on the Opequon Creek near Martinsburg, West Virginia, were 604,384 and 349,907 m3/d (cubic meters per day), respectively. The simulated base flow of 432,834 m3/d fell between the mean and median measured stream base flows for the station. Simulated base-flow yields for subwatersheds during average conditions ranged from 0 to 2,643 m3/d/km2, and the median for the entire Opequon Creek watershed area was 557 m3/d/km2. A drought was simulated by reducing model recharge by 40 percent, a rate that approximates the recharge during the prolonged 16-month drought that affected the region from November 1998 to February 2000. Mean and median measured streamflows for the Opequon Creek watershed area at the Martinsburg, West Virginia, streamflow-gaging station during the 1999 drought were 341,098 and 216,551 m3/d, respectively. The simulated drought base flow at the station of 252,356 m3/d is within the range of flows measured during the 1999 drought. Recharge was 413 m3/d/km2 over the entire watershed during the simulated drought, and was 388 m3/d/km2 at the gaging station. Simulated base-flow yields for drought conditions ranged from 0 to 1,865 m3/d/km2 and averaged 327 m3/d/km2 over the entire Opequon Creek watershed. Water budgets developed from the simulation results indicate a substantial component of direct ground-water discharge to the Potomac River. This phenomenon had long been suspected but had not been quantified. During average conditions, approximately 564,176 m3/d of base flow discharges to the Potomac River. An additional 124,379 m3/d of ground water is also estimated to discharge directly to the Potomac River and rep

Scientific Investigations Report↗

USGS2008

Bedrock structural controls on the occurrence of sinkholes and springs in the Northern Great Valley Karst, Virginia and West Virginia

Recent geologic mapping at a scale of 1:24,000 has enabled a qualitative correlation of the occurrence of springs and sinkholes with bedrock structures and ground-water conditions in the northern Great Valley of Virginia and West Virginia. Sinkholes tend to be concentrated in zones of faulting, local minor folding, and clustered within susceptible bedrock units at the noses and axes of large plunging folds. Alignment of sinkholes mainly occurs along strike of bedding. Enhanced rock solution and conduit formation correlates with carbonate units of greater limestone purity and finer grain size, suggesting some lithologic control on karst formation. In addition, there is an apparent topographic correlation, with sinkholes usually formed in elevated and flat (<5 degrees slope) areas, as well as frequent sinkhole occurrence proximal to entrenched surface streams. Density of sinkhole occurrence tends to increase in areas where water-table fluctuations are large. Large perennial springs occur along faults, and may lie above base level streams indicating upward flow gradients particularly where cross-strike faults and joints intersect bedding planes and strike-parallel faults. Sinkhole formation also frequently occurs in areas proximal to entrenched surface streams, reflecting subsequent vadose-zone modification and excavation of sediment-filled conduits where downward ground-water flow gradients are most steep. Geologic evidence indicates that deep karst development may have taken place by rising fluids under confined (hypogenic) conditions in the distant geologic past in this region.

Virginia, West Virginia↗

USGS2008

Hydrogeology and water quality of the Leetown area, West Virginia

The U.S. Geological Survey’s Leetown Science Center and the co-located U.S. Department of Agriculture’s National Center for Cool and Cold Water Aquaculture both depend on large volumes of cold clean ground water to support research operations at their facilities. Currently, ground-water demands are provided by three springs and two standby production wells used to augment supplies during periods of low spring flow. Future expansion of research operations at the Leetown Science Center is dependent on assessing the availability and quality of water to the facilities and in locating prospective sites for additional wells to augment existing water supplies. The hydrogeology of the Leetown area, West Virginia, is a structurally complex karst aquifer. Although the aquifer is a karst system, it is not typical of most highly cavernous karst systems, but is dominated by broad areas of fractured rock drained by a relatively small number of solution conduits. Characterization of the aquifer by use of fluorometric tracer tests, a common approach in most karst terranes, therefore only partly defines the hydrogeologic setting of the area. In order to fully assess the hydrogeology and water quality in the vicinity of Leetown, a multi-disciplinary approach that included both fractured rock and karst research components was needed. The U.S. Geological Survey developed this multi-disciplinary research effort to include geologic, hydrologic, geophysical, geographic, water-quality, and microbiological investigations in order to fully characterize the hydrogeology and water quality of the Leetown area, West Virginia. Detailed geologic and karst mapping provided the framework on which hydrologic investigations were based. Fracture trace and lineament analysis helped locate potential water-bearing fractures and guided installation of monitoring wells. Monitoring wells were drilled for borehole geophysical surveys, water-quality sampling, water-level measurements, and aquifer tests to characterize the quality of water and the hydraulic properties of the aquifer. Surface geophysical surveys provided a 3-dimensional view of bedrock resistivity in order to assess geologic and lithologic controls on ground-water flow. Borehole geophysical surveys were conducted in monitoring wells to assess the storage and movement of water in subsurface fractures. Numerous single-well, multi-well, and straddle packer aquifer tests and step-drawdown tests were conducted to define the hydraulic properties of the aquifer and to assess the role of bedrock fractures and solution conduits in the flow of ground water. Water samples collected from wells and springs were analyzed to assess the current quality of ground water and provide a baseline for future assessment. Microbiological sampling of wells for indicator bacteria and human and animal DNA provided an analysis of agricultural and suburban development impacts on ground-water quality. Light detection and ranging (LiDAR) data were analyzed to develop digital elevation models (DEMs) for assessing sinkhole distribution, to provide elevation data for development of a ground-water flow model, and to assess the distribution of major fractures and faults in the Leetown area. The flow of ground water in the study area is controlled by lithology and geologic structure. Bedrock, especially low permeability units such as the shale Martinsburg Formation and the Conococheague Limestone, act as barriers to water flowing down gradient and across bedding. This retardation of cross-strike flow is especially pronounced in the Leetown area, where bedding typically dips at steep angles. Highly permeable fault and fracture zones that disrupt the rocks in cross-strike directions provide avenues through which ground water can flow laterally across or through strata of low primary permeability. Significant strike parallel thrust faults and cross-strike faults typically coincide with larger solution conduits and act as drains for the more pervasive network of interconnected diffuse fractures. Results of borehole geophysical surveys indicate that although numerous fractures may intersect a borehole, only one or two of the fractures typically transmit most of the water to a well. The diffuse-flow dominated network of fractures that provides the majority of storage occupies only a small proportion of the total aquifer volume but constitutes the majority of porosity within the aquifer. Solution conduits, while occupying a relatively small volume of the overall aquifer, are especially important because they serve as primary drains for the ground-water flow system. Surface resistivity maps and cross-sectionsshow anomalous areas of low resistivities coincident with the prevailing geologic strike at N. 20º E., with major cross-strike faults, and with major springs in the region. Transmissivity derived from straddle packer tests was highly variable, and ranged over three orders of magnitude (1.8 x 10 -6 to 5.9 x 10 -3 ft 2 /d) in diffuse-flow fractures. A similar large variability in transmissivity was documented by single- and multi-well aquifer tests conducted in conduit-flow dominated portions of the aquifer (2.0 x 10 3 to 1.4 x 10 4 ft 2 /d) in lowland areas immediately adjacent to the Leetown Science Center. A stream-gaging station installed on Hopewell Run near the point where the stream exits the Leetown watershed indicates average daily streamflow for the Hopewell Run of approximately 11.2 ft 3 /s, and ranged from a minimum of 1.80 ft 3 /s on September 28, 2005, to a maximum of 73.0 ft 3 /s on December 11, 2003. Base-flow (ground-water) discharge surveys identified numerous small seeps adjacent to streams in the area. Hydrographs of the stage of Balch Spring show rapid response to individual storms. Strong correlation of the flow of Hopewell Run and Balch Spring indicates the nearby losing stream reach is partly responsible for higher fluctuations in the stage of Balch Spring. A water budget for the study period (2003-2005), based on measured precipitation and hydrograph analyses, is expressed as Precipitation (38.60 in/yr) = Surface Runoff (1.36 in/yr) + Ground-Water Discharge (17.73 in/yr) + Evapotranspiration (24.23 in/yr) – Change in storage (4.72 in/yr). Flow of ground water through the epikarst, a shallow zone of intensely weathered rock and regolith, can be rapid (on the order of days or weeks) as flow is concentrated in solution conduits. Flow within the intermediate and deeper zones is typically much slower. Eight dye-tracer tests conducted in the Leetown area found ground-water flow patterns to be divergent, with velocities ranging from about 12.5 to 610 ft/day and a median velocity of 50 ft/day. Estimates of ground-water age in carbonate rocks in the region are on the order of 15 years in the shallower portions of the aquifer to 50 years or older for deeper portions of the aquifer. Shallow springs can have a significant component of fairly young water (< 5 years in age). Ground-water samples collected from 16 sites (12 wells and 4 springs) in the Leetown area were analyzed for more than 340 constituents. Only turbidity, indicator bacteria, and radon were typically present in concentrations exceeding U.S. Environmental Protection Agency (USEPA) drinking-water or aquatic life standards.

West Virginia↗