Geology topics

Mark A. Hardy

Publications and source records attributed to Mark A. Hardy.

5 recordsLinked to original sources

USGS2014

Selenium in the upper Blackfoot River watershed, southeastern Idaho, 2001-12

The upper Blackfoot River in southeastern Idaho receives runoff from 12 large phosphate mines. Waste shales that are removed to access the phosphate ore are highly enriched with selenium, resulting in elevated selenium in runoff from the mine waste dumps. In 2001, in cooperation with the Bureau of Land Management, the U.S. Geological Survey (USGS) began monitoring streamflow, selenium, and other water-quality parameters at a single location near the outlet of the upper Blackfoot River to the Blackfoot Reservoir. Water samples primarily were collected by a flow triggered, automated pump sampler, supplemented by manual point and equal-width integrated manual samples. The approach to monitoring concentrations and streamflow over time at a fixed location is ideal for evaluating temporal trends, but provides no information about the relative source contributions from the mine waste dumps draining into various tributaries. In 2001, the Idaho Department of Environmental Quality (IDEQ) began an annual, mid-May, synoptic survey of selenium concentrations and streamflow at 21 locations along the main stem Blackfoot River and its tributaries. Individually, neither the intensive USGS sampling at the outlet nor the IDEQ annual synoptic sampling provides a comprehensive view of selenium runoff in the Blackfoot River watershed. Together, the efforts are complementary; therefore, in this report, results are presented from both sampling efforts. The USGS collected time-series data from 2001 to 2012 at a fixed location, the Blackfoot River near the outlet of the reservoir, near Henry, Idaho (USGS streamgage 13063000). Dissolved selenium concentrations from 450 filtered samples collected at this site ranged from 0.5 to 11.4 micrograms per liter (μg/L). The State of Idaho chronic aquatic life criterion concentration of 5 μg/L was exceeded in 31 percent of the samples, with most exceedances occurring during May of each year. No exceedances of the selenium criterion were recorded in months other than April, May, or June. Concentrations of selenium in unfiltered and filtered samples were similar, and concentrations from samples collected by depth and width integrated methods were similar to those collected by grab (point) samples, indicating that the grab samples adequately represent selenium concentrations across the entire river cross section. In speciation analyses made during 2003 and 2004, the median percentage of total selenium as selenate was 81 percent, ranging from 17 to 98 percent, and the median percentage of total selenium as selenite was 19 percent, ranging from 2 to 83 percent of the total selenium. During the period of study, selenium concentrations had an upward trend during the lowflow season of August–October. Time trends were not obvious during other seasons. Selenium daily loads varied by more than a factor of 900 during the study period and ranged from 0.03 kilograms per day (kg/d) to more than 24 kg/d. Annual maximum daily loads of selenium varied over nearly a factor of 12, ranging from about 2 to 24 kg/d. For the annual spring synoptic samples collected by the IDEQ along the main stem Blackfoot River and major tributaries, selenium concentrations ranged from less than 2 to 870 μg/L in 176 samples. In most years, the synoptic sampling showed that the majority of the selenium loads passing the USGS streamgage at the outlet of the watershed could be attributed to a single tributary, East Mill Creek, which enters the Blackfoot River through Spring Creek. Selenium loads decreased by about half from East Mill Creek before reaching the Blackfoot River, suggesting that much selenium is at least temporarily removed from the water column by uptake by aquatic vegetation or by losses to sediment. Similar decreases in selenium loads occurred through the main stem Blackfoot River before reaching the outlet in low flow years, but not in high flow years.

Idaho↗

USGS2005

Status of and changes in water quality monitored for the Idaho statewide surface-water-quality network, 1989—2002

The Idaho statewide surface-water-quality monitoring network consists of 56 sites that have been monitored from 1989 through 2002 to provide data to document status and changes in the quality of Idaho streams. Sampling at 33 sites has covered a wide range of flows and seasons that describe water-quality variations representing both natural conditions and human influences. Targeting additional high- or low-flow sampling would better describe conditions at 20 sites during hydrologic extremes. At the three spring site types, sampling covered the range of flow conditions from 1989 through 2002 well. However, high flows at these sites since 1989 were lower than historical high flows as a result of declining ground-water levels in the Snake River Plain. Summertime stream temperatures at 45 sites commonly exceeded 19 and 22 degrees Celsius, the Idaho maximum daily mean and daily maximum criteria, respectively, for the protection of coldwater aquatic life. Criteria exceedances in stream basins with minimal development suggest that such high temperatures may occur naturally in many Idaho streams. Suspended-sediment concentrations were generally higher in southern Idaho than in central and northern Idaho, and network data suggest that the turbidity criteria are most likely to be exceeded at sites in southern Idaho and other sections of the Columbia Plateaus geomorphic province. This is probably because this province has more fine-grained soils that are subject to erosion and disturbance by land uses than the Northern Rocky Mountains province of northern and central Idaho has. Although erodable soils are likely a cause of elevated turbidities, suspended-sediment concentrations were not strongly correlated with turbidities. Dissolved-solids and hardness concentrations were strongly correlated. This is probably because the limestones present in some basins are more soluble than the igneous rocks that predominate in others. Low hardness in streams of northern Idaho, where watersheds are underlain by resistant igneous rocks, enhances the toxicity of some trace elements to aquatic life in these streams. Only a few measurements of dissolved-oxygen concentrations at six sites were less than 6.0 milligrams per liter, the Idaho minimum criterion for protection of aquatic organisms. High supersaturations of dissolved oxygen at four sites suggest excessive photosynthetic activity by algal communities. Nighttime monitoring would help determine whether dissolved-oxygen concentrations at these sites might fall below the Idaho criterion. Data from four sites suggest that dissolved-oxygen concentrations may have decreased over time. The pH at 15 sites sometimes fell outside the range specified (6.5-9.0) for the protection of aquatic organisms in Idaho streams. Values exceeded 9.0 at 10 sites, probably because of excessive algal photosynthetic activity in waters where carbonate rocks are present. Values were sometimes less than 6.5 at five sites in areas of mountain bedrock geology where pH is likely to be naturally low. Mining activities also may contribute to low pH at some of these sites. Inorganic nitrogen and total phosphorus concentrations commonly exceeded those considered sufficient for supporting excess algal production (0.3 and 0.1 milligrams per liter, respectively). Data from a few sites suggest that nitrogen and(or) phosphorus concentrations might be changing over time. Low concentrations of nitrogen and phosphorus at six sites, most representing forested basins, might make them good candidates as reference sites that represent naturally occurring nutrient concentrations. Trace elements examined for this report were cadmium, copper, lead, mercury, selenium, and zinc. In water, many trace-element concentrations were below the minimum analytical reporting levels. Concentrations of cadmium, copper, lead, and zinc generally were highest in mined and other mineral-rich basins in northern Idaho. Concentrations of mercury were

Idaho↗

USGS2004

Reconnaissance of chemical and biological quality in the Owyhee River from the Oregon State line to the Owyhee Reservoir, Oregon, 2001–02

The Owyhee River drains an extremely rugged and sparsely populated landscape in northern Nevada, southwestern Idaho, and eastern Oregon. Most of the segment between the Oregon State line and Lake Owyhee is part of the National Wild and Scenic Rivers System, and few water-quality data exist for evaluating environmental impacts. As a result, the U.S. Geological Survey, in cooperation with the Bureau of Land Management, assessed this river segment to characterize chemical and biological quality of the river, identify where designated beneficial uses are met and where changes in stream quality occur, and provide data needed to address activities related to environmental impact assessments and Total Maximum Daily Loads. Water-quality issues identified at one or more sites were water temperature, suspended sediment, dissolved oxygen, pH, nutrients, trace elements, fecal bacteria, benthic invertebrate communities, and periphyton communities. Generally, summer water temperatures routinely exceeded Oregon's maximum 7-day average criteria of 17.8 degrees Celsius. The presence of few coldwater taxa in benthic invertebrate communities supports this observation. Suspended-sediment concentrations during summer base flow were less than 10 milligrams per liter (mg/L). Dissolved solids concentrations ranged from 46 to 222 mg/L, were highest during base flow, and tended to increase in a downstream direction. Chemical compositions of water samples indicated that large proportions of upland-derived water extend to the lower reaches of the study area during spring runoff. Dissolved fluoride and arsenic concentrations were highest during base flow and may be a result of geothermal springs discharging to the river. No dissolved selenium was detected. Upstream from the Rome area, spring runoff concentrations of suspended sediment ranged from 0 to 52 mg/L, and all except at the Three Forks site were typically below 20 mg/L. Stream-bottom materials from the North Fork Owyhee River, an area with no mines, were enriched with nine trace elements, which indicates that this basin may be a natural source of these elements. Near Rome, the part of the study area not included in the National Wild and Scenic Rivers System, land-use impacts resulted in elevated populations of Escherichia coli bacteria ( E. coli ) during base flow and elevated concentrations of nitrogen and phosphorus during spring runoff. Sites in this area had the highest numbers of benthic invertebrates; the fewest Ephemeroptera, Plecoptera, and Trichoptera taxa; and the highest Hilsenhoff Biotic Index scores. These results suggest degraded stream quality. Periphyton communities at sites in this area approached nuisance levels and could cause significant dissolved oxygen depletions and pH values that exceed Oregon's recommended criteria. Stream-bottom materials from Jordan Creek were enriched with mercury and manganese, which probably were ultimately caused by past mining in that basin. Below Crooked Creek, elevated suspended sediment concentrations (142 mg/L), phosphorus concentrations (0.23 mg/L), and E. coli populations (370 most probable number per 100 milliliters) during the largest spring runoff event could be the result of inputs at the lower end of Jordan Valley and (or) inputs from Crooked Creek. The New Zealand Mud Snail, a highly competitive gastropod introduced to the Snake River in the 1980s, was collected just downstream from the Crooked Creek confluence.

Idaho;Nevada;Oregon↗

USGS1981

Effects of coal fly-ash disposal on water quality in and around the Indiana Dunes National Lakeshore, Indiana

Dissolved constituents in seepage from fly-ash settling ponds bordering part of the Indiana Dunes National Lakeshore (the Lakeshore) have increased the concentrations of major ions (calcium, fluoride, potassium, and sulfate), trace elements (aluminum, arsenic, boron, iron, manganese, molybdenum, nickel, strontium, and zinc), and gross alpha and beta radioactivity in ground water and surface water downgradient from the settling ponds. Data collected from September 1976 through May 1978 suggest that concentrations of some dissolved trace elements may be greater beneath interdunal pond 2 than in the pond. The soil system downgradient from the settling ponds seems to have affected the concentrations of dissolved ions in the settling-pond seepage. Calcium concentrations were greater in ground water downgradient from the settling ponds than in the ponds. Where organic material was present downgradient from the settling ponds, concentrations of arsenic, fluoride, molybdenum, potassium, sulfate, and strontium were greater in the ground water than in the ponds. In contrast, the concentrations of cadmium, copper, nickel, aluminum, cobalt, lead, and zinc were less. Leachate from an ash fill bordering the Lakeshore increased concentrations of boron, molybdenum, and potassium in surface water. Although concentrations of chemical constituents were variable, data indicate that ground-water in a confined aquifer beneath the study area was not significantly affected by settling-pond seepage.

Indiana↗

USGS1978

A water-quality assessment of the Muddy Fork Silver Creek watershed, Clark, Floyd, and Washington counties, Indiana

Data collected for a wide range of flow conditions from September 8, 1975, to July 13, 1976, reveal that human and animal waste loading of streams and pesticide use in the watershed are probably the most significant water-quality problems. Generally, the type(s) of water in tributary streams in the south and southwest parts of the watershed was calcium bicarbonate and in other tributaries were calcium sulfate and magnesium sulfate. Dissolved-solids concentrations of discharge from top-spill reservoirs were lower and more consistent over a range of flows than concentrations from uncontrolled streams. Chemical characteristics of discharges from bottom-draw reservoirs differed from those of discharges from the other reservoirs. More than half the manganese concentrations equaled or exceeded 0.05 milligrams per liter, the maximum concentration recommended for domestic water supplies. Leaf fall in forested parts of the watershed are probably a source of this manganese. Nitrate (as nitrogen) concentration of streams ranged from 0.00 to 2.5 milligrams per liter; orthophosphate (as phosphorus), from 0.00 to 0.29 milligrams per liter, and total organic carbon, from 2.0 to 14 milligrams per liter. Concentrations of fecal coliform bacteria and fecal streptococcal bacteria ranged from 5 to 65,000 colonies per 100 milliliters and from 5 to 24,000 colonies per 100 milliliters, respectively. Occasional human-waste contamination is indicated downstream from the towns of Borden and Speed. Data on periphyton, phytoplankton, and benthic communities collected during low flow in September 1975 indicate organic loading of Muddy Fork downstream from the town of Speed. Phytoplankton community structures varied temporally and spatially. Ranges of concentration of various chlorinated hydrocarbons in samples of bed materials (in micrograms per kilogram) were: chlordane, from 0 to 14; DDT, from 0 to 19; and PCB's, from 0 to 11. Concentrations of aldrin, DDD, DDE, heptachlor, and heptachlor epoxide of 5.1 micrograms per kilogram or less were also detected. The presence of these compounds makes them potentially available for accumulation in the biological food chain.