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Madison L. Myers

Publications and source records attributed to Madison L. Myers.

5 recordsLinked to original sources

Ignimbrites of the Sour Creek dome, Yellowstone volcano, USA: Implications for the Lava Creek Tuff eruption and Yellowstone Caldera

Field observations plus sanidine compositional and 40 Ar/ 39 Ar age data collected on rocks from the Sour Creek dome (SCD) area of Yellowstone volcano (United States) serve to identify five new ignimbrite packages with ages (average 631.5 ± 0.9 ka) that are analytically indistinguishable from those of the Lava Creek Tuff (LCT), challenging the current framework of two LCT eruptive members. Newly recognized package 1 occurs as LCT-aged recycled clasts within a proximal lag breccia, reflecting a major time break in the LCT eruption sequence. Conformably above, the scoria-bearing ignimbrite of package 2 is extensively found in the dome, having been previously mis-mapped as Huck-leberry Ridge Tuff and LCT member A. To the south, package 3 is a crystal-rich, densely welded ignimbrite (inferred to be younger than package 2) that is conformably overlain by package 4, a fine-grained ignimbrite that contains abundant clasts of recycled tuff. Lastly, the topographically highest parts of the dome are made up of package 5, a multicomponent ignimbrite containing scoria, recycled clasts, and pumices, potentially correlative with package 2 and/or package 4. Cathodoluminescence imaging and zoning assessment was integrated with sanidine geochemistry from all five packages, including their recycled clasts. Four of the five packages were sourced from separate magmatic bodies within a larger plumbing system, each defined by their sanidine Ba distributions and componentry. Although the SCD was originally mapped as a resurgent dome and is actively deforming today, faults cutting the region show comparable offsets for NW-SE “resurgent faulting” as for orthogonal NE-SW faulting, the latter of which also cuts the 162 ka Elephant Back lava flow. We infer that faulting in the SCD well postdates eruption and that the SCD instead represents a domical accumulation of ignimbrite, not a resurgent structure. The abundance of recycled materials (and absence of Absaroka country rocks) in the SCD ignimbrites implies that vent locations were well inboard of the mapped caldera boundary, with some potentially along the line of the Yellowstone River, requiring a revision of the currently accepted LCT caldera outline. The LCT eruptive events were thus far more complex than currently recognized, with multiple deposits fed from multiple magma bodies over a time scale that cannot be resolved by radiometric dating.

Wyoming↗

Dismembering the Lava Creek Tuff, Yellowstone volcano

The youngest large explosive eruption of Yellowstone volcano generated the 0.63 Ma Lava Creek Tuff (LCT) ignimbrite and a voluminous, widespread fall deposit accompanying formation of Yellowstone Caldera. The tuff is conventionally divided into members A (LCT-A) and B (LCT-B), defined by a reversal in density/welding profiles and the presence of phenocrystic amphibole in LCT-A. Remapping within the northeastern caldera sector has, however, documented multiple ignimbrites that yield LCT eruption ages but are distinct from documented members A and B. Thus, the framework by which the LCT was originally subdivided is re-examined here using field observations, petrologic analyses, and sanidine geochemistry from LCT-A and LCT-B ignimbrite (as previously mapped) at reference localities around the caldera. Mineral modal abundances in both LCT-A and LCT-B outcrops are dominated by quartz, followed by sanidine, with sizes and abundances that generally increase up-section, as previously documented. Amphibole is found by us, however, only in western and southern sectors, in deposits mapped as both LCT-A and LCT-B, and only as a trace phase. Further, a locality reported as LCT-A with amphibole present yields a sanidine 40 Ar/ 39 Ar date of 0.775 ± 0.002 Ma, precluding any LCT correlation. Ignimbrite samples from mapped LCT-A and LCT-B exhibit variable crystal sizes, sanidine cathodoluminescence image populations and Ba concentrations, with no clear distinction between the mapped members. Collectively this research found no evidence for a definable LCT-A versus LCT-B, meaning that the traditional A and B subdivision does not accurately represent the eruptive architecture of the Lava Creek Tuff and warrants revision.

Idaho, Montana, Wyoming↗

Variable partitioning of lithium in rhyolitic melt during decompression and ascent

The partitioning behavior of Li in magmatic systems is increasingly being investigated due to the economic importance of Li in the transition to sustainable energy resources (e.g., batteries). However, at upper crustal pressures, it remains uncertain whether Li preferentially partitions into the vapor or liquid (brine) phase or remains in the silicate melt. This complicates our ability to determine where Li resides—silicate melt, minerals, or fluid phase—upon eruption, a crucial factor for understanding its postdepositional movement and concentration into a brine or volcano-sedimentary deposit. Here, we present a novel investigation into the behavior of Li within natural evolved melts during continuous magma decompression and ascent using melt embayments (open melt inclusions). Mineral-hosted melt embayments preserve records of the evolving composition of the exterior melt, including degassing pathways and ascent timescales, when paired with appropriate diffusion coefficients. Lithium concentration profiles were measured in quartz-hosted melt embayments from the rapidly quenched eruptive phases of five rhyolitic, caldera-forming eruptions to investigate the behavior of Li during magma decompression and ascent, where vapor partitioning and ascent dynamics were previously established by investigating H 2 O and CO 2 profiles. We find that in four systems, embayments contain lower interior Li concentrations than the coerupted melt inclusions; the fifth system contains the same Li concentrations in embayments and melt inclusions. However, many of these embayments contain gradients, with 84 % preserving Li enrichment near the melt-bubble interface, as compared to their interior concentration. We interpret these characteristics to represent two distinct stages of Li partitioning during magma decompression and ascent, in contrast to existing literature that proposes only one type of partitioning behavior. The first stage is interpreted as melt depletion of Li, likely driven by partitioning into an exsolved supercritical fluid phase, supported by the strong correlation between the extent of Li depletion and Cl concentration in the melt, as well as the decompression rate. This behavior then fundamentally shifts, where Li reenriches in the melt, postulated to be driven by the unmixing of the supercritical fluid phase at shallow pressures. For the one system that did not develop Li gradients through decompression, we attribute this to the lower values of Na and Cl in the melt, potentially inhibiting the partitioning of Li into a fluid phase. Importantly, the behavior of Li during decompression is not consistent within or between volcanic centers, highlighting the need for systematic experimental investigation in variable composition melts at pressures relevant to conduit dynamics. This knowledge would improve our ability to model Li profiles to understand magma decompression, and predict where Li resides (e.g., stored in volcanic glass, gas, or crystals) upon eruption prior to any later extraction.

Economic Geology↗

Pre- and post-eruptive geochemical and isotopic fingerprints of rhyolites parental to volcano-sedimentary lithium brine and clay resources in the western USA & central Andes

Lithium is a high-demand, critical element used not only in lightweight rechargeable lithium-ion batteries, but also in nuclear applications and industries producing ceramics, aluminum, and medical products. It is extracted primarily from pegmatites and volcano-sedimentary brines and clays in arid, closed lacustrine or caldera basins. Lithium brines of the central Andean salars in the AltiplanoPuna Plateau contain around ~70% of the world’s lithium resources. In contrast, Clayton Valley, Nevada is the only current producer of lithium brines in the United States and accounts for ~6% of current global lithium production. Clayton Valley hosts a newly defined Li-clay resource where locally exposed rhyolite tuffs have been proposed as a lithium source. Identifying magma evolution processes and determining the importance of syn- and post-eruptive processes on the source, mobility, and distribution of lithium is an ongoing area of research. These two regions illustrate distinctive magmatic-tectonic regimes for volcano-sedimentary lithium enrichment and therefore represent ideal regions to explore the key geological processes critical to the enrichment of lithium resources.

Clayton Valley, Puna Plateau↗

Outgassing through magmatic fractures enables effusive eruption of silicic magma

Several mechanisms have been proposed to allow highly viscous silicic magma to outgas efficiently enough to erupt effusively. There is increasing evidence that challenges the classic foam-collapse model in which gas escapes through permeable bubble networks, and instead suggests that magmatic fracturing and/or accompanying localized fragmentation and welding within the conduit play an important role in outgassing. The 2011–2012 eruption at Cordón Caulle volcano, Chile, provides direct observations of the role of magmatic fractures. This eruption exhibited a months-long hybrid phase, in which rhyolitic lava extrusion was accompanied by vigorous gas-and-tephra venting through fractures in the lava dome surface. Some of these fractures were preserved as tuffisites (tephra-filled veins) in erupted lava and bombs. We integrate constraints from petrologic analyses of erupted products and video analyses of gas-and-tephra venting to construct a model for magma ascent in a conduit. The one-dimensional, two-phase, steady-state model considers outgassing through deforming permeable bubble networks, magmatic fractures, and adjacent wall rock. Simulations for a range of plausible magma ascent conditions indicate that the eruption of low-porosity lava observed at Cordón Caulle volcano occurs because of significant gas flux through fracture networks in the upper conduit. This modeling emphasizes the important role that outgassing through magmatic fractures plays in sustaining effusive or hybrid eruptions of silicic magma and in facilitating explosive-effusive transitions.

Puyehue Cordon Caulle volcanic complex↗