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M.R. Perfit

Publications and source records attributed to M.R. Perfit.

6 recordsLinked to original sources

Dacite petrogenesis on mid-ocean ridges: Evidence for oceanic crustal melting and assimilation

Whereas the majority of eruptions at oceanic spreading centers produce lavas with relatively homogeneous mid-ocean ridge basalt (MORB) compositions, the formation of tholeiitic andesites and dacites at mid-ocean ridges (MORs) is a petrological enigma. Eruptions of MOR high-silica lavas are typically associated with ridge discontinuities and have produced regionally significant volumes of lava. Andesites and dacites have been observed and sampled at several locations along the global MOR system; these include propagating ridge tips at ridge-transform intersections on the Juan de Fuca Ridge and eastern Gal??pagos spreading center, and at the 9??N overlapping spreading center on the East Pacific Rise. Despite the formation of these lavas at various ridges, MOR dacites show remarkably similar major element trends and incompatible trace element enrichments, suggesting that similar processes are controlling their chemistry. Although most geochemical variability in MOR basalts is consistent with low-pressure fractional crystallization of various mantle-derived parental melts, our geochemical data for MOR dacitic glasses suggest that contamination from a seawater-altered component is important in their petrogenesis. MOR dacites are characterized by elevated U, Th, Zr, and Hf, low Nb and Ta concentrations relative to rare earth elements (REE), and Al2O3, K2O, and Cl concentrations that are higher than expected from low-pressure fractional crystallization alone. Petrological modeling of MOR dacites suggests that partial melting and assimilation are both integral to their petrogenesis. Extensive fractional crystallization of a MORB parent combined with partial melting and assimilation of amphibole-bearing altered crust produces a magma with a geochemical signature similar to a MOR dacite. This supports the hypothesis that crustal assimilation is an important process in the formation of highly evolved MOR lavas and may be significant in the generation of evolved MORB in general. Additionally, these processes are likely to be more common in regions of episodic magma supply and enhanced magma-crust interaction such as at the ends of ridge segments. ?? The Author 2010. Published by Oxford University Press. All rights reserved.

Journal of Petrology

Channelized lava flows at the East Pacific Rise crest 9°-10°N: the importance of off-axis lava transport in developing the architecture of young oceanic crust

Submarine lava flows are the building blocks of young oceanic crust. Lava erupted at the ridge axis is transported across the ridge crest in a manner dictated by the rheology of the lava, the characteristics of the eruption, and the topography it encounters. The resulting lava flows can vary dramatically in form and consequently in their impact on the physical characteristics of the seafloor and the architecture of the upper 50–500 m of the oceanic crust. We have mapped and measured numerous submarine channelized lava flows at the East Pacific Rise (EPR) crest 9°–10°N that reflect the high-effusion-rate and high-flow-velocity end-member of lava eruption and transport at mid-ocean ridges. Channel systems composed of identifiable segments 50–1000 m in length extend up to 3 km from the axial summit trough (AST) and have widths of 10–50 m and depths of 2–3 m. Samples collected within the channels are N-MORB with Mg# indicating eruption from the AST. We produce detailed maps of lava surface morphology across the channel surface from mosaics of digital images that show lineated or flat sheets at the channel center bounded by brecciated lava at the channel margins. Modeled velocity profiles across the channel surface allow us to determine flux through the channels from 0.4 to 4.7 × 10 3 m 3 /s, and modeled shear rates help explain the surface morphology variation. We suggest that channelized lava flows are a primary mechanism by which lava accumulates in the off-axis region (1–3 km) and produces the layer 2A thickening that is observed at fast and superfast spreading ridges. In addition, the rapid, high-volume-flux eruptions necessary to produce channelized flows may act as an indicator of the local magma budget along the EPR. We find that high concentrations of channelized lava flows correlate with local, across-axis ridge morphology indicative of an elevated magma budget. Additionally, in locations where channelized flows are located dominantly to the east or west of the AST, the ridge crest is asymmetric, and layer 2A appears to thicken over a greater distance from the AST toward the side of the ridge crest where the channels are located.

Geochemistry, Geophysics, Geosystems

Interaction of sea water and lava during submarine eruptions at mid-ocean ridges

Lava erupts into cold sea water on the ocean floor at mid-ocean ridges (at depths of 2,500 m and greater), and the resulting flows make up the upper part of the global oceanic crust. Interactions between heated sea water and molten basaltic lava could exert significant control on the dynamics of lava flows and on their chemistry. But it has been thought that heating sea water at pressures of several hundred bars cannot produce significant amounts of vapour and that a thick crust of chilled glass on the exterior of lava flows minimizes the interaction of lava with sea water. Here we present evidence to the contrary, and show that bubbles of vaporized sea water often rise through the base of lava flows and collect beneath the chilled upper crust. These bubbles of steam at magmatic temperatures may interact both chemically and physically with flowing lava, which could influence our understanding of deep-sea volcanic processes and oceanic crustal construction more generally. We infer that vapour formation plays an important role in creating the collapse features that characterize much of the upper oceanic crust and may accordingly contribute to the measured low seismic velocities in this layer.

Nature

Recent volcanism in the Siqueiros transform fault: Picritic basalts and implications for MORB magma genesis

Small constructional volcanic landforms and very fresh-looking lava flows are present along one of the inferred active strike-slip faults that connect two small spreading centers (A and B) in the western portion of the Siqueiros transform domain. The most primitive lavas (picritic and olivine-phyric basalts), exclusively recovered from the young-looking flows within the A-B strike-slip fault, contain millimeter-sized olivine phenocrysts (up to 20 modal%) that have a limited compositional range (Fo91.5-Fo89.5) and complexly zoned Cr-Al spinels. High-MgO (9.5-10.6 wt%) glasses sampled from the young lava flows contain 1-7% olivine phenocrysts (Fo90.5-Fo89) that could have formed by equilibrium crystallization from basaltic melts with Mg# values between 71 and 74. These high MgO (and high Al2O3) glasses may be near-primary melts from incompatible-element depleted oceanic mantle and little modified by crustal mixing and/or fractionation processes. Phase chemistry and major element systematics indicate that the picritic basalts are not primary liquids and formed by the accumulation of olivine and minor spinel from high-MgO melts (10% < MgO < 14%). Compared to typical N-MORB from the East Pacific Rise, the Siqueiros lavas are more primitive and depleted in incompatible elements. Phase equilibria calculations and comparisons with experimental data and trace element modeling support this hypothesis. They indicate such primary mid-ocean ridge basalt magmas formed by 10-18% accumulative decompression melting in the spinel peridotite field (but small amounts of melting in the garnet peridotite field are not precluded). The compositional variations of the primitive magmas may result from the accumulation of different small batch melt fractions from a polybaric melting column.

Earth and Planetary Science Letters

Hydrothermal alteration in oceanic ridge volcanics: A detailed study at the Galapagos Fossil Hydrothermal Field

The Galapagos Fossil Hydrothermal Field is composed of altered oceanic crust and extinct hydrothermal vents within the eastern Galapagos Rift between 85°49′W and 85°55′W. The discharge zone of the hydrothermal system is revealed along scarps, thus providing an opportunity to examine the uppermost mineralized, and highly altered interior parts of the crust. Altered rocks collected in situ by the submersible ALVIN show complex concentric alteration zones. Microsamples of individual zones have been analysed for major/minor, trace elements, and strontium isotopes in order to describe the complex compositional details of the hydrothermal alteration. Interlayered chlorite-smectite and chlorite with disequilibrium compositions dominate the secondary mineralogy as replacement phases of primary glass and acicular pyroxene. Phenocrysts and matrix grains of plagioclase are unaffected during alteration. Using a modification of the Gresens' equation we demonstrate that the trivalent rare earth elements (REEs) are relatively immobile, and calculate degrees of enrichment and depletion in other elements. Strontium isotopic ratios increase as Sr concentrations decrease from least-altered cores to most-altered rims and cross-cutting veins in individual samples, and can be modeled by open system behaviour under low fluid-rock ratio (< 10) conditions following a period of lower-temperature weathering of volcanics within the rift zone. The complex patterns of element enrichment and depletion and strontium isotope variations indicate mixing between pristine seawater and ascending hot fluids to produce a compositional spectrum of fluids. The precipitation of base-metal sulfides beneath the seafloor is probably a result of fluid mixing and cooling. If, as suggested here, the discharge zone alteration occurred under relatively low fluid-rock ratios, then this shallow region must play an important role in determining the exit composition of vent fluids in marine hydrothermal systems.

Geochimica et Cosmochimica Acta

Volcanic eruption of the mid-ocean ridge along the East Pacific Rise crest at 9°45-52'N: direct submersible observations of seafloor phenomena associated with an eruption event in April, 1991

In April, 1991, we witnessed from the submersible Alvin a suite of previously undocumented seafloor phenomena accompanying an in-progress eruption of the mid-ocean ridge on the East Pacific Rise crest at 9&deg;45&prime;N&ndash;52&prime;N. The volume of the eruption could not be precisely determined, although comparison of pre- and post-eruption SeaBeam bathymetry indicate that any changes in ridge crest morphology resulting from the eruption were < 10 m high. Effects of the eruption included: (1) increased abundance and redistribution of hydrothermal vents, disappearance of numerous vent communities, and changes in characteristics of vent fauna and mineral deposits within the eruption area since December, 1989; (2) murkiness of bottom waters up to tens of meters above the seafloor due to high densities of suspended mineral and biogenic particulates; (3) destruction of a vent community by lava flows, mass wasting, and possible hydrovolcanic explosion at a site known as &lsquo;Tubeworm Barbecue&rsquo; in the axial summit caldera (ASC) at 9&deg;50.6&prime;N; (4) near-critical temperatures of hydrothermal vent fluids, ranging up to 403&deg;C; (5) temporal variations over a 2 week interval in both temperatures and chemical/isotopic compositions of hydrothermal fluids; (6) unusual compositions of end-member vent fluids, with pH values ranging to a record low of 2.5, salinities ranging as low as 0.3 wt% NaCl (one-twelfth that of seawater), and dissolved gases reaching high concentrations (> 65 mmol/l for both CO 2 and H 2 S); (7) venting at temperatures above 380&deg;C of visually detectable white vapor that transformed to plumes of gray smoke a few centimeters above vent orifices; (8) disorganized venting of both high-temperature fluids (black and gray smoke) and large volumes of cooler, diffuse hydrothermal fluids directly from the basaltic seafloor, rather than from hydrothermal mineral constructions; (9) rapid and extensive growth of flocculent white bacterial mats (species unknown) on and under the seafloor in areas experiencing widespread venting of diffuse hydrothermal fluid; and (10) subseafloor downslope migration of magma normal to the ridge axis in a network of small-scale (1&ndash;5 m diameter) lava tubes and channels to distances at least 100&ndash;200 m outside the ASC. We suggest that, in April, 1991, intrusion of dikes in the eruption area to < 200 m beneath the ASC floor resulted in phase separation of fluids near the tops of the dikes and a large flux of vapor-rich hydrothermal fluids through the overlying rubbly, cavernous lavas. Low salinities and gas-rich compositions of hydrothermal fluids sampled in the eruption area are appropriate for a vapor phase in a seawater system undergoing subcritical liquid-vapor phase separation (boiling) and phase segregation. Hydrothermal fluids streamed directly from fissures and pits that may have been loci of lava drainback and/or hydrovolcanic explosions. These fissures and pits were lined with white mats of a unique fast-growing bacteria that was the only life associated with the brand-new vents. The prolific bacteria, which covered thousands of square meters on the ridge crest and were also abundant in subseafloor voids, may thrive on high levels of gases in the vapor-rich hydrothermal fluids initially escaping the hydrothermal system. White bacterial particulates swept from the seafloor by hydrothermal vents swirled in an unprecedented biogenic &lsquo;blizzard&rsquo; up to 50 m above the bottom. The bacterial proliferation of April, 1991 is likely to be a transient bloom that will be checked quickly either by decline of dissolved gas concentrations in the fluids as rapid heat loss brings about cessation of boiling, and/or by grazing as other organisms are re-established in the biologically devastated area.

Earth and Planetary Science Letters