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Geology topics

M.K. Landon

Publications and source records attributed to M.K. Landon.

At least 19 recordsLinked to original sources
USGS2011

Modeling the potential impact of seasonal and inactive multi-aquifer wells on contaminant movement to public water-supply wells

Wells screened across multiple aquifers can provide pathways for the movement of surprisingly large volumes of groundwater to confined aquifers used for public water supply (PWS). Using a simple numerical model, we examine the impact of several pumping scenarios on leakage from an unconfined aquifer to a confined aquifer and conclude that a single inactive multi-aquifer well can contribute nearly 10% of total PWS well flow over a wide range of pumping rates. This leakage can occur even when the multi-aquifer well is more than a kilometer from the PWS well. The contribution from multi-aquifer wells may be greater under conditions where seasonal pumping (e.g., irrigation) creates large, widespread downward hydraulic gradients between aquifers. Under those conditions, water can continue to leak down a multi-aquifer well from an unconfined aquifer to a confined aquifer even when those multi-aquifer wells are actively pumped. An important implication is that, if an unconfined aquifer is contaminated, multi-aquifer wells can increase the vulnerability of a confined-aquifer PWS well.

Journal of the American Water Resources Associatio↗
USGS2008

Source and transport controls on the movement of nitrate to public supply wells in selected principal aquifers of the United States

In 2003–2005, systematic studies in four contrasting hydrogeologic settings were undertaken to improve understanding of source and transport controls on nitrate movement to public supply wells (PSW) in principal aquifers of the United States. Chemical, isotopic, and age tracer data show that agricultural fertilizers and urban septic leachate were the primary sources of large nitrate concentrations in PSW capture zones at Modesto, California (Central Valley aquifer system) and York, Nebraska (High Plains aquifer). Urban septic leachate and fertilizer (possibly nonfarm) were the primary sources of large nitrate concentrations in PSW capture zones at Woodbury, Connecticut (glacial aquifer system), and Tampa, Florida (Floridan aquifer system), respectively. Nitrate fluxes to the water table were larger in agricultural settings than urban settings, indicating that it would be beneficial to reduce PSW capture zone areas in agricultural regions. Mixing calculations indicate that about 50 to 85% of the nitrate in water from the PSW could be from those modern anthropogenic sources, with the remainder coming from sources in old (>50 years) recharge or sources in young recharge in undisturbed settings such as forests. Excess N 2 concentrations and age tracers showed that denitrification at Modesto occurred gradually (first‐order rate constant of 0.02/a) in a thick reaction zone following a ∼30‐year lag time after recharge. Denitrification generally was not an important nitrate sink at Woodbury. At York and Tampa, denitrification occurred rapidly (0.5 to 6/a) in thin reaction zones in fine‐grained sediments that separated the anoxic PSW producing zones from overlying oxic, high‐nitrate ground water. Particle tracking showed that a major pathway by which anthropogenic nitrate reached the York and Tampa PSW was by movement through long well screens crossing multiple hydrogeologic units (York) and by movement through karst features (Tampa), processes which reduced ground water residence times in the denitrifying zones. These results illustrate how PSW vulnerability to nitrate contamination depends on complex variations and interactions between contaminant sources, reaction rates, transit times, mixing, and perturbation of ground water flow in contrasting hydrogeologic settings.

Water Resources Research↗
USGS2008

Low-Level detections of halogenated volatile organic compounds in groundwater: Use in vulnerability assessments

Concentrations of halogenated volatile organic compounds (VOCs) were determined by gas chromatography (GC) with an electron-capture detector (GC-ECD) and by gas chromatography with mass spectrometry (GC-MS) in 109 groundwater samples from five study areas in the United States. In each case, the untreated water sample was used for drinking-water purposes or was from a monitoring well in an area near a drinking-water source. The minimum detection levels (MDLs) for 25 VOCs that were identified in GC-ECD chromatograms, typically, were two to more than four orders of magnitude below the GC-MS MDLs. At least six halogenated VOCs were detected in all of the water samples analyzed by GC-ECD, although one or more VOCs were detected in only 43% of the water samples analyzed by GC-MS. In nearly all of the samples, VOC concentrations were very low and presented no known health risk. Most of the low-level VOC detections indicated post-1940s recharge, or mixtures of recharge that contained a fraction of post-1940s water. Concentrations of selected halogenated VOCs in groundwater from natural and anthropogenic atmospheric sources were estimated and used to recognize water samples that are being impacted by nonatmospheric sources. A classification is presented to perform vulnerability assessments at the scale of individual wells using the number of halogenated VOC detections and total dissolved VOC concentrations in samples of untreated drinking water. The low-level VOC detections are useful in vulnerability assessments, particularly for samples in which no VOCs are detected by GC-MS analysis.

Journal of Hydrologic Engineering↗
USGS2007

Effects of topography and soil properties on recharge at two sites in an agricultural field

Field experiments were conducted from 1992 to 1995 to estimate ground water recharge rates at two sites located within a 2.7-hectare agricultural field. The field lies in a sand plain setting in central Minnesota and is cropped continuously in field corn. The sites are located at a topographically high (upland) site and a topographically low (lowland) site in an effort to quantify the effects of depression focusing of recharge. Three site-specific methods were used to estimate recharge rates: well hydrograph analysis, chlorofluorocarbon age dating, and an unsaturated zone water balance. All three recharge methods indicated that recharge rates at the lowland site (annual average of all methods of 29 cm) exceeded those at the upland site (annual average of 18 cm). On an annual basis, estimates by the individual methods ranged from 12 to 44 percent of precipitation at the upland site and from 21 to 83 percent at the lowland site. The difference in recharge rates between the sites is primarily attributed to depression focusing of surface water runon at the lowland site. However, two other factors were also important: the presence of thin lamellae at the upland site, and coarser textured soils below a depth of 1.5 m at the lowland site.

Minnesota↗
USGS2005

Comparison of instream methods for measuring hydraulic conductivity in sandy streambeds

Streambed hydraulic conductivity (K) values were determined at seven stream transects in the Platte River Basin in Nebraska using different instream measurement techniques. Values were compared to determine the most appropriate technique(s) for use in sandy streambeds. Values of K determined from field falling‐ and constant‐head permeameter tests analyzed using the Darcy equation decreased as permeameter diameter increased. Seepage meters coupled with hydraulic gradient measurements failed to yield K values in 40% of the trials. Consequently, Darcy permeameter and seepage meter tests were not preferred approaches. In the upper 0.25 m of the streambed, field falling‐ and constant‐head permeameter tests analyzed with the Hvorslev solution generally had similar K values that were significantly greater than those determined using the Hazen grain‐size, Bouwer and Rice slug test for anisotropic and isotropic conditions, and Alyamani and Sen grain‐size methods; median differences between these tests and the Hvorslev falling‐head 60 cm diameter permeameter were about 8, 9, 17, and 35 m/day, respectively. The Hvorslev falling‐head permeameter test is considered the most robust method for measuring K of the upper 0.25 m of the streambed because of the inherent limitations of the empirical grain‐size methods and less sediment disturbance for permeameter than slug tests. However, lateral variability in K along transects on the Platte, North Platte, and Wood Rivers was greater than variability in K between valid permeameter, grain‐size, or slug tests, indicating that the method used may matter less than making enough measurements to characterize spatial variability adequately. At the Platte River tributary sites, the upper 0.3 m of the streambed typically had greater K than sediment located 0.3 to 2.5 m below the streambed surface, indicating that deposits below the streambed may limit ground water/surface water fluxes. The Hvorslev permeameter tests are not a practical measurement approach for these greater depths. Thus, selection of a method for measuring streambed K needs to consider the vertical location of the sediments that are most likely to limit the rate of ground water/surface water interaction.

Ground Water↗
USGS2005

Multiport well design for sampling of ground water at closely spaced vertical intervals

Detailed vertical sampling is useful in aquifers where vertical mixing is limited and steep vertical gradients in chemical concentrations are expected. Samples can be collected at closely spaced vertical intervals from nested wells with short screened intervals. However, this approach may not be appropriate in all situations. An easy-to-construct and easy-to-install multiport sampling well to collect ground-water samples from closely spaced vertical intervals was developed and tested. The multiport sampling well was designed to sample ground water from surficial sand-and-gravel aquifers. The device consists of multiple stainless-steel tubes within a polyvinyl chloride (PVC) protective casing. The tubes protrude through the wall of the PVC casing at the desired sampling depths. A peristaltic pump is used to collect ground-water samples from the sampling ports. The difference in hydraulic head between any two sampling ports can be measured with a vacuum pump and a modified manometer. The usefulness and versatility of this multiport well design was demonstrated at an agricultural research site near Princeton, Minnesota where sampling ports were installed to a maximum depth of about 12 m below land surface. Tracer experiments were conducted using potassium bromide to document the degree to which short-circuiting occurred between sampling ports. Samples were successfully collected for analysis of major cations and anions, nutrients, selected herbicides, isotopes, dissolved gases, and chlorofluorcarbon concentrations.

Minnesota↗
USGS2005

Relation of pathways and transit times of recharge water to nitrate concentrations using stable isotopes

Oxygen and hydrogen stable isotope values of precipitation, irrigation water, soil water, and ground water were used with soil-moisture contents and water levels to estimate transit times and pathways of recharge water in the unsaturated zone of a sand and gravel aquifer. Nitrate-nitrogen (nitrate) concentrations in ground water were also measured to assess their relation to seasonal recharge. Stable isotope values indicated that recharge water usually had a transit time through the unsaturated zone of several weeks to months. However, wetting fronts usually moved through the unsaturated zone in hours to weeks. The much slower transit of isotopic signals than that of wetting fronts indicates that recharge was predominantly composed of older soil water that was displaced downward by more recent infiltrating water. Comparison of observed and simulated isotopic values from pure-piston flow and mixing-cell water and isotope mass balance models indicates that soil water isotopic values were usually highly mixed. Thus, movement of recharge water did not occur following a pure piston-flow displacement model but rather follows a hydrid model involving displacement of mixed older soil water with new infiltration water. An exception to this model occurred in a topographic depression, where movement of water along preferential flowpaths to the water table occurred within hours to days following spring thaw as result of depression-focused infiltration of snow melt. In an adjacent upland area, recharge of snow melt occurred one to two months later. Increases in nitrate concentrations at the water table during April-May 1993 and 1994 in a topographic lowland within a corn field were related to recharge of water that had infiltrated the previous summer and was displaced from the unsaturated zone by spring infiltration. Increases in nitrate concentrations also occurred during July-August 1994 in response to recharge of water that infiltrated during May-August 1994. These results indicate that the largest ground water nitrate concentrations were associated with recharge of water that infiltrated into the soil during May-August, when most nitrogen fertilizer was applied.

Ground Water↗
USGS2002

Effects of topography on the transport of agricultural chemicals to groundwater in a sand-plain setting

Geochemical data were collected to investigate the effects of topography and focused recharge on the transport of agricultural chemicals to groundwater through sandy soils. The research was done at a topographically high (upland) site and a depressional (lowland) site within a corn field. Agricultural chemicals that move readily with water were most directly affected by focused recharge to the lowland site. Surface runoff of water to the lowland site was the primary cause for the generally greater flux of chloride, nitrate nitrogen, and sulfate compared with the upland site. Based on data from the unsaturated zone, for example, the average annual fluxes of these chemicals in 1992–1993 were 5.1, 3.4, and 1.7 times greater, respectively, at the lowland site. Study results indicate that consideration should be given to modifying site-specific management farming technology to account for varying recharge rates in different topographic settings. By reducing chemical application rates in topographic depressions, where focused recharge of chemicals occurs because of surface runoff, farmers could improve ground-water quality as well as reduce expenditures for agricultural chemicals.

Minnesota↗
USGS2002

Effects of surface run-off on the transport of agricultural chemicals to ground water in a sandplain setting

An experiment was conducted at a depressional (lowland) and an upland site in sandy soils to evaluate the effects of surface run-off on the transport of agricultural chemicals to ground water. Approximately 16.5 cm of water was applied to both sites during the experiment, representing a natural precipitation event with a recurrence interval of approximately 100 years. Run-off was quantified at the lowland site and was not detected at the upland site during the experiment. Run-off of water to the lowland site was the most important factor affecting differences in the concentrations and fluxes of the agricultural chemicals between the two sites. Run-off of water to the lowland site appears to have played a dual role by diluting chemical concentrations in the unsaturated zone as well as increasing the concentrations at the water table, compared to the upland site. Concentrations of chloride, nitrate and atrazine plus metabolites were noticeably greater at the water table than in the unsaturated zone at both sites. The estimated mass flux of chloride and nitrate to the water table during the test were 5–2 times greater, respectively, at the lowland site compared to the upland site, whereas the flux of sulfate and atrazine plus metabolites was slightly greater at the upland site. Results indicate that matrix flow of water and chemicals was the primary process causing the observed differences between the two sites. Results of the experiment illustrate the effects of heterogeneity and the complexity of evaluating chemical transport through the unsaturated zone.

Science of the Total Environment↗
USGS2000

Effects of ground-water withdrawals on the Rock River and associated valley aquifer, eastern Rock County, Minnesota

A better understanding of the ground-water and surface-water resources of the Rock River Valley in southwestern Minnesota was needed due to concerns surrounding future reliable sources of water for public supply. The Rock River Valley aquifer consists of a surficial sand and gravel unit that underlies the entire Rock River Valley and a buried sand and gravel unit that is present only in the vicinity of the Luverne Municipal and Airport well fields. The surficial and buried units of the aquifer are separated by a clay and till layer ranging in thickness from 1 to 38 feet. The combined maximum saturated thickness of the aquifer is 52 feet, with a median of 22 feet. The thickness of the buried unit ranges from 3 to 17 feet. Recharge to the Rock River Valley aquifer occurs primarily by infiltration of precipitation to the saturated zone (areal recharge) and by induced infiltration from the Rock River due to withdrawals from supply wells near the river. Discharge from the aquifer occurs primarily as leakage to streams and ground-water evapotranspiration. The water budget for the calibrated steady-state simulation indicated that areal recharge accounts for 38 percent of the sources of water to the Rock River Valley aquifer and leakage from streams contributes 58.7 percent. The largest discharge from the aquifer is leakage to streams, (71.1 percent). The net stream-aquifer leakage is approximately 5 cubic feet per second from the aquifer to the streams. The simulated contributing areas for the wells in the three well fields generally extend to the aquifer boundaries on the west and are generally truncated at the Rock River. The simulated transient water budget for 1996 indicated that the principal sources of water to the aquifer were as follows: (1) winter, spring, and late summer stress periods— leakage from streams and water released from storage and (2) early summer and fall stress periods—areal recharge and leakage from streams. The principal discharges from the aquifer were leakage to streams for all stress periods, ground-water evapotranspiration for the early and late summer stress periods, and addition to storage for the early summer and fall stress periods. The herbicides atrazine, alachlor, metolachlor, acetachlor, and cyanazine, and metabolites of these herbicides, occurred in concentrations of 0.05 to 11.5 micrograms per liter in the Rock River at Luverne during major runoff events following application of herbicides in the spring. Atrazine and metabolites, alachlor ESA (a metabolite of alachlor), metolachlor and metabolites, metolachlor ESA and metolachlor OA, and acetochlor metabolites acetochlor ESA and acetochlor OA, were detected at concentrations of 0.05 to 2.8 micrograms per liter in municipal supply wells less than 500 feet from the river during November 1995 through August 1997. The Rock River is the major source of the herbicides and metabolites. However, concentrations of atrazine and metabolites, alachlor ESA, metolachlor ESA, and metolachlor OA in supply wells may also reflect sources of these herbicides and metabolites in the ground-water contributing areas to the supply wells. Nitrite plus nitrate nitrogen concentrations in supply wells and in the ground-water contributing area to the Luverne Municipal well field were generally less than 1.5 milligrams per liter. Nitrite plus nitrate nitrogen concentrations of 2.4 to 8.5 milligrams per liter in the Rock River in the Rock County Rural Water well field and 14 to 18 milligrams per liter in the ground-water contributing area to the Rock County Rural Water supply wells are not having a substantial affect on nitrite plus nitrate nitrogen concentrations in most supply wells. Isotopic mixing calculations indicate that proportions of river water withdrawn from supply wells less than 500 feet from the river range from 5 to 60 percent of total withdrawals. The Rock River is a gaining stream in most reaches, but is losing water to the aquifer in the vicinity of the Luverne Municipal and Rock County Rural Water well fields, located 150 to 1,500 feet from the river. Simulated streamflow losses due to ground-water withdrawals in the well fields were approximately 2.1 cubic feet per second. Because an average of about 1.5 cubic feet per second of the water pumped by Luverne is returned to the Rock River as wastewater discharge, the net steady-state simulated streamflow loss for the study area is 0.6 cubic feet per second. The streamflow losses as a result of ground-water withdrawals are insignificant in comparison to typical streamflow, and are likely to have a measurable effect on streamflow only during low-flow conditions of less than approximately 10 cubic feet per second. Model results indicate that the additional water withdrawn by wells due to anticipated increased ground-water withdrawals was derived from a decrease in net leakage of ground water from the aquifer to the streams. The simulations indicated that the increased ground-water withdrawals and normal precipitation resulted in an increase in induced infiltration from the Rock River of 0.1 cubic feet per second for the Luverne Municipal well field and 0.3 cubic feet per second for the Rock County Rural Water well field. Maximum drawdowns ranged from 0.5 to 1.4 feet near the three well fields. For drought conditions, the simulated streamflow losses constituted approximately 30 percent and nearly 65 percent of the flows in the Rock River for the Luverne Municipal and Rock County Rural Water well fields, respectively. Maximum drawdowns ranged from 3.8 to 7.0 feet near the three well fields. Transient simulations with anticipated increased ground-water withdrawals and drought conditions indicated declines in hydraulic heads ranging from 0.2 to 0.4 feet per year in the vicinity of the three well fields, except for near the Rock River.

Minnesota↗
USGS1999

Comparison of the stable-isotopic composition of soil water collected from suction lysimeters, wick samplers, and cores in a sandy unsaturated zone

Soil water collected from suction lysimeters and wick samplers buried in the unsaturated zone of a sand and gravel aquifer and extracted from soil cores were analyzed for stable oxygen and hydrogen isotope values. Soil water isotopic values differed among the three sampling methods in most cases. However, because each sampling method collected different fractions of the total soil-water reservoir, the isotopic differences indicated that the soil water at a given depth and time was isotopically heterogeneous. This heterogeneity reflects the presence of relatively more and less mobile components of soil water. Isotopic results from three field tests indicated that 95–100% of the water collected from wick samplers was mobile soil water while samples from suction lysimeters and cores were mixtures of more and less mobile soil water. Suction lysimeter samples contained a higher proportion of more mobile water (15–95%) than samples from cores (5–80%) at the same depth. The results of this study indicate that, during infiltration events, soil water collected with wick samplers is more representative of the mobile soil water that is likely to recharge ground water during or soon after the event than soil water from suction lysimeters or cores.

Journal of Hydrology↗
USGS1998

Effects of farming systems on ground-water quality at the management systems evaluation area near Princeton, Minnesota, 1991-95

Ground-water quality in an unconfined sand and gravel aquifer was monitored during 1991-95 at the Minnesota Management Systems Evaluation Area (MSEA) near Princeton, Minnesota. The objectives of the study were to: (1) describe the effects of three farming systems on groundwater quality, and (2) evaluate the factors affecting ground-water quality and transport of agricultural chemicals at the site. Concentrations of nitrate nitrogen (nitrate-N) in the upper 1 meter (m) of the saturated zone were greatest beneath the two cropped areas having a potato-sweet corn annual rotation (median concentrations of 23 and 22 mg/L). Concentrations of nitrate-N were least beneath a cropped area having a field cornsoybean annual rotation (median of 14 mg/L); another cropped area having the field corn-soybean rotation had similar nitrate-N concentrations to those beneath a cropped area having field corn in consecutive years (continuous corn)(medians of 17 mg/L). Concentrations of atrazine plus metabolites de-ethylatrazine (DEA) and de-isopropylatrazine (DIA), atrazine plus metabolites, were significantly greater during 1994-95 than during 1992- 93 beneath all cropped areas in the upper 1 m of the saturated zone. Concentrations of atrazine plus metabolites during 1994-95 were greatest beneath the continuous corn (median of 1.07 ( μ g/L), intermediate beneath one cropped area with the potato-sweet corn rotation (median of 0.37 μ g/L), and least beneath the other cropped area with the potato-sweet corn rotation, the field corn-soybean rotation, and background areas (medians ranging from 0.11 to 0.21 μ g/L), for which concentrations were not significantly different. Concentrations of atrazine plus metabolites during 1992-93 were mostly similar beneath the different cropped areas and background areas. DEA was the predominant atrazine-metabolite detected in ground water; the average DEA to atrazine ratio was 8.0. The herbicides metribuzin, alachlor, and metolachlor were rarely detected in ground water at trace levels and could not be linked to the MSEA farming systems, with the exception of metribuzin detections during 1993-94 at concentrations of 0.14-1.24 ( μ g/L beneath one cropped area where metribuzin was applied to potatoes. Peak concentrations of chloride and bromide tracers were usually detected in the upper 2 m of the saturated zone 11 to 19 months after application. Peak concentrations of nitrate-N and atrazine plus metabolites were usually detected about 13 to 27 months and 2 years after application, respectively. The estimated proportion of applied nitrogen that reached ground water ranged from about 13 to 50 percent with an average of 30 percent. Differences in the concentrations of nitrate-N in ground water between different cropped areas were related to varying nitrogen application rates, timing of nitrogen application, timing of recharge in relation to crop rotation, and differences in nitrogen uptake by crops. In order of importance, plant uptake and leaching to ground water likely account for most of the nitrogen applied. Denitrification likely is an important mechanism affecting nitrate-N concentrations at depths greater than 2 m below the water table. The proportion of applied atrazine in ground water, detected as atrazine or its metabolites, ranged from 0 to about 1 percent with an average of 0.37 percent. The small proportion of applied atrazine detected in ground water indicates that atrazine was predominantly affected by processes occurring in the soil such as adsorption and degradation. Concentrations of atrazine plus metabolites were related to application rates.

Minnesota↗
USGS1997

Hydrogeologic and water-quality data used to evaluate the effects of focused recharge on ground-water quality near Princeton, Minnesota, 1991-95

This study was part of the Management Systems Evaluation Area (MSEA) Program, a multi-scale, inter-agency initiative to evaluate the effects of agricultural systems on water quality in the midwest corn belt. The research was part of the U.S. Geological Survey Toxics Substances Hydrology Program. The research area was located in the Anoka Sand Plain about 5 kilometers southwest of Princeton, Minnesota. This report presents temperature, precipitation, soil-moisture, water-quality, and other data collected during 1991-95 to evaluate the effects of focused recharge on ground-water quality at the Princeton MSEA.

Minnesota↗
USGS1997

Water-quality and hydrogeologic data used to evaluate the effects of farming systems on ground-water quality at the Management Systems Evaluation Area near Princeton, Minnesota, 1991-95

The Minnesota Management Systems Evaluation Area (MSEA) project was part of a multi-scale, inter-agency initiative to evaluate the effects of agricultural management systems on water quality in the midwest corn belt. The research area was located in the Anoka Sand Plain about 5 kilometers southwest of Princeton, Minnesota. The ground-water-quality monitoring network within and immediately surrounding the research area consisted of 73 observation wells and 25 multiport wells. The primary objectives of the ground-water monitoring program at the Minnesota MSEA were to: (1) determine the effects of three farming systems on ground-water quality, and (2) understand the processes and factors affecting the loading, transport, and fate of agricultural chemicals in ground water at the site. This report presents well construction, geologic, water-level, chemical application, water-quality, and quality-assurance data used to evaluate the effects of farming systems on ground-water quality during 1991-95.

Minnesota↗
USGS1995

Ground-water quality in agricultural areas, Anoka Sand Plain Aquifer, east-central Minnesota, 1984-90

Ground-water quality in the Anoka Sand Plain aquifer was studied as part of the multiscale Management Systems Evaluation Area (MSEA) study by collecting water samples from shallow wells during August through November 1990. The sampling was conducted to: (1) aid in selection of the MSEA research area; (2) facilitate comparison of results at the MSEA research area to the regional scale; and (3) evaluate changes in ground-water quality in the Anoka Sand Plain aquifer since a previous study during 1984 through 1987. Samples were collected from 34 wells screened in the upper 6 meters of the surficial aquifer and located in cultivated agricultural areas. Water temperature, pH, specific conductance, and presence or absence of triazine herbicides were determined at all sites and samples from selected wells were analyzed for concentrations of dissolved oxygen, alkalinity, major cations and anions, nutrients, and selected herbicides and herbicide metabolites. The results of the study indicate that the water-quality of some shallow ground water in areas of predominantly agricultural land use has been affected by applications of nitrogen fertilizers and the herbicide atrazine. Concentrations of nitrite plus nitrate nitrogen (nitrate-N) in 19 samples ranged from less than the detection limit of 0.1 to 21 milligrams per liter (mg/L) with a median of 10 mg/L. Concentrations of nitrate-N were not significantly correlated with depth below the water table or dissolved oxygen but were significantly correlated with concentrations of chloride. Concentrations of nitrate-N during 1990 were generally similar to concentrations measured during 1984 through 1987. Changes in concentrations of nitrate-N during 1984 through 1990 were likely related to variations in recharge or other site-specific factors. Immunoassay analyses were used as screening tools to detect the presence of triazine herbicides. All samples in which triazine herbicides were detected by immunoassay, and selected samples in which triazine herbicides were not detected by immunoassay, were analyzed for selected herbicides and herbicide metabolites by gas chromatography/mass spectroscopy (GC/MS). There was an excellent correspondence between concentrations of triazine herbicides indicated by immunoassay and concentrations of atrazine measured by GC/MS, indicating that the immunoassay method was a valuable qualitative to semi-quantitative tool for evaluating the presence and approximate concentration of atrazine. The combined results of immunoassay and GC/MS analyses indicate that atrazine was detected in 11 of the 34 wells with a median concentration less than the immunoassay detection limit of 0.1 micrograms per liter ( μ g/L). Atrazine was detected in 11 of the 17 samples analyzed by GC/MS at concentrations ranging from the detection limit of 0.05 to 0.81 μ g/L with a median of 0.09 μ g/L. Atrazine metabolite de-ethylatrazine (DEA) was the most frequently detected herbicide or herbicide metabolite and generally was present at the greatest concentrations. There were detections of DEA in 13 of the 17 samples analyzed at concentrations ranging from the detection limit of 0.05 to 1.12 μ g/L with a median of 0.15 μ g/L. Concentrations of DEA were significantly correlated with concentrations of calcium, magnesium, and specific conductance. The atrazine metabolite de-isopropylatrazine and the herbicide metolachlor both were detected in 1 of the 17 wells. The frequency of detection and the concentrations of atrazine in shallow ground water during 1990 were very similar to results of sampling conducted in 1984. Concentrations of atrazine and DEA generally were greater near the water table and decreased or were not detected in deeper wells. All of the samples in which atrazine and DEA were detected also had increased (greater than 3 mg/L) nitrate-N concentrations. However, not all samples with increased concentrations of nitrate-N had detections of atrazine or DEA. This likely indicates either that there were sources of nitrate-N other than cultivated fields on which both atrazine and nitrogen were applied or that nitrate-N reached ground water more readily than atrazine or DEA.

Minnesota↗
USGS1995

Effects of 1992 farming systems on ground-water quality at the management systems evaluation area near Princeton, Minnesota

The Management Systems Evaluation Area (MSEA) program was a multiscale, interagency initiative to evaluate the effects of agricultural systems on water quality in the midwest corn belt. The primary objective of the Minnesota MSEA was to evaluate the effects of ridge-tillage practices in a corn and soybean farming system on ground-water quality. The 65-hectare Minnesota MSEA was located in the Anoka Sand Plain near the town of Princeton, Minnesota. Three fanning systems were evaluated: corn-soybean rotation with ridge-tillage (areas B and D), sweet corn-potato rotation (areas A and C), and field corn in consecutive years (continuous corn; area E). Water samples were collected four different times per year from a network of 22 multiport wells and 29 observation wells installed in the saturated zone beneath and adjacent to the cropped areas. Bromide and chloride were used as tracers of water recharged through the cropped areas during 1992. Bromide applied in May 1992 was first detected above background levels between August 1992 and April 1993. Thus, the time of travel of water and bromide moving through the unsaturated zone during 1992 ranged from 3 to 11 months. Chloride applied to area C (sweet corn) in April 1992 was first detected above the residual levels of 1991 chloride applications in April 1993, 12 months after the chemical was applied. Chloride applies to areas A, B, D, and E in April 1992 was not detected above the residual effects from 1991 chloride applications. Nitrogen (N) fertilizer applied in 1992 on area C (potatoes) was first detected above background concentrations and the residual effects of the 1991 farming practices in April 1993, 12 months after application. Effects of 1992 N fertilizer applications on area E (continuous com) generally could not be distinguished from the effects of downgradient of area E were consistently greater than background concentrations during August 1992 through April 1993. These concentrations greater than background levels indicate that some N fertilizer applied to the continuous com crop during 1991 reached the water table. Nitrogen fertilizer applied on areas A, B, and D during 1992 could not be distinguished from the residual effects of the 1991 fanning practices but were detected above background concentrations. Atrazine concentrations beneath the cropped areas were generally indistinguishable from background concentrations. Atrazine was detected in 58 percent of the 361 ground water samples collected beneath cropped and buffer areas during June 1992 through April 1993. Most detections were at trace levels, between the detection limit of 0.01 micrograms per liter ( μ g/L) and the reporting limit of 0.04 μ g/L. De-ethylatrazine (DEA) was detected more frequently during June 1992 through April 1993 (78 percent of the 361 samples) and in greater concentrations than any other herbicide or herbicide metabolite, with a median concentration of 0.07 μ g/L. The maximum DEA concentration of 0.77 μ g/L was detected near the water table in the middle of area E (continuous corn) during April 1993. The likely source of this DEA detection was application of atrazine to area E during 1991-93. Additional data will be needed to conclusively evaluate whether atrazine applied as part of the MSEA farming systems reached the water table. Results indicate that the effects of the 1992 potassium-chloride and N fertilizer applications were reduced compared to the effects of 1991 applications. The most important factors associated with these differences were lower chemical application rates and lower recharge rates during 1992 than during 1991. Some of the chloride and N fertilizer applied to the cropped areas in 1992 likely did not reach the saturated zone in 1993 due to a 60-percent reduction in recharge compared to 1991. Therefore, analysis of data from additional years will be required to fully evaluate the effects of the fanning systems on ground-water quality.

Minnesota↗