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M. Zreda

Publications and source records attributed to M. Zreda.

6 recordsLinked to original sources

Ages and inferred causes of late Pleistocene glaciations on Mauna Kea, Hawai'i

Glacial landforms on Mauna Kea, Hawai'i, show that the summit area of the volcano was covered intermittently by ice caps during the Late Pleistocene. Cosmogen 36Cl dating of terminal moraines and other glacial landforms indicates that the last two ice caps, called Older Makanaka and Younger Makanaka, retreated from their maximum positions approximately 23ka and 13ka, respectively. The margins and equilibrium line altitudes of these ice caps on the remote, tropical Pacific island were nearly identical, which would seem to imply the same mechanism for ice growth. But modelling of glacier mass balance, combined with palaeotemperature proxy data from the subtropical North Pacific, suggests that the causes of the two glacial expansions may have been different. Older Makanaka airatop Mauna Kea was likely wetter than today and cold, whereas Younger Makanaka times were slightly warmer but significantly wetter than the previous glaciation. The modelled increase in precipitation rates atop Mauna Kea during the Late Pleistocene is consistent with that near sea level inferred from pollen data, which suggests that the additional precipitation was due to more frequent and/ or intense tropical storms associated with eastward-moving cold fronts. These conditions were similar to modern La Ni??a (weak ENSO) conditions, but persisted for millennia rather than years. Increased precipitation rates and the resulting steeper temperature lapse rates created glacial conditions atop Mauna Kea in the absence of sufficient cooling at sea level, suggesting that if similar correlations existed elsewhere in the tropics, the precipitation-dependent lapse rates could reconcile the apparent difference between glacial-time cooling of the tropics at low and high altitudes. Copyright ?? 2008 John Wiley & Sons, Ltd.

Journal of Quaternary Science

Chlorine-36 in groundwater of the United States: Empirical data

Natural production of the radionuclide chlorine - 36 ( 36 Cl) has provided a valuable tracer for groundwater studies. The nuclear industry, especially the testing of thermonuclear weapons, has also produced large amounts of 36 Cl that can be detected in many samples of groundwater . In order to be most useful in hydrologic studies, the natural production prior to 1952 should be distinguished from more recent artificial sources. The object of this study was to reconstruct the probable preanthropogenic levels of 36 Cl in groundwater in the United States . Although significant local variations exist, they are superimposed on a broad regional pattern of 36 Cl/Cl ratios in the United States . Owing to the influence of atmospherically transported ocean salt, natural ratios of 36 Cl/total Cl are lowest near the coast and increase to a maximum in the central Rocky Mountains of the United States .

Hydrogeology Journal

The distribution of meteoric 36Cl/Cl in the United States: A comparison of models

The natural distribution of 36Cl/Cl in groundwater across the continental United States has recently been reported by Davis et al. (2003). In this paper, the large-scale processes and atmospheric sources of 36Cl and chloride responsible for controlling the observed 36Cl/Cl distribution are discussed. The dominant process that affects 36Cl/Cl in meteoric groundwater at the continental scale is the fallout of stable chloride from the atmosphere, which is mainly derived from oceanic sources. Atmospheric circulation transports marine chloride to the continental interior, where distance from the coast, topography, and wind patterns define the chloride distribution. The only major deviation from this pattern is observed in northern Utah and southern Idaho where it is inferred that a continental source of chloride exists in the Bonneville Salt Flats, Utah. In contrast to previous studies, the atmospheric flux of 36Cl to the land surface was found to be approximately constant over the United States, without a strong correlation between local 36Cl fallout and annual precipitation. However, the correlation between these variables was significantly improved (R 2=0.15 to R 2=0.55) when data from the southeastern USA, which presumably have lower than average atmospheric 36Cl concentrations, were excluded. The total mean flux of 36Cl over the continental United States and total global mean flux of 36Cl are calculated to be 30.5??7.0 and 19.6??4.5 atoms m-2 s-1, respectively. The 36Cl/Cl distribution calculated by Bentley et al. (1996) underestimates the magnitude and variability observed for the measured 36Cl/Cl distribution across the continental United States. The model proposed by Hainsworth (1994) provides the best overall fit to the observed 36Cl/Cl distribution in this study. A process-oriented model by Phillips (2000) generally overestimates 36Cl/Cl in most parts of the country and has several significant local departures from the empirical data.

Hydrogeology Journal

Chlorine-36, bromide, and the origin of spring water

Natural ratios of chlorine-36 (36Cl) to stable chlorine (i.e., 36Cl/Cl ?? 10-15) vary in shallow groundwater of the United States from about 50 in coastal areas to about 1400 in the northern Rocky Mountains. Ratios lower than these indicate the presence of chloride (Cl-) that has been isolated from the atmosphere for hundreds of thousands of years, if not longer. Higher ratios, which can exceed 5000, usually originate from fallout from testing thermonuclear devices in the western Pacific in the 1950s. Natural mass ratios of chloride to bromide (Cl-/Br-) in precipitation vary in the United States from about 250 in coastal areas to about 50 in the north-central states. Lower ratios may suggest contamination from human sources. Higher ratios, which may exceed 2000, commonly reflect the dissolution of halite. Seawater has a Cl-/Br- ratio of 290. Both 36Cl and Cl-/Br- ratios have been measured in 21 samples of spring water collected from springs in 10 different states. Brackish water from Saratoga Springs area in New York has low values for both 36Cl and Cl-/Br- ratios. This indicates that a large component of the water has a very deep origin. Brackish water from Alexander Springs in Florida has a low 36Cl ratio but a high Cl-/Br- ratio similar to seawater. This suggests the addition of ancient seawater that may be trapped in the aquifer. Big Spring in Iowa discharges water with a very high Cl-/Br- ratio but a moderate 36Cl ratio. The high ratio of Cl-/Br- may be produced by dissolution of road salt or agricultural chemicals. Of the 21 springs sampled, only 10 appeared to have potable water not significantly affected by human activity. Chlorine-36 from testing of nuclear devices is still being flushed out of four of the spring systems that were sampled. Thus, more than 45 years have passed since 36Cl was introduced into the aquifers feeding the springs and the systems, as yet, have not been purged. Published by Elsevier Science B.V.

Chemical Geology

Chlorine-36 and the initial value problem

Chlorine-36 is a radionuclide with a half-life of 3.01×10 5 a. Most 36 Cl in the hydrosphere originates from cosmic radiation interacting with atmospheric gases. Large amounts were also produced by testing thermonuclear devices during 1952–58. Because the monovalent anion, chloride, is the most common form of chlorine found in the hydrosphere and because it is extremely mobile in aqueous systems, analyses of both total Cl – as well as 36 Cl have been important in numerous hydrologic studies. In almost all applications of 36 Cl, a knowledge of the initial, or pre-anthropogenic, levels of 36 Cl is useful, as well as essential in some cases. Standard approaches to the determination of initial values have been to: (a) calculate the theoretical cosmogenic production and fallout, which varies according to latitude; (b) measure 36 Cl in present-day precipitation and assume that anthropogenic components can be neglected; (c) assume that shallow groundwater retains a record of the initial concentration; (d) extract 36 Cl from vertical depth profiles in desert soils; (e) recover 36 Cl from cores of glacial ice; and (f) calculate subsurface production of 36 Cl for water that has been isolated from the atmosphere for more than one million years. The initial value from soil profiles and ice cores is taken as the value that occurs directly below the depth of the easily defined bomb peak. All six methods have serious weaknesses. Complicating factors include 36 Cl concentrations not related to cosmogenic sources, changes in cosmogenic production with time, mixed sources of chloride in groundwater, melting and refreezing of water in glaciers, and seasonal groundwater recharge that does not contain average year-long concentrations of 36 Cl.

Hydrogeology Journal

Dating previously balanced rocks in seismically active parts of California and Nevada

Precariously balanced boulders that could be knocked down by strong earthquake ground motion are found in some seismically active areas of southern California and Nevada. In this study we used two independent surface-exposure dating techniques—rock-varnish microlamination and cosmogenic 36 Cl dating methodologies—to estimate minimum- and maximum-limiting ages, respectively, of the precarious boulders and by inference the elapsed time since the sites were shaken down. The results of the exposure dating indicate that all of the precarious rocks are >10.5 ka and that some may be significantly older. At Victorville and Jacumba, California, these results show that the precarious rocks have not been knocked down for at least 10.5 k.y., a conclusion in apparent conflict with some commonly used probabilistic seismic hazard maps. At Yucca Mountain, Nevada, the ages of the precarious rocks are >10.5 to >27.0 ka, providing an independent measure of the minimum time elapsed since faulting occurred on the Solitario Canyon fault.

Geology