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M. Tatsumoto

Publications and source records attributed to M. Tatsumoto.

At least 19 recordsLinked to original sources
USGS2012

Lu-Hf and Sm-Nd evolution in lunar mare basalts

Lu-Hf and Sm-Nd data for mare basalts combined with Rb-Sr and total REE data taken from the literature suggest that the mare basalts were derived by small (≤10%) degrees of partial melting of cumulate sources, but that the magma ocean from which these sources formed was light REE and Hf-enriched. Calculated source compositions range from lherzolite to olivine websterite. Nonmodal melting of small amounts of ilmenite (≤3%) in the sources seems to be required by the Lu/Hf data. A comparison of the Hf and Nd isotopic characteristics between the mare basalts and terrestrial oceanic basalts reveals that the εHf/εNd ratios in low-Ti mare basalts are much higher than in terrestrial oceanic basalts. The results are qualitatively consistent with the hypothesis that terrestrial basalt sources are partial melt residues whereas mare basalt sources are cumulates. Alternatively, the results may imply that the terrestrial mantle has evolved in two (or more) stages of evolution, and that the net effect was depletion of the mantle during the first ∼1–3 b.y. followed by enrichment during the last 1–2 b.y.; or simply that there is a difference in Lu-Hf crystal-liquid partitioning (relative to Sm-Nd between the lunar and terrestrial mantles.

Journal of Geophysical Research Solid Earth↗
USGS2012

Pb, Sr, and Nd isotopes in seamount basalts from the Juan de Fuca Ridge and Kodiak-Bowie seamount chain, northeast Pacific

Pb, Sr, and Nd isotopic ratios and their parent/daughter element concentrations for 28 basalts from 10 hotspot and nonhotspot seamounts are reported. Nd and Sr isotopic compositions ( 143 Nd/ 144 Nd = 0.51325–0.51304; 87 Sr/ 86 Sr = 0.70237–0.70275) plot in the envelope for Juan de Fuca-Gorda ridge basalts with tholeiitic basalts showing more depleted sources and a better negative correlation than transitional to alkalic basalts. Pb isotopic ratios in tholeiitic and alkalic basalts overlap ( 206 Pb/ 204 Pb = 18.29–19.44) and display a trend toward more radiogenic Pb in alkalic basalts. The isotopic data for hotspot and nonhotspot basalts are indistinguishable and correlate broadly with rock composition, implying that they are controlled by partial melting. The isotopic variation in the seamount basalts is about 60% (Nd-Sr) to 100% (Pb) of that in East Pacific Rise basalts and is interpreted as a lower limit for the magnitude of mantle heterogeneity in the northeast Pacific. The data indicate absence of a chemically distinct plume component in the linear seamount chains and strongly suggest an origin from mid-ocean ridge basalt-like east Pacific mantle.

Journal of Geophysical Research Solid Earth↗
USGS2011

Diel biogeochemical processes and their effect on the aqueous chemistry of streams: A review

This review summarizes biogeochemical processes that operate on diel, or 24-h, time scales in streams and the changes in aqueous chemistry that are associated with these processes. Some biogeochemical processes, such as those producing diel cycles of dissolved O 2 and pH, were the first to be studied, whereas processes producing diel concentration cycles of a broader spectrum of chemical species including dissolved gases, dissolved inorganic and organic carbon, trace elements, nutrients, stable isotopes, and suspended particles have received attention only more recently. Diel biogeochemical cycles are interrelated because the cyclical variations produced by one biogeochemical process commonly affect another. Thus, understanding biogeochemical cycling is essential not only for guiding collection and interpretation of water-quality data but also for geochemical and ecological studies of streams. Expanded knowledge of diel biogeochemical cycling will improve understanding of how natural aquatic environments function and thus lead to better predictions of how stream ecosystems might react to changing conditions of contaminant loading, eutrophication, climate change, drought, industrialization, development, and other factors.

Chemical Geology↗
USGS2010

Pb-isotopic systematics of lunar highland rocks (>3.9 Ga): Constraints on early lunar evolution

The present lead (Pb)-isotopic database of over 200 analyses from nearly 90 samples of non-mare basalt, lunar highland rocks (>3.9 Ga) delineate at least three isotopically distinct signatures that in some combination can be interpreted to characterize the systematics of the entire database. Two are fairly new sets of lunar data and are typical of Pb data from other solar-system objects, describing nearly linear arrays slightly above the “geochron” values, with 207 Pb/ 206 Pb values <0.9. In aggregate, those data allow a relatively new interpretation of the Pb-isotopic evolution of the Moon, helping to identify and characterize a planetary evolutionary stage not preserved by Earth rocks. From the Pb-isotopic compositions, a source 238 U/ 204 Pb (μ) value can be calculated; differences in μ values from one Pb signature to another can have important implications on the age and evolution of Moon-forming events. In particular, the U/Pb ratio is one method of measuring the fractionation between refractory and volatile elements, an important indicator when considering large-scale planetary differentiation stages. The oldest Pb signature is represented solely by ferroan anorthosite 60025, presumably a piece of the early plagioclase-rich lunar crust produced from a magma ocean, and is characterized by source μ values between 35 and 100 at ~4.43 Ga. Another prominent and uniquely lunar Pb signature, identified more than 20 years ago, is representative of many ferroan anorthosites and most high-Mg suite rocks (particularly 15415, 62237, 76535, and 78235), and is characterized by extremely high 207 Pb/ 206 Pb values (∼1.45) that require extremely high source μ values (>500). Although the age and origin of this exotic Pb is not well constrained, it is interpreted to be related to the entrapment of incompatible-element-rich (U, Th) melts within the lunar upper mantle and crust between 4.36 and 4.46 Ga (urKREEP residuum?). The latest discovered Pb signature is found only in lunar meteorites and is characterized by relatively low source μ values between 10 and 50 at 3.9 Ga. The fact that most lunar crustal rocks (>3.9 Ga) exhibit high 207 Pb/ 206 Pb values requires that they were derived from, mixed with, or contaminated by Pb produced from early-formed, high-μ sources. The ubiquity of these U-Pb characteristics in the sample collection is probably an artifact of Apollo and Luna sampling sites, all located on the near side of the Moon, which was deeply excavated during the basin-forming event(s). However, the newest Pb-isotopic data support the idea that the Moon originally had a μ value of ~8 to 35, slightly elevated from Earth values, and that progressive U-Pb fractionations occurred within the Moon during later stages of differentiation between 4.36 and 4.46 Ga.

International Geology Review↗
USGS1997

Sedimentary carbonate-hosted giant Bayan Obo REE-Fe-Nb ore deposit of Inner Mongolia, China; a cornerstone example for giant polymetallic ore deposits of hydrothermal origin

Detailed, integrative field and laboratory studies of the textures, structures, chemical characteristics, and isotopically determined ages and signatures of mineralization of the Bayan Obo deposit provided evidence for the origin and characteristics favorable for its formation and parameters necessary for defining giant polymetallic deposits of hydrothermal origin. Bayan Obo is an epigenetic, metasomatic, hydrothermal rare earth element (REE)-Fe-Nb ore deposit that is hosted in the metasedimentary H8 dolostone marble of the Middle Proterozoic Bayan Obo Group. The metasedimentary sequence was deposited on the northern continental slope of the North China craton. The mine area is about 100 km south of the suture marking Caledonian subduction of the Mongolian oceanic plate from the north beneath the North China craton. The mineralogy of the deposit is very complex, consisting of more than 120 different minerals, some of which are epigenetic minerals introduced by hydrothermal solutions, and some of which are primary and secondary metamorphic minerals. The major REE minerals are monazite and bastnaesite, whereas magnetite and hematite are the dominant Fe-ore minerals, and columbite is the most abundant Nb mineral. Dolomite, alkali amphibole, fluorite, barite, aegirine augite, apatite, phlogopite, albite, and microcline are the most widespread gangue minerals. Three general types of ores occur at Bayan Obo: disseminated, banded, and massive ores. Broad zoning of these ore types occurs in the Main and East Orebodies. Disseminated ores are in the outermost zone, banded ores are in the intermediate zone, and massive ores are in the cores of the orebodies. On the basis of field relations, host rocks, textures, structures, and mineral assemblages, many varieties of these three types of ores have been recognized and mapped. Isotopic dating of monazite, bastnaesite, aeschynite, and metamorphic and metasomatic alkali amphiboles associated with the deposit provides constraints on the ages of mineralization and the history of the deposit. Textural relations, differences in chemical composition, and 232Th/208Pb internal isochron ages of monazite and bastnaesite samples indicate that many episodes of REE mineralization occurred at Bayan Obo, ranging from about 555 Ma to about 398 Ma. Initial 208Pb/204Pb ratios suggest different sources of REE's for different generations of REE minerals. Relative ages of Fe mineralization were deduced from textural relationships of Fe minerals with other, dated mineral phases in the deposit. Most Nb mineralization was in the area of the West Orebodies and resulted in disseminated ore. Aeschynite, an early stage of Nb mineralization (438+-25.1 Ma), occurs with huanghoite and alkali amphiboles in veins. The 40Ar/39Ar ages of amphiboles, as well as petrographic textures, were used to distinguish three periods of regional metamorphism in the Bayan Obo mine area: (1) Late Proterozoic, about 890 Ma, which recrystallized H8 carbonate to marble and crystallized lineated alkali amphiboles along foliation planes in the marble; (2) Caledonian, about 425-395 Ma, which resulted in metamorphic and metasomatic-metamorphic alkali amphiboles; and (3) Hercynian, about 300 Ma, based on biotite 40Ar/39Ar analyses from biotite schist and folded banded ores. The 40Ar/39Ar ages of metasomatic alkali amphiboles also place time constraints on the hydrothermal history of the ore deposit. Metasomatic amphiboles represent periods of intense hydrothermal activity, which began as early as 1.26 Ga; that date is based on the age of amphibole from a vein that crosscuts the H6 quartzite that underlies the H8 dolostone marble. Although much of the metasomatic amphibole formed during periods that overlapped the peak period of REE mineralization of banded ores, REE and alkali amphibole phases generally occur in different mineral assemblages or are of very different ages in the same assemblage and, therefore, may have been derived from

Bulletin↗
USGS1996

Isotopic evolution of Mauna Kea volcano: Results from the initial phase of the Hawaii Scientific Drilling Project

We have examined the Sr, Nd, and Pb isotopic compositions of Mauna Kea lavas recovered by the first drilling phase of the Hawaii Scientific Drilling Project. These lavas, which range in age from ∼200 to 400 ka, provide a detailed record of chemical and isotopic changes in basalt composition during the shield/postshield transition and extend our record of Mauna Kea volcanism to a late-shield period roughly equivalent to the last ∼100 ka of Mauna Loa activity. Stratigraphic variations in isotopic composition reveal a gradual shift over time toward a more depleted source composition (e.g., higher 143 Nd/ 144 Nd, lower 87 Sr/ 86 Sr, and lower 3 He/ 4 He). This gradual evolution is in sharp contrast with the abrupt appearance of alkalic lavas at ∼240 ka recorded by the upper 50 m of Mauna Kea lavas from the core. Intercalated tholeiitic and alkalic lavas from the uppermost Mauna Kea section are isotopically indistinguishable. Combined with major element evidence (e.g., decreasing SiO 2 and increasing FeO) that the depth of melt segregation increased during the transition from tholeiitic to alkalic volcanism, the isotopic similarity of tholeiitic and alkalic lavas argues against significant lithosphere involvement during melt generation. Instead, the depleted isotopic signatures found in late shield-stage lavas are best explained by increasing the proportion of melt generated from a depleted upper mantle component entrained and heated by the rising central plume. Direct comparison of Mauna Kea and Mauna Loa lavas erupted at equivalent stages in these volcanoes' life cycles reveals persistent chemical and isotopic differences independent of the temporal evolution of each volcano. The oldest lavas recovered from the drillcore are similar to modern Kilauea lavas, but are distinct from Mauna Loa lavas. Mauna Kea lavas have higher 143 Nd/ 144 Nd and 206 Pb/ 204 Pb and lower 87 Sr/ 86 Sr. Higher concentrations of incompatible trace elements in primary magmas, lower SiO 2 , and higher FeO also indicate that Mauna Kea lavas formed through smaller degrees of partial melting at greater depth than Mauna Loa lavas. These chemical and isotopic differences are consistently found between volcanoes along the western “Loa” and eastern “Kea” trends and reflect large-scale variations in source composition and melting environment. We propose a simple model of a radially zoned plume centered beneath the Loa trend. Loa trend lavas generated from the hot plume axis reflect high degrees of partial melting from a source containing a mixture of enriched plume-source material and entrained lower mantle. Kea trend lavas, in contrast, are generated from the cooler, peripheral portions of the plume, record lower degrees of partial melting, and tap a source containing a greater proportion of depleted upper mantle.

Journal of Geophysical Research B: Solid Earth↗
USGS1996

Hawaii scientific drilling protect: Summary of preliminary results

Petrological, geochemical, geomagnetic, and volcanological characterization of the recovered core from a 1056-m-deep well into the flank of the Mauna Kea volcano in Hilo, Hawaii, and downhole logging and fluid sampling have provided a unique view of the evolution and internal structure of a major oceanic volcano unavailable from surface exposures. Core recovery was ~90%, yielding a time series of fresh, subaerial lavas extending back to ~400 ka. Results of this 1993 project provide a basis for a more ambitious project to core drill a well 4.5 km deep in a nearby location with the goal of recovering an extended, high-density stratigraphic sequence of lavas.

Hawaii↗
USGS1994

A precise 232Th-208Pb chronology of fine-grained monazite: Age of the Bayan Obo REE-Fe-Nb ore deposit, China

We have obtained precise Th-Pb internal isochron ages on monazite and bastnaesite for the world's largest known rare earth elements (REE)-Fe-Nb ore deposit, the Bayan Obo of Inner Mongolia, China. The monazite samples, collected from the carbonate-hosted ore zone, contain extremely small amounts of uranium (less than 10 ppm) but up to 0.7% ThO 2 . Previous estimates of the age of mineralization ranged from 1.8 to 0.255 Ga. Magnetic fractions of monazite and bastnaesite samples (<60-μm size) showed large ranges in 232 Th 204 Pb "> 232 Th 204 Pb values (900–400,000) and provided precise Th-Pb internal isochron ages for paragenetic monazite mineralization ranging from 555 to 398 Ma within a few percent error (0.8% for two samples). These results are the first indication that REE mineralization within the giant Bayan Obo ore deposit occurred over a long period of time. The initial lead isotopic compositions (low 206 Pb 204 Pb "> 206 Pb 204 Pb and high 208 Pb 204 Pb) "> 208 Pb 204 Pb) and large negative ϵ Nd values for Bayan Obo ore minerals indicate that the main source(s) for the ores was the lower crust which was depleted in uranium, but enriched in thorium and light rare earth elements for a long period of time. Zircon from a quartz monzonite, located 50 km south of the ore complex and thought to be related to Caledonian subduction, gave an age of 451 Ma, within the range of monazite ages. Textural relations together with the mineral ages favor an epigenetic rather than a syngenetic origin for the orebodies. REE mineralization started around 555 Ma (disseminated monazite in the West, the Main, and south of the East Orebody), but the main mineralization (banded ores) was related to the Caledonian subduction event ca. 474-400 Ma.

Bayan Obo, Kuanggou Fault↗
USGS1993

An extremely low UPb source in the Moon: U Th Pb, Sm Nd, Rb Sr, and 40Ar 39Ar isotopic systematics and age of lunar meteorite Asuka 881757

We have undertaken U Th Pb, Sm Nd, Rb Sr, and 40 Ar 39 Ar "> 40 Ar 39 Ar isotopic studies on Asuka 881757, a coarse-grained basaltic lunar meteorite whose chemical composition is close to low-Ti and very low-Ti (VLT) mare basalts. The Pb Pb internal isochron obtained for acid leached residues of separated mineral fractions yields an age of 3940 ± 28 Ma, which is similar to the U-Pb (3850 ± 150 Ma) and Th-Pb (3820 ± 290 Ma) internal isochron ages. The Sm-Nd data for the mineral separates yield an internal isochron age of 3871 ± 57 Ma and an initial 143 Nd 144 Nd "> 143 Nd 144 Nd value of 0.50797 ± 10. The Rb-Sr data yield an internal isochron age of 3840 ± 32 Ma ( &#x3BB;( 87 Rb) = 1.42 &#xD7; 10 &#x2212;11 yr &#x2212;1 "> λ( 87 Rb) = 1.42 × 10 −11 yr −1 ) and a low initial 87 Sr 86 Sr "> 87 Sr 86 Sr ratio of 0.69910 ± 2. The 40 Ar 39 Ar "> 40 Ar 39 Ar age spectra for a glass fragment and a maskelynitized plagioclase are relatively flat and give a weighted mean plateau age of 3798 ± 12 Ma. We interpret these ages to indicate that the basalt crystallized from a melt 3.87 Ga ago (the Sm-Nd age) and an impact event disturbed the Rb-Sr system and completely reset the K-Ar system at 3.80 Ga. The slightly higher Pb-Pb age compared to the Sm-Nd age could be due to the secondary Pb (from terrestrial and/or lunar surface Pb contamination) that remained in the residues after acid leaching. Alternatively, the following interpretation is also possible; the meteorite crystallized at 3.94 Ga (the Pb-Pb age) and the Sm-Nd, Rb-Sr, and K-Ar systems were disturbed by an impact event at 3.80 Ga. The crystallization age obtained here is older than those reported for low-Ti basalts (3.2–3.5 Ga) and for VLT basalts (3.4 Ga), but similar to ages of some mare basalts, indicating that the basalt may have formed from a magma related to a basin-forming event (Imbrium?). The age span for VLT basalts from different sampling sites suggest that they were erupted over a wide area during an interval of at least ~500 million years. The impact event that thermally reset the K-Ar system of Asuka 881757 must have been post-Imbrium (perhaps Orientale) in age. The lead isotopic composition of Asuka 881757 is nonradiogenic compared with typical Apollo mare basalts and the estimated 238 U 204 Pb "> 238 U 204 Pb (μ) value for the basalt source is 10 ± 3. This source-μ value is the lowest so far measured for lunar rocks. A large positive ϵ Nd value (7.4 ± 0.5) and the time averaged 147 Sm 144 Nd "> 1 47 147 Sm 144 Nd "> Sm 144 Nd ratio for the basalt source are similar to those for some Apollo 12, 15, and 17 basalts, suggesting a LREE-depleted mantle, which is consistent with the global magma ocean hypothesis. The U-Th-Pb, Sm-Nd, and Rb-Sr data on Asuka 881757 suggest that the basalt was derived from a low U Pb "> UPb , low Rb Sr "> RbSr , and high Sm Nd "> SmNd source region, mainly composed of olivine and orthopyroxene with minor amounts of plagioclase (or clinopyroxene) and with sulfides enriched in volatile chalcophile elements. The basalt source may be deep in origin and different in chemistry from those previously estimated from studies of Apollo and Luna mare basalts, indicating heterogeneous sources for mare basalts.

Geochimica et Cosmochimica Acta↗
USGS1992

Sr, Nd, and Pb isotopes of ultramafic xenoliths in volcanic rocks of Eastern China: Enriched components EMI and EMII in subcontinental lithosphere

The U-Th-Pb, Sm-Nd, and Rb-Sr isotopic systematics of mafic and ultramafic xenolithic rocks and associated megacrystic inclusions of aluminous augite and garnet, that occur in three alkalic volcanic suites: Kuandian in eastern Liaoning Province, Hanluoba in Hebei Province, and Minxi in western Fujian Province, China are described. In various isotopic data plots, the inclusion data invariably fall outside the isotopic ranges displayed by the host volcanic rocks, testifying to the true xenolithic nature of the inclusions. The major element partitioning data on Ca, Mg, Fe, and Al among the coexisting silicate minerals of the xenoliths establish their growth at ambient mantle temperatures of 1000–1100°C and possible depths of 70–80 km in the subcontinental lithosphere. Although the partitioning of these elements reflects equilibrium between coexisting minerals, equilibria of the Pb, Nd, and Sr isotopic systems among the minerals were not preserved. The disequilibria are most notable with respect to the 206 Pb/ 204 Pb ratios of the minerals. On a Nd-Sr isotopic diagram, the inclusion data plot in a wider area than that for oceanic basalts from a distinctly more depleted component than MORB with higher 143 Nd/ 144 Nd and a much broader range of 87 Sr/ 86 Sr values, paralleling the theoretical trajectory of a sea-water altered lithosphere in Nd-Sr space. The garnets consistently show lowerμ andκ values than the pyroxenes and pyroxenites, whereas a phlogopite shows the highestμ andκ values among all the minerals and rocks studied.

Earth and Planetary Science Letters↗
USGS1991

Major element, REE, and Pb, Nd and Sr isotopic geochemistry of Cenozoic volcanic rocks of eastern China: Implications for their origin from suboceanic-type mantle reservoirs

Major- and rare-earth-element (REE) concentrations and U Th Pb, Sm Nd, and Rb Sr isotope systematics are reported for Cenozoic volcanic rocks from northeastern and eastern China. These volcanic rocks, characteristically lacking the calc-alkaline suite of orogenic belts, were emplaced in a rift system which formed in response to the subduction of the western Pacific plate beneath the eastern Asiatic continental margin. The rocks sampled range from basanite and alkali olivine basalt, through olivine tholeiite and quartz tholeiite, to potassic basalts, alkali trachytes, pantellerite, and limburgite. These rock suites represent the volcanic centers of Datong, Hanobar, Kuandian, Changbaishan and Wudalianchi in northeastern China, and Mingxi in the Fujian Province of eastern China.

Earth and Planetary Science Letters↗
USGS1990

Actinide abundances in ordinary chondrites

Measurements of 244 Pu fission Xe, U, Th, and light REE (LREE) abundances, along with modal petrographic determinations of phosphate abundances, were carried out on equilibrated ordinary chondrites in order to define better the solar system Pu abundance and to determine the degree of variation of actinide and LREE abundances. Our data permit comparison of the directly measured Pu/ U ratio with that determined indirectly as ( Pu / Nd ) × ( Nd / U ) assuming that Pu behaves chemically as a LREE. Except for Guareña, and perhaps H chondrites in general, Pu concentrations are similar to that determined previously for St. Séverin, although less precise because of higher trapped Xe contents. Trapped 130 Xe 136 Xe "> 130 Xe 136 Xe ratios appear to vary from meteorite to meteorite, but, relative to AVCC, all are similar in the sense of having less of the interstellar heavy Xe found in carbonaceous chondrite acid residues. The Pu/U and Pu/Nd ratios are consistent with previous data for St. Séverin, but both tend to be slightly higher than those inferred from previous data on Angra dos Reis. Although significant variations exist, the distribution of our Th/U ratios, along with other precise isotope dilution data for ordinary chondrites, is rather symmetric about the CI chondrite value; however, actinide/(LREE) ratios are systematically lower than the CI value. Variations in actinide or LREE absolute and relative abundances are interpreted as reflecting differences in the proportions and/or compositions of more primitive components (chondrules and CAI materials?) incorporated into different regions of the ordinary chondrite parent bodies. The observed variations of Th/U, Nd/U, or Ce/U suggest that measurements of Pu/U on any single equilibrated ordinary chondrite specimen, such as St. Séverin, should statistically be within ±20–30% of the average solar system value, although it is also clear that anomalous samples exist.

Geochimica et Cosmochimica Acta↗