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M. T. Meyer

Publications and source records attributed to M. T. Meyer.

44 records · Page 3Linked to original sources

Herbicides and their metabolites in rainfall: Origin, transport, and deposition patterns across the midwestern and northeastern United States, 1990-1991

Herbicides were detected in rainfall throughout the midwestern and northeastern United States during late spring and summer of 1990 and 1991. Herbicide concentrations exhibited distinct geographic and seasonal patterns. The highest concentrations occurred in midwestern cornbelt states following herbicide application to cropland. Volume-weighted concentrations of 0.2−0.4 μg/L for atrazine and alachlor were typical in this area during mid-April through mid-July, and weighted concentrations as large as 0.6−0.9 μg/L occurred at several sites. Concentrations of 1−3 μg/L were measured in a few individual samples. Atrazine was detected most often followed by alachlor, deethylatrazine, metolachlor, cyanazine, and deisopropylatrazine. The high ratio (∼0.5) of deethylatrazine to atrazine in rainfall suggests atmospheric degradation of atrazine. Mass deposition of herbicides was greatest in areas where herbicide use was high and decreased with distance from the cornbelt. Estimated deposition rates for both atrazine and alachlor ranged from more than 240 μg m - 2 yr - 1 for some areas in the midwestern states to less than 10 μg m - 2 yr - 1 for the New England states. The estimated annual deposition of atrazine on the Great Lakes ranged from about 12 to 63 μg m - 2 yr - 1 . The total amounts of atrazine and alachlor deposited annually in rainfall in the study area represent about 0.6% of the atrazine and 0.4% of the alachlor applied annually to crops in the study area.

Environmental Science & Technology↗

Results of the application of seismic-reflection and electromagnetic techniques for near-surface hydrogeologic and environmental investigations at Fort Bragg, North Carolina

As part of the U.S. Geological Survey's Resource Conservation and Recovery Act, Facilities Investigations at Fort Bragg, North Carolina, selected geophysical techniques were evaluated for their usefulness as assessment tools for determining subsurface geology, delineating the areal extent of potentially contaminated landfill sites, and locating buried objects and debris of potential environmental concern. Two shallow seismic-reflection techniques (compression and shear wave) and two electromagnetic techniques (ground-penetrating radar and terrain conductivity) were evaluated at several sites at the U.S. Army Base. The electromagnetic techniques also were tested for tolerance to cultural noise, such as nearby fences, vehicles, and power lines. For the terrain conductivity tests, two instruments were used--the EM31 and EM34, which have variable depths of exploration. The shallowest reflection event was 70 feet below land surface observed in common-depth point, stacked compression-wave data from 24- and 12-fold shallow-seismic-reflection surveys. Several reflection events consistent with clay-sand interfaces between 70 and 120 feet below land surface, along with basement-saprolite surfaces, were imaged in the 24-fold, common- depth-point stacked data. 12-fold, common-depth-point stacked data set contained considerably more noise than the 24-fold, common-depth-point data, due to reduced shot-to-receiver redundancy. Coherent stacked reflection events were not observed in the 24-fold, common-depth-point stacked shear-wave data because of the partial decoupling of the shear- wave generator from the ground. At one site, ground-penetrating radar effectively delineated a shallow, 2- to 5-foot thick sand unit bounded by thin (less than 1 foot) clay layers. The radar signal was completely attenuated where the overlying and underlying clay units thickened and the sand unit thinned. The pene- tration depth of the radar signal was less than 10 feet below land surface. A slight increase in electromagnetic conductivity across shallow sampling EM31 and EM34 profiles provided corroborative evidence of the shallow, thickening clay units. Plots of raw EM31 and EM34 data provided no direct interpretable information to delineate sand and clay units in the shallow subsurface. At two sites, the ground-penetrating radar effectively delineated the lateral continuity of surficial sand units 5 to 25 feet in thickness and the tops of their underlying clay units. The effective exploration depth of the ground-penetrating radar was limited by the proximity of clay units to the subsurface and their thickness. The ground-penetrating radar delineated the areal extent and depth of cover at a previously unrecognized extension of a trench-like landfill underlying a vehicle salvage yard. Attenuation of the radar signal beneath the landfill cover and the adjacent subsurface clays made these two mediums indistinguishable by ground-penetrating radar; however, EM31 data indicated that the electrical conductivity of the landfill was higher than the subsurface material adjacent to the landfill. The EM31 and EM34 conductivity surveys defined the areal extent of a landfill whose boundaries were inaccurately mapped, and also identified the locations of an old dumpsite and waste incinerator site at another landfill. A follow-up ground-penetrating radar survey of the abandoned dumpsite showed incongruities in some of the shallow radar reflections interpreted as buried refuse dispersed throughout the landfill. The ground-penetrating radar and EM31 effectively delineated a shallow buried fuel-oil tank. Of the three electromagnetic instruments, the ground-penetrating radar with the shielded 100-megahertz antenna was the least affected by cultural noise followed, in order, by the EM31 and EM34. The combination of terrain- conductivity and ground-penetrating radar for the site assessment of the landfill provided a powerful means to identify the areal extent of the landfill, potenti

Water-Resources Investigations Report↗

Occurrence of alachlor and its sulfonated metabolite in rivers and reservoirs of the midwestern United States: The importance of sulfonation in the transport of chloroacetanilide herbicides

Alachlor and its metabolite, 2-[(2',6'-diethylphenyl)- (methoxymethyl)amino]-2-oxoethanesulfonate (ESA), were identified in 76 reservoirs in the midwestern United States using immunoassay, liquid chromatography, and gas chromatography/mass spectrometry. The median concentration of ESA (0.48 ??g/L) exceeded the median concentration of alachlor (<0.05 ??g/L), with highest values in the upper Midwest. ESA also was detected in the Mississippi River from the mouth to the headwaters at concentrations of 0.2-1.5 ??g/L, exceeding the concentration of alachlor. In a field runoff study, alachlor rapidly formed ESA. It is hypothesized that a glutathione conjugate forms, which later oxidizes in soil to ESA. The removal of the chlorine atom lessens the toxicity of the parent compound and increases runoff potential. It is hypothesized further that sulfonic acid metabolites of other chloroacetanilides, including acetochlor, butachlor, metolachlor, and propachlor, also occur in surface water.

Midwest↗

Concentrations of selected herbicides, herbicide metabolites, and nutrients in outflow from selected midwestern reservoirs, April 1992 through September 1993

This data set consists of digital aquifer boundaries for the High Plains aquifer in the central United States. The High Plains aquifer extends from south of 32 degrees to almost 45 degrees north latitude and from 96 degrees 30 minutes to almost 104 degrees west longitude. The area covers 174,000 square miles and is present in Texas, Oklahoma, New Mexico, Kansas, Colorado, Nebraska, Wyoming, and South Dakota. This digital data set was created by digitizing the aquifer boundaries from a 1:1,000,000 base map created by the High Plains RASA project (Gutentag and others, 1984).

Texas, Oklahoma, New Mexico, Kansas, Colorado, Neb↗

Data on selected herbicides and two triazine metabolites in precipitation of the Midwestern and Northeastern United States, 1990-91

Weekly precipitation (rain and snow) samples were collected from 81 National Atmospheric Deposition Program/National Trends Network sites in the Midwestern and Northeastern United States for the analysis of herbicides. In addition, five high- elevation background sites along the Rocky Mountains and in Alaska were sampled to provide data on herbicides in precipitation at sites far from the study area. The study began in March 1990 and continued through September 1991. The precipitation samples were shipped to the Central Analytical Laboratory operated by the Illinois State Water Survey for analyses of inorganic compounds. Subsamples of the precipitation were shipped to the U.S. Geological Survey laboratory in Lawrence, Kansas, for the analysis of 11 herbicides and 2 triazines metabolites. This report provides descriptions of the study area, sample-collection methods, laboratory methods, and quality assurance. The report also includes a compilation of herbicide concentration data from both enzyme-linked immunosorbent assay and gas chromatography/mass spectrometry methods. Laboratory analyses consisted of 6,230 samples that were analyzed by enzyme-linked immunosorbent assay using alachlor and atrazine microtiter plates and 2,341 samples that were confirmed by gas chromatography/mass spectrometry analysis. Graphical and statistical comparisons of the two analytical methods are given in this report. Data from this study have been useful in determining the spatial and temporal distribution of herbicide concentrations and deposition in precipitation of over a 26-State area of the Midwestern and Northeastern United States. The data also provide evidence of long-range atmospheric transport of herbicides and triazine metabolites.

Open-File Report↗

Automated solid-phase extraction of herbicides from water for gas chromatographic-mass spectrometric analysis

An automated solid-phase extraction (SPE) method was developed for the pre-concentration of chloroacetanilide and triazine herbicides, and two triazine metabolites from 100-ml water samples. Breakthrough experiments for the C 18 SPE cartridge show that the two triazine metabolites are not fully retained and that increasing flow-rate decreases their retention. Standard curve r 2 values of 0.998–1.000 for each compound were consistently obtained and a quantitation level of 0.05 μg/l was achieved for each compound tested. More than 10 000 surface and ground water samples have been analyzed by this method.

Journal of Chromatography A↗

Reconnaissance data for selected herbicides, two atrazine metabolities, and nitrate in surface water of the Midwestern United States, 1989-90

Water-quality data were collected from 147 rivers and streams during 1989-90 to assess selected preemergent herbicides, two atrazine metabolites, and nitrate in 10 Midwestern States. This report includes a description of the sampling design, data collection techniques, laboratory and analytical methods, and a compilation of constituent concentrations and quality-assurance data. All water samples were collected by depth-integrating techniques at three to five locations across the wetted perimeter of each stream. Sites were sampled three times in l989--before application of herbi- cides, during the first major runoff after appli- cation of herbicides, and in the fall during a low-flow period when ground water contributed to most of the streamflow. About 50 sites were selected by a stratified random procedure and resampled for both pre- and post-application herbicide concen- trations in 1990 to verify the 1989 results. Laboratory analyses consisted of both enzyme-linked immunosorbent assay (ELISA) with confirmation by gas chromatography-mass spectrometry (GC/MS). The data are useful in studying herbicide transport, in comparison of the spatial distribution of the post-application concentrations of 11 herbicides and 2 atrazine metabolites (deethylatrazine and deisopropylatrazine) in streams and rivers at a regional scale. It is also useful in examination of annual persistence of herbicides and two metabolites in surface water, and in the assessment of atrazine metabolites as indicators of surface- and ground- water interaction. The reconnaissance data are contained in this report and are also available on computer diskette from the U.S. Geological Survey in Lawrence, Kansas.

Open-File Report↗