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M. R. Burkart

Publications and source records attributed to M. R. Burkart.

12 recordsLinked to original sources
USGS2007

Infiltration of atrazine and metabolites from a stream to an alluvial aquifer

ABSTRACT: The infiltration of atrazine, deethylatrazine, and deisopropylatrazine from Walnut Creek, a tributary stream, to the alluvial valley aquifer along the South Skunk River in central Iowa occurred where the stream transects the river's flood plain. A preliminary estimate indicated that the infiltration was significant and warrants further investigation. Infiltration was estimated by measuring the loss of stream discharge in Walnut Creek and the concentrations of atrazine and its metabolites deethylatrazine and deisopropylatrazine, in ground water 1 m beneath the streambed. Infiltration was estimated before application of agrichemicals to the fields during a dry period on April 7, 1994, and after application of agrichemicals during a period of small runoff on June 8, 1994. On April 7, the flux of atrazine, deethylatrazine, and deisopropylatrazine from Walnut Creek into the alluvial valley aquifer ranged from less than 10 to 60 (μg/d)/m 2 , whereas on June 8 an increased flux ranged from 270 to 3060 (μg/d)/m 2 . By way of comparison, the calculated fluxes of atrazine beneath Walnut Creek, for these two dates, were two to five orders of magnitude greater than an estimated flux of atrazine to ground water caused by leaching from a field on a per-unit-area basis. Furthermore, the unit-area flux rates of water from Walnut Creek to the alluvial valley aquifer were about three orders of magnitude greater than estimated recharge to the alluvial aquifer from precipitation. The large flux of chemicals from Walnut Creek to the alluvial valley aquifer was due in part to the conductive streambed and rather fast ground water velocities; average vertical hydraulic conductivity through the streambed was calculated as 35 and 90 m/d for the two sampling dates, and estimated ground water velocities ranged from 1 to 5 m/d.

Journal of the American Water Resources Associatio↗
USGS2002

Nitrate in aquifers beneath agricultural systems

Research from several regions of the world provides spatially anecdotal evidence to hypothesize which hydrologic and agricultural factors contribute to groundwater vulnerability to nitrate contamination. Analysis of nationally consistent measurements from the U.S. Geological Survey's NAWOA program confirms these hypotheses for a substantial range of agricultural systems. Shallow unconfined aquifers are most susceptible to nitrate contamination associated with agricultural systems. Alluvial and other unconsolidated aquifers are the most vulnerable and shallow carbonate aquifers provide a substantial but smaller contamination risk. Where any of these aquifers are overlain by permeable soils the risk of contamination is larger. Irrigated systems can compound this vulnerability by increasing leaching facilitated by additional recharge and additional nutrient applications. The agricultural system of corn, soybeans, and hogs produced significantly larger concentrations of groundwater nitrate than all other agricultural systems, although mean nitrate concentrations in counties with dairy, poultry, cattle and grains, and horticulture systems were similar. If trends in the relation between increased fertilizer use and groundwater nitrate in the United States are repeated in other regions of the world, Asia may experience increasing problems because of recent increases in fertilizer use. Groundwater monitoring in Western and Eastern Europe as well as Russia over the next decade may provide data to determine if the trend in increased nitrate contamination can be reversed. If the concentrated livestock trend in the United States is global, it may be accompanied by increasing nitrogen contamination in groundwater. Concentrated livestock provide both point sources in the confinement area and intense non-point sources as fields close to facilities are used for manure disposal. Regions where irrigated cropland is expanding, such as in Asia, may experience the greatest impact of this practice.

Conference Paper↗
USGS1999

Agrichemicals in ground water of the midwestern USA: Relations to soil characteristics

A comprehensive set of soil characteristics were examined to determine the effect of soil on the transport of agrichemicals to ground water. This paper examines the relation of local soil characteristics to concentrations and occurrence of nitrate, atrazine (2-chloro-4 ethylamino-6-isopropylamino- s -trazine), and atrazine residue [atrazine + deethylatrazine (2-amino-4-chloro-6-isopropylamino- s -triazine) + deisopropylatrazine (2-amino-4-chloro-6-ethylamino- s -triazine)] from 99 wells completed in unconsolidated aquifers across the midwestern USA. The occurrence and concentrations of nitrate and atrazine in ground water were directly related to soil characteristics that determine the rate of water movement. The substantial differences in the relations found among soil characteristics and nitrate and atrazine in ground water suggest that different processes affect the transformation, adsorption, and transport of these contaminants. A multivariate analysis determined that the soil characteristics examined explained the amount of variability in concentrations for nitrate (19.0%), atrazine (33.4%), and atrazine residue (28.6%). These results document that, although soils do affect the transport of agrichemicals to ground water, other factors such as hydrology, land use, and climate must also be considered to understand the occurrence of agrichemicals in ground water.

Journal of Environmental Quality↗
USGS1993

Hydrogeologic, water-quality, and land-use data for the reconnaissance of herbicides and nitrate in near-surface aquifers of the Midcontinental United States, 1991

Water samples were collected during the spring and summer of 1991 from 303 wells penetrating near-surface unconsolidated and bedrock aquifers of the midcontinental United States. Samples were analyzed for 11 herbicides, 2 dealkylated atrazine metabolites, and 4 nutrients. Specific conductance, pH, and dissolved-oxygen concentrations of the ground water were measured onsite. Ancillary data on well construction, hydrogeology, and land use also were obtained for each well.

Open-File Report↗
USGS1993

Application of a geographic information system in analyzing the occurrence of atrazine in groundwater of the mid-continental United States

The US Geological Survey, US Department of Agriculture, and US Environmental Protection Agency are conducting research and regional assessments in support of policy alternatives intended to protect water resources from agricultural chemical contamination. The mid-continent was selected because of the intense row crop agriculture and associated herbicide application in this region. An application of a geographic information system is demonstrated for analyzing and comparing the distribution of estimated atrazine use to the detection rate of atrazine in groundwater. Understanding the relations between atrazine use and detection in groundwater is important in policy deliberations to protect water resources. Relational analyses between measures of chemical use and detection rate by natural resource units may provide insight into critical factors controlling the processes that result in groundwater contamination from agricultural chemicals.

Conference Paper↗
USGS1991

Work plan for regional reconnaissance for selected herbicides and nitrate in ground water of the mid-continent United States, 1991

An approach was developed to obtain a consistent, regional distribution of herbicide and nitrate data from near-surface aquifers in the corn and soybean producing region of the mid-continent. Near-surface aquifers are defined as those with the top of aquifer material within 50 feet of land surface, regardless of whether the material is saturated or unsaturated. Three hundred wells will be selected for sampling from 12 states. These States include Illinois, Indiana, Iowa, Kansas, Michigan, Minnesota, Missouri, Nebraska, North Dakota, Ohio, South Dakota, and Wisconsin. The reconnaissance data obtained will be used to determine the spatial and seasonal distribution of selected herbicides, two atrazine metabolites, and nitrate in near-surface aquifers in the study region. Hydrologic, geologic, and land-use data will be collected for use in an exploratory statistical analysis to help explain the herbicide distribution.

Illinois, Indiana, Iowa, Kansas, Michigan, Minneso↗
USGS1991

Agricultural research to improve water quality

ime courses for ingest~on, retention and release via feces of microbial food was investigated using 2 b~valves w~th d~fferent feeding strategies, Potamocorbula amurensis and Macoma balthica. The results showed 2 pathways for the uptake of food material in these clams. The first is represented by an initlal label pulse in the feces. The second pathway operates over longer time periods. Inert "Cr-labeled beads were used to determine time frames for these pathways. The first pathway, involving extracellular digestion and intestinal uptake, is relatively inefficient In the digestion of bacter~al cells by P amurensis but more efficient in M. balthica. The second pathway, involving intracellular digestion withln the digestive gland of both clams, was highly efficient in absorb~ng bacterial carbon, and was responsible for most chromium uptake. Differences in the overall retention of microbial "Cr and I4C relate not to gut-passage times but to the processing and release strategies of the food material by these 2 clams.

Journal of Soil and Water Conservation↗
USGS1990

Regional evaluation of hydrologic factors and effects of pumping, St Peter-Jordan aquifer, Iowa

The St. Peter-Jordan aquifer includes the Cambrian Jordan Sandstone and the overlying Ordovician Prairie du Chien Group and St. Peter Sandstone. The aquifer is present throughout Iowa and is confined beneath other aquifers in much of the State. Information on the aquifer available from drillers and contractors, provided estimates of aquifer transmissivity values ranging from about 500 to about 3,000 square feet per day. The largest transmissivity values are for dolomite and dolomite-cemented sandstone, indicating that permeability in much of the aquifer is due to secondary fractures. The aquifer is vertically bounded by an upper leaky confining unit with a vertical hydraulic conductivity of 10 -10 feet per second. The aquifer was simulated using a two-layer finite-difference ground-water flow model. The upper layer simulated a source bed in aquifers composed of Silurian and Devonian rocks overlying the St. Peter-Jordan aquifer. The lower layer simulated flow in the St. Peter-Jordan aquifer. Lateral boundaries assigned in the model include constant heads in northeastern Iowa, where the aquifer is in contact with the Mississippi River or is unconfined, and no-flow boundaries in western and northwestern Iowa, where the rocks are insufficiently permeable to form an aquifer. The aquifer boundaries to the north, east, and south of Iowa were determined by geohydrologic conditions and the relation of the St. Peter-Jordan aquifer with the lateral extent of adjacent aquifers. An assumption that the largest part of recharge to the aquifer is from outcrop areas in northeastern Iowa and from Minnesota is not supported by the results of this study. Vertical leakage from overlying rocks accounted for most of the recharge to the aquifer in northwestern Iowa. Discharge is mostly through lateral boundaries and to rivers. Pumping has caused changes in the flow system that include regional declines in the potentiometric surface of the aquifer. Simulation indicates that pumping through 1980 increased net vertical leakage into the aquifer to about double the predevelopment rate. Discharge across lateral boundaries has been substantially reduced or reversed by pumping. Aquifer storage provided about one-third of the water required to supply pumping in the 1970's. Simulation of future conditions, assuming no increase in pumping rates, indicates that the rate of decline in water levels will decrease by the year 2020. As equilibrium with pumping is approached in 2020, 75 percent of the pumpage will be balanced by vertical leakage, eight percent by water released from aquifer storage, and 17 percent by increases in boundary recharge or decreases in boundary discharge. Future pumping at an increasing rate of about 10 percent per decade of the average pumping rate in 1975 will require about one and one-half times the vertical leakage of the 1971-1980 period and about fivetimes the net inflow from lateral boundaries; however, the rate of water released from aquifer storage will be about half the 1970's rate. Under these conditions, the head in the aquifer will continue to decline at an almost constant rate until 2020.

Illinois, Indiana, Iowa, Minnesota, Missouri, Wiis↗
USGS1984

Availability and quality of water from the Dakota aquifer, northwest Iowa

The Dakota aquifer in northwest Iowa consists of sandstones in the Dakota Formation. It underlies most of the study area and is the most extensive source of ground water in the area. Individual sandstone beds are from less than 10 to more than 150 feet thick. The cumulative thickness of sandstone is more than 200 feet throughout much of the area. The aquifer is confined by overlying Cretaceous limestone and shale, Quaternary glacial deposits and loess. The underlying confining material is shale of the Dakota Formation, undifferentiated Paleozoic age rocks, or Precambrian crystalline rock. Water flows through the aquifer from the northcentral part of the study area to the east, south and southwest. Recharge is dominantly by infiltration from the land surface through the confining materials. Discharge is to underlying Paleozoic aquifers and to the alluvium and glacial outwash deposits along the Missouri and Big Sioux Rivers in the southwest part of the area. Flow components toward bedrock valleys may reflect discharge to Quaternary sand and gravel deposits in these valleys. Pumping tests conducted in the study area indicate a narrow" range of hydraulic conductivities of the Dakota aquifer, from 37 to 50 feet per day. Consequently, an average hydraulic conductivity of 40 feet per day was used to estimate the potential yield to wells completed in the aquifer. Yields of more than 250 gallons per minute can be expected throughout much of the study area and more than 1,000 gallons per minute could be produced in some areas. The quality of water from the Dakota is a calcium, magnesium, sulfate type. It is generally suitable for irrigation purposes, based on comparisons of sodium adsorption ratios and electrical conductivities. In some areas the aquifer has water with high salinity hazard that may restrict its use to irrigation of only well-drained types of soil. The concentration of radium-226 and other radionuclides exceeds recommended limits at several sites. The quality of water pumped from the aquifer may be altered by induced leakage from the underlying aquifers in Paleozoic age rocks if withdrawals reverse the pattern of natural flow from the Dakota into the Paleozoic aquifers. Evidence for such a reversal exists in the area around the city of LeMars.

Iowa↗
USGS1982

Availability and quality of water from the Dakota aquifer, northwest Iowa

The Dakota aquifer in northwest Iowa consists of sandstones in the Dakota Formation. It underlies most of the study area and is the most extensive source of ground water in the area. Individual sandstone beds are from less than 10 to more than 150 feet thick. The cumulative thickness of sandstone is more than 200 feet throughout much of the area. The aquifer is confined by overlying Cretaceous limestone and shale, Quaternary glacial deposits and loess. The underlying confining material is shale of the Dakota Formation, undifferentiated Paleozoic age rocks, or Precambrian crystalline rock. Water flows through the aquifer from the north-central part of the study area to the east, south and southwest. Recharge is dominantly by infiltration from the land surface through the confining materials. Discharge is to underlying Paleozoic aquifers and to the alluvium and glacial outwash deposits along the Missouri and Big Sioux Rivers in the southwest part of the area. Flow components toward bedrock valleys may reflect discharge to Quaternary sand and gravel deposits in these valleys. Pumping tests conducted in the study area indicate a narrow range of hydraulic conductivities of the Dakota aquifer, from 37 to 50 feet per day. Consequently, an average hydraulic conductivity of 40 feet per day was used to estimate the potential yield to wells completed in the aquifer. Yields of more than 250 gallons per minute can be expected throughout much of the study area and more than 1000 gallons per minute could be produced in some areas. The quality of water from the Dakota is a calcium, magnesium, sulfate type. It is generally suitable for irrigation purposes, based on comparisons of sodium adsorption ratios and electrical conductivities. In some areas the aquifer has water with high salinity hazard that may restrict its use to irrigation of only well drained types of soil. The concentration of radium226 and other radionuclides exceed recommended limits at several sites. The quality of water pumped from the aquifer may be altered by induced leakage from the underlying aquifers in Paleozoic age rocks if withdrawals reverse the pattern of natural flow from the Dakota into the Paleozoic aquifers. Evidence for such a reversal exists in the area around the city of LeMars.

Iowa↗