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M. E. Brigham

Publications and source records attributed to M. E. Brigham.

11 recordsLinked to original sources
USGS2012

Landscape controls on total and methyl Hg in the Upper Hudson River basin, New York, USA

Approaches are needed to better predict spatial variation in riverine Hg concentrations across heterogeneous landscapes that include mountains, wetlands, and open waters. We applied multivariate linear regression to determine the landscape factors and chemical variables that best account for the spatial variation of total Hg (THg) and methyl Hg (MeHg) concentrations in 27 sub-basins across the 493 km 2 upper Hudson River basin in the Adirondack Mountains of New York. THg concentrations varied by sixfold, and those of MeHg by 40-fold in synoptic samples collected at low-to-moderate flow, during spring and summer of 2006 and 2008. Bivariate linear regression relations of THg and MeHg concentrations with either percent wetland area or DOC concentrations were significant but could account for only about 1/3 of the variation in these Hg forms in summer. In contrast, multivariate linear regression relations that included metrics of (1) hydrogeomorphology, (2) riparian/wetland area, and (3) open water, explained about 66% to >90% of spatial variation in each Hg form in spring and summer samples. These metrics reflect the influence of basin morphometry and riparian soils on Hg source and transport, and the role of open water as a Hg sink. Multivariate models based solely on these landscape metrics generally accounted for as much or more of the variation in Hg concentrations than models based on chemical and physical metrics, and show great promise for identifying waters with expected high Hg concentrations in the Adirondack region and similar glaciated riverine ecosystems.

New York↗
USGS2012

Characterizing mercury concentrations and fluxes in a Coastal Plain watershed: Insights from dynamic modeling and data

Mercury (Hg) is one of the leading water quality concerns in surface waters of the United States. Although watershed-scale Hg cycling research has increased in the past two decades, advances in modeling watershed Hg processes in diverse physiographic regions, spatial scales, and land cover types are needed. The goal of this study was to assess Hg cycling in a Coastal Plain system using concentrations and fluxes estimated by multiple watershed-scale models with distinct mathematical frameworks reflecting different system dynamics. We simulated total mercury (Hg T , the sum of filtered and particulate forms) concentrations and fluxes from a Coastal Plain watershed (McTier Creek) using three watershed Hg models and an empirical load model. Model output was compared with observed in-stream Hg T . We found that shallow subsurface flow is a potentially important transport mechanism of particulate Hg T during periods when connectivity between the uplands and surface waters is maximized. Other processes (e.g., stream bank erosion, sediment re-suspension) may increase particulate Hg T in the water column. Simulations and data suggest that variable source area (VSA) flow and lack of rainfall interactions with surface soil horizons result in increased dissolved Hg T concentrations unrelated to DOC mobilization following precipitation events. Although flushing of DOC-Hg T complexes from surface soils can also occur during this period, DOC-complexed Hg T becomes more important during base flow conditions. TOPLOAD simulations highlight saturated subsurface flow as a primary driver of daily Hg T loadings, but shallow subsurface flow is important for Hg T loads during high-flow events. Results suggest limited seasonal trends in Hg T dynamics.

South Carolina↗
USGS2002

Methylmercury in flood-control impoundments and natural waters of northwestern Minnesota, 1997-99

We studied methylmercury (MeHg) and total mercury (HgT) in impounded and natural surface waters in northwestern Minnesota, in settings ranging from agricultural to undeveloped. In a recently constructed (1995) permanent-pool impoundment, MeHg levels typically increased from inflow to outflow during 1997; this trend broke down from late 1998 to early 1999. MeHg levels in the outflow reached seasonal maxima in mid-summer (maximum of 1.0 ng L −1 in July 1997) and late-winter (maximum of 6.6 ng L −1 in February 1999), and are comparable to high levels observed in new hydroelectric reservoirs in Canada. Spring and autumn MeHg levels were typically about 0.1–0.2 ng L −1 . Overall, MeHg levels in both the inflow (a ditch that drains peatlands) and outflow were significantly higher than in three nearby reference natural lakes. Eleven older permanent-pool impoundments and six natural lakes in northwestern Minnesota were sampled five times. The impoundments typically had higher MeHg levels (0.071–8.36 ng L −1 ) than natural lakes. Five of six lakes MeHg levels typical of uncontaminated lakes (0.014–1.04 ng L −1 ) with highest levels in late winter, whereas a hypereutrophic lake had high levels (0.37–3.67 ng L −1 ) with highest levels in mid-summer. Seven temporary-pool impoundments were sampled during summer high-flow events. Temporary-pool impoundments that retained water for about 10–15 days after innundation yielded pronounced increases in MeHg from inflow to outflow, in one case reaching 4.6 ng L −1 , which was about 2 ng L −1 greater than the mean inflow concentration during the runoff event.

Minnesota↗
USGS1998

Water quality in the Red River of the North Basin, Minnesota, North Dakota, and South Dakota, 1992-95

This report is intended to summarize major findings that emerged between 1992 and 1995 from the water-quality assessment of the River River of the North basin study unit and to relate these findings to water-quality issues of regional and national concern. The information in primarily intended for those who are involved in water-resource management. Yet the information contained here may also interest those who simply wish to know more about the quality of water in the rivers and aquifers in the area where they live.

Circular↗
USGS1997

Ground-water sampling methods and quality-control data for the Red River of the North basin, Minnesota, North Dakota, and South Dakota, 1993-95

Ground-water-quality samples were collected for the intensive data-collection phase of the Red River of the P Torth Basin study unit, one of 60 study units of the National Water Quality Assessment (NAWQA) Program throughout the United States. The sampling protocols used were designed for the NAWQA Program. The protocols include sampling equipment, cleaning procedures, sample-collection methods, and quality-control plans to monitor the accuracy of the data collected. One of the goals of the NAWQA Program was to collect data using similar methcds to build a nationally consistent water-quality data base. Quality-control data demonstrated that most constituents measured for this study yielded reproducible data, with low to undetectable contamination from the sampling and analytical procedures. Several constituents were occasionally or frequently detected in blank samples at levels similar to low-concentration ground-water-quality samples. For example, iron was detected in 75 percent of the blank samples, with a maximum concentration of 27 [ig/L, indicating that iron contamination may interfere with its determination at low levels in ground waters. Copper, aluminum, and dissolved organic carbon concentrations in blank samples overlap those determined in ground-waterquality samples, thereby precluding quantitative reporting of those constituents. Most pesticide data are reproducible, with minimal bias. Some pesticides had low but consistent recoveries; these data may be useful if spike and surrogate data are carefully considered. Data for some pesticides measured in this study should not be quantitatively reported or used, because they may underestimate the concentrations of those pesticides in ground waters.

Minnesota, North Dakota, South Dakota↗
USGS1997

Nutrients, suspended sediment, and pesticides in streams in the Red River of the North basin, Minnesota, North Dakota, and South Dakota, 1993-95

Fifteen stream sites in the Red River of the North Basin were sampled during 1993-95 to assess levels of nutrients, organic carbon, and suspended sediment, and five sites were sampled for pesticides. Concentrations varied seasonally and were related to periods of fertilizer and pesticide application, and to runoff. Concentrations of several constituents were related to the physiographic area the stream drains, but other factors such as local land use frequently complicated that relation. Median dissolved nitrogen concentrations were highest in streams influenced by the Red River Valley Lake Plain physiographic area. Organic nitrogen comprised the largest part of the dissolved nitrogen in streams. Ammonia was negligible most of the year, but accumulated under ice in late winter. Nitrate concentrations generally were highest during snowmelt and rainfall runoff. Phosphorus in streams mostly was in the dissolved form, which is readily available to biota. Streams draining the Moraine and Lake-Washed Till Plain had the lowest concentrations of total phosphorus, while Drift Prairie and Red River Valley Lake Plain streams had the highest concentrations. Concentrations of both dissolved and suspended phosphorus increased substantially during runoff of snowmelt and rainfall. The Bois de Sioux River Basin had the highest nitrogen yield. High nitrogen and phosphorus yields probably were related to agricultural practices in the Bois de Sioux River Basin. High phosphorus concentrations in the Pembina River probably result from agricultural practices and runoff from the steep terrain in the basin. Improved wastewater treatment appears to have reduced ammonia concentrations in streams, but has resulted in increased nitrate concentrations. The loads of nitrogen and phosphorus in the Red River of the North during this study were about twice as high as historical loads, but still were only about 4.1 and 2.4 percent, respectively, of the amounts introduced to the study unit. Dissolved organic carbon concentrations above 15 mg/L were common in streams draining peatlands. Suspended organic carbon concentrations were highly variable and generally were highest during runoff. Most suspended sediment in streams was clay and silt sized particles. The Pembina River had the highest concentrations and yields of suspended sediment, probably the result of erosion along this relatively high-gradient stream. Streams having an abundance of lakes, reservoirs, and wetlands in their watersheds had the lowest sediment concentrations and yields. Several pesticides were frequently detected. Atrazine and other triazine compounds were detected in most stream-water samples throughout the study. Concentrations of triazine herbicides were highest in streams draining southern parts of the study unit where they are applied to corn. Triallate was commonly detected in northern streams where it is applied to small grains and sunflowers. Simazine and prometon were commonly detected, but generally are used only for nonagricultural purposes. Few insecticides were detected in stream-water samples. Carbofuran was the most commonly detected insecticide and was found in 16 percent of the samples. The most heavily used herbicides, 2,4-D and MCPA, were infrequently detected in stream-water samples. Of the estimated applications of atrazine, triallate, and 2,4-D, about 0.9, 0.06, and 0.02 percent of each of these compounds, respectively, was carried out of the study unit by the Red River of the North during 1993-95.

Minnesota, North Dakota, South Dakota↗
USGS1996

Trace elements and organic contaminants in stream sediments from the Red River of the North Basin

To assess the presence and distribution of a variety of hydro-phobic chemicals in streams in the Red River of the North Basin, bottom sediments were analyzed for trace elements, organochlorines, and polycyclic aromatic hydrocarbons (PAHs). Glaciolacustrine clays and carbonate minerals are common in fine sediments of the region, and can help explain the distribution of many elements. Aluminum (Al), an indicator of glaciolacustrine clay minerals, correlates strongly (r>0.75, p<0.05) with Cr, Co, Fe, La, Li, K, Sc, and Ti; and moderately (0.55<r<0.75) with Ce, Cu, Ga, Nd, Ni, Th, V, and Y. Excluding the tributary Pembina River Basin, Eu, Nb, Ce, La, Nd, and Ni also have strong correlations with Al. Al correlates negatively with major elements associated with carbonate minerals (Ca, Mg, and inorganic carbon). No significant correlations with Al, Ca, or Mg were observed for As, Pb, Mn, Hg, Se, or Ag, which implies that these elements have different environmental sources or behaviors than glaciolacustrine clays or carbonate minerals. Reduction-oxidation processes may influence Mn distribution. Lead (Pb) and mercury (Hg) are known to be anthropogenically enriched in the environment--their distribution may indicate environmental enrichment in Red River of the North Basin streams. Organochlorines detected are limited to traces of DDT and its metabolites (mostlyp,p'-DDE). Fourteen PAHs, which are constituents of fossil fuels and of combustion byproducts, were detected in at least halfthe sediment samples; pyrene and fluoranthene were detected in about 90 percent of samples. The contaminants detected in this study were present at low levels, likely indicative of diffuse or remote sources; they occur widely in the environment.

Minnesota, North Dakota, South Dakota↗