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Lewis L. DeLong

Publications and source records attributed to Lewis L. DeLong.

4 recordsLinked to original sources

Estimating constituent loads

Several recent articles have called attention to the problem of retransformation bias, which can arise when log linear regression models are used to estimate sediment or other constituent loads. In some cases the bias can lead to underestimation of constituent loads by as much as 50%, and several procedures have been suggested for reducing or eliminating it. However, some of the procedures recommended for reducing the bias can actually increase it. This paper compares the bias and variance of three procedures that can be used with log linear regression models: the traditional rating curve estimator, a modified rating curve method, and a minimum variance unbiased estimator (MVUE). Analytical derivations of the bias and efficiency of all three estimators are presented. It is shown that for many conditions the traditional and the modified estimator can provide satisfactory estimates. However, other conditions exist where they have substantial bias and a large mean square error. These conditions commonly occur when sample sizes are small, or when loads are estimated during high-flow conditions. The MVUE, however, is unbiased and always performs nearly as well or better than the rating curve estimator or the modified estimator provided that the hypothesis of the log linear model is correct. Since an efficient unbiased estimator is available, there seems to be no reason to employ biased estimators.

Water Resources Research↗

Extraction and concentration of organic solutes from water

A continuous extraction apparatus is described. It extracts and simultaneously concentrates organic solutes from water. Any immiscible solvent can be used in this apparatus if the solute will partition between the solvent and water. A concentration factor of up to 10 5 is obtained with this technique. The dipole moment difference between the solute and solvent is demonstrated to be an index of the extraction efficiency. Optimum extraction of a given molecular species may be obtained by use of this index.

Analytical Chemistry↗

Mass conservation: 1-D open channel flow equations

Unsteady flow simulation in natural rivers is often complicated by meandering channels of compound section. Hydraulic properties and the length of the wetted channel may vary significantly as a meandering river inundates its adjacent floodplain. The one-dimensional, unsteady, open-channel flow equations can be extended to simulate floods in channels of compound section if it is assumed that the lateral velocities are negligible, the water surface is level across the section, and the effects of turbulence and friction may be adequately described by resistance laws used for uniform flow. It is shown that the equations derived from the addition of differential equations individually describing flow in main and overbank channels do not conserve mass when overbank and main channels are of different lengths. Equations derived through the use of appropriate integral relations, however, do conserve mass and momentum in the general case and are not limited to the specification of one main and two overbank channels.

Journal of Hydraulic Engineering↗