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Lawrence W. Snee

Publications and source records attributed to Lawrence W. Snee.

At least 19 recordsLinked to original sources

The Miocene stratigraphy of the Laberinto area (Río Ica Valley) and its bearing on the geological history of the East Pisco Basin (south-central Peru)

Global sea-level changes and substantial vertical displacement along the Monte Grande Fault (MGF) in the lower Río Ica Valley of south-central Peru influenced the accumulation of bioclast-bearing and diatom-bearing Miocene siliciclastic sediments in an area of the East Pisco forearc basin (EPB) colloquially known as Laberinto. Two depositional hiatuses in the Laberinto area (∼17–14 Ma, ∼12.5–10 Ma) manifest as sediment-filled erosional depressions a few kilometers in breadth. Erosion of the older depression was preceded by an ∼18-Ma massive debris flow, possibly triggered by motion on the MGF causing lower Miocene lithoclastic olistoliths of up to two hundred meters length to spill off the footwall block. Sediment shed from the same footwall block may have formed previously recognized early Miocene deltas. From 14–13 Ma, the older depression filled with sediments herein assigned to the provisionally named Laberinto, Pampa, and Naranja members of the Pisco Formation, the latter member being characterized by marine delta foreset beds. The three members are at least partly correlative with the Pisco-0 sequence of the Pisco Formation. The younger depression was overrun at 10 Ma by debris flows of lithoclastic and granitic cobbles and boulders, then filled with diatomaceous silty sand with five-meter-sized lithoclastic olistoliths. The two lithologies constitute the provisionally named Mature Formation. Radiometric and newly revised biochronological data from throughout the EPB coupled with new diatom data from the Laberinto area have provided new insights into the correlation of sequences within the Chilcatay and Pisco formations and the interaction of local and basin-wide tectonism and global eustatic sea-level events across the basin.

southern Peru

Geochronology of Cenozoic rocks in the Bodie Hills, California and Nevada

The purpose of this report is to present geochronologic data for unaltered volcanic rocks, hydrothermally altered volcanic rocks, and mineral deposits of the Miocene Bodie Hills and Pliocene to Pleistocene Aurora volcanic fields of east-central California and west-central Nevada. Most of the data presented here were derived from samples collected between 2000–13, but some of the geochronologic data, compiled from a variety of sources, pertain to samples collected during prior investigations. New data presented here (tables 1 and 2; Appendixes 1–3) were acquired in three U.S. Geological Survey (USGS) 40 Ar/ 39 Ar labs by three different geochronologists: Robert J. Fleck (Menlo Park, CA), Lawrence W. Snee (Denver, CO), and Michael A. Cosca (Denver, CO). Analytical methods and data derived from each of these labs are presented separately. The middle to late Miocene Bodie Hills volcanic field (BHVF) is a large (>700 km 2 ), long-lived (~9 million years [m.y.]), episodic eruptive complex (John and others, 2012) in the southern segment of the ancestral Cascades arc (du Bray and others, written commun., 2015) north of Mono Lake and east of Bridgeport, California (fig. 1). The field is near the west edge of the Walker Lane and the northwest edge of the Mina deflection where structures related to these shear zones may have localized magmatism. The Walker Lane (fig. 1) is a broad, northwest-striking zone of right-lateral shear that accommodates right-lateral motion between the Pacific and North America plates; the Mina deflection constitutes a 60-km-long right step in the Walker Lane (Faulds and Henry, 2008; Oldow, 1992, 2003; Stewart, 1988). The Bodie Hills volcanic field includes at least 31 volcanic rock units erupted from 21 significant volcanic eruptive centers. Four trachyandesite stratovolcanoes developed along the margins of the volcanic field and numerous silicic trachyandesite to rhyolite flow dome complexes erupted more centrally. Volcanism in the Bodie Hills volcanic field peaked at two periods, ~15.0 to 12.6 million years before present (Ma) and ~9.9 to 8.0 Ma, which were dominated by emplacement of large stratovolcanoes and large silicic trachyandesite-dacite lava domes, respectively. A final period of small-volume silicic dome emplacement began in the western part of the volcanic field at ~6 Ma and culminated at ~5.5 Ma (John and others, 2012).

California, Nevada

Geologic Map of Baranof Island, southeastern Alaska

This map updates the geology of Baranof Island based on fieldwork, petrographic analyses, paleontologic ages, and isotopic ages. These new data provide constraints on depositional and metamorphic ages of lithostratigraphic rock units and the timing of structures that separate them. Kinematic analyses and thermobarometric calculations provide insights on the regional tectonic processes that affected the rocks on Baranof Island. The rocks on Baranof Island are components of a Paleozoic to Early Tertiary oceanic volcanic arc complex, including sedimentary and volcanic rocks that were deposited on and adjacent to the arc complex, deformed, and accreted. The arc complex consists of greenschist to amphibolite facies Paleozoic metavolcanic and metasedimentary rocks overlain by lower-grade Triassic metasedimentary and metavolcanic rocks and intruded by Jurassic calc-alkaline plutons. The Paleozoic rocks correlate well in age and lithology with rocks of the Sicker and Buttle Lake Groups of the Wrangellia terrane on Vancouver Island and differ from rocks of the Skolai Group that constitute basement to type-Wrangellia in the Wrangell Mountains. The Jurassic intrusive rocks are correlative with plutons that intrude the Wrangellia terrane on Vancouver Island but are lacking in the Wrangell Mountains. The rocks accreted beneath the arc complex are referred to as the Baranof Accretionary Complex in this report and are correlated with the Chugach Accretionary Complex of southern and southeastern Alaska and with the Pacific Rim Complex on Vancouver Island. Stratigraphic correlations between upper- and lower-plate rocks on Baranof Island and western Chichagof Island with rocks on Haida Gwaii and Vancouver Island, in addition to correlative ages of intrusive rocks and restorations of the Fairweather-Queen Charlotte, Chatham Strait, and Peril Strait Faults that define the Baranof-Chichagof block, suggest Baranof Island was near Vancouver Island at the time of initiation of arc magmatism in the Early Jurassic. Early Eocene plutons that intruded the accretionary complex outboard of the arc on Baranof Island are attributed to anatectic melting of trench sediments resulting from subduction of a spreading center. Oligocene intrusive rocks on Baranof Island correlate in age and composition with intrusive rocks in the Kano Plutonic Suite on Haida Gwaii, and similar magmatic sources are inferred.

Alaska

Mapping advanced argillic alteration at Cuprite, Nevada, using imaging spectroscopy

Mineral maps based on Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data were used to study late Miocene advanced argillic alteration at Cuprite, Nevada. Distributions of Fe-bearing minerals, clays, micas, sulfates, and carbonates were mapped using the Tetracorder spectral-shape matching system. The Al content of white micas increases toward altered areas and near intrusive rocks. Alunite composition varies from pure K to intimate mixtures of Na-K endmembers with subpixel occurrences of huangite, the Ca analogue of alunite. Intimately mixed Na-K alunite marks areas of relatively lower alteration temperature, whereas co-occurring Na-alunite and dickite may delineate relict hydrothermal conduits. The presence of dickite, halloysite, and well-ordered kaolinite, but absence of disordered kaolinite, is consistent with acidic conditions during hydrothermal alteration. Partial lichen cover on opal spectrally mimics chalcedony, limiting its detection to lichen-free areas. Pods of buddingtonite are remnants of initial quartz-adularia-smectite alteration. Thus, spectral maps provide a synoptic view of the surface mineralogy, and define a previously unrecognized early steam-heated hydrothermal event. Faulting and episodes of hydrothermal alteration at Cuprite were intimately linked to upper plate movements above the Silver Peak-Lone Mountain detachment and growth, collapse, and resurgence of the nearby Stonewall Mountain volcanic complex between 8 and 5 Ma. Isotopic dating indicates that hydrothermal activity started at least by 7.61 Ma and ended by about 6.2 Ma. Spectral and stable isotope data suggest that Cuprite is a late Miocene low-sulfidation adularia-sericite type hot spring deposit overprinted by late-stage, steam-heated advanced argillic alteration formed along the margin of the Stonewall Mountain caldera.

Nevada

Thermochronology of Cretaceous batholithic rocks in the northern Peninsular Ranges batholith, southern California: Implications for the Late Cretaceous tectonic evolution of southern California

The thermochronology for several suites of Mesozoic metamorphic and plutonic rocks collected throughout the northern Peninsular Ranges batholith (PRB) was studied as part of a collaborative isotopic study to further our understanding of the magmatic and tectonic history of southern California. These sample suites include: a traverse through the plutonic rocks across the northern PRB ( N = 29), a traverse across a central structural and metamorphic transition zone of mainly metasedimentary rocks at Searl ridge ( N = 20), plutonic samples from several drill cores ( N = 7) and surface samples ( N = 2) from the Los Angeles Basin, a traverse across the Eastern Peninsular Ranges mylonite zone ( N = 6), and a suite of plutonic samples collected across the northern PRB ( N = 13) from which only biotite 40 Ar/ 39 Ar ages were obtained. These geochronologic data help to characterize five major petrologic, geochemical, and isotopic zonations of the PRB (western zone, WZ; western transition zone, WTZ; eastern transition zone, ETZ; eastern zone, EZ; and upper-plate zone, UPZ). Apparent cooling rates were calculated using U-Pb zircon (zr) and titanite (sphene) ages; 40 Ar/ 39 Ar ages from hornblende (hbl), biotite (bi), and K-feldspar (Kf); and apatite fission-track (AFT) ages from the same samples. The apparent cooling rates across the northern PRB vary from relatively rapid in the west (zr-hbl ~210 °C/m.y.; zr-bio ~160 °C/m.y.; zr-Kf ~80 °C/m.y.) to less rapid in the central (zr-hb ~280 °C/m.y.; zr-bio ~90 °C/m.y.; zr-Kf ~60 °C/m.y.) and eastern (zr-hbl ~185 °C/m.y.; zr-bio ~180 °C/m.y.; zr-Kf ~60 °C/m.y.) zones. An exception in the eastern zone, the massive San Jacinto pluton, appears to have cooled very rapidly (zr-bio ~385 °C/m.y.). Apparent cooling rates for the UPZ samples are consistently slower in comparison (~25–45 °C/m.y.), regardless of which geochronometers are used. Notable characteristics of the various ages from different dating methods include: (1) Zircon ages indicate a progressive younging of magmatic activity from west to east between ca. 125 and 90 Ma. (2) Various geochronometers were apparently affected by emplacement of the voluminous (ETZ and EZ) La Posta–type plutons emplaced between 99 and 91 Ma. Those minerals affected include K-feldspar in the western zone rocks, biotite and K-feldspar in the WTZ rocks, and white mica and K-feldspar in rocks from Searl ridge. (3) The AFT ages record the time the rocks cooled through the AFT closure temperature (~100 °C in these rocks), likely due to exhumation. Throughout most of the northern traverse, the apatite data indicate the rocks cooled relatively quickly through the apatite partial annealing zone (PAZ; from ~110 °C to 60 °C) and remained at temperatures less than 60 °C as continued exhumation cooled them to present-day surface temperatures. The ages indicate that the western “arc” terrane of the WZ was being uplifted and cooled at ca. 91 Ma, during or shortly after intrusion of the 99–91 Ma La Posta–type plutons to the east. Uplift and cooling occurred later, between ca. 70 Ma and ca. 55 Ma, in the central WTZ, ETZ, and EZ rocks, possibly as upwarping in response to events in the UPZ. The UPZ experienced differential exhumation at ca. 50–35 Ma: Cooling on the western edge was taking place at about the same time or shortly after cooling in the younger samples in the ETZ and EZ, whereas on the east side of the UPZ, the rocks cooled later (ca. 35 Ma) and spent a prolonged time in the apatite PAZ compared to most northern traverse samples. Apparent cooling rates from Los Angeles Basin drill core samples of plutonic rocks show that four are similar to the WTZ thermal histories, and two are similar to the WTZ histories, indicating that the eastern part of the Los Angeles Basin area is underlain by mainly western zone PRB rocks. Thermal histories revealed by samples from Searl ridge indicate that the WTZ magmatism intruded the metasedimentary rocks prior to their deformation and metamorphism at ca. 97 Ma. Both low-grade schists and metasandstones of the western side of the ridge and high-grade gneisses of the eastern side of the ridge have thermal histories consistent with eastern zone rocks—suggesting a temporal/thermal relationship between the western transition zone and the eastern zones. Limited ages from six samples across the Eastern Peninsular Ranges mylonite zone (EPRMZ) indicate that this zone underwent cooling after emplacement of the youngest UPZ rocks at 85 Ma, suggesting that thrusting along the EPRMZ was either coeval with emplacement of the UPZ plutonic rocks or occurred shortly afterwards (~10–15 m.y.). Alternatively, the EPRMZ thrusting may have occurred at temperatures under ~180 °C at yet a later date. The geochronology presented here differs slightly from previous studies for similar rocks exposed across the middle and southern portions of the PRB, in that our data define a relatively smooth progression of magmatism from west to east, and the transition from western, oceanic-arc plutonism to eastern, continental arc plutonism is interpreted to have occurred at ca. 99–97 Ma and not at ca. 105 Ma.

Book chapter

Geochronology and correlation of Tertiary volcanic and intrusive rocks in part of the southern Toquima Range, Nye County, Nevada

Extensive volcanic and intrusive igneous activity, partly localized along regional structural zones, characterized the southern Toquima Range, Nevada, in the late Eocene, Oligocene, and Miocene. The general chronology of igneous activity has been defined previously. This major episode of Tertiary magmatism began with emplacement of a variety of intrusive rocks, followed by formation of nine major calderas and associated with voluminous extrusive and additional intrusive activity. Emplacement of volcanic eruptive and collapse megabreccias accompanied formation of some calderas. Penecontemporaneous volcanism in central Nevada resulted in deposition of distally derived outflow facies ash-flow tuff units that are interleaved in the Toquima Range with proximally derived ash-flow tuffs. Eruption of the Northumberland Tuff in the north part of the southern Toquima Range and collapse of the Northumberland caldera occurred about 32.3 million years ago. The poorly defined Corcoran Canyon caldera farther to the southeast formed following eruption of the tuff of Corcoran Canyon about 27.2 million years ago. The Big Ten Peak caldera in the south part of the southern Toquima Range Tertiary volcanic complex formed about 27 million years ago during eruption of the tuff of Big Ten Peak and associated air-fall tuffs. The inferred Ryecroft Canyon caldera formed in the south end of the Monitor Valley adjacent to the southern Toquima Range and just north of the Big Ten Peak caldera in response to eruption of the tuff of Ryecroft Canyon about 27 million years ago, and the Moores Creek caldera just south of the Northumberland caldera developed at about the same time. Eruption of the tuff of Mount Jefferson about 26.8 million years ago was accompanied by collapse of the Mount Jefferson caldera in the central part of the southern Toquima Range. An inferred caldera, mostly buried beneath alluvium of Big Smoky Valley southwest of the Mount Jefferson caldera, formed about 26.5 million years ago with eruption of the tuff of Round Mountain. The Manhattan caldera south of the Mount Jefferson caldera and northwest of the Big Ten Peak caldera formed in association with eruption of a series of tuffs, principally the Round Rock Formation, mostly ash-flow tuff, about 24.4 million years ago. Extensive 40 Ar/ 39 Ar dating of about 60 samples that represent many of the Tertiary extrusive and intrusive rocks in the southern Toquima Range provides precise ages that refine the chronology of previously dated units. New geochronologic data indicate that the petrogenetically related Corcoran Canyon, Ryecroft Canyon, and Mount Jefferson calderas formed during a period of about 560,000 years. Electron microprobe analyses of phenocrysts from 20 samples of six dated units underscore inferred petrogenetic relations among some of these units. In particular, compositions of augite, hornblende, and biotite in tuffs erupted from the Corcoran Canyon, Ryecroft Canyon, and Mount Jefferson calderas are similar, which suggests that magmas represented by these tuffs have similar petrogenetic histories. The unique occurrence of hypersthene in Isom-type tuff confirms its derivation from a source beyond the southern Toquima Range.

Nevada

Structure, metamorphism, and geochronology of the Cosmos Hills and Ruby Ridge, Brooks Range schist belt, Alaska

The boundary of the internal zones of the Brooks Range orogenic belt (the schist belt) is a fault contact that dips toward the hinterland (the Yukon-Koyukuk province). This fault, here referred to as the Cosmos Hills fault zone, juxtaposes oceanic rocks and unmetamorphosed sedimentary rocks structurally above blueschist-to-greenschist facies metamorphic rocks of the schist belt. Near the fault contact, schist belt rocks are increasingly affected by a prominent, subhorizontal transposition foliation that is locally mylonitic in the fault zone. Structural and petrologic observations combined with 40 Ar/ 39 Ar incremental-release geochronology give evidence for a polyphase metamorphic and deformational history beginning in the Middle Jurassic and continuing until the Late Cretaceous. Our 40 Ar/ 39 Ar cooling age for Jurassic metamorphism is consistent with stratigraphic and other evidence for the onset of Brooks Range orogenesis. Jurassic metamorphism is nearly everywhere overprinted by a regional greenschist-facies event dated at 130–125 Ma. Near the contact with the Cosmos Hills fault zone, the schist belt is increasingly affected by a younger greenschist metamorphism that is texturally related to a prominent foliation that folds and transposes an older fabric. The 40 Ar/ 39 Ar results on phengite and fuchsite that define this younger fabric give recrystallization ages ranging from 103 to less than 90 Ma. We conclude that metamorphism that formed the transposition fabric peaked around 100 Ma and may have continued until well after 90 Ma. This age for greenschist metamorphism is broadly synchronous with the depositional age of locally derived, shallow-marine clastic sedimentary strata in the hanging wall of the fault zone and thus substantiates the interpretation that the fault zone accommodated extension in the Late Cretaceous. This extension unroofed and exhumed the schist belt during relative subsidence of the Yukon-Koyukuk province.

Tectonics

A chronicle of Miocene extension near the Colorado Plateau-Basin and Range boundary, southern White Hills, northwestern Arizona: Paleogeographic and tectonic implications

In northwestern Arizona, the high-standing, relatively unextended Colorado Plateau abruptly gives way across a system of major west-dipping normal faults to a highly extended part of the Basin and Range province known as the northern Colorado River extensional corridor. The transition from unextended to highly extended upper crust is unusually sharp within this region, contrasting with a broad transition zone elsewhere. The southern White Hills lie near the eastern margin of the extensional corridor in northwestern Arizona and contain a large east-tilted half graben that chronicles Miocene extension and constrains the timing of structural demarcation between the Colorado Plateau and Basin and Range province during Neogene time. This growth-fault basin is bounded on the east by the west-dipping Cyclopic and Cerbat Mountains fault zones. Greater tilts in the hanging walls suggest that these faults have listric geometries. The stratigraphy in the half graben consists of Miocene vol canic rocks intercalated with an eastward-thickening wedge of synextensional fanglomerates. Tilts in the Miocene units decrease up section from ~75° to 5°. Recent 40 Ar/ 39 Ar dating (11 new dates) of variably tilted volcanic rocks in the growth-fault basin and regional relations constrain the timing of east-west extension between ca. 16.6 and <9 Ma, with peak extension from ca. 16.6 to 15.2 Ma. Capping 8.7 Ma basalts are tilted 5°–10° and record the waning stages of extension. Thus, the sharp boundary between the Colorado Plateau and Basin and Range began developing by ca. 16.5 Ma and has changed little since ca. 9 Ma. Major extension and basin development significantly lowered base level within the extensional corridor and induced headward erosion into the western margin of the Colorado Plateau, which ultimately facilitated development of the western Grand Canyon. Abundant clasts of 1.7 Ga megacrystic granite in the eastward-thickening fanglomerates within the growth-fault basin suggest a partial provenance from the Garnet Mountain area along or near the western margin of the Colorado Plateau beginning as early as ca. 16 Ma and continuing to ca. 9 Ma.

Arizona

Uranium-Lead Zircon Ages and Sr, Nd, and Pb Isotope Geochemistry of Selected Plutonic Rocks from Western Idaho

Across the Salmon River suture in western Idaho, where allochthonous Permian to Cretaceous oceanic rocks are juxtaposed against Proterozoic North American rocks, a wide variety of plutonic rocks are exposed. Available data indicate much variation in composition, source, and structural state of these plutons. The plutonic rocks were long described as the western border zone of the Cretaceous Idaho batholith but limited pre-existing age data indicate more complicated origins. Because the affinity and age of the plutonic rocks cannot be reliably determined from field relations, TIMS U-Pb dating in conjunction with Sr, Nd, and Pb isotopic studies of selected plutons across the suture in western Idaho were undertaken. The data indicate three general groups of plutons including (1) those that intruded the island arc terranes during the Triassic and Jurassic, those that intruded near the western edge of oceanic rocks along the suture in the Early Cretaceous, and the plutons of the Idaho batholith that intruded Proterozoic North American rocks in the Late Cretaceous. Plutons that intruded Proterozoic North American rocks commonly include xenocrystic zircons and in several cases, ages could not be determined. The least radiogenic Sr and most radiogenic Nd are found among the Blue Mountains superterrane island arc samples. Suture-zone plutons have isotopic characteristics that span the range between Idaho batholith and island arc samples but mostly follow island arc signatures. Plutons of the Idaho batholith have the most radiogenic initial Pb and Sr ratios and the least radiogenic Nd of the samples analyzed.

Open-File Report

Paleoproterozoic high-sulfidation mineralization in the Tapajós gold province, Amazonian Craton, Brazil: geology, mineralogy, alunite argon age, and stable-isotope constraints

The Brazilian Tapaj&oacute;s gold province contains the first evidence of high-sulfidation gold mineralization in the Amazonian Craton. The mineralization appears to be in large nested calderas. The Tapaj&oacute;s&ndash;Parima (or Ventuari&ndash;Tapaj&oacute;s) geological province consists of a metamorphic, igneous, and sedimentary sequence formed during a 2.10 to 1.87 Ga ocean&minus;continent orogeny. The high-sulfidation mineralization with magmatic-hydrothermal alunite is related to hydrothermal breccias hosted in a rhyolitic volcanic ring complex that contains granitic stocks ranging in age from 1.89 to 1.87 Ga. Cone-shaped hydrothermal breccias, which flare upward, contain vuggy silica and have an overlying brecciated cap of massive silica; the deposits are located in the uppermost part of a ring-structure volcanic cone. Drill cores of one of the hydrothermal breccias contain alunite, natroalunite, pyrophyllite, andalusite, quartz, rutile, diaspore, woodhouseite&ndash;svanbergite, kaolinite, and pyrite along with inclusions of enargite&ndash;luzonite, chalcopyrite, bornite, and covellite. The siliceous core of this alteration center is surrounded by advanced argillic and argillic alteration zones that grade outward into large areas of propylitically altered rocks with sericitic alteration assemblages at depth. Several occurrences and generations of alunite are observed. Alunite is disseminated in the advanced argillic haloes that envelop massive and vuggy silica or that underlie the brecciated silica cap. Coarse-grained alunite also occurs in branching veins and locally is partly replaced by a later generation of fine-grained alunite. Silicified hydrothermal breccias associated with the alunite contain an estimated reserve of 30 tonnes of gold in rock that grades up to 4.5 g t &minus;1 Au. Seven alunite samples gave 40 Ar/ 39 Ar ages of 1.869 to 1.846 Ga, with various degrees of apparent minor Ar loss. Stable isotopic data require a magmatic-hydrothermal origin for the alunite, typical for high-sulfidation mineralization. The &delta; 34 S values of most samples of alunite range from 14.0&permil; to 36.9&permil;. Sulfur isotopic alunite&ndash;pyrite and oxygen isotopic alunite SO 4 &minus;OH temperatures range from 130 to 420 &deg;C. The &delta;D H 2 O and &delta; 18 O H 2 O values for alunite-forming hydrothermal fluids suggest a predominance of magmatic water, with a small meteoric contribution. A rare sample of supergene alunite has a &delta; 34 S value of 4.1&permil; and an 40 Ar/ 39 Ar age of 51.3&plusmn;0.1 Ma. Other than local foliation in the volcanic rocks and recrystallization of alunite near faults, the mineralization and associated alteration appears to have been remarkably undisturbed by later metamorphism and by supergene alteration. The Au mineralization was preserved because of burial by sediments and tuffs in taphrogenic basins that probably developed shortly after mineralization and were probably first exhumed at about 60 Ma. Because high-sulfidation mineralization forms at relatively shallow crustal levels, the discoveries in Tapaj&oacute;s province provide new perspectives for mineral exploration for the Amazonian and perhaps for other Precambrian cratons.

Chemical Geology

Overview of radiometric ages in three allochthonous belts of northern Venezuela: Old ones, new ones, and their impact on regional geology

The margin of northern Venezuela is a complex zone representing the orogenic events from basement formation to subsequent subduction and exhumation during transpressional collision. This boundary zone has six east-west–trending belts that each record a different segment of its development. This geologic complexity requires radiometric ages to unravel, and we herein provide 48 new ages including U-Pb (4), Rb-Sr (2), 40 Ar/ 39 Ar (24), zircon and apatite fission-track (17), and 14 C (1) ages to constrain the evolution of three of these belts. These three belts are the Cordillera de la Costa, Caucagua–El Tinaco, and Serranía del Interior belts. In the Cordillera de la Costa belt, U-Pb geochronologic data indicate portions of the basement igneous and metaigneous rocks formed in the Cambro-Ordovician (513–471 Ma). New 40 Ar/ 39 Ar data from Margarita Island indicate that some of the subduction complex was rapidly cooled and exhumed, whereas other portions indicate slower cooling. This contrasts with new 40 Ar/ 39 Ar data from the Puerto Cabello portion of the subduction complex that has Eocene to Oligocene (42–28 Ma) cooling ages. New fission-track data imply the entire Cordillera de la Costa belt from Puerto Cabello to La Guaira (∼150 km) was uplifted at the same time. In the Caucagua–El Tinaco belt, the oldest 40 Ar/ 39 Ar amphibole ages from the Tinaquillo ultramafic complex are Jurassic (190 Ma). Additional amphibole 40 Ar/ 39 Ar cooling ages are older than previously recorded in either the Tinaco or Tinaquillo complex. One amphibole 40 Ar/ 39 Ar cooling age for the Tinaco complex is similar to previous U-Pb results. New apatite fission-track results from the Serranía del Interior foreland fold and thrust belt are synchronous with exhumation in the Cordillera de la Costa belt. In addition, several zircon fission-track ages in the Serranía del Interior belt are older than their fossil ages, indicating a Cretaceous minimum provenance age for Miocene beds. Significant new findings from these geochronologic studies include (1) several igneous and metaigneous bodies that may be correlated with orogenic events in the Appalachians occur within the subduction mélange; (2) the Tinaquillo complex may record Jurassic rifting; (3) Cretaceous source rocks for the Serranía del Interior sedimentary strata; (4) exhumation of the subduction complex is segmented because two regions have significantly different cooling histories, with Margarita Island exhumed in the Cretaceous, whereas to the west, the Puerto Cabello region has widespread Paleogene cooling and exhumation ages; and (5) earthquake activity in 1812 caused uplift as recorded by exposure of Recent corals.

northern Venezuela

Geology and stratigraphy of the Challis Volcanic Group and related rocks, Little Wood River area, south-central Idaho

The southwestern part of the Challis volcanic field occupies the valley of the Little Wood River and its tributaries in the Hailey and Idaho Falls 1°×2° quadrangles of south-central Idaho. The Little Wood River area is a structurally controlled topographic basin that is partly filled by Eocene Challis Volcanic Group and younger rocks. Rock types in the Challis Volcanic Group of the Little Wood River area include, in order of decreasing abundance, andesite lava flows and tuff breccia, dacite lava flows and flow breccia, volcaniclastic sedimentary rocks, lithic tuff, nonvolcanic conglomerate, and rhyolite dikes. A basal nonvolcanic conglomerate, that locally rests on upper Paleozoic sedimentary rocks at a regional unconformity, was deposited prior to eruption of volcanic rocks. Andesite was the first volcanic rock erupted and is a voluminous sequence as thick as 3,000 ft (1,000 m). Locally thick volcaniclastic sedimentary rocks accumulated in topographic lows. A sharp transition marks the beginning of dacite eruption from fissures and flow-dome complexes. Dacite flows and breccias are as thick as 2,000 ft (600 m). An upper volcaniclastic unit was deposited in paleotopographic lows following emplacement of the main dacite unit. Next, a widespread, distinctive, lithic rich ash flow tuff, correlated with the tuff of Stoddard Gulch, was deposited over much of the area. Deposition of the tuff was followed by eruption of thin andesite and dacite lava flows and deposition of conglomeratic sedimentary rocks. The entire sequence was then intruded by a dacite flow-dome complex composed of at least three separate intrusions. The Challis Volcanic Group in the study area is calcalkaline. Andesitic rocks are typically high potassium basaltic andesite, high potassium andesite, shoshonite, and banakite (latite). Dacitic rocks are high potassium dacite and trachyte. Tuffs and vitrophyres range in composition from basaltic andesite to trachyte. The paleotopographic basin in which the Challis Volcanic Group accumulated was in part structurally controlled by preexisting west and northwest trending normal faults. Paleorelief was probably more than 2,000 ft (600 m). Rocks of the Challis Volcanic Group typically dip about 36° E., probably owing to Eocene extension and (or) basin-and-range faulting and tilting. Some potential for precious- and base- metal hydrothermal deposits is associated with northeast trending lineaments, argillic alteration, and rhyolite dikes.

Idaho

Geochemistry and Geochronology of Middle Tertiary Volcanic Rocks of the Central Chiricahua Mountains, Southeast Arizona

Middle Tertiary volcanic rocks of the central Chiricahua Mountains in southeast Arizona are the westernmost constituents of the Eocene-Oligocene Boot Heel volcanic field of southwestern New Mexico and southeastern Arizona. About two dozen volumetric ally and stratigraphically significant volcanic units are present in this area. These include large-volume, regionally distributed ash-flow tuffs and smaller volume, locally distributed lava flows. The most voluminous of these units is the Rhyolite Canyon Tuff, which erupted 26.9 million years ago from the Turkey Creek caldera in the central Chiricahua Mountains. The Rhyolite Canyon Tuff consists of 500-1,000 cubic kilometers of rhyolite that was erupted from a normally zoned reservoir. The tuff represents sequential eruptions, which became systematically less geochemically evolved with time, from progressively deeper levels of the source reservoir. Like the Rhyolite Canyon Tuff, other ashflow tuffs preserved in the central Chiricahua Mountains have equivalents in nearby, though isolated mountain ranges. However, correlation of these other tuffs, from range to range, has been hindered by stratigraphic discontinuity, structural complexity, and various lithologic similarities and ambiguities. New geochemical and geochronologic data presented here enable correlation of these units between their occurrences in the central Chiricahua Mountains and the remainder of the Boot Heel volcanic field. Volcanic rocks in the central Chiricahua Mountains are composed dominantly of weakly peraluminous, high-silica rhyolite welded tuff and rhyolite lavas of the high-potassium and shoshonitic series. Trace-element, and to a lesser extent, major-oxide abundances are distinct for most of the units studied. Geochemical and geochronologic data depict a time and spatial transgression from subduction to within-plate and extensional tectonic settings. Compositions of the lavas tend to be relatively homogeneous within particular units. In contrast, compositions of the ash-flow tuffs, including the Rhyolite Canyon Tuff, vary significantly owing to eruption from compositionally zoned reservoirs. Reservoir zonation is consistent with fractional crystallization of observed phenocryst phases and resulting residual liquid compositional evolution. Rhyolite lavas preserved in the moat of the Turkey Creek caldera depict compositional zonation that is the reverse of that expected of magma extraction from progressively deeper parts of a normally zoned reservoir. Presuming that the source reservoir was sequentially tapped from its top downward, development of reverse zonation in the rhyolite lava sequence may indicate that later erupted, more evolved magma contains systematically less wallrock contamination derived from the geochemically primitive margins of its incompletely mixed reservoir. New 40Ar/39Ar geochronology data indicate that the principal middle Tertiary volcanic rocks in the central Chiricahua Mountains were erupted between about 34.2 and 26.2 Ma, and that the 5.2 m.y. period between 33.3 and 28.1 Ma was amagmatic. The initial phase of eruptive activity in the central Chiricahua Mountains, between 34.2 and 33.3 Ma, was associated with a regional tectonic regime dominated by subduction along the west edge of North America. We infer that the magmatic hiatus, nearly simultaneous with a hiatus of similar duration in parts of the Boot Heel volcanic field east of the central Chiricahua Mountains, is related to a period of more rapid convergence and therefore shallower subduction that may have displaced subduction-related magmatic activity to a position east of the present-day Boot Heel volcanic field. The hiatus also coincides with a major plate tectonic reorganization along the west edge of North America that resulted in cessation of subduction and initiation of transform faulting along the San Andreas fault. The final period of magmatism in the central Chiricahua Mountains, between 28.1 and 23.2 Ma, ap

Professional Paper

Argon thermochronology of mineral deposits; a review of analytical methods, formulations, and selected applications

40Ar/39Ar geochronology is an experimentally robust and versatile method for constraining time and temperature in geologic processes. The argon method is the most broadly applied in mineral-deposit studies. Standard analytical methods and formulations exist, making the fundamentals of the method well defined. A variety of graphical representations exist for evaluating argon data. A broad range of minerals found in mineral deposits, alteration zones, and host rocks commonly is analyzed to provide age, temporal duration, and thermal conditions for mineralization events and processes. All are discussed in this report. The usefulness of and evolution of the applicability of the method are demonstrated in studies of the Panasqueira, Portugal, tin-tungsten deposit; the Cornubian batholith and associated mineral deposits, southwest England; the Red Mountain intrusive system and associated Urad-Henderson molybdenum deposits; and the Eastern Goldfields Province, Western Australia.

Bulletin

Geochronology and geology of late Oligocene through Miocene volcanism and mineralization in the western San Juan Mountains, Colorado

This paper presents 25 new 40Ar/39Ar dates from the main calc-alkaline ash-flow sheets and related younger plutons of the western San Juan volcanic field, the ash-flow sheets of the Lake City caldera cycle, and veins and other altered rocks in the Lake City region. The goal of the study was to produce similar quality 40Ar/39Ar ages to those currently published for the eastern and central San Juan Mountains. These new data provide a much more precise chronological framework for interpreting durations of events and their relationship to mineralization than do previously published conventional K-Ar dates for the western San Juan Mountains.

Professional Paper

Preliminary geologic map of the Chugach National Forest special study area, Alaska

In 1990, both the U.S. Geological Survey and U.S. Bureau of Mines were contacted by the Chugach National Forest (CNF) for the purpose of providing mineral resource information for the CNF Master Plan during the planning period fiscal years 1991-1994. This information is to address the terms and requirements of the 1986 Settlement Agreement and to provide mineral and geologic information useful to the CNF for making land-use decisions. In early 1992 an Interagency Agreement between the U.S. Geological Survey, the U.S. Bureau of Mines and the Chugach National Forest was signed. In this agreement the U.S. Geological Survey is to provide a report which estimates the undiscovered mineral endowments of the 'special' study area and to identify the potential for mineral discovery and development. The U.S. Bureau of Mines was to prepare a report updating the discovered mineral endowment of the Special Study Area. These reports are now published (Roe and Balen, 1994; Nelson and others, 1994). This geologic map is a component of the U.S. Geological Survey contribution to the overall project.

Alaska