Geology topics

Laurie S. Balistrieri

Publications and source records attributed to Laurie S. Balistrieri.

54 records · Page 3Linked to original sources

USGS2003

Importance of Sediment-Water Interactions in Coeur d'Alene Lake, Idaho, USA: Management Implications

A field study at Coeur d'Alene Lake, Idaho, USA, was conducted between October 1998 and August 2001 to examine the potential importance of sediment-water interactions on contaminant transport and to provide the first direct measurements of the benthic flux of dissolved solutes of environmental concern in this lake. Because of potential ecological effects, dissolved zinc and orthophosphate were the solutes of primary interest. Results from deployments of an in situ flux chamber indicated that benthic fluxes of dissolved Zn and orthophosphate were comparable in magnitude to riverine inputs. Tracer analyses and benthic-community metrics provided evidence that solute benthic flux were diffusion-controlled at the flux-chamber deployment sites. That is, effects of biomixing (or bioturbation) and ground-water interactions did not strongly influence benthic flux. Remediation efforts in the river might not produce desired water-quality effects in the lake because imposed shifts in concentration gradients near the sediment-water interface would generate a benthic feedback response. Therefore, development of water-quality models to justify remediation strategies requires consideration of contaminant flux between the water column and underlying sediment in basins that have been affected by long-term (decadal) anthropogenic activities.

Idaho↗

USGS2000

A study of porewater in water saturated sediments of levee banks and marshes in the lower Coeur d'Alene River valley, Idaho: Sampling, analytical methods, and results

This report contains information about the composition of interstitial porewater and solids from water saturated, metal contaminated levee banks at the river's edge and marshes in the lower Coeur d'Alene River valley. Data include pH, alkalinity, and concentrations of sulfate and metals (arsenic [As], cadmium [Cd], copper [Cu], iron [Fe], mercury [Hg], manganese [Mn], lead [Pb], antimony [Sb], and zinc [Zn]) in porewater and sulfur (S), carbon (C), and metal contents of associated solids. The results indicate that the pH of the porewater in all of the sediments is less than the pH of the Coeur d'Alene River. Dissolved concentrations of Mn and Fe are elevated in all of the porewater and levels of sulfate in porewater are below detection limits in almost all marsh sediments and in levee banks at the 2 sites furthest downstream. These observations suggest that levee bank and marsh sediments are suboxic or anoxic below the surface. Concentrations of dissolved Cd are greater in the Coeur d'Alene River than in porewater, while concentrations of As are greater in the porewater relative to the Coeur d'Alene River. Some concentrations of Cu, Pb, Sb, and Zn in porewater are lower, while others are higher, than dissolved concentrations in the Coeur d'Alene River. In addition, leaching experiments (i.e., Standard Elutriate Tests [SET]) were done in the laboratory to evaluate potential water quality impacts resulting from the addition of oxygen and water to these sediments. The intent of the experiments was to simulate how metal concentrations in water may be affected during dredging of contaminated sediments in the lower Coeur d'Alene River valley. The results indicate that there are releases of protons, sulfate, As, Mn, Pb, Sb, and Zn from the majority of levee bank and marsh sediments during leaching by Coeur d'Alene River water. At a water to sediment ratio of 4 to 1, most values of pH and dissolved concentrations of Cd, Fe, Pb, and Zn in the leaching solutions exceed the freshwater aquatic life standards for water of a hardness of 100 mg CaCOa/L. This work was funded by the U.S. EPA and was done to support their Remedial Investigation/Feasibility Study of the Coeur d'Alene and Spokane River basins.

Idaho↗

USGS2000

Benthic flux of metals and nutrients into the water column of Lake Coeur d'Alene, Idaho: Report of an August, 1999, pilot study

A field study was conducted between August 16-27, 1999, to provide the first direct measurements of the benthic flux of dissolved (0.2-micron filtered) solutes between the bottom sediment and water column at two sites in Lake Coeur d'Alene, Idaho. Trace metals (namely, cadmium, copper, manganese, mercury species, and zinc) and nutrients (namely, ammonia, nitrate plus nitrite, oxygen, orthophosphate and silica) were solutes of primary interest. Benthic flux (sometimes referred to as internal recycling) represents the transport of dissolved chemical species between the water column and the underlying sediment.

Idaho↗

USGS1999

Modelling removal mechanisms of Pb, Cu, Zn and Cd in acidic groundwater during the neutralization by ambient surface and ground waters

Removal of Pb, Cu, Zn, and Cd during neutralization of acid rock drainage is examined using model simulations of field conditions and laboratory experiments involving mixing of natural drainage and surface waters or groundwaters. The simulations consider sorption onto hydrous Fe and Al oxides and particulate organic carbon, mineral precipitation, and organic and inorganic solution complexation of metals for two physical systems where newly formed oxides and particulate organic matter are either transported or retained along the chemical pathway. The calculations indicate that metal removal is a strong function of the physical system. Relative to direct discharge of ARD into streams, lower metal removals are observed where ARD enters streamwaters during the latter stages of neutralization by ambient groundwater after most of the Fe has precipitated and been retained in the soils. The mixing experiments, which represent the field simulations, also demonstrated the importance of dissolved metal to particle Fe ratios in controlling dissolved metal removal along the chemical pathway. Finally, model calculations indicate that hydrous Fe oxides and particulate organic carbon are more important than hydrous Al oxides in removing metals and that both inorganic and organic complexation must be considered when modeling metal removal from aquatic systems that are impacted by sulfide oxidation.

Environmental Science & Technology↗

USGS1999

Assessing the influence of reacting pyrite and carbonate minerals on the geochemistry of drainage in the Coeur d'Alene mining district

The relative abundance of minerals that react to generate or consume acid in mineralized areas is critical in determining the quality of water draining from such areas. This work examines the fundamental reactions that influence the pH and composition of drainage from mine adits and tailings piles. We construct triangle diagrams that predict stoichiometric relationships between concentrations of dissolved SO4 dissolved Ca and Mg, and either alkalinity or acidity by considering reactions involving the oxidation of pyrite, dissolution of carbonate minerals, and precipitation of iron oxide and iron hydroxysulfate minerals. Drainage data from the Coeur d'Alene mining district are used to test our stoichiometric approach. Comparisons between theoretical predictions and drainage data indicate that the range of pH values in the mining district is due to reacting pyrite to carbonate mineral ratios that range from near 0/1 to 1/1. Calcite and ankerite are the dominant carbonate minerals that buffer the acid produced during pyrite oxidation and ferrihydrite or schwertmannite precipitation.The relative abundance of minerals that react to generate or consume acid in mineralized areas is critical in determining the quality of water draining from such areas. This work examines the fundamental reactions that influence the pH and composition of drainage from mine adits and tailings piles. We construct triangle diagrams that predict stoichiometric relationships between concentrations of dissolved SO4, dissolved Ca and Mg, and either alkalinity or acidity by considering reactions involving the oxidation of pyrite, dissolution of carbonate minerals, and precipitation of iron oxide and iron hydroxysulfate minerals. Drainage data from the Coeur d'Alene mining district are used to test our stoichiometric approach. Comparisons between theoretical predictions and drainage data indicate that the range of pH values in the mining district is due to reacting pyrite to carbonate mineral ratios that range from near 0/1 to 1/1. Calcite and ankerite are the dominant carbonate minerals that buffer the acid produced during pyrite oxidation and ferrihydrite or schwertmannite precipitation.

Idaho↗

USGS1998

Drainage from adits and tailings piles in the Coeur d'Alene mining district, Idaho; sampling, analytical methods and results

This report contains information about collecting, handling, and analyzing waters draining from adits and seeping from beneath tailings piles in the Coeur d'Alene mining district during August 1996, November 1996, and June 1997. Data include temperature, pH, conductivity, dissolved oxygen, alkalinity, flow, and total acid soluble and dissolved (<0.45 \im) major and trace ion concentrations for 11 adits and 5 tailings deposits. Interpretations of these data will be discussed in other publications.

Idaho↗

USGS1998

Preliminary estimates of benthic fluxes of dissolved metals in Coeur d'Alene Lake, Idaho

This report presents porewater and selected water column data collected from Coeur d'Alene Lake in September of 1992. Despite probable oxidation of the porewater samples during collection and handling, these data are used to calculate molecular diffusive fluxes of dissolved metals (that is, Zn, Pb, Cu, and Mn) across the sediment-water interface. While these data and calculations provide preliminary information on benthic metal fluxes in Coeur d'Alene Lake, further work is needed to verify their direction and magnitude. The benthic flux calculations indicate that the sediment is generally a source of dissolved Zn, Cu, Mn, and, possibly, Pb to the overlying water column. These benthic fluxes are compared with two other major sources of metals to Coeur d'Alene Lake-the Coeur d'Alene and St. Joe Rivers. Comparisons indicate that benthic fluxes of Zn, Pb, and Cu are generally less than half of the fluxes of these metals into the lake from the Coeur d'Alene River. However, in a few cases, the calculated benthic metal fluxes exceed the Coeur d'Alene River fluxes. Benthic fluxes of Zn and, possibly, Pb may be greater than the corresponding metal fluxes from the St. Joe River. These results have implications for changes in the relative importance of metal sources to the lake as remediation activities in the Coeur d'Alene River basin proceed.

Idaho↗

USGS1997

Distribution and mobility of molybdenum in the terrestrial environment

Molybdenum (Mo) is an essential element for many plants and animals (Newton and Otsuka, 1980). Because of its chemical properties, Mo readily provides sites for reactions and catalysis in biochemical systems (Haight and Boston, 1973). It is therefore important to understand the processes that control the distribution, speciation, and behavior of Mo in the surficial environment. These processes will affect the bioavalability of Mo and ultimately its passage into the food chain. In this chapter we discuss the distribution of Mo in the terrestrial environment and examine the factors that control its mobility.

Book chapter↗

USGS1995

The geochemical cycling of stable Pb, 210Pb, and 210Po in seasonally anoxic Lake Sammamish, Washington, USA

The geochemical processes controlling the behavior of stable Pb, 210 Pb, and 210 po in seasonally anoxic Lake Sammamish, Washington were identified from water column distributions and box model calculations. Total (sum of dissolved and particulate) inventories of stable Pb, 210 Pb, and 210 Po increased in the whole lake during the latter part of the oxic stage of the lake and were attributed to diffusion from sediments. Large decreases in the total inventories of these elements occurred during the transition from oxic to anoxic conditions, and the lowest inventories were observed during the sulfidic stage of stratification. The cycling of stable Pb and 210 Pb during oxic periods appeared to be linked to Fe cycling while 210 Po cycling was more closely linked to the cycling of Mn. The behavior of stable and radioactive Pb and, possibly, 210 Po during anoxia was influenced by sulfur cycling. Thermodynamic calculations indicated that dissolved Pb concentrations might be controlled by PbS precipitation during anoxia. Flux balance calculations during stratification indicated that atmospheric deposition was the major source of both 210 Pb and 210 Po to the lake and fluvial input was more important for 210 Po than for 210 Pb. 210 Pb and 210 Po supplied by atmospheric deposition were scavenged and removed by sedimentation from the epilimnion. Residence times with respect to scavenging and sedimentation in the epilimnion were 1–3 and 617 days, respectively, for 210 Pb and 9–22 and 9–26 days for 210 Po. Model results in the hypolimnion indicated that at certain times the radionuclides diffused out of the sediments and at other times into the sediments. Residence times with respect to sedimentation of particulate nuclides in the hypolimnion were 2–124 days for 210 Pb and 8–48 days for 210 Po. The behavior of 210 Pb and 210 Po in Lake Sammamish was compared to that in B~' kford Reservoir, Massachusetts. Although the comparison indicated similarities (e.g., links to Fe and Mn cycling, larger scavenging rates for 210 Pb than for 210 Po), the major differences between the systems were that atmospheric inputs were greater than fluvial inputs, activities of the radionuclides were lower, and the presence of sulfide in the hypolimnion during anoxia affected the cycling of stable Pb, 210 Pb, and 210 Po in Lake Sammamish.

Washington↗

USGS1995

Geochemistry of sediments from coastal marshes of Louisiana

As a part of the U.S. Geological Survey Global Change and Climate History Program we have been studying the biogeochemistry of coastal marshes in Terrebonne Basin, Louisiana. Louisiana has about 40 percent of the coastal wetlands in the conterminous U.S. and it is losing wetlands at one of the highest rates in the U.S. with the conversion of about 65 km2/yr of marsh to open water (Britsch and Dunbar, 1993). The losses have been attributed to human and natural causes including saltwater intrusion through man-made canals, reduced sediment input, and regional subsidence. The net effect of these influences is to change the salinity of interior marshes in a fashion similar to a eustatic sea level rise. We are studying the cycling of carbon, sulfur, and other elements in sediments, waters, and marsh macrophytes in fresh, intermediate/brackish, and saltwater marshes in order to better understand how sea level rise, one aspect of global change, will influence and in turn be influenced by cycling of these elements. By characterizing the critical biogeochemical processes and the recent past environments in these rapidly changing marshes, we can improve predictions of future changes and interpretations of the historic geologic record in similar environments. In this report we describe our coastal marsh study sites in Louisiana, the types of samples collected, the collection methods, the chemical analysis methods, and selected chemical analysis results. Also included are summaries of the project quality control results. The raw chemical analysis results are provided in this report without interpretation. Interpretations will be provided in subsequent reports.

Louisiana↗

USGS1995

The effect of acidic, metal-enriched drainage from the Wightman Fork and Alamosa River on the composition of selected wetlands in San Luis Valley, Colorado

The biogeochemistry of selected wetlands in the San Luis Valley, Colorado, was examined to assess the effect of acidic, metal-enriched water draining mineralized areas near and around the Summitville Mine. The sampling protocols, analytical methods, and chemical composition of water and stream bed sediment from the Wightman Fork and Alamosa River as well as water, surface sediment or cores, and rooted aquatic vegetation from wetland sites within and west of the Alamosa National Wildlife Refuge are presented. The data indicate that As, Co, Cr, Cu, Ni, and Zn are tracers of drainage from mineralized areas around the Summitville Mine. Sediments and aquatic plants in wetlands in the San Luis Valley that receive surface water from the Alamosa River tend to have larger concentrations of certain tracer elements (e.g., Co and Cu) than wetlands that receive water from other sources. Larger concentrations of Cu, Ni, and Zn in the sediments of wetlands receiving Alamosa River water appear to be related to the presence of larger amounts of Fe oxyhydroxides. However, there is little to no variation in the concentrations of tracer elements with depth in wetlands that receive Alamosa River water. This observation suggests that the geochemistry of these wetlands has not been significantly affected by recent mining activities at the Summitville Mine.

Colorado↗

USGS1995

The biogeochemistry of wetlands in the San Luis Valley, Colorado: The effects of acid drainage from natural and mine sources

The Summitville Mine, located near the old mining town of Summitville in Rio Grande County, Colorado, operated between July 1986 and December 1992 as a large-tonnage open-pit heap-leach gold mine. During its 6 years of existence the trace metal levels in drainage water from the mine site were elevated over historical (pre-1986) levels (Moran and Wentz, 1974) due to input from three sources—heap leach water, seeps that occur throughout the mine workings, and an increase in the metal load of water coming from the old Reynolds Adit. Mine-drainage waters flow into Wightman Fork, a small tributary of the Alamosa River, which in turn flows east into the San Luis Valley. The increase in the trace metal burden of the Alamosa River watershed is of concern to farmers, land owners, and Federal and State wildlife agencies. The information presented here is largely abstracted from reports previously published (Balistrieri and others, 1995; Gough and others, 1995).

Colorado↗

USGS1994

The geochemical cycling of trace elements in a biogenic meromictic lake

The geochemical processes affecting the behavior and speciation of As, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb, V, and Zn in Hall Lake, Washington, USA, are assessed by examining dissolved and acid soluble particulate profiles of the elements and utilizing results from thermodynamic calculations. The water column of this meromictic lake is highly stratified and contains distinctive oxic, suboxic, and anoxic layers. Changes in the redox state of the water column with depth affect the distribution of all the elements studied. Most noticeable are increases in dissolved Co, Cr, Fe, Mn, Ni, Pb, and Zn concentrations across the oxic-suboxic boundary, increases in dissolved As, Co, Cr, Fe, Mn, and V concentrations with depth in the anoxic layer, significant decreases in dissolved Cu, Ni, Pb, and Zn concentrations in the anoxic region below the sulfide maximum, and large increases in acid soluble particulate concentrations of As, Cr, Cu, Fe, Mo, Ni, Pb, V, and Zn in the anoxic zone below the sulfide maximum. Thermodynamic calculations for the anoxic region indicate that all redox sensitive elements exist in their reduced forms, the primary dissolved forms of Cu, Ni, Pb, and Zn are metal sulfide solution complexes, and solid sulfide phases of Cu, Fe, Mo, and Pb are supersaturated. Calculations using a vertical diffusion and reaction model indicate that the oxidation rate constant for Mn(II) in Hall Lake is estimated to be 0.006 d-1 and is at the lower end of the range of microbial oxidation rates observed in other natural systems. The main geochemical processes influencing the distribution and speciation of trace elements in Hall Lake appear to be transformations of dissolved elements between their oxidation states (As, Cr, Cu, Fe, Mn, V), cocycling of trace elements with Mn and Fe (As, Co, Cr, Cu, Mo, Ni, Pb, V, Zn), formation of soluble metal sulfide complexes (Co, Cu, Ni, Pb, Zn), sorption (As, Co, Cr, Ni, V), and precipitation (Cu, Fe, Mn, Mo, Pb, Zn).

Geochimica et Cosmochimica Acta↗

USGS1993

Understanding our fragile environment; Lessons from geochemical studies

An understanding of our fragile environment can begin with a recognition of the importance of certain elements, commonly called "minerals substances" (such as iron and zinc), in the lives of humans and animals and in the soils that support plants. This recognition is well deserved because these elements are essential for the life or optimum health of an organism. Some elements such as carbon, hydrogen, oxygen, magnesium, potassium, and phosphorus are required in relatively large amounts by organisms. However, others are required in smaller quantities; these are referred to as trace elements. Diseases have been related to the deficiency of about 20 elements in animals and humans and to the deficiency of approximately 13 elements in plants. At the same time, if these and other elements occur in quantities great enough, toxicity can result. An element, or any substance, that occurs in the environment and contains concentrations above what are considered to be background levels may be considered a contaminant. When contaminants occur at levels that are potentially harmful to organisms, they are labeled as hazards. Often the quantitative difference between essential amounts and toxic concentrations of these elements is very small. For example, the trace element selenium is required at a level of no less than 0.4 ppm in the diet of cattle but can be toxic at levels greater than approximately 4ppm. Elements that are required for survival by animals and plants are termed essential, while those not required are nonessential. Trace essential elements such as fluorine, copper, selenium, molybdenum, and others listed in the table on page 1 can be hazardous to life forms if present at high levels. Nonessential heavy metals such as arsenic, lead, mercury, cadmium, and chromium are usually toxic to organisms at much lower levels than trace essential elements. Depending on the association that these nonessential elements may form with natural geologic materials such as organic matter, other elements or minerals, and adsorbers (such as clays), these elements can range from being safe to being extremely toxic. The elemental composition of plants, animals, and humans correlates with the geologic makeup of the Earth, and life has evolved reflecting these natural occurrences. The science of environmental geochemistry examines the interrelationship of life with the physical and chemical Earth.

Circular↗

USGS1993

Analytical results for As species and related elements in interstitial porewater and sediment from the Maurice River and Union Lake in Vineland, New Jersey

Union Lake, the Maurice River, and the Blackwater Branch , a tributary of the Maurice River, all parts of a small watershed near Vineland, New Jersey, are contaminated by arsenic (As) from a local chemical factory (fig. l)(Faust and others, 1987). An indepth study to be used for the design of the remedial action at the Vineland Chemical Co. Superfund site was initiated by the U.S. Environmental Protection Agency to determine the extent and severity of the contamination. The Vineland Chemical Co. site is located in Cumberland County, New Jersey. Organic As herbicides were manufactured there from approximately 1949 to the late 1980's. As part of the effort, core samples were collected in the Maurice River close to the chemical factory and from Union Lake, a reservoir approximately seven miles from the factory. This report summarizes the analytical results for As speciation and various constituents in the interstitial porewater and associated sediment from these cores. Because the U.S. Geological Survey has the analytical expertise and necessary equipment, the samples were analyzed in USGS laboratories in Denver, Colorado and Seattle, Washington.

New Jersey↗

USGS1992

Hydrological, geomorphological, and chemical effects of Hurricane Andrew on coastal marshes of Louisiana

Hydrological conditions are reported for the hurricane-induced storm surge at marsh sites in Terrebonne and Barataria Basins. There was a 6 hour or greater delay in the arrival of the storm surge at interior marsh sites compared to coastal locations. A water surge of about 1.5 m with a salinity of 10–15‰ was recorded at an intermediate salinity marsh site in Terrebonne Basin where significant geomorphological changes occurred with lateral movement and stacking of marsh vegetation and sediment, erosion, and the conversion of wetlands to open water. A residual salt wedge attributed to the storm surge was detected in sediments at this intermediate marsh site about 55 days after the hurricane. In the pore water, at 30 cm in depth, there were increases in alkalinity, ammonia, phosphate, and manganese, but not iron or sulfide, although there was a significant depletion of sulfur with respect to chloride. The increases in concentration of these species in the pore water suggests that there was an increase in organic matter decomposition. Although increases in sulfide phytotoxicity were not obvious, the residual salinity of pore water may influence wetland loss through longer-term impacts on macrophyte production. Storm-induced sediment deposition, which will help ameliorate wetland loss, was observed at a salt marsh site in Terrebonne Basin.

Louisiana↗

USGS1990

Adsorption of selenium by amorphous iron oxyhydroxide and manganese dioxide

This work compares and models the adsorption of selenium and other anions on a neutral to alkaline surface (amorphous iron oxyhydroxide) and an acidic surface (manganese dioxide). Selenium adsorption on these oxides is examined as a function of pH, particle concentration, oxidation state, and competing anion concentration in order to assess how these factors might influence the mobility of selenium in the environment. The data indicate that 1. 1) amorphous iron oxyhydroxide has a greater affinity for selenium than manganese dioxide, 2. 2) selenite [Se(IV)] adsorption increases with decreasing pH and increasing particle concentration and is stronger than selenate [Se(VI)] adsorption on both oxides, and 3. 3) selenate does not adsorb on manganese dioxide. The relative affinity of selenate and selenite for the oxides and the lack of adsorption of selenate on a strongly acidic surface suggests that selenate forms outer-sphere complexes while selenite forms inner-sphere complexes with the surfaces. The data also indicate that the competition sequence of other anions with respect to selenite adsorption at pH 7.0 is phosphate > silicate > molybdate > fluoride > sulfate on amorphous iron oxyhydroxide and molybdate ??? phosphate > silicate > fluoride > sulfate on manganese dioxide. The adsorption of phosphate, molybdate, and silicate on these oxides as a function of pH indicates that the competition sequences reflect the relative affinities of these anions for the surfaces. The Triple Layer surface complexation model is used to provide a quantitative description of these observations and to assess the importance of surface site heterogeneity on anion adsorption. The modeling results suggest that selenite forms binuclear, innersphere complexes with amorphous iron oxyhydroxide and monodentate, inner-sphere complexes with manganese dioxide and that selenate forms outer-sphere, monodentate complexes with amorphous iron oxyhydroxide. The heterogeneity of the oxide surface sites is reflected in decreasing equilibrium constants for selenite with increasing adsorption density and both experimental observations and modeling results suggest that manganese dioxide has fewer sites of higher energy for selenite adsorption than amorphous iron oxyhydroxide. Modeling and interpreting the adsorption of phosphate, molybdate, and silicate on the oxides are made difficult by the lack of constraint in choosing surface species and the fact that equally good fits can be obtained with different surface species. Finally, predictions of anion competition using the model results from single adsorbate systems are not very successful because the model does not account for surface site heterogeneity. Selenite adsorption data from a multi-adsorbate system could be fit if the equilibrium constant for selenite is decreased with increasing anion adsorption density.

Geochimica et Cosmochimica Acta↗

USGS1987

Selenium adsorption by goethite

The adsorption of Se by goethite was studied as a function of time (10 min–24 h), temperature (295.5 and 303.5 K), pH (4–11), particle concentration (3–300 mg/L), total Se concentration (0.02–5 × 10 −5 M ), oxidation state [Se(IV) and Se(VI)], and competing anion concentration [(anion)/(Se(IV) = 0.25 to 50 000] in order to assess the influence of these factors on Se mobility. The data indicate that (i) the surface sites of goethite are heterogeneous, (ii) the adsorption of selenite [Se(IV)] reaches equilibrium in 2 h and is completely reversible with respect to pH, (iii) the removal of selenite from solution increases with decreasing pH and increasing particle concentration, (iv) the adsorption edge for selenite shifts to lower pH values with increasing total selenite concentrations, (v) selenite adsorbs much more strongly than selenate [Se(VI)], and (vi) the influence of additional anions on selenite adsorption depends on the relative affinity of the anions for the surface and the relative concentrations of the anions. For a given anion concentration ratio, the competition sequence with selenite is phosphate > silicate ≥ citrate > molybdate > bicarbonate/carbonate > oxalate > fluoride > sulfate. Therefore, the conditions that favor the mobility of Se in the environment with respect to adsorption are alkaline pH, high Se concentrations, oxidizing conditions, and high concentrations of additional anions that strongly adsorb.

Soil Science Society of America Journal↗