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L.A. Senior

Publications and source records attributed to L.A. Senior.

4 recordsLinked to original sources

Hydrogeologic structure of the Newark Basin, Pennsylvania, from borehole geophysical logs

The Brunswick and the underlying Lockatong Formations are comprised of littrifled Mesozoic sediments that constitute part of the Newark Basin in southeastern Pennsylvania (USA). These fractured rocks form an important regional aquifer that consists of gmdational sequences of shale, siltstone, and sandstone, with fluid transport occurring primarily in fractures. An extensive suite of geophysical logs was obtained in seven wells located at the borough of Iamsdale, PA in order to characterize the areal hydrogeologic system. Analyses of these data indicate that the aquifer can be separated into two distinct structural domains which may, in turn, reflect different mechanical responses to basin bxtension: (1) In the shallow zone above 125 m, the dominant fmcucre population consists of gertfly dipping bedding-plane partings that strike N46°E and dip to the NW at about 11°. Fluid flow is concentrated within the upper 80 m and transmissivities rapidly diminish in magnitude with depth. (2) The zone below 125 m marks the appearance of numerous steeply dipping fractures that are orthogonal to the bedding plane features, striking subparallel at N227°E but dipping sharply to the SE at 77°. This secondary set of fractures is associated with a reasonably thick (= 60 m) high-resistivity, low- transmissivity sandstoned siltstone unit that is abruptly terminated by a thin shale bed at a depth of 190 m. This lower contact effectively delineates the aquifer's vertical extent and the observed lack of hydraulic productivity with increasing depth may be associated with the gradational transition into the Lockatong Formation.

Pennsylvania

Radium and radon in ground water in the Chickies Quartzite, southeastern Pennsylvania

The Chickies Quartzite, a Lower Cambrian-age formation compromised of quartzite and slate overlying a basal conglomerate, forms a narrow ridges and crops out discontinuously over 112 square miles in the Piedmont physiographic province of southeastern Pennsylvania. The formation is a low-yielding, fractured- rock, water-table aquifer recharged primarily by local precipitation. It is the sole source of water supply for thousands of domestic users. Ground water in the Chickies Quartzite generally is soft and acidic. During 1986-88, the U.S. Geological Survey sampled water from 160 wells that penetrate the Chickies Quartzite to determine the magnitude and distribution of radium-226 (Ra-226), radium-228 (Ra-228), and radon-222 (Rn-222) activities in ground water in the formation and to characterize the geochemical environmental associated with elevated activities of radium (Ra). In addition, 28 wells penetrating adjacent geologic units and 1 well in the Hardyston Quartzite were sampled to determine relative background Ra and RN-222 activities in ground water. Analyses included determination of activities of dissolved Ra-226, Ra-228, and RN-222, and concentrations of dissolved uranium (U), dissolved organic carbon (DOC), and major and minor dissolved inorganic ions. Rock samples were analyzed for U and thorium (Th) and geophysical logs were run to determine sources of Ra and RN-222 in the Chickies Quartzite. Activities of up to 41 pCi/L (picocuries per liter) for Ra-226, 160 pCi/L for Ra-228, and 32,300 pCi/L for RN-222 were measured in ground water in the Chickies Quartzite. Forty-seven percent of the samples contained Ra-226 and Ra-228 activities greater than 5 pCi/L. Median activities measured were 1.2 pCi/L for Ra-226, 2.6 pCi/L for Ra-228, 4.2 pCi/L for combined Ra-226 and Ra-228, and 2,400 pCi/L for RN-222 Ra-228 activity exceeded Ra-226 activity in about 92 percent of 100 water samples; the median Ra-228/Ra226 activity ratio was 2.4. Ra-228/Ra-226 activity ratios commonly were greater in ground water than calculated Th/U ratios in rock samples, suggesting perferential leaching of Ra-228 from aquifer solids. Of ground water in the adjacent geologic units, the highest activities (up to 2.9 pCi/L for Ra-226, 12 pCi/L for Ra-228, and 25,300 pCi/L for RN-222) were measured in ground water in the Harpers Phyllite and Antietam Quartzite. Nonparametric (Spearman rho test) statistical correlations show that the activity of dissolved Ra is inversely related to pH and directly related to concentrations of total dissolved solids, DOC, barium, and sulfate. Low pH decreases absorption of Ra onto the aquifer matrix. The other factors may favor Ra mobility by enhancing complexation or increasing solubility. RN-222 activity does not correlate with and is not supported by the activity of its parent, Ra-226, in solution. Ra-226 activity correlates positively, but weakly, with U concentrations. Ra-226 does not appear to be supported by its parent, U-238, in solution. Observed distributions of Ra-228, Ra-226, and RN-222 activities in ground water in different lithologies of the Chickies Quartzite reflect different geochemical controls on absorption and distribution of parent thorium-232 (Th-232) and uranium-238 (U-238) in the formation. Radium activities were greatest in acidic ground water in the conglomerate and quartzite (median pH of 5.0 and 5.2, respectively) and least in the more neutral water in the slate (median pH of 6.4). For ground water in the conglomerate, quartzite, and slate, respectively, median activities measured were 1.3, 1.5, and .02 pCi/L for Ra-226; and 3.7, 2.5, and 1.0 pCi/L for Ra-228. Natural-gamma-ray geophysical logs and results of rock analyses indicate that the conglomerate may contain more Th and U than the quartzite and that the conglomerate may be more enriched in Th with respect to U than the quartzite; Th and U distribution in both lithogies is variable. Median RN-222 activities in gro

Water-Resources Investigations Report

Geohydrology of, and nitrogen and chloride in, the glacial aquifer, Milford-Matamoras area, Pike County, Pennsylvania

The glacial aquifer that underlies the Routes 209 and 6 corridor between Milford and Matamoras, Pa., is one of the most productive in Pike County. The aquifer is comprised of unconsolidated glacial outwash and kame-terrace deposits that lie within a glacially carved valley now occupied by the Delaware River. Most businesses and residences along this narrow, 7-mile-long corridor rely on individual wells for water supply and septic systems for waste-water disposal. A study of nutrients and chloride in ground water in the glacial aquifer was conducted to determine the effect of these constituents contributed from septic systems and road runoff on ground-water quality. Sources of nutrients and chloride in the recharge zone upgradient of the aquifer include road and parking-lot runoff, septic systems, and precipitation. Nitrate and chloride from these sources can infiltrate and move in the direction of ground-water flow in the saturated zone of the aquifer. A water-table map based on 29 water levels measured in August 1991 indicates that the direction of ground-water flow is from the edges of the valley toward t he Delaware River but is nearly parallel to the Delaware River in the central area of the valley. The average concentrations of nitrogen and chloride in recharge and total annual loads of nitrogen and chloride to ground water were estimated for six areas with different population densities. These estimates assumed a recharge rate to the glacial aquifer of 20 inches per year and a 15 percent loss of chloride and nitrogen in the atmospheric precipitation to surface runoff. The estimated average concentration of nitrogen in recharge ranged from 2.5 to 10 mg/L (milligrams per liter), which corresponds to a total annual load of nitrogen as ammonium released from septic tanks and present in precipitation was oxidized to nitrate as the dominant nitrogen species in ground water. Contributions of nitrogen from septic tanks were greater than contributions from runoff. Observed concentrations of nitrate, which was the most abundant nitrogen species in ground water in t he glacial aquifer, ranged from less than 0.05 to 5.1 mg/L as nitrogen, with a median of 1.1 mg/L as nitrogen. Concentrations of nitrogen measured in ground water were lower than estimated concentrations for recharge suggesting that dissolved nitrogen species may not be conservative in ground water. Nitrate is unstable in anoxic ground water and can be removed by denitrification. Ammonium can be sorbed onto the aquifer materials. Evidence for reducing conditions included a positive correlation between low concentrations of dissolved oxygen and low concentrations of nitrate. The estimated concentration of chloride in recharge ranged from 6.7 to 21 mg/L, and total annual load of chloride to ground water ranged from 19.4 to 50.6 x 10(3) lb/mi2. Chloride is considered to be a chemically conservative ion in ground water. Contributions of chloride to ground water from road salting were greater than contributions from septic tanks. Observed concentrations of chloride in 18 ground-water samples from the glacial aquifer ranged from 2.1 to 32 mg/L, with a median of 17.5 mg/L. Local contamination is indicated by the elevated concentrations of chloride (up to 680 mg/L) detected in four wells located downgradient of an abandoned industry that may have released salts in processing waste. Chloride concentrations in ground water appeared to be greater near major roads and in areas of relatively greater septic-system density than in areas upgradient of roads, farther downgradient from roads, or with less densely spaced septic systems.

Water-Resources Investigations Report

Hydrogeology and ground-water flow in the carbonate rocks of the Little Lehigh Creek basin, Lehigh County, Pennsylvania

The Little Lehigh Creek basin is underlain mainly by a complex assemblage of highly-deformed Cambrian and Ordovician carbonate rocks. The Leithsville Formation, Allentown Dolomite, Beekmantown Group, and Jacksonburg Limestone act as a single hydrologic unit. Ground water moves through fractures and other secondary openings and generally is under water-table conditions. Median annual ground-water discharge (base flow) to Little Lehigh Creek near Allentown (station 01451500) during 1946-86 was 12.97 inches or 82 percent of streamflow. Average annual recharge for 1975-83 was 21.75 inches. Groundwater and surface-water divides do not coincide in the basin. Ground-water underflow from the Little Lehigh Creek basin to the Cedar Creek basin in 1987 was 4 inches per year. A double-mass curve analysis of the relation of cumulative precipitation at Allentown to the flow of Schantz Spring for 1956-84 showed that cessation of quarry pumping and development of ground water for public supply in the Schantz Spring basin did not affect the flow of Schantz Spring. Ground-water flow in the Little Lehigh Creek basin was simulated using a finite-difference, two-dimensional computer model. The geologic units in the modeled area were simulated as a single water-table aquifer. The 134-squaremile area of carbonate rocks between the Lehigh River and Sacony Creek was modeled to include the natural hydrologic boundaries of the ground-water-flow system. The ground-water-flow model was calibrated under steady-state conditions using 1975-83 average recharge, evapotranspiration, and pumping rates. Each geologic unit was assigned a different hydraulic conductivity. Initial aquifer hydraulic conductivity was estimated from specific-capacity data. The average (1975-83) water budget for the Little Lehigh Creek basin was simulated. The simulated base flow from the carbonate rocks of the Little Lehigh Creek basin above gaging station 01451500 is 11.85 inches per year. The simulated ground-water underflow from the Little Lehigh Creek basin to the Cedar Creek basin is 4.04 inches per year. For steady-state calibration, the root-mean-squared difference between observed and simulated heads was 21.19 feet. The effects of increased ground-water development on base flow and underflow out of the Little Lehigh Creek basin for average and drought conditions were simulated by locating a hypothetical well field in different parts of the basin. Steady-state simulations were used to represent equilibrium conditions, which would be the maximum expected long-term effect. Increased ground-water development was simulated as hypothetical well fields pumping at the rate of 15, 25, and 45 million gallons per day in addition to existing ground-water withdrawals. Four hypothetical well fields were located near and away from Little Lehigh Creek in upstream and downstream areas. The effects of pumping a well field in different parts of the Little Lehigh Creek basin were compared. Pumping a well field located near the headwaters of Little Lehigh Creek and away from the stream would have greatest effect on inducing underflow from the Sacony Greek basin and the least effect on reducing base flow and underflow to the Ceda^r Creek basin. Pumping a well field located near the headwaters of Little Leh|igh Creek near the stream would have less impact on inducing underflow from|the Sacony Creek basin and a greater impact on reducing the base flow of Little Lehigh Creek because more of the pumpage would come from diverted base flow. Pumping a well field located in the downstream area of the Little Lehigh Creek basin away from the stream would have the greatest effect on the underflow to the Cedar Creek basin. Pumping a well field located in the downstream area of the Little Lehigh Creek basin near the stream would have the greatest effect on reducing the base flow of Little Lehigh Cteek. Model simulations show that groundwater withdrawals do not cause a proportional reduction in base flow. Under average conditions, ground-water withdrawals are equal to 48 to 70 percent of simulated base-flow reductions; under drought conditions, ground-water withdrawals are equal to 35 to 73 percent of simulated base-flow reductions. The hydraulic effects of pumping largely depend on well location. In the Little Lehigh basin, surface-water and ground-water divides do not coincide, and ground-water development, especially near surface-water divides, can cause ground-water divides to shift and induce ground-water underflow from adjacent basins. Large-scale ground-water pumping in a basin may not produce expected reductions of base flow in that basin because of shifts in the ground-water divide; however, such shifts can reduce base flow in adjacent surface-water basins.

Water-Resources Investigations Report