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L. Slater

Publications and source records attributed to L. Slater.

9 recordsLinked to original sources
USGS2025

Groundwater flowpath characteristics drive variability in per- and polyfluoroalkyl substances (PFAS) loading across a stream-wetland system

Groundwater-dependent ecosystems in areas with industrial land use are at risk of exposure to a PFAS chemicals. We investigated one such system with several known PFAS source areas, where high and low permeability sediments (glacial) coupled with groundwater-lake and groundwater/surface-water interactions created complex ‘source to seep’ dynamics. Using heat-tracing and chemical methods, numerous preferential groundwater discharge zones were identified and sampled across the upper Quashnet River stream-wetland system in Mashpee, MA, USA, downgradient of Joint Base Cape Cod (JBCC). Surface-water and groundwater samples were analyzed for 40 PFAS compounds between March and October 2022. Samples were collected from groundwater seeps identified as preferential discharge points (PDPs), wells upgradient of the stream-wetland system, contributing flow-through kettle lakes, and along Quashnet River surface-waters. PFAS from sampled waters contained perfluorinated carboxylates (PFPea, PFHxA, PFNA), perfluorinated sulfonates (PFBS, PFPeS, PFHxS, PFOS), fluorotelomer sulfonates (6:2, 8:2 FtS), and perfluoroalkyl sulfonamides (PFOSA). Samples from PDPs and wells had measured PFAS concentrations ranging from non-detect to 4677 ng/L ng/L (mean = 418 ng/L, std. = 709 ng/L), and a range of deuterium excess values (3.2 to 15.9 per mil) indicative of varying degrees of groundwater-lake interaction prior to groundwater flowpath emergence at PDPs. Correlations ( p < 0.01) between deuterium excess, %PFAS precursors, and terminal PFAS compounds highlighted potential precursor transformations associated with lake-groundwater exchange along flowpaths sourcing PDPs. However, some seepages had higher total PFAS concentrations (>1000 ng/L) than upgradient kettle lakes despite showing lake (evaporative) isotopic signatures, indicating the potential for groundwater flowpath convergence at wetland discharge zones and the influence of lakebed PFAS precursor reactions. Results from these synoptic surveys address gaps in the existing PFAS literature by demonstrating the importance of subsurface fate and transport on PFAS compound concentrations and mass loading in preferential groundwater discharge zones.

Massachusetts↗
USGS2022

Near-surface geophysics perspectives on Integrated, Coordinated, Open, Networked (ICON) Science

Pointing to the Integrated, Coordinated, Open, Networked Findability, Accessibility, Interoperability, and Reusability (ICON-FAIR) principles, we have determined several opportunities for implementation within the realm of near-surface geophysics (NSG), representing a broad range of data acquisition and processing technologies. Our work explores the multifaceted community-driven nature of NSG and, by applying ICON-FAIR principles, we identify three key strategic objectives: (i) the development of an approach to integrating NSG into other geoscience data collection projects, (ii) the creation of coordinated and open standardized NSG data, and (iii) the networking of post-secondary institutions to foster an equipment sharing consortium. The precedence within the geoscientific community demonstrates that there are significant opportunities for advancing interdisciplinary applications of NSG through the implementation of structural change within the ICON-FAIR framework.

Earth and Space Science↗
USGS2021

Evaluation of riverbed magnetic susceptibility for mapping biogeochemical hot spots in groundwater-impacted rivers

Redox hot spots occurring as metal-rich anoxic groundwater discharges through oxic wetland and river sediments commonly result in the formation of iron (Fe) oxide precipitates. These redox-sensitive precipitates influence the release of nutrients and metals to surface water and can act as ‘contaminant sponges’ by absorbing toxic compounds. We explore the feasibility of a non-invasive, high-resolution magnetic susceptibility (MS) technique to efficiently map the spatial variations of magnetic Fe oxide precipitates in the shallow bed of three rivers impacted by anoxic groundwater discharge. Laboratory analyses on Mashpee River (MA, USA) sediments demonstrate the sensitivity of MS to sediment Fe concentrations. Field surveys in the Mashpee and Quashnet rivers (MA, USA) reveal several discrete high MS zones, which are associated with likely anoxic groundwater discharge as evaluated by riverbed temperature, vertical head gradient, and groundwater chemistry measurements. In the East River (CO, USA), widespread cobbles/rocks exhibit high background MS from geological ferrimagnetic minerals, thereby obscuring the relatively small enhancement of MS from groundwater induced Fe oxide precipitates. Our study suggests that, in settings with low geological sources of magnetic minerals such as lowland rivers and wetlands, MS may serve as a complementary tool to temperature methods for efficiently mapping Fe oxide accumulation zones due to anoxic groundwater discharges that may function as biogeochemical hot spots and water quality control points in gaining systems.

Colorado, Massachusetts↗
USGS2021

Characterizing physical properties of streambed interface sediments using in situ complex electrical conductivity measurements

Streambed sediment physical properties such as surface area, are difficult to quantify in situ but exert a high‐level control on a wide range of biogeochemical processes and sorption of contaminants. We introduce the use of complex electrical conductivity (CC) methods (also known as spectral induced polarization (SIP)) that measure both real and imaginary conductivity to non‐invasively and efficiently characterize shallow streambed sediments. We explore the method through synthetic modeling, laboratory, and field measurements to demonstrate the sensitivity of imaginary conductivity to sediment surface area, controlled in part by fine‐grained iron oxides produced by anoxic groundwater discharge. Laboratory measurements verify expected relationships between CC parameters and sediment properties. Synthetic modeling using a 1D analytical model illustrates the influence of water layer depth and conductivity on the field CC measurements made at the streambed‐stream water interface. Specifically, the inverted sediment imaginary conductivity is less impacted by uncertainty in the water layer depth and conductivity relative to the real conductivity and phase shift. Field CC measurements along a landfill‐impacted river reveal discrete streambed zones with enhanced bulk surface area generally corresponding to anoxic groundwater discharges zones with high concentrations of fine‐grained iron oxide precipitates.

Water Resources Research↗
USGS2011

Expansion rate and geometry of floating vegetation mats on the margins of thermokarst lakes, northern Seward Peninsula, Alaska, USA

Investigations on the northern Seward Peninsula in Alaska identified zones of recent (<50 years) permafrost collapse that led to the formation of floating vegetation mats along thermokarst lake margins. The occurrence of floating vegetation mat features indicates rapid degradation of near‐surface permafrost and lake expansion. This paper reports on the recent expansion of these collapse features and their geometry is determined using geophysical and remote sensing measurements. The vegetation mats were observed to have an average thickness of 0.57 m and petrophysical modeling indicated that gas content of 1.5–5% enabled floatation above the lake surface. Furthermore, geophysical investigation provides evidence that the mats form by thaw and subsidence of the underlying permafrost rather than terrestrialization. The temperature of the water below a vegetation mat was observed to remain above freezing late in the winter. Analysis of satellite and aerial imagery indicates that these features have expanded at maximum rates of 1–2 m yr ‐1 over a 56 year period. Including the spatial coverage of floating ‘thermokarst mats’ increases estimates of lake area by as much as 4% in some lakes.

Alaska↗
USGS2008

Advancing process‐based watershed hydrological research using near‐surface geophysics: A vision for, and review of, electrical and magnetic geophysical methods

We want to develop a dialogue between geophysicists and hydrologists interested in synergistically advancing process based watershed research. We identify recent advances in geophysical instrumentation, and provide a vision for the use of electrical and magnetic geophysical instrumentation in watershed scale hydrology. The focus of the paper is to identify instrumentation that could significantly advance this vision for geophysics and hydrology during the next 3–5 years. We acknowledge that this is one of a number of possible ways forward and seek only to offer a relatively narrow and achievable vision. The vision focuses on the measurement of geological structure and identification of flow paths using electrical and magnetic methods. The paper identifies instruments, provides examples of their use, and describes how synergy between measurement and modelling could be achieved. Of specific interest are the airborne systems that can cover large areas and are appropriate for watershed studies. Although airborne geophysics has been around for some time, only in the last few years have systems designed exclusively for hydrological applications begun to emerge. These systems, such as airborne electromagnetic (EM) and transient electromagnetic (TEM), could revolutionize hydrogeological interpretations. Our vision centers on developing nested and cross scale electrical and magnetic measurements that can be used to construct a three‐dimensional (3D) electrical or magnetic model of the subsurface in watersheds. The methodological framework assumes a ‘top down’ approach using airborne methods to identify the large scale, dominant architecture of the subsurface. We recognize that the integration of geophysical measurement methods, and data, into watershed process characterization and modelling can only be achieved through dialogue. Especially, through the development of partnerships between geophysicists and hydrologists, partnerships that explore how the application of geophysics can answer critical hydrological science questions, and conversely provide an understanding of the limitations of geophysical measurements and interpretation.

Hydrological Processes↗
USGS2008

Forage fish of the Pacific Rim as revealed by diet of a piscivorous seabird: Synchrony and relationships with sea surface temperature

We tested the hypothesis of synchronous interannual changes in forage fish dynamics around the North Pacific Rim. To do this, we sampled forage fish communities using a seabird predator, the rhinoceros auklet ( Cerorhinca monocerata ), at six coastal study sites from Japan to California. We investigated whether take of forage fishes was related to local marine conditions as indexed by sea surface temperature (SST). SST was concordant across sites in the eastern Pacific, but inversely correlated between east and west. Forage fish communities consisted of anchovy ( Engraulis spp.), sandlance ( Ammodytes spp.), capelin ( Mallotus spp.), and juvenile rockfish ( Sebastes spp.), among others, and take of forage fish varied in response to interannual and possibly lower-frequency oceanographic variability. Take of primary forage species were significantly related to changes in SST only at the eastern sites. We found synchrony in interannual variation of primary forage fishes across several regions in the eastern Pacific, but no significant east–west correlations. Specifically in the Japan Sea, factors other than local SST or interannual variability may more strongly influence forage fishes. Predator diet sampling offers a fishery-independent, large-scale perspective on forage fish dynamics that may be difficult to obtain using conventional means of study.

Canadian Journal of Fisheries and Aquatic Sciences↗
USGS1990

Decrease in deformation rate as a possible precursor to the next Parkfield earthquake

Crustal deformations along fault zones are monitored because they show the accumulation and possible premonitory release of strain energy before major earthquakes. On the Parkfield segment of the San Andreas fault the next mainshock (local magnitude M L =5.7) is expected to occur between 1983 and 1993, based on the relatively regular recurrence of characteristic earthquakes in 1857, 1881, 1901, 1922, 1934 and 1966 1 . A concerted monitoring effort is therefore underway at Parkfield, with the aim of detecting precursory changes in observable quantities that can be measured reliably 2 . Here we report data from two geodetic lines crossing the San Andreas fault near Parkfield which show that the rate of shortening decreased by ˜20% starting in August 1986. This change coincided with a rate decrease of 45% for earthquakes of M L ⩾ 2.1 in the area 3,4 . Both phenomena may have been caused by temporary locking of the fault surface, or a decrease in strain accumulation rate, and they are interpreted as intermediate-term precursors to the next Parkfield earthquake.

California↗